Segment OXO 2016 Oxoplast.com Oxoplast.com

Transcription

1 Segment OXO 2016 Oxoplast.com Oxoplast.com

2 Grupa Azoty ZAK S.A. WE ARE A PART OF GRUPA AZOTY Adam Leszkiewicz Chairman of the Board Grupa Azoty Zakłady Azotowe Kędzierzyn S.A. Grupa Azoty Police Multicompound ferilizers (NPK, NP) Nitrogen fertilizers (Urea) Nitrogen fertilizers with sulphur (AS) Titanium Oxide NAVITRANS sp. z o.o. Logistics Dear Sirs, 30 years ago we have started our adventure with OXO alcohols manufacturing. Since then we have been continuously building our experience and improving our professional competence. Today we are a paragon of product quality referred to as ZAK Quality. We focus on innovation which fuels our daily work and gives us great deal of joy. GZNF Fosfory Multicompound ferilizers The is a very important business for our company. We develop it on daily basis and set new, ambitious goals. We have changed and incorporated new commercial strategy fitting our partners needs as a priority of business strategy of Grupa Azoty ZAK S.A. It is a joint and mutual advantage for us and our commercial partners to build innovative product portfolio tailored to specific requirements. We will do that in multicompetence teams focused on different products. We have already taken decisions concerning specialty esters and other projects will follow. In 2015th we started a new one of the most technologically advanced non-phthalate plasticizer plant in this part of Europe. Our Oxoviflex immediately gained recognition not only from commercial side but also of Polish Agency of Enterprise Development (PARP) who awarded our product with prestigious Award Polish Product of the Future. This is only an example that we do perceive innovation in a very broad way. We want to pioneer in terms of technology and customer relations. Yet another example of our innovative attitude is OXO and Polymers Application Centre which has been initiated by Grupa Azoty ZAK S.A. The Center is to be a think tank and a platform to exchange ideas and experiences between industry and scientific circles. I m sure that together Grupa Azoty ZAK S.A. and our business partners will succeed. Grupa Azoty ATT Polymers Construction Plastics (PA6) Grupa Azoty ZAK S.A. Nitrogen fertilizers (AN, CAN, UREA, UAN) Nitrogen fertilizers with sulphur (CAN+S) OXO alcohols Plasticizers Zakłady Azotowe Chorzów S.A. Multicompound ferilizers (NPK) Stearin Grupa Azoty Puławy Nitrogen fertilizers (AN, UAN, Urea) Melamine Caprolactam Grupa Azoty Kopalnie i Zakłady Chemiczne Siarki Siarkopol S.A. Sulphur based products Grupa Azoty S.A. Construction plastics (PA6, POM, compounds) Caprolactam Nitrogen fertilizers (AN, CAN) Nitrogen fertilizers with sulphur (ASN, AS)

3 Grupa Azoty ZAK S.A. OXO HISTORY fot. KK24.pl, Grzegorz Stępień Our experience in OXO products dates back to This is when we started production of our first PVC plasticizer. We have started-up a modern OXO alcohols plant (2-Ethylhexanol, n-butanol, Isobutanol) as well as hydrogen and synthesis gas facilities. The investment had been started in 1982 and employed Davy Process technology. We began production of diisobutyl phthalate (DIBP). It was known as Oxoplast IB. Observing trends and dynamic changes in the market we have introduced a high molecular weight phthalate plasticizer DPHP. It is known as Oxoplast PH. We decided to build a large scale plant for Oxoviflex a non-pthalate plasticizer (50 kt /year). We have started-up a large scale plant for a non-pthalate, PTA based plasticizer (50 kt /year). The product has been introduced under Oxoviflex brand Grupa Azoty ZAK S.A. initiated an OXO and Polymers Application Centre In 1963 we have started to produce diethylhexyl phthalate (DEHP). It is known worldwide as Oxoplast O. In co-operation with Davy Process we commenced OXO plant modernization aimed at increasing its capacity. The process ended in November We changed our internal structure and a dedicated Oxoplast Business Unit was created. As one of the first in Europe we developed a non-pthalate, PTA based plasticizer and put it to small scale production. We have introduced a new product brand - Oxoplast Medica, a plasticizer for medical purposes.

