MATERIAL SAFETY DATA SHEET

Transcription

1 Print date: MATERIAL SAFETY DATA SHEET. PRODUCT AND COMPANY IDENTIFICATION Formula Number: # Lab.No UPC Code(s) and Size: Recommended / Intended Use: Manufacturer: Freshener for dishwashing machines Reckitt Benckiser Hungary Fatalepi UT Tatabanya Hungary Tel Distributor: Reckitt Benckiser Inc. Morris Corporate Center IV 399 Interpace Parkway (P.O. Box 225) Parsippany, New Jersey Telephone: Emergency Telephone Number: Transportation Emergencies: (U.S) (U.S. & Canada) CHEMTREC Outside U.S. and Canada (North America), call Chemtrec: MSDS Number: Page of 0

2 2. HAZARDS IDENTIFICATION Emergency Overview CAUTION! May cause skin and eye irritation DO NOT ingest. DO NOT get in eyes. KEEP OUT OF REACH OF CHILDREN 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name Proportion (%w/w) ACGIH - Occupational Exposure Limits - TWAs OSHA PEL Nerol Decanal Octanal <2.5% - - <2.5% - - <2.5% FIRST AID MEASURES Inhalation Skin Contact Eye Contact Ingestion Notes to Physician Protection of First-aiders Aggravated Medical Conditions: Move to fresh air. If symptoms persist, call a physician. Wash off immediately with plenty of water. If skin irritation persists, call a physician. In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice if symptoms persist. Rinse mouth. DO NOT INDUCE VOMITING. Drink plenty of water. Consult a physician. Treat symptomatically Use personal protective equipment. Page 2 of 0

3 5. FIRE-FIGHTING MEASURES Flash point: See section 9 Suitable Extinguishing Media: Extinguishing media which must not be used for safety reasons: Unusual hazards: Special protective equipment for firefighters Precautions for fire-fighting Alcohol-resistant foam. Dry powder. Carbon dioxide (CO2). No information available None known. Wear self contained breathing apparatus for fire fighting if necessary. Standard procedure for chemical fires. NFPA: Health Hazard: 2 Flammability: 2 Physical Hazard: 0 HMIS: Health Hazard: 2 Flammability: 2 Physical Hazard: 0 Personal Protection: B Key: B. (Also see Sections 3 & 8) 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Environmental Precautions: Methods for Cleaning Up: Ensure adequate ventilation. Avoid contact with skin, eyes and inhalation of vapors Wear gloves and safety goggles. Prevent product from entering drains. Do not contaminate surface water. Small spills: Wearing appropriate protective equipment, soak up with an inert absorbent material and dispose of in an appropriate waste container. Rinse surface residue and flush to sink or sanitary sewer. Methods for Containment: Prevent further leakage or spillage if safe to do so 7. HANDLING AND STORAGE Handling: Storage: Avoid contact with skin and eyes Ensure adequate ventilation Do not breathe vapors/dust In case of insufficient ventilation, wear suitable respiratory equipment Wear gloves and safety goggles. Do not eat, drink or smoke when using this product Keep containers tightly closed in a cool, well-ventilated place Keep away from heat and sources of ignition. For quality reasons keep around 25 C. Page 3 of 0

4 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Chemical Name ACGIH TLV OSHA PEL Nerol Decanal Octanal Engineering Controls: Environmental exposure controls For occupational exposures, ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained Personal Protective Equipment Respiratory Protection: Hand Protection: Skin and Body Protection: Hygiene Measures: Use only with adequate ventilation In case of mist, spray or aerosol exposure wear suitable personal respiratory protection and protective suit. Rubber gloves Usual safety precautions while handling the product will provide adequate protection against injury or irritation. Follow product label instructions. Avoid contact with eyes, skin, and clothing. Page 4 of 0

5 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Appearance: Colour: Odour: ph Liquid. Liquid. Yellow Green perfumed, typical to meet the Tradename descriptor No information available Flash Point: 76 C / 69 F Flammability Limits in Air: Autoignition Temperature: Specific Gravity / Density [g/ml]: Vapour Pressure: No information available 0.9g/ml(20 C) 0.2 (at 20 C in mmhg) Solubility: VOC content(%): <39% 0. STABILITY AND REACTIVITY Stability: Conditions to Avoid: Materials to Avoid: Stable under recommended storage conditions. Store away from excessive heat and moisture Keep away from strong oxidizers. Hazardous Decomposition Products: Oxides of carbon and unknown organic compounds. Polymerization: Hazardous polymerization does not occur. Page 5 of 0

