Components: STAINLESS STEEL PUTTY (ST) HARDENER STAINLESS STEEL PUTTY (ST) RESIN ITW Performance Polymers (Finished Goods) Product Code : 10270

Transcription

1 MSDS Name: DEVCON Stainless Steel Putty (ST) Manufacturer Name: ITW Devcon Stock No.: Components: STAINLESS STEEL PUTTY (ST) HARDENER STAINLESS STEEL PUTTY (ST) RESIN ITW Performance Polymers (Finished Goods) Product Code : View Section : SECTION 1: PRODUCT AND COMPANY IDENTIFICATION Product Name: Manufacturer Name: Address: STAINLESS STEEL PUTTY (ST) RESIN ITW Devcon 30 Endicott Street Danvers, MA MSDS Revision Date: 10/10/2006 Emergency telephone number (800) HMIS Health Hazard 2* Fire Hazard 1 REACTIVITY 1 Personal Protection x * Chronic Health Effects: In the US, call CHEMTREC: (800) SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS# Nickel powder by Weight Iron by Weight Bisphenol A diglycidyl ether resin by Weight Chromium by Weight 12-hydroxy-octadecanoic acid glyceride by Weight Manganese by Weight SECTION 3: HAZARDS IDENTIFICATION Emergency Overview: WARNING! Potential Sensitizer. Irritant. Primary Routes of Exposure: Potential Health Effects: Eye Contact: Skin Contact: Eyes. Skin. Inhalation. Ingestion. Can cause moderate irritation, burning sensation, tearing, redness, and swelling. Overexposure may cause lacrimation, conjunctivitis, corneal damage and permanent injury.. Can cause skin irritation; itching, redness, rashes, hives, burning, and swelling. Allergic reactions are possible. May cause skin sensitization, an allergic reaction, which becomes evident on

2 Inhalation: Ingestion: reexposure to this material. Respiratory tract irritant. High concentration may cause dizziness, headache, and anesthetic effects. May cause respiratory sensitization with asthma-like symptoms in susceptible individuals. Causes irritation, a burning sensation of the mouth, throat and gastrointestinal tract and abdominal pain. Chronic Health Effects: Signs/Symptoms: Target Organs: Aggravation of Pre-Existing Conditions: Prolonged skin contact may lead to burning associated with severe reddening, swelling, and possible tissue destruction Overexposure can cause headaches, dizziness, nausea, and vomiting. Eyes. Skin. Respiratory system. Digestive system. Kidney. Liver. Central nervous system. Reproductive System. Individuals with pre-existing skin disorders, asthma, allergies or known sensitization may be more susceptible to the effects of this product. SECTION 4: FIRST AID MEASURES Eye Contact: Skin Contact: Inhalation: Ingestion: Immediately flush eyes with plenty of water for at least 15 to 20 minutes. Ensure adequate flushing of the eyes by separating the eyelids with fingers. Get immediate medical attention. Immediately wash skin with plenty of soap and water for 15 to 20 minutes, while removing contaminated clothing and shoes. Get medical attention if irritation develops or persists. If inhaled, remove to fresh air. If not breathing, give artificial respiration or give oxygen by trained personnel. Seek immediate medical attention. If swallowed, do NOT induce vomiting. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. SECTION 5: FIRE FIGHTING MEASURES Auto Ignition Temp : Flash Point: Flash Point Method: Lower Explosive Limit (LEL) Upper Explosive Limit (UEL) Extinguishing Media: Protective Equipment: Fire Fighting Instructions: Unsuitable Media: >400 F (204.4 C) Pensky-Martens Closed Cup Use carbon dioxide (CO2) or dry chemical when fighting fires involving this material. As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Evacuate area of unprotected personnel. Use cold water spray to cool fire exposed containers to minimize risk of rupture. Do not enter confined fire space without full protective gear. If possible, contain fire run-off water. Water or foam may cause frothing. SECTION 6: ACCIDENTAL RELEASE MEASURES Personal Precautions: Spill Cleanup Measures: Environmental Precautions: Other Precautions: Evacuate area and keep unnecessary and unprotected personnel from entering the spill area. Absorb spill with inert material (e,g., dry sand or earth), then place in a chemical waste container. Provide ventilation. Clean up spills immediately observing precautions in the protective equipment section. After removal, flush spill area with soap and water to remove trace residue. Avoid personal contact and breathing vapors or mists. Ventilate area. Use proper personal protective equipment as listed in section 8. Avoid runoff into storm sewers, ditches, and waterways. Pump or shovel to storage/salvage vessels. SECTION 7: HANDLING AND STORAGE Handling: Storage: Hygiene Practices: Special Handling Procedures: Use with adequate ventilation. Avoid breathing vapor, aerosol or mist. Store in a cool, dry, well ventilated area away from sources of heat and incompatible materials. Keep container tightly closed when not in use. Wash thoroughly after handling. Provide appropriate ventilation/respiratory protection against decomposition products (see Section 10) during welding/flame cutting operations and to protect against dust during sanding/grinding of cured product.

