1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY / UNDERTAKING

Transcription

1 1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY / UNDERTAKING Product Aimed/recommend application Pro-Mac Poultry Complementary feeding stuff that can be added to drinking water of poultry. Supplier Kanters Special Products B.V. De Stater RV Lieshout - The Netherlands Tel.: Emergency telephone (Fax.: ) 2 COMPOSITION INGREDIENTS Description of the substances which are responsible for the danger classification of the preparation: Chemical name EINECS number Concentration Symbol R-phrases Ethanol % F R11 Formic acid < 2% C R35 Lactic acid % Xi R38-41 Zinc chloride < 0.5% C, N R34-50/53 3 HAZARDS IDENTIFICATION Irritating Flammable R10 Flammable R38 Irritating to skin. R41 Risk of serious damage to eyes. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 4 FIRST AID MEASURES General information After inhalation After skin contact After eye contact After swallowing Immediately remove any clothing soiled by the product. Dependent on the situation contact a doctor or the hospital. Bring the patient into fresh air. Dependent on the situation contact a doctor. Immediately wash with plenty of water. Rinse opened eye for several minutes under running water. Then consult a doctor. Rinse mouth with water and then drink plenty of water. Call for a doctor immediately. Revision of 17/02/2006 page 1 of 7

2 5 FIRE-FIGHTING MEASURES Suitable extinguishing agents Powder, alcohol prove foam, a large amount of water, CO 2. Fires in direct surroundings: all extinguishing agents allowed. Extinguish instructions Direct fire-risk Indirect fire-risk Cool tanks/cans and/or bring them in safety. Do not move the load when it is exposed to heat. Minimize the extinguish water, when possible catch or dam. Flammable product. At temperatures above flash point there is a higher change of fire/explosion. 6 ACCIDENTAL RELEASE MEASURES Personal precautionary measures Environmental precautions Cleaning/collecting measures Wear suitable gloves, safety goggles and protective clothing. Take care of ventilation or local extracting. Do not eat, drink or smoke during work. Prevent entering of the product into sewerage, surface water and/or ground water. Keep cans closed. Catch or dam liberated material in suitable barrels. Stop leak and close supply. Dam leaking fluid. Try to limit evaporation. Absorb with liquid binding material (sand, diatomite, acid binders, universal binders). 7 HANDLING AND STORAGE Handling Storage requirements During use of the product do not eat, drink or smoke. Wear suitable protective equipment. Open and handle receptacle with care. Avoid as much as possible inhalation. Immediately remove any clothing soiled by the product. Keep away from open fire, sparks, heat and direct sunlight. Take care of ventilation or of local extracting. Do not spill waste in de sewerage. Wash hands and other exposed body parts with water and soap after use. In agreement with the legal requirements (PGS-15). Store only in the original packing. Store in a fire safe, cool and dry location. Keep away from oxidizing agents. Keep out of reach of children. Revision of 17/02/2006 page 2 of 7

3 Specific application Use as complementary feeding stuff that can be added to drinking water of poultry. 8 EXPOSURE CONTROLS AND PERSONAL PROTECTION GEAR Exposure limits Chemical name MAC tgg 8 hours MAC tgg 15 minutes Ethanol 1000 mg/m 3* - Formic acid 9 mg/m 3* 19 mg/m 3 Lactic acid - - Zinc chloride 1 mg/m 3* (fume) - * Legal exposure value ** Recommended exposure value Concentration measurement Chemical name Measuring method Ethanol Formic acid Auer (Trichloorethane-5, ) Dräger (Formic acid 1/a, ) Zinc chloride Respiratory protection Take care of ventilation or local extracting. Gloves (EN 374) Eye protection Skin protection Environment Nitrile rubber, > 480 minutes (break trough time of lactic acid). Butyl rubber, > 480 minutes (break trough time of lactic acid). Neoprene, > 480 minutes (break trough time of lactic acid). Tightly sealed goggles. Protective work clothing. Harmful for the environment. Prevent spreading. 9 PHYSICAL AND CHEMICAL PROPERTIES Appearance Liquid Colour Green/brown Odour Slightly acid ph 5% Boiling point Flashpoint Ethanol 7-11% = ~ 50 C Inflammability Flammable Explosion properties Explosive under influence of a flame Oxidizing properties None Vapour pressure at 20 C Ethanol: 58.5 mbar Formic acid: 28 hpa Zinc chloride: < 1 hpa Revision of 17/02/2006 page 3 of 7