4 Grupa Azoty ZAK S.A. 30 YEARS OF OXO Eventually shortly after the start-up we Poland became the largest. 10 years after putting our OXO plant into operation we started a 2 year long revamping process in terms of capacity and modernized the technology to be capable to produce highest quality oxo alcohols. Source: album pt. 65 lat Grupa Azoty Zakłady Azotowe Kędzierzyn S.A. The history behind our OXO plant This year we celebrate a 30th anniversary of starting up our OXO plant. This is a backbone of our thanks to which we are 2nd largest European producer of 2-EH. It is a good time to recall the beginnings of this turning point in Grupa Azoty ZAK S.A. history. Seventies and eighties of XX century was a hard time both for the company and Polish economy. Yet we have always been looking ambitiously to the future and utilizing our innovative capabilities to make key investments and changes within our company. Looking ahead the decision has been made to commence an investment in OXO alcohols facility. At that time this was a largest projected investment in Opole voivodship and was to become a turning point for our company. The contract to put up this facility was granted to a German contracting company and we utilized the most modern British/ American technology at that time. Yet it took couple of years since 1979 when the technology was licensed to 1982 when the investment started. Since we needed to develop professional and technical capabilities to operate the plant our engineers and technical staff responsible for this investment were later on assigned to start-up and operate the unit. Some of them went through a thorough training in Texas on a similar plant operated by Dow Chemichals, the rest of the staff was trained in Great Britain. In August of 1986 the plant went through initial startup. In October a WGS unit has been started up and couple days later our OXO plant was up and running, producing initially butanols and couple of weeks later 2-EH. years At that time our OXO plant was 3rd largest worldwide. We used approximately 10 kt of steel constructions and 5 kt of machinery to build it. Initially the capacities of alcohols were set at 100 kt/year of 2-EH, 20 kt/year of N-Butanol and 13,5 kt/year of Isobutanol. years

5 Grupa Azoty ZAK S.A. INNOVATION PUT INTO PRACTICE ACTIVITY AND PRIZES 2015th was a very fruitful year for our. On 29th of April we officially launched our non-phthalate plasticizer Oxoviflex plant and in November we started yet another forward looking initiative - an OXO and Polymers Application Centre chemical think tank and a platform to exchange ideas and experiences between companies and scientific circles. Apart from Grupa Azoty ZAK S.A. the Center Intent Letter has been signed by Ergis SA, SILEKOL Sp. z o.o., Silesian University, Opole Technical University, Institute of Biopolymers and Chemical Fibres, Institute of Heavy Organic Synthesis Blachownia The main objective of OXO and Polymers Application Centre is to seek and define innovative technologies and products within specialty chemistry through R&D activities. I am convinced that the Centre will help us in becoming even more efficient in developing innovative products which will fulfill our client s needs said Mr. Adam Leszkiewicz, CEO of Grupa Azoty ZAK S.A. One of the main roles of OXO and Polymers Application Centre is to shape and promote effective cooperation between science and industry Cooperation with science is very important for us. We are convinced that implementing innovative products and technologies developed by Polish science is the top priority issue for our company underlines Mr. Leszkiewicz. The Centre is an open platform, thus any company sharing its ideas and active within OXO and polymer chain may join it to work out synergies within the Centre. Adam Leszkiewicz Chairman of the Board April 2015 Grupa Azoty ZAK S.A. officially launched its new 50 kt/year, non-phthalate plasticizer plant to produce Oxoviflex May 2015 Grupa Azoty ZAK S.A. headlined The 3rd ICIS Oxo-alcohols Conference in Amsterdam. We also took this opportunity to share our views on European Oxo alcohols markets from a producer s perspective and exchange opinions with conference delegates April 2015 Grupa Azoty ZAK S.A. contributed as a partner to PVC Formulation Conference 2015 in Cologne. This was also a chance to show our Oxoviflex to experts of PVC processing industry from all of the world June 2015 Oxoviflex has been awarded during XIX International Rubber & Plastics Fairs -PLASTPOL in Kielce Ergis SA September 2015 Opole Technical University Institute of Heavy Organic Synthesis Blachownia is a very important part of our business. We are operating one of the most technologically advanced plants in Europe. We are No.1 Oxo alcohols and plasticizer producer in Poland and No.5 in Europe. We always strive to meet our clients needs especially from plastics sector and others who utilize products. Innovation by Grupa Azoty ZAK S.A. is not only the technology but also pioneer application, by which our company becomes most competitive player on the European market. Silesian University SILEKOL Sp. z o.o Institute of Biopolymers and Chemical Fibres Our product portfolio comprises products that are often reffered to as intelligent additives and produced according to strictest European chemical regulation. In near future we will expand our plasticizer portfolio by introducing specialty esters including bio-esters. Grupa Azoty ZAK S.A. and ICSO Blachownia (Institute of Heavy Organic Synthesis Blachownia ) has been awarded Grand Prix at XIII International Naphtha- Gas Chemistry Conference for elaboration Oxoviflex - nonphthalate plasticizer December 2015 Grupa Azoty ZAK S.A. and ICSO Blachownia has been awarded a Reaction Innovation prize for Oxoviflex and its plant at annual Naphtha/Chemistry Conference November 2015 Grupa Azoty ZAK S.A. along with other companies and Scientific Institutes initiated an OXO and Polymers Application Centre. The Centre aims at providing a platform for co-operation between its members and a place to exchange professional knowledge and experience December 2015 fot. KK24.pl, Grzegorz Stępień Mr. Paweł Jarczewski - Grupa Azoty S.A. Chairman has been placed on ICIS Top 40 Power Players list. ICIS valued the fast development of Grupa Azoty

