3 Scotch-Weld TM. Urethane Adhesives 3532 B/A 3535 B/A 3549 B/A. Technical Data January, 2010



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3 Scotch-Weld TM Technical Data January, 2010 Product Description 3M Scotch-Weld 3532 B/A, 3535 B/A and 3549 B/A are two-component, polyurethane adhesives which cure at room temperature or with heat to form tough, impact-resistant structural bonds. Their adhesion properties are identical and they vary only in work life, cure time and color. They provide excellent adhesion to many primed or painted metal and plastic substrates and are designed to develop sag resistance approximately 30 seconds after mixing. 3M Scotch-Weld Structural Adhesive Primer EC-3901 is suggested for use on metal surfaces to achieve maximum resistance to water, humidity and salt spray. (See Primer Information in Directions for Use section on page 2.) Typical Physical Properties Note: The following technical information and data should be considered representative or typical only and should not be used for specification purposes. 3M Scotch-Weld Urethane Adhesive 3532 B/A Base Accelerator Color (Cured: Brown) Off-White Brown Base Polyol Isocyanate Net Weight (lbs./gal.) 10.3 11.2 Viscosity Brookfield RVF #6 sp. Brookfield RVF #5 sp. cps @ 75 F (24 C) @ 20 rpm: 10,000-55,000 cps @ 10 rpm: 15,000-40,000 cps Mix Ratio: By Weight 100 109 By Volume 100 100 Work Life: 100 grams mixed at 75 F (24 C): 5-15 min. Time to Reach Full Cure @ 75 F (24 C) 24 hours 3M Scotch-Weld Urethane Adhesive 3535 B/A Base Accelerator Color (Cured: Off-White) White Brown Base Polyol Isocyanate Net Weight (lbs./gal.) 10.9 11.3 Viscosity Brookfield RVF #6 sp. Brookfield RVF #5 sp. cps @ 75 F (24 C) @ 10 rpm: 5,000-40,000 cps @ 10 rpm: 15,000-40,000 cps Mix Ratio: By Weight 100 105 By Volume 100 100 Work Life: 100 grams mixed at 75 F (24 C): 45 sec.-240 sec. Time to Reach Full Cure @ 75 F (24 C) 8 hours

Typical Physical Properties (continued) Note: The following technical information and data should be considered representative or typical only and should not be used for specification purposes. 3M Scotch-Weld Urethane Adhesive 3549 B/A Base Accelerator Color (Cured: Brown) Off-White Brown Base Polyol Isocyanate Net Weight (lbs./gal.) 10.3 11.2 Viscosity Brookfield RVF #6 sp. Brookfield RVF #5 sp. cps @ 75 F (24 C) @ 10 rpm: 10,000-40,000 cps @ 10 rpm: 15,000-40,000 cps Mix Ratio: By Weight 100 109 By Volume 100 100 Work Life: 100 grams mixed at 75 F (24 C): 45-70 min. Time to Reach Full Cure @ 75 F (24 C) 7 days. Application and Equipment Suggestions These products may be applied with spatula, trowel, or flow equipment. Appropriate two-part metering and mixing equipment is also commercially available. Directions for Use 1. Surfaces to be bonded must be dry and free from rust, oil, grease and wax. Surfaces can be cleaned with an abrasive such as 3M TM Coated Abrasives (240 grit) followed by wiping with a solvent such as Scotch-Grip TM Solvent No. 3.* 2. Primer Information: 3M Scotch-Weld Structural Adhesive Primer EC-3901 may be applied by spray or brush. Air dry cycles for periods as short as 1/2 hour have been used successfully with the force dry cycle. Humidity contributes greatly to satisfactory use of this primer. Relative humidity of 25% or lower may cause difficulties and should be thoroughly evaluated in the customers application. The primed surface, after cooling to ambient temperatures, is ready for adhesive bonding. The primed surface should be protected from contamination introduced by dust, fingerprints, oil, etc. See Data Sheet for Scotch-Weld Structural Adhesive Primer EC-3901 for directions for use. *Note: When using solvents, extinguish all ignition sources and follow the manufacturer s precautions and directions for use when handling such materials. - 2 -