4 Density at 20 C g/cm 3 Solubility in water Fully miscible Solubility in fat Not miscible. Log K oct/water Ethanol: Log K ow Viscosity at 20 C Vapour density at 20 C Ethanol: 1.6 Formic acid: 1.59 Lactic acid: STABILITY AND REACTIVITY Stability Conditions to be avoided Materials to be avoided Dangerous decomposition products The product is stable under normal circumstances. Keep away from open fire, sparks, heat and direct sunlight. Oxidation agents, (strong) acids, (strong) base and metals. CO, CO 2 and HCl. 11 TOXICOLOGICAL INFORMATION Toxicological information Chemical name LD50 Oral rat LD50 Dermal rat LD50 Dermal rabbit LC50 Inhalation rat Ethanol 7060 mg/kg mg/l/10h Formic acid > 1100 mg/kg mg/l/4u Lactic acid 3730 mg/kg - > 2000 mg/kg - Zinc chloride 350 mg/kg Acute toxicity Chronicle toxicity Acute effects/symptoms After swallowing After inhalation After skin contact After eye contact See table above. By prolonged, repeated ingestion of ethanol there is a change of liver damage. It can reduce male fertility. It can harm the unborn child. After long exposure of lactic acid there is a change of corrosion of the upper bronchial tubes. Not included in carcinogenety class, mutagenity class and teratogenity class. Head ache, dizziness, dullness sickness, vomiting, irritating of the bronchial tubes. Coughing, head ache, dizziness, dullness. Redness. Redness, pain. Revision of 17/02/2006 page 4 of 7

5 12 ECOLOGICAL INFORMATION Ecological information of this product is unknown, but there is information about the in category 2 mentioned component. Ethanol Degradable Easy bio-degradable in water. Bio-accumulation Ecotoxicity LC50 fish: mg/l/96h EC50 daphnia: > mg/l/48h IC50 algae: 1450 mg/l/72h Other effects. Formic acid Degradable Easy bio-degradable in water. Bio-accumulation Not applicable. Ecotoxicity LC50 leuciscus idus (fish): mg/l/96h EC50 daphnia magna: 34.2 mg/l/48h EC50 scenedesmus subspicatus (algae): 26.9 mg/l/72h Other effects ph shifting in water. Lactic acid Degradable Bio-degradable in water. Bio-accumulation Not applicable Ecotoxicity Other effects Causes ph-shifting in water Zinc chloride Degradable. Bio-accumulation Moderate bio-accumulation. Ecotoxicity LC50 (fish): 21 mg/l/96h EC50 daphnia magna: 0.8 mg/l/48h EC50 (algae): mg/l/72h Other effects May cause long-term adverse effects in the aquatic environment 13 DISPOSAL CONSIDERATIONS Product Packaging Dangerous residues Relevant regulations Keep waste apart. Must be specially treated adhering to official regulations. Disposal of uncleaned packaging must be made according to official regulations. None. Waste must be specially treated adhering to official regulations (see Eural). Revision of 17/02/2006 page 5 of 7

6 14 TRANSPORT INFORMATION International transport regulations UN-number Proper technical name - Road/rail transport ADR/RID class Packaging group - ADR/RID classification code - Danger code - ADR/RID label - Inland waters transport ADNR class Sea IMDG class Packaging group - Marine pollutant - EMS number - Air IATA class Remarks - 15 REGULATORY INFORMATION EU-classification danger symbol Xi Irritating Risk phrases R10 Flammable R38 Irritating to skin. R41 Risk of serious damage to eyes. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Revision of 17/02/2006 page 6 of 7

7 Safety phrases S1/2 Keep locked up and out of reach of children. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S39 Wear eye/face protection S46 If swallowed, seek medical advice immediately and show this container or label. Contains - 16 OTHER INFORMATION This information only concerns the in paragraph 1 mentioned product and the in this safety data sheet mentioned circumstances. The information does not need to be valid if used with other product(s) or in any process. It remains the user's own responsibility to make sure that the information is appropriate and complete for his special use of this product. Existing laws and regulations must be fulfilled through the receiver of our product on own responsibility. R11 Highly flammable R34 Causes burns R35 Causes severe burns R38 Irritating to skin R41 Risk of serious damage to eyes R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Sources: Course Labelling & Safety data sheets Changes were made in section 14, and 16 Revision of 17/02/2006 page 7 of 7