: C1 - C8 in Balance Nitrogen

Transcription

1 50231 Date of issue: 10/02/2014 Revision date: 10/02/2014 Version: 1.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Product name Product code : Mixture : C1 - C8 in Balance Nitrogen : StG 4.02.CTA Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Test gas/calibration gas Details of the supplier of the safety data sheet Calgaz, division of Air Liquide 821 Chesapeake Drive Cambridge, USA T F [email protected] Emergency telephone number Emergency number : CHEMTREC: Internationally: SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Compressed gas H Label elements GHS-US labeling Hazard pictograms (GHS-US) : Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) GHS04 : Warning : H280 - Contains gas under pressure; may explode if heated : P202 - Do not handle until all safety precautions have been read and understood P271 - Use only outdoors or in a well-ventilated area P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing P313 - Get medical advice/attention CGA-PG05 - Use a back flow preventive device in the piping CGA-PG21 - Open valve slowly CGA-PG06 - Close valve after each use and when empty CGA-PG10 - Use only with equipment rated for cylinder pressure CGA-PG14 - Approach suspected leak area with caution CGA-PG02 - Protect from sunlight when ambient temperature exceeds 52 C (125 F) P403 - Store in a well-ventilated place 2.3. Other hazards No additional information available 2.4. Unknown acute toxicity (GHS-US) No data available SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Classification (GHS-US) Nitrogen (CAS No) Compressed gas, H280 10/02/2014 EN (English US) SDS ID: Page 1

2 Name Product identifier % Classification (GHS-US) Methane (CAS No) Flam. Gas 1, H220 Compressed gas, H280 Ethane (CAS No) Flam. Gas 1, H220 Compressed gas, H280 Propane (CAS No) Flam. Gas 1, H220 Liquefied gas, H280 Isobutane (CAS No) Liquefied gas, H280 Butane (CAS No) Liquefied gas, H280 Isopentane (CAS No) Flam. Liq. 1, H224 STOT SE 3, H336 Asp. Tox. 1, H304 Aquatic Chronic 2, H411 Pentane (CAS No) Flam. Liq. 2, H225 STOT SE 3, H336 Asp. Tox. 1, H304 Hexane (CAS No) Flam. Liq. 2, H225 Skin Irrit. 2, H315 Repr. 2, H361 STOT SE 3, H336 STOT RE 2, H373 Asp. Tox. 1, H304 Aquatic Chronic 2, H411 n-heptane (CAS No) Flam. Liq. 2, H225 Skin Irrit. 2, H315 STOT SE 3, H336 Asp. Tox. 1, H304 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Octane (CAS No) Flam. Liq. 2, H225 Skin Irrit. 2, H315 Eye Irrit. 2B, H320 Asp. Tox. 1, H304 Benzene (CAS No) Flam. Liq. 2, H225 Acute Tox. 4 (Oral), H302 Carc. 1A, H350 TOLUENE (CAS No) Flam. Liq. 2, H225 Acute Tox. 4 (Oral), H302 Cyclohexane (CAS No) Flam. Liq. 2, H225 Skin Irrit. 2, H315 STOT SE 3, H336 Asp. Tox. 1, H304 Methylcyclohexane (CAS No) Flam. Liq. 2, H225 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Remove to fresh air and keep at rest in a position comfortable for breathing. If you feel unwell, seek medical advice. : Ingestion is not considered a potential route of exposure Most important symptoms and effects, both acute and delayed Symptoms/injuries Symptoms/injuries after inhalation : May displace oxygen and cause rapid suffocation. Symptoms/injuries after skin contact Symptoms/injuries after eye contact Symptoms/injuries after ingestion : Ingestion is not considered a potential route of exposure. Symptoms/injuries upon intravenous : Not known. administration Chronic symptoms 4.3. Indication of any immediate medical attention and special treatment needed If you feel unwell, seek medical advice. If breathing is difficult, give oxygen. 10/02/2014 EN (English US) SDS ID: /16