3 SECTION 8: EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Skin Protection Description: Eye/Face Protection: Respiratory Protection: Other Protective: Nickel powder: Guideline ACGIH : Guideline OSHA : Chromium: Guideline ACGIH : Guideline OSHA : Manganese: Guideline ACGIH : Guideline OSHA : Notes : Use appropriate engineering control such as process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Good general ventilation should be sufficient to control airborne levels. Where such systems are not effective wear suitable personal protective equipment, which performs satisfactorily and meets OSHA or other recognized standards. Consult with local procedures for selection, training, inspection and maintenance of the personal protective equipment. Wear appropriate protective gloves and other protective apparel to prevent skin contact. Consult manufacturer's data for permeability data. Wear appropriate protective glasses or splash goggles as described by 29 CFR , OSHA eye and face protection regulation, or the European standard EN 166. A NIOSH approved air-purifying respirator with an organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air purifying respirators may not provide adequate protection. Facilities storing or utilizing this material should be equipped with an eyewash and a deluge shower safety station. ACGIH TLV-TWA 1.5 mg/m3 OSHA PEL-TWA 1 mg/m3 ACGIH TLV-TWA 0.5 mg/m3 OSHA PEL-TWA 1 mg/m3 ACGIH TLV-TWA 0.2 mg/m3 OSHA PEL-STEL 5 mg/m3 Ceiling/Peak Only established PEL and TLV values for the ingredients are listed below. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Physical State/Appearance: Paste. Color: dark grey. Odor: slight odor Boiling Point: >500 F (260 C) Melting / Freezing Point : Solubility: negligible Specific Gravity: 3.1 ph: Neutral. Vapor Density: >1 (air = 1) Vapor Pressure: 0.03 F Molecular Formula: Mixture Molecular Weight: Mixture Percent Volatile: 0 VOC Data : 0 g/l Percent Solids by Weight 100 SECTION 10: STABILITY AND REACTIVITY Chemical Stability: Conditions to Avoid: Incompatibilities with Other Materials: Hazardous Polymerization: Stable under normal temperatures and pressures. Extreme heat, sparks, and open flame. Incompatible materials, oxidizers and oxidizing conditions. Heating resin above 300 F in the presence of air may cause slow oxidative decomposition. Strong Lewis or mineral acids, strong oxidizing agents, strong mineral and organic bases (especially primary and secondary aliphatic amines). Not reported. SECTION 11: TOXICOLOGICAL INFORMATION Nickel powder: Oral - Mouse LDLo: 500 mg/kg - [Gastrointestinal - other changes] (RTECS)

