PRODUCT SAFETY DATA SHEET

Transcription

1 PRODUCT SAFETY DATA SHEET 1. PRODUCT AND COMPANY IDENTIFICATION Page 1 of 9 Commercial Product Name: Recommended use Mortein Low Irritant Odourless Mozzie Zapper Insecticide Insecticide mat Supplier: AUSTRALIA Reckitt Benckiser (Australia) Pty Limited 44 Wharf Road, West Ryde NSW 2114 TEL: (02) NEW ZEALAND Reckitt Benckiser (New Zealand) Limited 2 Fred Thomas Drive, Takapuna, Auckland 0622 TEL: Manufacturer: Reckitt Benckiser (Malaysia) Sdn Bhd LOT PLO 141 Jalan Angkasa Mas Utama, Kawasan Perindustrian Tebrau 2 Mukim Tebrau, Johor Bahru Johor, Malaysia TEL: / 4941 Emergency Telephone Number: After Hours (5 pm to 8 am EST Australia): +61 (02) POISONS CENTRE INFORMATION Australia New Zealand or 0800 POISON Australian Business Number (ABN):

2 2. HAZARDS IDENTIFICATION Page 2 of 9 Non-Hazardous Substance According to Criteria of NOHSC Australia Not classified as dangerous goods according to the ADG Code. Risk Combination Phrases S -phrase(s) Safety Combination Phrases R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment S 2 - Keep out of the reach of children S13 - Keep away from food, drink and animal feedingstuffs S35 - This material and its container must be disposed of in a safe way S46 - If swallowed, seek medical advice immediately and show this container or label S61 - Avoid release to the environment. Refer to special instructions/safety data sheets S24/25 - Avoid contact with skin and eyes 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS-No Proportion (% w /w ) Cellulose fiber PROPRIETARY > 60 % Isopropyl myristate < 10 % d-allethrin < 10 % Paraffins (petroleum), normal C < 10 % Butylated hydroxytoluene < 1 % Other ingredients: The other ingredients to 100%w /w are classified as not hazardous according to NOHSC (Australia) 4. FIRST AID MEASURES General Advice For advice, contact a Poisons lnformation Centre (Phone eg Australia ; New Zealand ) or a doctor. Skin Contact Eye Contact Inhalation Ingestion Notes to Physician Wash skin with soap and water. Get medical attention if irritation develops and persists. Do not rub affected area. Flush eyes with water as a precaution. If symptoms develop or persist, call a physician. Move to fresh air. If breathing difficulties are experienced, contact a doctor.. Clean mouth with water and afterwards drink plenty of water. Call a doctor or Poisons Control Centre. Treat symptomatically

3 5. FIRE-FIGHTING MEASURES Page 3 of 9 Flash point: Suitable Extinguishing Media: Precautions for fire-fighting Not flammable. Water. Foam. Carbon dioxide (CO2). Standard procedure for chemical fires. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Environmental Precautions: Methods for Cleaning up: Ensure adequate ventilation. Do not let product enter drains or natural waterways. Sweep up and shovel into suitable containers for disposal 7. HANDLING AND STORAGE Handling: Storage: Avoid contact with skin and eyes. Wash hands after handling. No special technical protective measures required. Keep cool and protect from sunlight 8. EXPOSURE CONTROLS / PERSONAL PROTECTION National Exposure Standards: Exposure Standards have been set for the following ingredients: Chemical Name Australian Workplace Exposure Standards New Zealand Workplace Exposure Standards Butylated hydroxytoluene TWA: 10 mg/m3 TWA: 10 mg/m3 TWA - The Time-Weighted Average airborne concentration over an eight-hour w orking day, for a five-day w orking w eek over an entire w orking life. According to current know ledge this concentration should neither impair the health or, not cause undue discomfort to, nearly all w orkers. STEL (Short Term Exposure Limit) the average airborne concentration over a 15 minute period w hich should not be exceeded at any time during a normal eight hour w ork day. According to current know ledge this concentration should neither impair the health or, not cause undue discomfort to, nearly all w orkers Biological Limit Values Engineering Controls: Personal Protection Eye Protection: Hand Protection: Skin and Body Protection: Respiratory Protection: Hygiene Measures: No biological limit values allocated. Ensure adequate ventilation. Maintain air concentrations below exposure standards. Use the following personal protective equipment when handling bulk quantities of product: Safety glasses. Wear suitable gloves In case of continuous exposure or occupational operations, wear lightweight protective clothing. In case of insufficient ventilation wear suitable respiratory equipment Handle in accordance with good industrial hygiene and safety practice.

4 9. PHYSICAL AND CHEMICAL PROPERTIES Page 4 of 9 Physical State: Appearance: Colour: Odour: ph Solid. Mat Blue Odorless. Vapour pressure: Boiling Point/Range: <0.43 C (solvent) Not applicable Solubility: Water solubility: immiscible. Specific Gravity / Density [g/ml]: at 25 C(concentrate) Flash Point: Not Flammable 10. STABILITY AND REACTIVITY Stability Conditions to Avoid: Hazardous Decomposition Products: Polymerization: Stable under normal conditions. None known. Carbon oxides..