6 Grupa Azoty ZAK S.A. OUR TEAM Dariusz Bednorz Vice Chairman of the Board Grupa Azoty Zakłady Azotowe Kędzierzyn S.A. Oxoplast Business Unit Director Aleksander Grymel Oxoplast BU Production Director Bogusław Gaca Esters Department Manager Daniel Strzyż Oxoplast BU Commercial Director Agnieszka Kurpińska Technology Office Manager Lech Janik WGS Department Manager Andrzej Dorosz Aldehydes Department Manager Paweł Polański Sales Coordinator Ludomira Trojnar Senior Sales Specialist Adam Rogala Oxo Alcohols Department Manager Andrzej Stypułkowski Marketing Specialist Rafał Bobko Sales Manager Western Europe & World Waldemar Pawelczyk Sales Manager Southern Europe & World Monika Urbańczyk Sales Manager Poland & Central Eastern Europe Jolanta Kamys Sales Specialist Anna Jamrozik Sales Specialist Małgorzata Góreczna Sales Specialist Katarzyna Łukasik Sales Specialist Agnieszka Grządziel Sales Specialist Barbara Skrzypczyk-Scheit Sales Specialist Tomasz Bednarz

7 MISSION / VISION CAPACITIES OXO ALKOHOLS ETHYLHEXANOL kt/year 55 BUTANOLS kt/year TOTAL 225 kt/year Mission of OXO segment To deliver chemical products meeting customers needs. Vision of OXO segment We will become leading player in our industry. Our company will be a fi rst choice supplier for the customer. We will achieve a highest value addend factor in our industry regardless of economic situation. PLASTICIZERS #2 w 2-EH 50 12% #2 w DEHT 5% w przeliczeniu na 2-EH i Butanole 5. kt/year miejsce 36kT/year Oxoplast Medica Oxoplast O Oxoplast PH TOTAL miejsce kt/year w przeliczeniu na DEHT, DINCH, DINP, DPHP Strategic aim Growth of sales and margins through market development, expanding port folio and product placement. MARKET SHARE IN UE Activities OXO ALCOHOLS PLASTICIZERS To introduce new generation plasticizers. To lengthen value chains. To perfect customer services employing innovative logistics solutions. To utilize new perspective market segments and markets. To optimize production and storage costs. #2 w 2-EH #2 w 2-EH 12% #2 w DEHT 12% #2 w DEHT 5% 5% 5. miejsce 5 th place 5. miejsce 5 th place w przeliczeniu na 2-EH i Butanole with reference to 2-EH i Butanole w przeliczeniu na DEHT, DINCH, DINP, DPHP with reference to DEHT, DINCH, DINP, DPHP