3 SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Use extinguishing media appropriate for surrounding fire. : Do not use water jet Special hazards arising from the substance or mixture Fire hazard : The product is not flammable. Explosion hazard : Product is not explosive. Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of burns and injuries. Reactivity : None known Advice for firefighters Firefighting instructions Protection during firefighting : In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. : Standard protective clothing and equipment (e.g., Self Contained Breathing Apparatus) for fire fighters. Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Ensure adequate ventilation For non-emergency personnel Protective equipment Emergency procedures For emergency responders Protective equipment Emergency procedures : Wear protective equipment consistent with the site emergency plan. : Escape the danger area by the closest safe route. Close doors and windows of adjacent premises. Keep containers closed. Mark the danger area. Seal off low-lying areas. Keep upwind. : Standard protective clothing and equipment (e.g., Self Contained Breathing Apparatus) for fire fighters. Equip cleanup crew with proper protection. : Evacuate and limit access. Ventilate area Environmental precautions Try to stop release if safe to do so Methods and material for containment and cleaning up For containment : Try to stop release if safe to do so. Methods for cleaning up : Dispose of this material and its container in accordance with local regulations Reference to other sections See also Sections 8 and 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed Precautions for safe handling Safe handling of the gas receptacle Safe use of the product Hygiene measures : Pressurized container: Do not pierce or burn, even after use. Use equipment rated for cylinder pressure. : Do not handle until all safety precautions have been read and understood. Use only outdoors or in a well-ventilated area. : Protect cylinders from physical damage; do not drag, roll, slide or drop. Do not remove or deface labels provided by the supplier for the identification of the cylinder contents. : Only experienced and properly instructed persons should handle gases under pressure. Use only properly specified equipment which is suitable for this product, its supply pressure and temperature. Contact your gas supplier if in doubt. : Do not eat, drink or smoke when using this product Conditions for safe storage, including any incompatibilities Technical measures : Comply with applicable regulations. Storage conditions : Do not expose to temperatures exceeding 52 C (125 F). Keep container closed when not in use. Protect cylinder from physical damage. Store in well ventilated area. Incompatible products : None known. Incompatible materials : None known. Storage area : Store away from heat. Store in a well-ventilated place. 10/02/2014 EN (English US) SDS ID: /16

4 7.3. Specific end use(s) Test gas/calibration gas. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Methane ( ) USA ACGIH ACGIH TWA (ppm) 1000 ppm Ethane ( ) USA ACGIH ACGIH TWA (ppm) 1000 ppm Propane ( ) USA ACGIH ACGIH TWA (ppm) 1000 ppm USA OSHA OSHA PEL (TWA) (mg/m³) 1800 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 1000 ppm Isobutane ( ) USA ACGIH ACGIH STEL (ppm) 1000 ppm Butane ( ) USA ACGIH ACGIH STEL (ppm) 1000 ppm Isopentane ( ) USA ACGIH ACGIH TWA (ppm) 600 ppm USA ACGIH ACGIH TWA (ppm) 0.5 ppm USA ACGIH ACGIH STEL (ppm) 2.5 ppm USA OSHA OSHA PEL (TWA) (ppm) 1 ppm USA OSHA OSHA PEL (STEL) (ppm) 5 ppm (see 29 CFR ) USA OSHA OSHA PEL (Ceiling) (ppm) 25 ppm USA ACGIH ACGIH TWA (ppm) 20 ppm USA OSHA OSHA PEL (TWA) (ppm) 200 ppm USA OSHA OSHA PEL (Ceiling) (ppm) 300 ppm Nitrogen ( ) Pentane ( ) USA ACGIH ACGIH TWA (ppm) 600 ppm USA OSHA OSHA PEL (TWA) (mg/m³) 2950 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 1000 ppm Hexane ( ) USA ACGIH ACGIH TWA (ppm) 50 ppm USA OSHA OSHA PEL (TWA) (mg/m³) 1800 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 500 ppm Octane ( ) USA ACGIH ACGIH TWA (ppm) 300 ppm USA OSHA OSHA PEL (TWA) (mg/m³) 2350 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 500 ppm 10/02/2014 EN (English US) SDS ID: /16