4 Carcinogenicity: Iron: IARC: Group 2B: Possibly carcinogenic to humans NTP: Reasonably anticipated to be a human carcinogen Oral - Rat LD50: 30 gm/kg - [Nutritional and Gross Metabolic - weight loss or decreased weight gain ] (RTECS) Bisphenol A diglycidyl ether resin: Skin Effects: Skin - rat LD: >2 gm/kg - [Nutritional and Gross Metabolic - other changes] (RTECS) Oral - Rat LD: >5 gm/kg - [Nutritional and Gross Metabolic - other changes] (RTECS) Manganese: Eye Effect: Eye - Rabbit Standard Draize Test : 500 mg/24h - [mild ](RTECS) Skin Effects: Skin - Rat Standard Draize Test : 500 mg/24h - [mild ](RTECS) Inhalation Effects: Inhalation - Human man TCLo - Lowest published toxic concentration: 2300 ug/m3 - [Brain and Coverings - other degenerative changes Behavioral - changes in motor activity (specific assay) Behavioral - muscle weakness ] (RTECS) Oral - Rat LD50: 9 gm/kg - [Details of toxic effects not reported other than lethal dose value ] (RTECS) SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity: Environmental Fate: No ecotoxicity data was found for the product. No environmental information found for this product. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal: RCRA Number : Consult with the US EPA Guidelines listed in 40 CFR Part for the classifications of hazardous waste prior to disposal. Furthermore, consult with your state and local waste requirements or guidelines, if applicable, to ensure compliance. Arrange disposal in accordance to the EPA and/or state and local guidelines. None SECTION 14: TRANSPORT INFORMATION DOT Shipping Name: DOT UN Number: DOT Hazard Class: DOT Packing Group: Non regulated. N/A Not applicable. Not applicable. SECTION 15: REGULATORY INFORMATION Nickel powder: in the State of Massachusetts Hazardous Substance List. in the New Jersey State Right to Know List. in the Pennsylvania State Hazardous Substances List. EC Num : Bisphenol A diglycidyl ether resin: EC Num : Chromium: in the State of Massachusetts Hazardous Substance List. in the New Jersey State Right to Know List. in the Pennsylvania State Hazardous Substances List. Manganese: in the State of Massachusetts Hazardous Substance List. in the New Jersey State Right to Know List. in the Pennsylvania State Hazardous Substances List. Canadian Regulations. WHMIS Hazard Class(es): D2B All components of this product are on the Canadian Domestic Substances List.

5 SECTION 16: ADDITIONAL INFORMATION HMIS Health Hazard: 2* HMIS Fire Hazard: 1 HMIS Reactivity: 1 HMIS Personal Protection: x MSDS Revision Date: 10/10/2006 Disclaimer: "This Health and Safety Information is correct to the best of our knowledge and belief at the date of its publication but we cannot accept liability for any loss, injury or damage which may result from its use. The information given in the Data Sheet is designed only as a guidance for safe handling, storage and the use of the substance. It is not a specification nor does it guarantee any specific properties. All chemicals should be handled only by competent personnel, within a controlled environment." Copyright Actio Software Corporation. All Rights Reserved. View Section : SECTION 1: PRODUCT AND COMPANY IDENTIFICATION Product Name: Manufacturer Name: Address: STAINLESS STEEL PUTTY (ST) HARDENER ITW Devcon 30 Endicott Street Danvers, MA MSDS Revision Date: 10/10/2006 Emergency telephone number (800) HMIS Health Hazard 3* Fire Hazard 1 REACTIVITY 1 Personal Protection x * Chronic Health Effects: In the US, call CHEMTREC: (800) SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS# Inert material N/A 5-10 by Weight Dimer/TOFA, reaction products with TETA by Weight Triethylenetetramine by Weight Titanium dioxide by Weight SECTION 3: HAZARDS IDENTIFICATION Emergency Overview: WARNING! Harmful. Potential Sensitizer. Irritant. Primary Routes of Exposure: Potential Health Effects: Eye Contact: Skin Contact: Inhalation: Ingestion: Eyes. Skin. Inhalation. Ingestion. Can cause severe eye irritation and burns. Eye contact may cause permanent damage or blindness. Causes severe skin irritation. May cause permanent skin damage. Allergic reactions are possible. May cause skin sensitization, an allergic reaction, which becomes evident on reexposure to this material. Vapor or mist may cause severe respiratory system irritation. May cause respiratory sensitization with asthma-like symptoms in susceptible individuals. Causes irritation, a burning sensation of the mouth, throat and gastrointestinal