8 Azoty Grupa ZAK S.A. OUR ADVANTAGES High and repeatable quality of products product fatures and parameters customized to individual customer needs. Compettive sales conditions refl ecting current market situation and customer s type and field of application. Efficient and effective logistics employing all means of transportation available, satysfying specifi c requirements of each customer. Long-term co-operation perspective based on partnership and mutual under standing of needs. PRODUCTION PROCESS MAIN APPLICATIONS INDUSTRY n-butyraldehyde Propylene Aldehydes Aldehydes OXO Alcohols Plant Isobutyraldehyde 2-Ethylhexanol n-butanol Isobutanol Octyl alcohol F Plasticizers Oxoviflex Oxoplast Medica Oxoplast O Oxoplast PH PVC additive (for polymer flexibility), coatings, rubber products, glues, sealants Construction Shoe production Wire & cable Packaging Medical devices Synthesis gas Hydrogen Aldehydes OXO alcohols n-butyraldehyde Isobutyraldehyd MAIN APPLICATIONS INDUSTRY CH 4 O 2 H 2 Water Gas Shift Hydrogen Hydrogen PTA 2PH BKF Plasticizers Facility Oxoviflex Oxoplast Medica Oxoplast O Oxoplast PH Oxo Alcohols 2-Ethylhexanol n-butanol Isobutanol Octyl alcohol F Plasticizers Solvents Acrylates Acetates Fuel additives Plasticizers Paints and varnishes Glues Fuels

9 Oxoviflex Oxoplast Medica Oxoviflex bis(2-ethylhexyl) terephthalate CAS: Status REACH: DEHT registered 06/09/2012 Oxoplast Medica bis(2-ethylhexyl) phthalate CAS: Status REACH: DPHP registered 20/09/2010 PLASTICIZERS Oxoplast Medica is our response to medical grade PVC processing where highest quality and extra safety is required especially for blood bags manufacturing. Oxoplast Medica fulfils strict safety standards of European pharmacopeia and is certifi ed for its quality. Oxoplast Medica do not apply to registration according to EC regulation No. 1907/2006 because of its special application fi eld. PLASTICIZERS Oxoviflex is our response to growing interest in nonphathalate plasticizers. It has been positively tested for usage in food packaging and child toys according to European regulation. Oxoviflex formulation is based on our 2-EH OXO alcohol and PTA which is also used in PET bottles manufacturing. Oxoviflex is completely safe in terms of CLP classifi cation and in most cases it can substitute phthalate plasticizers. Oxoviflex is REACH registered according to EC regulation No. 1907/2006. Specification Value Test Colour, Pt-Co scale max. 30 [ Hz] DIN ISO 6271 Flash point min. 206 [ C] ISO 2592 Volatile matter content (150 C/2 h) max. 0.4 [wt %] ZAK s internal Oxoplast Medica is our response to medical grade PVC processing Esters as di(2-ethylhexyl) phthalate min [wt %] ISO 1385/V Technical Gases Specification Value Test Colour, Pt-Co scale <20 max. [ Hz] 20 [ Hz] ISO DIN 6271 ISO 6271 Flash point 230 min. 230 [ C] [ C] ISO 2592 Volatile matter content (150 C/2 (150 C/2 h) h) <0.20 max [% m/m] [wt %] Bis(2-ethylhexyl) terephthalate 98.0 min [% m/m] [wt %] GC Density at 20 C min [g/cm [g/cm 3 ] 3 ] <0.985 max [g/cm [g/cm 3 ] 3 ] ZAK s internal Areometric Free acids as phthalic acid max. < [% m/m] [wt %] ISO 1385/IV Water content max. <0.1 [% 0.1 m/m] [wt %] ISO 760 Di(2-ethylhexyl) phthalate content min [wt %] GC Density at 20 C min [g/cm 3 ] max [g/cm 3 ] Areometric Free acids as phthalic acid max [wt %] ISO 1385/IV Water content max [wt %] ISO 760 Metals content Cd Sn Zn Ba Ca max. 0.1 [ppm] max. 1.0 [ppm] max. 10 [ppm] max. 1.0 [ppm] max. 10 [ppm] Absorbance (260 nm; water extract) max. 0.3 ICP-OES According to Ph. Eur. 8th Edition Technical Gases Textiles Reducing substances (water extract) max. 0.1 [ml] According to Ph. Eur. 8th Edition Te x ti les ex/

