CHEMICAL PRODUCT SAFETY INFORMATION FORM

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1 1. PRODUCT AND COMPANY IDENTIFICATION Product Name: ROSCA CORTE Application: Oil for machining (threading) Manufacturer s CNPJ: / IN CONFORMITY WITH ABNT RULE NBR 14725: HAZARD IDENTIFICATION Most significant hazards: The product presents environmental risk. Product effects: Adverse effects for human health: Eye contact: Slightly irritant when contacting eyes. Skin contact: Slightly irritant when contacting skin. Inhalation: Slightly irritant to the respiratory tract. Ingestion: Slightly irritant to the gastrointestinal system. Environmental effects: Product deemed as harmful to the environment. Physical and chemical hazards: Not applicable. Specific hazards: It can contaminate the water table. It might contaminate surface water by forming a film that prevents oxygen absorption. When in prolonged contact with the skin, it might remove natural fat, exposing the skin. Main symptoms: Not applicable. Chemical product hazard classification and used classification system: This product is classified as a substance presenting risk to the environment according to ANTT 420/04 resolution and its updates. General emergency view: The product presents risk to the environment. 3. COMPOSITION AND INGREDIENT INFORMATION Chemical nature: Mixture containing numberless oil-based refinements and additives. 1

2 Controlled Products: Chemical name CAS no. % Concentration Risk Mixture of paraffinic mineral oils It may cause sensitization at skin contact. Harmful to the aquatic environment. Chlorinated paraffin Harmful to the environment. Synonym: Not applicable Chemical Mixture. 4. FIRST AID MEASURES First aid measures: Inhalation: Remove the victim to a ventilated place and administer oxygen. Search for medical aid. Skin contact: Remove contaminated clothes. Wash the affected skin with water and soap in abundance. Seek medical aid if needed. Eye contact: Keep eyelids opened and wash with water in abundance for at least 20 minutes. Seek medical aid if irritation occurs. Ingestion: Do not induce vomiting. If the victim is conscious, administer water and seek medical aid. Protection for the aid provider: Masks with filter for organic vapors when the environment presents contamination by vapor or mist. Gloves, apron and boots when the environment is saturated with liquid. Notes for the doctor: There is no specific antidote. 5. FIRE PREVENTION AND FIGHTING MEASURES Proper extinction means: Water in mist form, dry chemical powder, carbon dioxide. Not recommended extinction means: Do not apply water jets directly over the ablaze product, as it might spread itself and increase the fire intensity even more. Special firefighting methods: Use extinguishing agents properly. Specific chemical product combustion hazards: When ablaze, it might generate carbon monoxide gas besides carbon dioxide. Special equipment for fireman protection: Wear individual respiration equipment. Wear autonomous air equipment to enter closed environments. 6. SPILLAGE/LEAKAGE CONTROL MEASURES Personal precautions: Wear PVC gloves, apron, and boots. If there is presence of mist or vapors, wear respiratory mask with filter for organic vapors. 2

3 Precautions for the environment: Do not enable product outflow to water courses, sewage network, basements, or confined areas. Non-controlled spillages or discharges in water courses must be reported to the competent authority. Removal and cleaning methods: Use an absorbing material (sawdust, sand, or vermiculite) and collect it for disposal. Prevention of secondary hazards: None in particular. Recovery: There is no recovery. The collected material must be forwarded to disposal. Disposal: Incinerate the product according to the legislation in effect. 7. HANDLING AND STORAGE HANDLING Proper technical measures: Handle the product with PVC gloves. Worker exposure prevention: If there are leakages, mist or vapors, wear PVC gloves, boots, and apron and mask with filter for organic vapors for respiration. Fire and explosion prevention: Keep away of heating sources, sparks, open flames, and heated surfaces. Precautions for chemical safe handling: Wear PVC gloves. Safe handling warning: Prevent aerosol formation. Hygiene measures: Handle the product as indicated. STORAGE Proper technical measures: Do not store close to food. Proper storage conditions: The product must be stored in covered environments, protected against weather and with cemented floor. Storage conditions to be avoided: Avoid exposure to heat and ignition sources. Non-compatible products: Prevent contact with strong oxidants. Packing materials: Recommended: Carbon steel, stainless steel, PEAD, and PEBD. Improper: Paper, cardboard, and other materials susceptible to mineral oils. 8. INDIVIDUAL EXPOSURE AND PROTECTION CONTROL Specific control parameters: Occupational exposure limits: Mineral oil - Limit value (USA, ACGIH) TLV/TWA: 5 mg/m 3. Limit value (USA, ACGIH) TLV/STEL: 10 mg/m 3. 3