6 tract and abdominal pain. Chronic Health Effects: Signs/Symptoms: Target Organs: Aggravation of Pre-Existing Conditions: Prolonged skin contact may lead to burning associated with severe reddening, swelling, and possible tissue destruction Overexposure may cause eye watering or discomfort, redness and swelling. Eyes. Skin. Respiratory system. Digestive system. Individuals with pre-existing skin disorders, asthma, allergies or known sensitization may be more susceptible to the effects of this product. SECTION 4: FIRST AID MEASURES Eye Contact: Skin Contact: Inhalation: Ingestion: Immediately flush eyes with plenty of water for at least 15 to 20 minutes. Ensure adequate flushing of the eyes by separating the eyelids with fingers. Get immediate medical attention. Immediately wash skin with plenty of soap and water for 15 to 20 minutes, while removing contaminated clothing and shoes. Get medical attention if irritation develops or persists. If inhaled, remove to fresh air. If not breathing, give artificial respiration or give oxygen by trained personnel. Seek immediate medical attention. If swallowed, do NOT induce vomiting. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. SECTION 5: FIRE FIGHTING MEASURES Flammable Properties : Class III B. Auto Ignition Temp : Flash Point: >200 F (93.3 C) Flash Point Method: Tag Closed Cup (TCC) Lower Explosive Limit (LEL) Upper Explosive Limit (UEL) Extinguishing Media: Use carbon dioxide (CO2) or dry chemical when fighting fires involving this material. Protective Equipment: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Fire Fighting Instructions: Evacuate area of unprotected personnel. Use cold water spray to cool fire exposed containers to minimize risk of rupture. Do not enter confined fire space without full protective gear. If possible, contain fire run-off water. Unsuitable Media: Water or foam may cause frothing. SECTION 6: ACCIDENTAL RELEASE MEASURES Personal Precautions: Spill Cleanup Measures: Environmental Precautions: Other Precautions: Evacuate area and keep unnecessary and unprotected personnel from entering the spill area. Absorb spill with inert material (e,g., dry sand or earth), then place in a chemical waste container. Provide ventilation. Clean up spills immediately observing precautions in the protective equipment section. After removal, flush spill area with soap and water to remove trace residue. Avoid personal contact and breathing vapors or mists. Ventilate area. Use proper personal protective equipment as listed in section 8. Avoid runoff into storm sewers, ditches, and waterways. Pump or shovel to storage/salvage vessels. SECTION 7: HANDLING AND STORAGE Handling: Storage: Hygiene Practices: Special Handling Procedures: Use with adequate ventilation. Avoid breathing vapor, aerosol or mist. Store in a cool, dry, well ventilated area away from sources of heat and incompatible materials. Keep container tightly closed when not in use. Do not store in reactive metal containers. Keep away from acids, oxidizers. Wash thoroughly after handling. Provide appropriate ventilation/respiratory protection against decomposition products (see Section 10) during welding/flame cutting operations and to protect against dust during sanding/grinding of cured product. SECTION 8: EXPOSURE CONTROLS, PERSONAL PROTECTION