5 USA ACGIH ACGIH TWA (ppm) 100 ppm USA OSHA OSHA PEL (TWA) (mg/m³) 1050 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 300 ppm Methylcyclohexane ( ) USA ACGIH ACGIH TWA (ppm) 400 ppm USA OSHA OSHA PEL (TWA) (mg/m³) 2000 mg/m³ USA OSHA OSHA PEL (TWA) (ppm) 500 ppm 8.2. Exposure controls Appropriate engineering controls : Provide adequate general and local exhaust ventilation. Systems under pressure should be regularly checked for leakages. Ensure exposure is below occupational exposure limits. Oxygen detectors should be used when asphyxiating gases may be released. Consider work permit system e.g. for maintenance activities. : Wear working gloves when handling gas containers. 29CFR : Hand Protection. : Wear safety glasses with side shields. 29 CFR : Eye and Face Protection. : Wear suitable protective clothing, e.g. - lab coats, coveralls or flame resistant clothing. Hand protection Eye protection Skin and body protection Respiratory protection : None necessary during normal and routine operations. See sections 5 & 6. Thermal hazard protection : None necessary during normal and routine operations. Environmental exposure controls : Refer to local regulations for restriction of emissions to the atmosphere. See section 13 for specific methods for waste gas treatment. Other information SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Gas Appearance : Clear, colorless gas. Molecular mass : Not applicable for gas-mixtures. Color : Colorless Odor : odorless Odor threshold ph : Not applicable for gas-mixtures. Relative evaporation rate (butyl acetate=1) Relative evaporation rate (ether=1) : Not applicable for gas-mixtures. Melting point Freezing point Boiling point Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) : Not applicable - not flammable Vapor pressure Relative vapor density at 20 C Relative density : Wear safety shoes while handling containers. 29 CFR : Foot Protection. : Not applicable. Relative gas density : Lighter or similar to air. Solubility : Water: Solubility in water of component(s) of the mixture : : 26 mg/l : 61 mg/l : 75 mg/l : 54 mg/l : Insoluble : 48 mg/l : 1.8 mg/l : 515 mg/l : 20 mg/l : < 1 mg/l : Insoluble : Insoluble : Insoluble : Insoluble Log Pow Log Kow Viscosity, kinematic Viscosity, dynamic Explosive properties : Not applicable for gas-mixtures. : Not applicable for gas-mixtures. : Not applicable. : Not applicable. : Not applicable - not flammable. 10/02/2014 EN (English US) SDS ID: /16

6 Oxidizing properties Explosive limits 9.2. Other information Additional information : None. : Not applicable - not flammable : None. SECTION 10: Stability and reactivity Reactivity None known Chemical stability Stable under normal conditions Possibility of hazardous reactions None known Conditions to avoid None under recommended storage and handling conditions (see section 7) Incompatible materials None known Hazardous decomposition products Under normal conditions of storage and use hazardous decomposition products should not be produced. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Methane ( ) ATE US (gases) Ethane ( ) LC50 inhalation rat (mg/l) ATE US (gases) ATE US (vapors) ATE US (dust, mist) Propane ( ) LC50 inhalation rat (mg/l) ATE US (gases) ATE US (vapors) ATE US (dust, mist) Isobutane ( ) LC50 inhalation rat (mg/l) ATE US (gases) ATE US (vapors) ATE US (dust, mist) ppm/4h ppmv/4h 658 mg/l/4h ppm/4h ppmv/4h mg/l/4h mg/l/4h 658 mg/l/4h ppm/4h ppmv/4h mg/l/4h mg/l/4h 658 mg/l/4h ppm/4h ppmv/4h mg/l/4h mg/l/4h Butane ( ) LC50 inhalation rat (mg/l) 658 g/m³ (Exposure time: 4 h) ppm/4h ATE US (gases) ppmv/4h ATE US (vapors) mg/l/4h ATE US (dust, mist) mg/l/4h LD50 oral rat 930 mg/kg 10/02/2014 EN (English US) SDS ID: /16