4 Biological indicators: Not available. Other limits and values: Not available. Individual protection equipment: Respiratory protection: None in usual product use conditions. However, when there is mist and/or vapors, wear respiratory mask with filter for organic vapors. Hand protection: PVC gloves. Eye protection: Safety goggles with side protection for liquids. Skin and body protection: PVC apron. Special precautions: Always keep the workplace clean. Wash hands after handling. Do not eat, drink, or smoke at the place where the product is handled. 9. PHYSICAL AND CHEMICAL PROPERTIES Aspect: Liquid Odor: Characteristic Color: Dark brown ph: Not applicable Non-aqueous product. Specific temperatures or temperature ranges where physical status changes occur Boiling point: > 200ºC Melting point: Not determined Freezing point: < 0 C Decomposition temperature only in combustion cases Flash point (ASTM 92): 194 ºC Explosivity Limits: Not applicable. Non-explosive product. Density (20/4ºC): Solubility: Only in organic solvents Kinematic viscosity (CST 40ºC): STABILITY AND REACTIVITY Chemical stability: Product stable in usual use and storage conditions. Hazardous reactions: No hazardous reaction in particular. 4

5 Conditions to be avoided: Avoid exposure to strong heat and ignition sources. Non-compatible materials or substances: Avoid contact with strong oxidants. Hazardous decomposition products: When in combustion, it might release carbon monoxide besides carbon dioxide and chlorine. 11. TOXICOLOGICAL INFORMATION Information according to different exposure routes Acute toxicity: Inhalation: It causes mild irritation. Oral LD 50 (rats): > mg/kg (Reference: IE LATO /022). Skin and eye contact: Significant or prolonged irritation is not expected. Dermal LD 50 (rats): > mg/kg (Reference: IE LATO /022). Ingestion: Not available. Chronic toxicity: Irritation in respiratory tract after repeated mist inhalation. Persons susceptible to dermatitis might have their condition aggravated after repeated contact. Sensitization: It can cause sensitivity in hypersensitive persons. Specific effects: Removal of natural fat from skin. 12. ECOLOGICAL INFORMATION Product environmental effects, behaviors, and impacts: The product presents environmental risk. Ecotoxicity: Not available. Persistence and degradability: Product persists in the environment. It is not biodegradable. Bioaccumulative potential: Not available. Mobility in soil: Not available. 13. CONSIDERATIONS ON TREATMENT AND DISPOSAL Methods recommended for treatment and disposal applied to: Product remains: These must be incinerated according to the legislation in effect or must be forwarded to an authorized recuperator. Used package: This can be forwarded to an authorized recuperator. 14. INFORMATION ON TRANSPORTATION 5

6 HIGHWAY TRANSPORTATION IN BRAZIL Proper name for boarding: SUBSTANCE PRESENTING ENVIRONMENTAL RISK, LÍQUID, N.E. UN number: 3082 Risk class/subclass: 9 Description of risk class or subclass: DIVERSE HAZARDOUS SUBSTANCES AND ITEMS. Risk number: 90 Package group: III HIGHWAY TRANSPORTATION IN MERCOSUL Proper name for boarding: SUBSTANCE PRESENTING ENVIRONMENTAL RISK, LÍQUID, N.E. UN number: 3082 Risk class/subclass: 9 Description of risk class or subclass: DIVERSE HAZARDOUS SUBSTANCES AND ITEMS. Risk number: 90 Package Group: III DOMESTIC AND INTERNATIONAL AERIAL TRANSPORTATION - ICAO & IATA SECTION 4.2 Legislation currently not available. INTERNATIONAL MARITIME TRANSPORTATION - IMDG CODE AMENDMENT Legislation currently not available. 15. REGULATIONS Labeling (Risk symbols / labels: health, physical risks, and the environment): Product complies with ANTT resolution 420/04 and NBR and their updates. 16. OTHER INFORMATION "The information in this FISPQ represents current data and accurately reflects our best knowledge on the proper handling of this product under normal conditions and according to the specific application in the package and/or literature. Any other product use involving the combined use with other product or other processes is the user s responsibility". 6

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