5 11. TOXICOLOGICAL INFORMATION Page 5 of 9 PRODUCT TOXICITY DATA LD50 Oral: LD50 Dermal: LC50 Inhalation (Dust): LC50 Inhalation (Vapor): ACUTE EFFECTS Eye Irritation: Skin Irritation Inhalation Ingestion: Sensitization CHRONIC EFFECTS None expected during normal conditions of use. May cause skin irritation. None expected during normal conditions of use. May cause abdominal discomfort if swallowed. May be harmful. Not expected to be a skin sensitiser.. The chronic toxicity of this product has not been determined. SPECIFIC EFFECTS Carcinogenic Effects: Mutagenic Effects Reproductive Toxicity: Additional Toxicity Information: Not listed as carcinogenic by OSHA, NTP or IARC... Information is based on available component data. COMPONENT TOXICITY DATA Chemical Name CAS-No LD50 Oral - w ith units - Rat - mg/kg LD50 Dermal - With Units - Rat/Rabbit - mg/kg LC50 Inhalation - With units - Rat/Rabbit Isopropyl myristate mg/kg ( Rat ) 5000 mg/kg ( Rabbit ) 41 mg ( Rat ) d-allethrin mg/kg ( Rat ) mg/kg ( Rabbit ) Butylated hydroxytoluene mg/kg ( Rat ) Chemical Name CAS-No Eye Irritation Sensitization Skin Irritation d-allethrin Eye - Non-irrittating (rabbit) Skin - Non-irritating (rabbit) Butylated hydroxytoluene Eye irritation rabbit: 100mg/24 hr moderately irritating. Skin irritation rabbit: 500mg/48 hr moderately irritating.

6 12. ECOLOGICAL INFORMATION Page 6 of 9 PRODUCT TOXICITY DATA The ecotoxicity of this product has not been determined. However, the following component information is available. COMPONENT TOXICITY DATA Isopropyl myristate Freshwater Algae Freshwater Fish Water Flea d-allethrin Daphnia Fish (Other) EC50 72 h >100 mg/l LC50 96 h Brachydanio rerio 8400 mg/l EC50 48 h 100 mg/l LC50 (48 h): mg/l Acute toxicity, LC50 Oncorhyncus kisutch (96 h): mg/lacute toxicity, LC50 Salmo gairdneri (96 h): mg/lacute toxicity, LC50 Ictalurus panctatus (96 h): mg/l Paraffins (petroleum), normal C Freshwater Fish LC50 96 h Pimephales promelas >5000 mg/l SUMMARY OF PRODUCT ECOTOXICITY DATA Ecotoxicity: Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. This classification applies to bulk quantities only. Persistence and Biodegradability: Mobility in Soil: 13. DISPOSAL CONSIDERATIONS Disposal Methods and Containers: Special Precautions for Landfill or Incineration: Bulk quantities of product must be disposed of according to Local, State and Federal regulations.

7 14. TRANSPORT INFORMATION Page 7 of 9 General remarks For long distance transport of bulk material or shrunk pallet take into consideration sections 7 and 10. IATA UN-No: UN 3077 Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (D-ALLETHRIN) Hazard Class 9 Subsidiary Class Packing group: III ERG Code 9L Description: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (D-ALLETHRIN), 9, PG III IMDG / IMO Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (D-ALLETHRIN) Hazard Class 9 UN-No UN 3077 Packing Group III EmS: F - A, S - F Marine Pollutant MARINE POLLUTANT Description ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (D-ALLETHRIN), 9, PG III ADG (Australian Road and Rail) Proper Shipping Name Hazard Class Packing Group UN-No ADG (Australian Road and Rail)

8 15. REGULATORY INFORMATION Page 8 of 9 Risk Combination Phrases S -phrase(s) Safety Combination Phrases R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment S 2 - Keep out of the reach of children S13 - Keep away from food, drink and animal feedingstuffs S35 - This material and its container must be disposed of in a safe way S46 - If swallowed, seek medical advice immediately and show this container or label S61 - Avoid release to the environment. Refer to special instructions/safety data sheets S24/25 - Avoid contact with skin and eyes Regulatory Status Australia This product has been registered by APVMA, Australia ; APVMA No Poisons Schedule No. (SUSMP) Australia: Not scheduled New Zealand Approved Handler Tracking This product has been approved under HSNO - ERMA Approval Number: HSR Not required. Not required.

9 16. OTHER INFORMATION Page 9 of 9 Key: Reason for revision: Contact Validation/Revision Date ADG = Australian Code for the Transport of Dangerous Goods by Road and Rail AICS = Australian Inventory of Chemical Substances EC50 = median effective concentration IATA = International Air Transport Association IMDG = International Maritime Dangerous Goods IMO = International Maritime Organization LC50 = concentration required to kill 50% of test organisms. LD50 = dose required to kill 50% of test organisms. NOHSC = National Occupational Health and Safety Commission (Australia) Update NZ new address & phone number. Australia and New Zealand Regulatory, Safety & Environmental Services From outside Australia: Ph: (61) (2) From within Australia: Ph: (02) Dec-2015 This MSDS has been prepared according to the National Code of Practice for the Preparation of Safety Data Sheets 2nd Edition [NOHSC:2011(2003)]. The information contained in this Safety Data Sheet was compiled using the latest and most reliable information available to Reckitt Benckiser. The information is provided without warranty, expressed or implied regarding its correctness or accuracy. Similarly no warranty expressed or implied regarding the product described herein shall be created by or inferred from any statement or omission from this Safety Data Sheet nor will Reckitt Benckiser assume any liability for any loss or damage arising out of the use of this information. It is solely the responsibility of the user to determine safe conditions for use of this product and to assume liability for any loss, damage or expense whatsoever arising out of the product's improper use. This document is only current on the day of viewing. Printed copies are UNCONTROLLED unless they are part of a Quality/Technical Manual or attached to a letter referring to a Purchase Order Number. End of Safety Data Sheet