Typical Performance Characteristics Overlap Shear Strength-Metals: The following are typical data after a full cure showing the adhesion of 3M Scotch-Weld 3532 B/A, 3535 B/A and 3549 B/A to various metal substrates. All aluminum data were developed on.063-inch thick 2024 T-3 clad aluminum and all steel data on.035-inch cold rolled steel. Test specimens were 1/2-inch overlap, 1-inch wide with.005-inch thick bondlines pulled at a testing rate of.1-inch/min. All values are psi. Substrate Test Temperature -40 F (-40 C) 75 F (24 C) 180 F (82 C) Etched Aluminum 2500 2000 300 Abraded and Solvent Wiped Aluminum 2000 2000 300 Solvent Wiped Aluminum 1000 1000 100 Abraded and Solvent Wiped Steel 2000 1200 100 Solvent Wiped Steel 1000 700 20 Overlap Shear Strength-Plastics: The following are typical data after a full cure showing the adhesion of Scotch-Weld 3532 B/A, 3535 B/A and 3549 B/A to various plastic substrates. All data were developed on 1/8-inch thick, 1/2-inch overlap, 1-inch wide specimens with.005-inch thick bondlines that had been abraded and alcohol wiped prior to bonding. Values are in psi. Substrate Test Temperature -40 F (-40 C) 75 F (24 C) 180 F (82 C) Nylon 240 580 40 Lexan 1240 3 1840 3 125 Plexiglass 620 1300 70 FRP 1660 3 1150 3 180 Rigid PVC 370 960 110 ABS 440 3 810 300 Polystyrene 330 530 110 3 Denotes substrate failure. Tensile and Elongation: Scotch-Weld 3532 B/A, 3535 B/A and 3549 B/A have been tested according to ASTM-D-738 at 2 inches/min. Cure: 1 hour at 250 F (121 C), 30 min. at 285 F (141 C). Temperature Tensile Elongation Room Temperature 3000 psi 96% Rate of Strength Buildup: The following are typical test data showing the rate of strength buildup at various temperatures and times. - 3 -

Typical Performance Characteristics (continued) 3M Scotch-Weld Urethane Adhesive 3532 B/A at room temperature Specimens: 1/2-inch overlap fiber reinforced plastic to primed steel, 0.032-inch bondline. Specimens were pulled at 2 inches/min. Time (Hours) Scotch-Weld Urethane Adhesive 3532 B/A at various temperatures Specimens: 1/2-inch overlap shear, fiber reinforced plastic to primed steel.032-inch bondline. Specimens were placed in an oven at designated temperature for the specified time. Bonds were then cooled for 1 minute and pulled at a rate of 2-inch/min. Temperature Time (Minutes) 100 F (38 C) 10 0 30 240 45 500 60 650 120 F (49 C) 10 140 20 480 30 750 150 F (66 C) 5 120 10 400 15 760 180 F (82 C) 5 400 10 660 15 900 200 F (93 C) 2 340 5 660 10 900 225 F (107 C) 2 440 5 760 10 900 3M Scotch-Weld Urethane Adhesive 3535 B/A at 73 F (23 C) Specimens: 1/2-inch overlap prepared from 1 x 4-inch x 2024 T-3 clad FPL etched aluminum,.005-inch bondline. Specimens were pulled at 2 inches/min. Time (Minutes) - 4-0.5 5 1 20 2 90 3 400 4 490 5 560 6 680 7 790 16 1200 24 1550 5 0 15 16 30 227 45 689 60 858 75 1202 90 1507 105 1640 120 1460 180 1877