7 ATE US (oral) ATE US (gases) LD50 oral rat LD50 dermal rabbit LC50 inhalation rat (mg/l) ATE US (oral) ATE US (dermal) ATE US (vapors) ATE US (dust, mist) Nitrogen ( ) ppm/4h mg/kg body weight ppmv/4h 636 mg/kg 8390 mg/kg 12.5 mg/l/4h mg/kg body weight mg/kg body weight mg/l/4h mg/l/4h ppm/4h Pentane ( ) LD50 dermal rabbit 3000 mg/kg LC50 inhalation rat (mg/l) 364 g/m³ (Exposure time: 4 h) ppm/4h ATE US (dermal) mg/kg body weight ATE US (gases) ppmv/4h ATE US (vapors) mg/l/4h ATE US (dust, mist) mg/l/4h Hexane ( ) LD50 dermal rabbit ATE US (dermal) ATE US (gases) 3000 mg/kg ppm/4h mg/kg body weight ppmv/4h Octane ( ) LC50 inhalation rat (mg/l) 118 g/m³ (Exposure time: 4 h) ATE US (vapors) mg/l/4h ATE US (dust, mist) mg/l/4h LD50 oral rat LD50 dermal rabbit LC50 inhalation rat (mg/l) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity IARC group National Toxicity Program (NTP) Status IARC group Reproductive toxicity Specific target organ toxicity (single exposure) > 5000 mg/kg > 2000 mg/kg 13.9 mg/l/4h ph: Not applicable for gas-mixtures. ph: Not applicable for gas-mixtures. 1 - Carcinogenic to humans 1 - Evidence of Carcinogenicity, 2 - Known Human Carcinogens 3 - Not classifiable 10/02/2014 EN (English US) SDS ID: /16

8 Specific target organ toxicity (repeated exposure) Aspiration hazard Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact Symptoms/injuries after ingestion Symptoms/injuries upon intravenous administration Chronic symptoms SECTION 12: Ecological information Toxicity Ecology - general Isopentane ( ) EC50 Daphnia 1 LC50 fish 1 EC50 Daphnia 1 EC50 other aquatic organisms 1 LC50 fish 2 EC50 Daphnia 2 LC50 fish 1 EC50 Daphnia 1 EC50 other aquatic organisms 1 LC50 fish 2 EC50 Daphnia 2 EC50 other aquatic organisms 2 Pentane ( ) LC50 fish 1 EC50 Daphnia 1 LC50 fish 2 Hexane ( ) LC50 fish 1 Octane ( ) EC50 Daphnia 1 LC50 fish 1 EC50 other aquatic organisms 1 LC50 fish 2 No known effects from this product. Not applicable for gases and gas-mixtures. : May displace oxygen and cause rapid suffocation. : Ingestion is not considered a potential route of exposure. : Not known. : Classification criteria are not met. 2.3 mg/l (Exposure time: 48 h - Species: Daphnia magna) mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through]) mg/l (Exposure time: 48 h - Species: Daphnia magna [Static]) 29 mg/l (Exposure time: 72 h - Species: Pseudokirchneriella subcapitata) 5.3 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [flow-through]) 10 mg/l (Exposure time: 48 h - Species: Daphnia magna) mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through]) mg/l (Exposure time: 48 h - Species: Daphnia magna [Static]) > 433 mg/l (Exposure time: 96 h - Species: Pseudokirchneriella subcapitata) 12.6 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static]) 11.5 mg/l (Exposure time: 48 h - Species: Daphnia magna) 12.5 mg/l (Exposure time: 72 h - Species: Pseudokirchneriella subcapitata [static]) 9.87 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss) 9.74 mg/l (Exposure time: 48 h - Species: Daphnia magna) mg/l (Exposure time: 96 h - Species: Pimephales promelas) mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through]) 0.38 mg/l (Exposure time: 48 h - Species: water flea) mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through]) > 500 mg/l (Exposure time: 72 h - Species: Desmodesmus subspicatus) mg/l (Exposure time: 96 h - Species: Pimephales promelas [static]) Persistence and degradability C1 - C8 in Balance Nitrogen Persistence and degradability Methane ( ) Persistence and degradability Ethane ( ) Persistence and degradability Propane ( ) Persistence and degradability The substance is biodegradable. Unlikely to persist. The substance is biodegradable. Unlikely to persist. The substance is biodegradable. Unlikely to persist. 10/02/2014 EN (English US) SDS ID: /16