6 . TOXICOLOGICAL INFORMATION PRODUCT TOXICITY DATA LD 50 Oral: LD50 Dermal: LC 50 Inhalation (Dust): LC50 Inhalation (Vapor): >2000 mg/kg (rat) estimated >2000 mg/kg (rat) estimated No information available No information available ACUTE EFFECTS:: Eye Irritation Skin Irritation Inhalation Ingestion Sensitization None expected during normal use. May cause eye irritation upon direct contact with eyes. None expected during normal conditions of use. May cause skin irritation and/or dermatitis None expected during normal conditions of use. May cause irritation of respiratory tract. Vapors may cause drowsiness and dizziness Health injuries are not known or expected under normal use. Notexpectedtobeaskinsensitiser. Specific Effects Carcinogenic Effects: Mutagenic Effects Reproductive Toxicity: Additional Toxicity Information: Not listed as carcinogenic by OSHA, NTP or IARC. Information is based on available component data and toxicity result of similar products. COMPONENT TOXICITY DATA Chemical Name CAS-No LD50 Oral - w ith units -Rat-mg/kg LD50 Dermal - With Units - Rat/Rabbit - mg/kg Nerol mg/kg ( Rat ) 5000 mg/kg ( Rabbit ) Decanal µl/kg ( Rat ) 5040 µl/kg ( Rabbit ) LC50 Inhalation - With units - Rat/Rabbit Page 6 of 0

7 2. ECOLOGICAL INFORMATION PRODUCT TOXICITY DATA Ecotoxicity effects Aquatic toxicity: May be harmful to aquatic organisms if bulk quantities are spilled into a watersource. COMPONENT TOXICITY DATA Decanal (< 2.5 %) Microtox EC50 = 3.59 mg/l 5 min EC50 = 4.7 mg/l 5 min Other Information Ozone depletion potential; ODP; (R- = ) Global Warming Potential (GWP): Additional Ecological Information: Information given is based on data on the components and the ecotoxicology of similar products. 3. DISPOSAL CONSIDERATIONS Waste from residues / unused products: Contaminated Packaging: Dispose of in accordance with local regulations. Dispose of empty container in household trash. Waste Disposal: Dispose of according to Local, State, Provincial and / or Federal regulations. Page 7 of 0

8 General remarks DOT TDG MEX ICAO IATA IMDG/IMO RID ADR ADN MATERIAL SAFETY DATA SHEET 4. TRANSPORT INFORMATION Not classified as dangerous in the meaning of transport regulations. For long distance transport of bulk material or shrunk pallet take into consideration sections 7 and 0. Not regulated Not regulated Not applicable. Not regulated Not regulated Not regulated Not applicable. Not applicable. Not applicable. 5. REGULATORY INFORMATION Chemical Name PICCS TSCA DSL NDSL ENCS CHINA AICS EINECS/ ELINCS Nerol Present X X X X Decanal Present X X X X Octanal Present X X X X South Africa STELs Page 8 of 0

9 U.S. Regulations: Nerol NJRTK Appearance SARA33 California Prop. 65 Decanal NJRTK Appearance SARA33 California Prop. 65 Octanal NJRTK Appearance SARA33 California Prop. 65 Not Listed. None. None Not Listed Not Listed. None. None Not Listed Not Listed. None. None Not Listed WHMIS (Canada) WHMIS Hazard Class B3 Combustible liquid D2B Toxic materials Page 9 of 0

10 6. OTHER INFORMATION National Fire Protection Association (U.S.A.): HMIS (U.S.A.): Health Hazard Flammability: 2 2 Physical hazards 0 PERSONAL PROTECTION B Reason for revision: Additional advice: Prepared by: New product This product should only be used as directed on the label and for the purpose intended. Regulatory, Safety and Environmental Services RSE Dishwashing Reckitt Benckiser Produktions GmbH Benckiserplatz D Ludwigshafen am Rhein Germany Phone: +49 (0) Fax: +49 (0) rse-lu@reckittbenckiser.com To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Page 0 of 0