10 Oxoplast O Oxoplast PH Oxoplast O bis(2-ethylhexyl) phthalate CAS: REACH Status: DEHP registered 20/09/2010 Oxoplast PH bis(2-propylheptyl) phthalate CAS: REACH Status: DEHP registered 23/11/2010 PLASTICIZERS PLASTICIZERS Oxoplast O has the longest production history within our plasticizers portfolio. For our European customers we have initiated REACH authorisation process due to safety concerns risen by European regulation authorities. We aim at providing our customers with full legal safety towards employing Oxoplast O in their PVC processing and fi nal products. Oxoplast PH unique feature is low volatility thus it is highly recommended for high temperature applications such as automotive (cables, car interior trims). Oxoplast PH is also resistant to ambient conditions and suitable for roofi ng and exterior coatings. Oxoplast PH is REACH registered according to EC regulation No. 1907/2006. Oxoplast PH is a high molecular weight plasticizer (C10) used in PVC processing. Specification Value Test Specification Value Test Colour, Pt-Co scale max. 30 [ Hz] DIN ISO 6271 Colour, Pt-Co scale max. 30 [ Hz] DIN ISO 6271 Flash point min. 206 [ C] ISO 2592 Flash point min. 220 [ C] ISO 2592 Volatile matter content (150 C/2 h) max. 0.4 [wt %] ZAK s internal Volatile matter content (150 C/2 h) max. 0.4 [wt %] ZAK s internal Esters as di(2-ethylhexyl) phthalate min [wt %] ISO 1385/V Esters as bis(2-propylheptyl) phthalate min [wt %] ISO 1385/V Di(2-ethylhexyl) phthalate content min [wt %] GC Density at 20 C min [g/cm 3 ] max [g/cm 3 ] Areometric Density at 20 C min [g/cm 3 ] max [g/cm 3 ] Areometric Free acids as phthalic acid max [wt %] ISO 1385/IV Technical Gases Free acids as phthalic acid max [wt %] ISO 1385/IV Water content max. 0.1 [wt %] ISO 760 Te chnic al G ases Textiles Water content max [wt %] ISO 760 Text i les

11 2-Ethylhexanol n-butanol 2-Ethylhexanol 2-Ethylhexan-1-ol CAS: REACH Status: 2-Ethylhexanol registered 28/09/2010 n-butanol Butan-1-ol, n-butanol CAS: REACH Status: n-butanol registered 02/11/2010 OXO ALCOHOLS OXO ALCOHOLS 2-Ethylhexanol(2-EH) is our main OXO alcohol. It is produced according to strict process regime derived from our experience. We put an extra emphasis on its quality which is transferred to further processed products: plasticizers, acrylates, fuel additives (2-EHN) and other chemical products. It is manufactured according to highest quality standards which guarantees our customers that all requirements concerning its further processing to acrylates, acetates and solvents and other chemical substances are met. n-butanol s our second most important OXO alcohol. 2-EH is REACH registered according to EC regulation No. 1907/2006 N-butanol is REACH registered according to EC regulation No. 1907/2006 Specification Value Test Specification Value Test 2-Ethylhexanol min [wt %] GC n-butanol min [wt %] GC Colour, Pt-Co scale max. 5 [APHA] ISO 6271 Colour, Pt-Co scale max. 5 [APHA] ISO 6271 Density at 20 C min [g/cm 3 ] max [g/cm 3 ] Areometric Density at 20 C 1 min [g/cm 3 ] max [g/cm 3 ] Areometric Acids as acetic acid max [wt %] ASTM D 1613 Acids as acetic acid 1 max [wt %] ASTM D 1613 Aldehydes as 2-ethylhexanal max [wt %] BS 4583 Aldehydes as butanal 1 max [wt %] BS 4583 Technical Gases Water content max [wt %] ISO 12937:2000 Water content max [wt %] ISO 12937: These parameters are covered by the producer s guarantee, to be analysed in case of a claim only. Te chnic al G ases Textiles Text i les