7 Engineering Controls: Skin Protection Description: Eye/Face Protection: Respiratory Protection: Other Protective: Titanium dioxide: Guideline ACGIH : Notes : Use appropriate engineering control such as process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Good general ventilation should be sufficient to control airborne levels. Where such systems are not effective wear suitable personal protective equipment, which performs satisfactorily and meets OSHA or other recognized standards. Consult with local procedures for selection, training, inspection and maintenance of the personal protective equipment. Wear appropriate protective gloves and other protective apparel to prevent skin contact. Consult manufacturer's data for permeability data. Wear appropriate protective glasses or splash goggles as described by 29 CFR , OSHA eye and face protection regulation, or the European standard EN 166. A NIOSH approved air-purifying respirator with an organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air purifying respirators may not provide adequate protection. Facilities storing or utilizing this material should be equipped with an eyewash and a deluge shower safety station. ACGIH TLV-TWA 10 mg/m3 Only established PEL and TLV values for the ingredients are listed below. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Physical State/Appearance: Paste. Color: White. Odor: mild ammonia like. Boiling Point: >450 F (232.2 C) Melting / Freezing Point : Solubility: 30-60% Specific Gravity: 1.02 ph: 5 Percent Solution Vapor Density: >1 (air = 1) Vapor Pressure: <0.01 F Molecular Formula: Mixture Molecular Weight: Mixture Percent Volatile: 0 VOC Data : 0 g/l Percent Solids by Weight 100 SECTION 10: STABILITY AND REACTIVITY Chemical Stability: Conditions to Avoid: Incompatibilities with Other Materials: Hazardous Polymerization: Stable under normal temperatures and pressures. Extreme heat, sparks, and open flame. Incompatible materials, oxidizers and oxidizing conditions. Oxidizers, acids, and chlorinated organic compounds. Reactive metals (e.g. sodium, calcium, zinc). Sodium/calcium hypochlorite. Nitrous acid/ oxide, nitrites. Peroxides. Materials reactive with hydroxyl compounds. Not reported. SECTION 11: TOXICOLOGICAL INFORMATION Triethylenetetramine: Eye Effect: Skin Effects: Titanium dioxide: Skin Effects: Inhalation Effects: Eye - Rabbit Standard Draize Test : 20 mg/24h - [Moderate](RTECS) Skin - Rat Standard Draize Test : 5 mg/24h - [severe](rtecs) Skin - Rat LD50: 805 mg/kg - [Details of toxic effects not reported other than lethal dose value ](RTECS) Oral - Rat LD50: 2500 mg/kg - [Details of toxic effects not reported other than lethal dose value ] (RTECS) Oral - Mouse LD50: 38.5 mg/kg - [Details of toxic effects not reported other than lethal dose value ] (RTECS) Skin - Human Standard Draize Test : 300 ug/3d-i - [mild](rtecs) Inhalation - Rat TCLo - Lowest published toxic concentration: 1 mg/kg - [Lungs, Thorax, or Respiration - other changes Biochemical - Metabolism (Intermediary)

8 - effect on inflammation or mediation of inflammation ] (RTECS) Oral - Rat TDLo - Lowest published toxic dose: 60 gm/kg - [Gastrointestinal - hypermotility, diarrhea Gastrointestinal - other changes ] (RTECS) Carcinogenicity: IARC: Group 2B: Possibly carcinogenic to humans SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity: Environmental Fate: No ecotoxicity data was found for the product. No environmental information found for this product. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal: RCRA Number : Consult with the US EPA Guidelines listed in 40 CFR Part for the classifications of hazardous waste prior to disposal. Furthermore, consult with your state and local waste requirements or guidelines, if applicable, to ensure compliance. Arrange disposal in accordance to the EPA and/or state and local guidelines. None SECTION 14: TRANSPORT INFORMATION DOT Shipping Name: DOT UN Number: DOT Hazard Class: DOT Packing Group: Non regulated. N/A Not applicable. Not applicable. SECTION 15: REGULATORY INFORMATION Triethylenetetramine: in the State of Massachusetts Hazardous Substance List. in the Pennsylvania State Hazardous Substances List. EC Num : Titanium dioxide: in the State of Massachusetts Hazardous Substance List. in the Pennsylvania State Hazardous Substances List. Canadian Regulations. WHMIS Hazard Class(es): D2B All components of this product are on the Canadian Domestic Substances List. SECTION 16: ADDITIONAL INFORMATION HMIS Health Hazard: 3* HMIS Fire Hazard: 1 HMIS Reactivity: 1 HMIS Personal Protection: x MSDS Revision Date: 10/10/2006 Disclaimer: "This Health and Safety Information is correct to the best of our knowledge and belief at the date of its publication but we cannot accept liability for any loss, injury or damage which may result from its use. The information given in the Data Sheet is designed only as a guidance for safe handling, storage and the use of the substance. It is not a specification nor does it guarantee any specific properties. All chemicals should be handled only by competent personnel, within a controlled environment." Copyright Actio Software Corporation. All Rights Reserved.