9 Isobutane ( ) Persistence and degradability Butane ( ) Persistence and degradability Isopentane ( ) Persistence and degradability Nitrogen ( ) Persistence and degradability The substance is biodegradable. Unlikely to persist. No ecological damage caused by this product Bioaccumulative potential C1 - C8 in Balance Nitrogen Log Pow Log Kow Bioaccumulative potential Not applicable for gas-mixtures. Not applicable for gas-mixtures. Methane ( ) Log Pow 1.09 Log Kow Not applicable for gas-mixtures. Bioaccumulative potential Not expected to bioaccumulate due to the low log Kow (log Kow < 4). Refer to section 9. Ethane ( ) Log Pow 1.81 Bioaccumulative potential Not expected to bioaccumulate due to the low log Kow (log Kow < 4). Refer to section 9. Propane ( ) Log Pow 2.36 Bioaccumulative potential Not expected to bioaccumulate due to the low log Kow (log Kow < 4). Refer to section 9. Isobutane ( ) BCF fish Log Pow 2.76 Bioaccumulative potential Not expected to bioaccumulate due to the low log Kow (log Kow < 4). Refer to section 9. Butane ( ) Log Pow 2.89 Log Kow Not applicable for gas-mixtures. Bioaccumulative potential Not expected to bioaccumulate due to the low log Kow (log Kow < 4). Refer to section 9. Isopentane ( ) Log Pow Log Kow Not applicable for gas-mixtures. Bioaccumulative potential BCF fish Log Pow 1.83 Log Pow 2.65 Nitrogen ( ) Log Pow Bioaccumulative potential Not applicable for inorganic gases. No ecological damage caused by this product. Pentane ( ) Log Pow 3.39 Octane ( ) Log Pow 5.18 Log Pow /02/2014 EN (English US) SDS ID: /16

10 12.4. Mobility in soil C1 - C8 in Balance Nitrogen Mobility in soil Methane ( ) Mobility in soil Ecology - soil Ethane ( ) Ecology - soil Propane ( ) Ecology - soil Isobutane ( ) Ecology - soil Butane ( ) Mobility in soil Ecology - soil Isopentane ( ) Mobility in soil Nitrogen ( ) Ecology - soil Other adverse effects Effect on ozone layer Effect on the global warming Because of its high volatility, the product is unlikely to cause ground or water pollution. Because of its high volatility, the product is unlikely to cause ground or water pollution. Because of its high volatility, the product is unlikely to cause ground or water pollution. Because of its high volatility, the product is unlikely to cause ground or water pollution. Because of its high volatility, the product is unlikely to cause ground or water pollution. No ecological damage caused by this product. : None. : Contains greenhouse gas(es) not covered by 842/2006/EC. SECTION 13: Disposal considerations Waste treatment methods Waste treatment methods Waste disposal recommendations SECTION 14: Transport information In accordance with DOT Transport document description : UN1956 Compressed gas, n.o.s. (Nitrogen) UN-No.(DOT) : 1956 DOT NA no. : UN1956 DOT Proper Shipping Name : Compressed gas, n.o.s. (Nitrogen) Hazard labels (DOT) : Non-flammable gas : Contact supplier if guidance is required. Do not discharge into any place where its accumulation could be dangerous. Ensure that the emission levels from local regulations or operating permits are not exceeded. : Refer to the CGA Pamphlet P-63 "Disposal of Gases" available at for more guidance on suitable disposal methods. DOT Symbols : G - Identifies PSN requiring a technical name DOT Packaging Exceptions (49 CFR 173.xxx) : 306;307 DOT Packaging Non Bulk (49 CFR 173.xxx) : 302;305 DOT Packaging Bulk (49 CFR 173.xxx) : 314;315 DOT Quantity Limitations Passenger aircraft/rail : 75 kg (49 CFR ) DOT Quantity Limitations Cargo aircraft only (49 : 150 kg CFR ) 10/02/2014 EN (English US) SDS ID: /16

