Issuing Date January 5, 2015 Revision Date New Revision Number 0 I 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
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1 SAFETY DATA SHEET Issuing Date January 5, 2015 Revision Number 0 Product identifier I 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product Name Aplicare One-Step Body Bath Concentrate Other means of identification Product Code(s) , Recommended use of the chemical and restrictions on use Recommended Use Uses advised against Dilutable no-rinse body cleanser No information available Details of the supplier of the safety data sheet Supplier Name Supplier Address Aplicare Inc. 550 Research Parkway Meriden, CT Supplier Phone Number Phone: Emergency telephone number Emergency Phone Numbers For Medical Emergencies call: For Transportation Emergencies, call Chemtrec: Page 1 / 11
2 2. HAZARDS IDENTIFICATION Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR ) Serious eye damage/eye irritation Carcinogenicity Category 2B Category 1A GHS Label elements, including precautionary statements Emergency Overview Signal word Danger Hazard Statements Causes eye irritation May cause cancer Appearance Clear, colorless Physical State Thin liquid Odor Pleasant, shampoo Precautionary Statements - Prevention Wash hands and face thoroughly after handling. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves. Precautionary Statements - Response If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. If exposed or concerned: Get medical advice. Precautionary Statements - Storage Store locked up. Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal in accordance with all applicable federal, state, and local regulations. Hazards not otherwise classified (HNOC) Not applicable Unknown Toxicity 5.6% of the mixture consists of ingredient(s) of unknown toxicity Other information Harmful to aquatic life. Interactions with Other Chemicals None known. Page 2 / 11
3 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% Trade Secret Triethanolamine lauryl sulfate * Propylene glycol * Coconut diethanolamide * * <0.2 * *The exact percentage (concentration) of composition has been withheld as a trade secret First aid measures 4. FIRST AID MEASURES General Advice Eye Contact Skin Contact Inhalation Ingestion Show this safety data sheet to the doctor in attendance. Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician. Wash skin with soap and water. Remove to fresh air. Rinse mouth immediately and drink plenty of water. Self-protection of the first aider Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Most important symptoms and effects, both acute and delayed Most Important Symptoms and Effects Burning sensation. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. Page 3 / 11
4 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media CAUTION: Use of water spray when fighting fire may be inefficient. Specific Hazards Arising from the Chemical Hazardous Combustion Products Carbon oxides. Explosion Data Sensitivity to Mechanical Impact Sensitivity to Static Discharge No. No. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Ensure adequate ventilation. Other Information Refer to protective measures listed in Sections 7 and 8. Environmental Precautions Environmental Precautions Prevent further leakage or spillage if safe to do so. Methods and material for containment and cleaning up Methods for Containment Methods for cleaning up Prevent further leakage or spillage if safe to do so. Soak up with inert absorbent material. Keep in suitable, closed containers for disposal. 7. HANDLING AND STORAGE Precautions for safe handling Handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with eyes. Conditions for safe storage, including any incompatibilities Storage Incompatible Products Keep tightly closed in a dry and cool place. Keep in properly labeled containers. None known based on information supplied. Page 4 / 11
5 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH TWA: 1 mg/m 3 (inhalable fraction TWA: 3 ppm and vapor) - TWA: 15 mg/m 3 Skin IDLH: 20 ppm TWA: 0.75 ppm Ceiling: 0.3 ppm Ceiling: 0.1 ppm 15 min STEL: 2 ppm TWA: ppm ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value OSHA PEL: Occupational Safety and Health Administration - Permissible Exposure Limits NIOSH IDLH Immediately Dangerous to Life or Health Appropriate engineering controls Engineering Measures Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/Face Protection Skin and Body Protection Respiratory Protection Hygiene Measures None required for consumer use. If splashes are likely to occur, wear safety glasses with side-shields. Wear protective gloves and protective clothing. If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. Handle in accordance with good industrial hygiene and safety practice. Physical and Chemical Properties 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Thin liquid Appearance Clear Odor Pleasant, shampoo Color Colorless Odor Threshold No information available Property Values Remarks/ Method ph None known Melting / freezing point None known Boiling point / boiling range None known Flash Point None known Evaporation Rate None known Flammability (solid, gas) None known Flammability Limit in Air Upper flammability limit None known Lower flammability limit None known Vapor pressure None known Vapor density None known Specific Gravity ~1.0 None known Water Solubility Completely soluble None known Solubility in other solvents None known Partition coefficient: n-octanol/water None known Page 5 / 11