Typical Performance Characteristics (continued) 3M Scotch-Weld Urethane Adhesive 3535 B/A at 150 F (66 C) Specimens: 1/2-inch overlap prepared from 1 x 4-inch x 2024 T-3 clad FPL etched aluminum,.005-inch bondline. Specimens were placed in 150 F (66 C) oven and cured for specified time. Time to reach 150 F (66 C) was 4 min. Specimens were then removed and tested at 2-in./min. During testing the specimens were a approximately 125 F (49 C). Time (Minutes) 5 844 10 1055 15 1175 20 1165 30 1305 45 1490 60 1455 3M Scotch-Weld Urethane Adhesive 3549 B/A at room temperature Specimens: 1/2-inch overlap fiber reinforced plastic to primed steel, 0.32-inch bondline. Specimens were pulled at 2 inches/min. Time (Hours) 4 2 6 11 8 80 16 460 24 700 48 1170 Scotch-Weld Urethane Adhesive 3549 B/A at various temperatures Specimens: 1/2-inch overlap fiber reinforced plastic to primed steel,.032-inch bondline. Specimens were placed in an oven at designated temperature for the specified time. Bonds were then cooled for 1 min. and pulled at a rate of 2 inches/min. Temperature Time (Minutes) 150 F (66 C) 20 53 30 227 40 259 50 508 180 F (82 C) 20 293 30 391 40 576 50 684 200 F (93 C) 10 177 20 409 30 614 40 683 225 F (107 C) 10 392 20 730-5 -

Storage Store product at 60-80 F (16-27 C) for maximum storage life. Higher temperatures reduce normal storage life. Lower temperatures cause increased viscosity of a temporary nature. Rotate stock on a first in-first out basis. Shelf Life These products have a shelf life of one year from date of shipment when properly stored in their unopened containers. Precautionary Information Refer to Product Label and Material Safety Data Sheet for health and safety information before using this product. For additional health and safety information, call 1-800-364-3577 or (651) 737-6501. Technical Information The technical information, recommendations and other statements contained in this document are based upon tests or experience that 3M believes are reliable, but the accuracy or completeness of such information is not guaranteed. Product Use Many factors beyond 3M s control and uniquely within user s knowledge and control can affect the use and performance of a 3M product in a particular application. Given the variety of factors that can affect the use and performance of a 3M product, user is solely responsible for evaluating the 3M product and determining whether it is fit for a particular purpose and suitable for user s method of application. Warranty, Limited Remedy, and Disclaimer Unless an additional warranty is specifically stated on the applicable 3M product packaging or product literature, 3M warrants that each 3M product meets the applicable 3M product specification at the time 3M ships the product. 3M MAKES NO OTHER WARRANTIES OR CONDITIONS, EXPRESS OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OR CONDITION OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR ANY IMPLIED WARRANTY OR CONDITION ARISING OUT OF A COURSE OF DEALING, CUSTOM OR USAGE OF TRADE. If the 3M product does not conform to this warranty, then the sole and exclusive remedy is, at 3M s option, replacement of the 3M product or refund of the purchase price. Limitation of Liability Except where prohibited by law, 3M will not be liable for any loss or damage arising from the 3M product, whether direct, indirect, special, incidental or consequential, regardless of the legal theory asserted, including warranty, contract, negligence or strict liability. ISO 9001:2000 This Industrial Adhesives and Tapes Division product was manufactured under a 3M quality system registered to ISO 9001:2000 standards. 3 Industrial Adhesives and Tapes Division 3M Center, Building 225-3S-06 St. Paul, MN 55144-1000 800-362-3550 877-369-2923 (Fax) www.3m.com/industrial Recycled Paper 40% pre-consumer 10% post-consumer - 6-3M, Scotch-Weld and Scotch-Grip are trademarks of 3M Company. Lexan is a registered trademark of General Electric Co. Plexiglass is a registered trademark of Rohm & Haas Co. Printed in U.S.A. 3M 2010 78-6900-1037-2 (1/10)