11 DOT Vessel Stowage Location Additional information Other information Special transport precautions : A - The material may be stowed on deck or under deck on a cargo vessel and on a passenger vessel. : No supplementary information available. : Avoid transport on vehicles where the load space is not separated from the driver's compartment. Ensure vehicle driver is aware of the potential hazards of the load and knows what to do in the event of an accident or an emergency. Before transporting product containers: - Ensure there is adequate ventilation. - Ensure that containers are firmly secured. - Ensure cylinder valve is closed and not leaking. - Ensure valve outlet cap nut or plug (where provided) is correctly fitted. - Ensure valve protection device (where provided) is correctly fitted. ADR Transport document description : UN 1956 COMPRESSED GAS, N.O.S., 2.2 Class (ADR) : 2 - Gases Hazard labels (ADR) : Non-flammable compressed gas Transport by sea UN-No. (IMDG) : 1956 Proper Shipping Name (IMDG) : COMPRESSED GAS, N.O.S. Class (IMDG) : Non-flammable, non-toxic gases Air transport UN-No.(IATA) : 1956 Proper Shipping Name (IATA) : COMPRESSED GAS, N.O.S. Class (IATA) : 2 SECTION 15: Regulatory information US Federal regulations Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on United States SARA Section 313 SARA Section Emission Reporting 0.1 % Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on United States SARA Section 313 SARA Section Emission Reporting 1.0 % Pentane ( ) Listed on the United States TSCA (Toxic Substances Control Act) inventory EPA TSCA Regulatory Flag Hexane ( ) Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on United States SARA Section 313 SARA Section Emission Reporting 1.0 % T - T - indicates a substance that is the subject of a Section 4 test rule under TSCA. Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on United States SARA Section 313 EPA TSCA Regulatory Flag T - T - indicates a substance that is the subject of a Section 4 test rule under TSCA. SARA Section Emission Reporting 1.0 % International regulations CANADA 10/02/2014 EN (English US) SDS ID: /16

12 Methane ( ) Class A - Compressed Gas Class B Division 1 - Flammable Gas Ethane ( ) Class A - Compressed Gas Class B Division 1 - Flammable Gas Propane ( ) Class A - Compressed Gas Class B Division 1 - Flammable Gas Isobutane ( ) Class A - Compressed Gas Class B Division 1 - Flammable Gas Butane ( ) Class A - Compressed Gas Class B Division 1 - Flammable Gas Isopentane ( ) Class B Division 2 - Flammable Liquid Class B Division 2 - Flammable Liquid Class D Division 2 Subdivision A - Very toxic material causing other toxic effects Class D Division 2 Subdivision B - Toxic material causing other toxic effects Class B Division 2 - Flammable Liquid Class D Division 2 Subdivision A - Very toxic material causing other toxic effects Class D Division 2 Subdivision B - Toxic material causing other toxic effects Nitrogen ( ) Class A - Compressed Gas Pentane ( ) Class B Division 2 - Flammable Liquid Hexane ( ) Class B Division 2 - Flammable Liquid Class D Division 2 Subdivision A - Very toxic material causing other toxic effects Class D Division 2 Subdivision B - Toxic material causing other toxic effects Octane ( ) Class B Division 2 - Flammable Liquid Class D Division 2 Subdivision B - Toxic material causing other toxic effects Class B Division 2 - Flammable Liquid Class D Division 2 Subdivision B - Toxic material causing other toxic effects 10/02/2014 EN (English US) SDS ID: /16