6 Autoignition temperature None known Decomposition temperature None known Kinematic viscosity None known Dynamic viscosity None known Explosive properties Oxidizing Properties Other Information Softening Point VOC Content (%) Particle Size Particle Size Distribution 10. STABILITY AND REACTIVITY Reactivity. Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization Hazardous polymerization does not occur. Conditions to avoid None known based on information supplied. Incompatible materials None known based on information supplied. Hazardous Decomposition Products Carbon oxides. Information on likely routes of exposure Product Information 11. TOXICOLOGICAL INFORMATION Inhalation Eye Contact Skin Contact Ingestion May cause irritation of respiratory tract. May cause eye irritation. Prolonged contact may cause mild irritation. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Page 6 / 11
7 Component Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Propylene glycol g/kg (Rat) 20.8 g/kg (Rabbit) - > 11.3 g/kg (Rabbit) > 2 g/kg (Rat) Lauryl alcohol > 5 g/kg (Rat) > 1.6 g/kg (Rat) > 10.2 g/kg (Rabbit) mg/l (Rat, 4 h) > 3.3 g/kg (Rat) 500 mg/kg (Rat) 270 mg/kg (Rabbit) mg/l (Rat, 4 h) Information on toxicological effects Symptoms May cause redness and tearing of the eyes. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization Mutagenic Effects Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA Coconut diethanolamide Group 2B X A3 Group 2B X A2 Group 1 Reasonably Anticipated X ACGIH (American Conference of Governmental Industrial Hygienists) A2 - Suspected Human Carcinogen A3 - Animal Carcinogen IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans Group 2B - Possibly Carcinogenic to Humans Group 3 - Not Classifiable as to Carcinogenicity in Humans NTP (National Toxicology Program) Reasonably Anticipated - Reasonably Anticipated to be a Human Carcinogen OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Reproductive Toxicity STOT - single exposure STOT - repeated exposure Chronic Toxicity Target Organ Effects Aspiration Hazard No known effect based on information supplied. Carcinogenic potential is unknown. Eyes. Numerical measures of toxicity - Product Information The following values are calculated based on chapter 3.1 of the GHS document ATEmix (oral) 70 g/kg Page 7 / 11
8 ATEmix (inhalation-dust/mist) mg/l ATEmix (inhalation-vapor) 2, ATEmix 12. ECOLOGICAL INFORMATION Ecotoxicity Harmful to aquatic life. Chemical Name Toxicity to Algae Toxicity to Fish Triethanolamine lauryl sulfate Propylene glycol Coconut diethanolamide Lauryl alcohol Persistence and Degradability Bioaccumulation 96h EC50: = mg/l (Pseudokirchneriella subcapitata) 48h LC50: mg/l (Leuciscus idus) 96h LC50: = mg/l (Oncorhynchus mykiss) 96h LC50: ml/l (Oncorhynchus mykiss) 96h LC50: = mg/l (Pimephales promelas) 96h LC50: = 710 mg/l (Pimephales promelas) 96h LC50: = 3.6 mg/l (Brachydanio rerio) 96h LC50: h EC50: = 7.8 mg/l mg/l (Pimephales promelas) (Desmodesmus subspicatus) 96h LC50: h EC50: mg/l mg/l (Pimephales promelas) (Pseudokirchneriella 96h LC50: mg/l subcapitata) (Lepomis macrochirus) 96h LC50: = 1.01 mg/l 96h EC50: = 0.62 mg/l (Pimephales promelas) 96h (Desmodesmus subspicatus) LC50: = mg/l (Pimephales promelas) 96h LC50: mg/l (Pimephales promelas) 96h LC50: = 1510 µg/l (Lepomis macrochirus) 96h LC50: ml/l (Oncorhynchus mykiss) 96h LC50: = 41 mg/l (Brachydanio rerio) 96h LC50: mg/l (Oncorhynchus mykiss) 96h LC50: mg/l (Pimephales promelas) Toxicity to Microorganisms EC50 = 710 mg/l 30 min EC50 = 6000 mg/l 16 h EC50 = mg/l 5 min EC50 = mg/l 15 min EC50 = mg/l 30 min EC50 = 2 mg/l 48 h EC50 = 1.2 mg/l 1 h EC50 = 16.5 mg/l 30 min EC50 = 3.7 mg/l 5 h EC50 = 5.39 mg/l 72 h EC50 = 6.81 mg/l 25 min EC50 = 7.26 mg/l 15 min EC50 = 9.0 mg/l 5 min Daphnia Magna (Water Flea) 24h EC50: mg/l 24h EC50: > mg/l 48h EC50: > 1000 mg/l 24h EC50: = 4.2 mg/l 48h EC50: = 55 mg/l 48h EC50: = 320 mg/l 48h LC50: = 2 mg/l 48h EC50: mg/l Chemical Name Lauryl alcohol Log Pow Other adverse effects Page 8 / 11
9 13. DISPOSAL CONSIDERATIONS Disposal methods Dispose of in accordance with all applicable federal, state, and local regulations. Contaminated Packaging Dispose of in accordance with all applicable federal, state, and local regulations. 14. TRANSPORT INFORMATION DOT TDG ICAO IATA IMDG/IMO Not regulated Not regulated Not regulated Not regulated Not regulated 15. REGULATORY INFORMATION Chemical Inventories TSCA DSL Exempt All components are listed either on the DSL or NDSL. TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains the following chemicals that are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name CAS No Weight-% SARA Threshold Values % SARA 311/312 Hazard Categories Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden release of pressure hazard Reactive Hazard Yes Yes No No No CWA (Clean Water Act) This product contains the following substance that is a regulated pollutant pursuant to the Clean Water Act (40 CFR and 40 CFR ) Chemical Name CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances 100 lb X Page 9 / 11
10 CERCLA This material, as supplied, contains the following substances that are regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical Name US State Regulations Hazardous Substances RQs 100 lb Extremely Hazardous Substances RQs 100 lb 100 lb RQ RQ 100 lb final RQ RQ 45.4 kg final RQ RQ= 100 lb final RQ RQ= 45.4 kg final RQ California Proposition 65 This product contains the following Proposition 65 chemicals. Chemical Name California Proposition 65 Coconut diethanolamide Carcinogen - Carcinogen - Carcinogen U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania Rhode Island Illinois Propylene glycol X X Coconut diethanolamide X X X X X X X X X X X International Regulations Canada WHMIS Hazard Class D2A - Very toxic materials Page 10 / 11
11 16. OTHER INFORMATION NFPA Health Hazards 2 Flammability 0 Instability 0 Physical and Chemical Hazards N/A HMIS Health Hazards 2* Flammability 0 Physical Hazard 0 Personal Protection X Chronic Hazard Star Legend * = Chronic Health Hazard Prepared By Revision Date Revision Note Reference Product Stewardship 23 British American Blvd. Latham, NY New New CLX0021/720 Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of Safety Data Sheet Page 11 / 11
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