12 Isobutanol Octyl alcohol F Isobutanol 2-Metylopropan-1-ol, Isobutanol CAS: REACH Status: Isobutanol registered 04/11/2010 Octyl alcohol F 1-Hexanol, 2-ethyl-, manuf. of, by-products from, distn. residues CAS: REACH Status: Octyl alcohol F registered 12/01/2012 OXO ALCOHOLS OXO ALCOHOLS Isobutanol is produced from our isobutrylaldehyde. Our product is mailny used as solvent in many appreciated brands of paints, varnishes and resins. Octyl alcohol F is a by-product of our 2-EH production process, nonetheless it is a sought additive in such branches as textiles, mining (fl otation agent), refi ning industry (fuel additive). Isobutanol is REACH registered according to EC regulation No. 1907/2006 Octyl alcohol F is REACH registered according to EC regulation No. 1907/2006 Specification Value Test Specification Value Test Isobutanol min [wt %] GC 2-Ethylhexanol max. 30 [wt %] GC Colour, Pt-Co scale max. 5 [APHA] ISO 6271 High molecular weight compounds (>C 8 ) min. 70 [wt %] GC Density at 20 C min [g/cm 3 ] max [g/cm 3 ] Areometric Acids as acetic acid max [wt %] ASTM D 1613 Aldehydes as butyraldehyde max [wt %] BS 4583 Water content max [wt %] ISO 12937:2000 Technical Gases Te chnic al G ases Textiles Text i les

13 Aldehydes n-butrylaldehyde Aldehydes Isobutyraldehyde n-butrylaldehyde n-butyraldehyde; n-butanal CAS: REACH Status: n-butrylaldehyde registered 07/10/2010 Isobutrylaldehyde Isobutanal; 2-methylpropanal CAS: REACH Status: Isobutyraldehyde registered 11/08/2010 ALDEHYDES ALDEHYDES N-butrylaldehyde is a main intermediate in our OXO alcohols (2-EH, NBA) production process. Owing to its high quality our alcohols are recognised as leading products on the market. Apart from captive usage we off er our aldehyde to customers who process it and produce solvents, esters, acids, resins, etc. N-butrylaldehyde is REACH registered according to EC regulation No. 1907/2006 We process it to isobutanol. With its specifi c proprieties isobutrylaldehyde is also used by our customers for production of resins, amines and specialty esters. Isobutrylaldehyde is REACH registered according to EC regulation No. 1907/2006 Isobutrylaldehyde is a second intermidiate in our OXO alcohols facility. Specification Value Test Specification Value Test Colour max. 15 [Pt-Co] ISO 6271 Colour max. 15 [Pt-Co] ISO 6271 Acid number max. 1 [mg KOH/g] ZAK s internal Acid number max. 2 [mg KOH/g] ZAK s internal Isobutyraldehyde content max. 0.1 [wt %] GC n-butyraldehyde, content max. 0.2* [wt %] GC Water content max. 0.2 [wt %] ISO 760 Water content max. 1.5 [wt %] ISO 760 n-butyraldehyde min [wt %] GC Isobutyraldehyde min. 99.5* [wt %] GC * These values give no consideration to the water content in the product. Technical Gases Te chnic al G ases Textiles Text i les

14 Azoty Grupa ZAK S.A. CONTACTS Grupa Azoty ZAK S.A. ul. Mostowa 30 A Kędzierzyn-Koźle Poland tel.: [email protected] Oxoplast BU Commercial Director Agnieszka Kurpińska tel.: fax: [email protected] Sales Manager Western Europe & World Waldemar Pawelczyk tel.: fax: [email protected] Sales Manager Poland & Central Eastern Europe Jolanta Kamys tel.: fax: [email protected] Sales Manager Southern Europe & World Monika Urbańczyk tel.: fax: [email protected]