13 Methylcyclohexane ( ) EU-Regulations Class B Division 2 - Flammable Liquid Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances) Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances) Hexane ( ) Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances) Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances) Classification according to Regulation (EC) No. 1272/2008 [CLP] Not classified Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] National regulations Listed on IARC (International Agency for Research on Cancer) Listed on AICS (Australian Inventory of Chemical Substances) Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China) Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory Listed on the Korean ECL (Existing Chemicals List) Listed on NZIoC (New Zealand Inventory of Chemicals) Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances) Japanese Pollutant Release and Transfer Register Law (PRTR Law) Listed as carcinogen on NTP (National Toxicology Program) Listed on the Canadian IDL (Ingredient Disclosure List) Listed on AICS (Australian Inventory of Chemical Substances) Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China) Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory Listed on the Korean ECL (Existing Chemicals List) Listed on NZIoC (New Zealand Inventory of Chemicals) Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances) Japanese Poisonous and Deleterious Substances Control Law Japanese Pollutant Release and Transfer Register Law (PRTR Law) Listed on the Canadian IDL (Ingredient Disclosure List) Hexane ( ) Listed on AICS (Australian Inventory of Chemical Substances) Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China) Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory Listed on the Korean ECL (Existing Chemicals List) Listed on NZIoC (New Zealand Inventory of Chemicals) Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances) Japanese Pollutant Release and Transfer Register Law (PRTR Law) Listed on the Canadian IDL (Ingredient Disclosure List) Listed on AICS (Australian Inventory of Chemical Substances) Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China) Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory Listed on the Korean ECL (Existing Chemicals List) Listed on NZIoC (New Zealand Inventory of Chemicals) Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances) Listed on the Canadian IDL (Ingredient Disclosure List) US State regulations 10/02/2014 EN (English US) SDS ID: /16

14 U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female Yes Yes Yes U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significance risk level (NSRL) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female Yes U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significance risk level (NSRL) Yes Methane ( ) Ethane ( ) Propane ( ) Isobutane ( ) Butane ( ) Isopentane ( ) U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List U.S. - Pennsylvania - RTK (Right to Know) - Special Hazardous Substances U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List Nitrogen ( ) Pentane ( ) 10/02/2014 EN (English US) SDS ID: /16

15 Pentane ( ) Hexane ( ) Octane ( ) U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List Methylcyclohexane ( ) SECTION 16: Other information Indication of changes : Revised safety data sheet in accordance with OSHA final rule on GHS implementation promulgated March 26, Revision date : 10/02/2014 Other information : This is offered pursuant to OSHA s Hazard Communication Standard, 29 CFR, Other government regulations must be reviewed for applicability to this product. Full text of H-phrases: see section 16: Acute Tox. 4 (Oral) Acute toxicity (oral) Category Aquatic Acute 1 Hazardous to the aquatic environment - Acute Hazard Category Aquatic Chronic 1 Hazardous to the aquatic environment - Chronic Hazard Category Aquatic Chronic 2 Hazardous to the aquatic environment - Chronic Hazard Category Asp. Tox. 1 Aspiration hazard Category Carc. 1A Carcinogenicity Category 1A Compressed gas Gases under pressure Compressed gas Eye Irrit. 2B Serious eye damage/eye irritation Category 2B Flam. Gas 1 Flammable gases Category Flam. Liq. 1 Flammable liquids Category Flam. Liq. 2 Flammable liquids Category Liquefied gas Gases under pressure Liquefied gas Repr. 2 Reproductive toxicity Category Skin Irrit. 2 Skin corrosion/irritation Category STOT RE 2 Specific target organ toxicity (repeated exposure) Category STOT SE 3 Specific target organ toxicity (single exposure) Category H220 Extremely flammable gas H224 Extremely flammable liquid and vapor H225 Highly flammable liquid and vapor H280 Contains gas under pressure; may explode if heated H302 Harmful if swallowed H304 May be fatal if swallowed and enters airways H315 Causes skin irritation H320 Causes eye irritation H336 May cause drowsiness or dizziness H350 May cause cancer H361 Suspected of damaging fertility or the unborn child H373 May cause damage to organs through prolonged or repeated exposure H400 Very toxic to aquatic life 10/02/2014 EN (English US) SDS ID: /16

16 H410 Very toxic to aquatic life with long lasting effects H411 Toxic to aquatic life with long lasting effects SDS US (GHS HazCom 2012) This is offered pursuant to OSHA's Hazard Communication Standard, 29 CFR, Other government regulations must be reviewed for applicability to this gas mixture. To the best of Calgaz's knowledge, the information contained herein is reliable and accurate as of this date; however, accruacy, suitability or completeness are not guaranteed and no warranties of any type, either express or implied, are provided. The information contained herein relates only to this specific product. If this gas mixture is combined with other materials, all component properties must be considered. Data may be changed from time to time. Be sure to consult the latest edition. 10/02/2014 EN (English US) SDS ID: /16