KLEENEX Moisturizing Instant Hand Sanitizer

Transcription

1 SECTION 1. IDENTIFICATION Product name : Product code : 31294, 32181, 33987, 33958, 34023, 35722, 35804, 36873, 37342, 39868, 91562, 91600, Manufacturer or supplier's details Company name of supplier : Kimberly-Clark Corporation Address : 1400 Holcomb Bridge Road, Roswell, GA Telephone : Emergency telephone : SECTION 2. HAZARDS IDENTIFICATION GHS Classification Flammable liquids : Category 2 Serious eye damage/eye irritation : Category 2B GHS Label element Hazard pictograms : Signal Word Hazard Statements Precautionary Statements : Danger : H225 Highly flammable liquid and vapor. H320 Causes eye irritation. : Prevention: P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Response: P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. P337 + P313 If eye irritation persists: Get medical advice/ attention. Storage: 1 / 8

2 P403 + P235 Store in a well-ventilated place. Keep cool. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant. Other hazards The following percentage of the mixture consists of ingredient(s) with unknown acute toxicity: % SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Hazardous ingredients Chemical Name CAS-No. Concentration (%) Ethanol >= 50 - < 70 Glycerol >= 1 - < 5 SECTION 4. FIRST AID MEASURES General advice If inhaled In case of skin contact In case of eye contact If swallowed Most important symptoms and effects, both acute and delayed Notes to physician : No hazards which require special first aid measures. : Remove person to fresh air. If signs/symptoms continue, get medical attention. : Wash off with soap and water. If symptoms persist, call a physician. : Flush eyes with water at least 15 minutes. Get medical attention if eye irritation develops or persists. : If swallowed, DO NOT induce vomiting. Drink 1 or 2 glasses of water. If symptoms persist, call a physician or Poison Control Center immediately. : No information available. : No information available. SECTION 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Unsuitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. : Water spray jet 2 / 8

3 Hazardous combustion products Specific extinguishing methods Special protective equipment for fire-fighters : Carbon monoxide, carbon dioxide and unburned hydrocarbons (smoke). : Standard procedure for chemical fires. : In the event of fire, wear self-contained breathing apparatus. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Not required under normal use. No conditions to be specially mentioned. SECTION 7. HANDLING AND STORAGE SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ingredients with workplace control parameters Ingredients CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis Ethanol TWA 1,000 ppm OSHA Z-1 1,900 mg/m3 TWA 1,000 ppm OSHA P0 1,900 mg/m3 TWA 1,000 ppm NIOSH REL 1,900 mg/m3 STEL 1,000 ppm ACGIH Glycerol TWA (total 15 mg/m3 OSHA Z-1 dust) TWA (respirable 5 mg/m3 OSHA Z-1 fraction) TWA (mist, respirable fraction) 5 mg/m3 OSHA Z-1 TWA (mist, total dust) TWA (Mist - total dust) TWA (Mist - respirable fraction) 15 mg/m3 OSHA Z-1 10 mg/m3 OSHA P0 5 mg/m3 OSHA P0 SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES 3 / 8

4 Appearance Color Odor : gel : white : pleasant ph : 7 Melting point/range : -114 C Boiling point/boiling range : 78 C Flash point : 20 C Upper explosion limit Lower explosion limit Vapor pressure Solubility(ies) Solubility in other solvents : 19 %(V) : 3.3 %(V) : 60 hpa : completely soluble SECTION 10. STABILITY AND REACTIVITY SECTION 11. TOXICOLOGICAL INFORMATION Acute toxicity Product: Acute oral toxicity Acute dermal toxicity : Acute toxicity estimate: > 5,000 mg/kg Method: Calculation method : Acute toxicity estimate: > 5,000 mg/kg Method: Calculation method Ethanol: Acute oral toxicity Acute oral toxicity Acute dermal toxicity : LD50 (Rat, female): 15,000 mg/kg : LD50 Oral (Mouse, male): 23,000 mg/kg : LD50 Dermal (Guinea pig, male and female): 56,750 mg/kg Skin corrosion/irritation Species: Rabbit 4 / 8

5 Exposure time: 24 h Result: No skin irritation Serious eye damage/eye irritation Species: Rabbit Result: No eye irritation Exposure time: 20 s Germ cell mutagenicity Genotoxicity in vitro : Method: OECD Test Guideline 482 Result: negative Carcinogenicity Species: Rat, (male and female) Application Route: Oral Exposure time: 24 month(s) Frequency of Treatment: 1 daily IARC OSHA NTP No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. No ingredient of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. No ingredient of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. Reproductive toxicity Effects on fetal development : Test Type: Two-generation study Species: Rat, male and female Application Route: Oral Dose: 2000 milligram per kilogram Frequency of Treatment: 1 daily 5 / 8

6 SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Ethanol: Toxicity to fish Toxicity to daphnia and other aquatic invertebrates Toxicity to algae Toxicity to fish Toxicity to daphnia and other aquatic invertebrates : LC50 (Pimephales promelas (fathead minnow)): 14.2 g/l Exposure time: 96 h Test Type: flow-through test : EC50 (Ceriodaphnia dubia (water flea)): 5,012 mg/l Exposure time: 48 h Test Type: static test : EC50 (Chlorella vulgaris (Fresh water algae)): 275 mg/l Exposure time: 72 h Test Type: static test : LC50 (Oncorhynchus mykiss (rainbow trout)): 54,000 mg/l Exposure time: 96 h GLP: see user defined free text : EC50: 1,955 mg/l Exposure time: 48 h Persistence and degradability Biodegradability : Result: Readily biodegradable. Bioaccumulative potential No data available Mobility in soil No data available Other adverse effects No data available SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods SECTION 14. TRANSPORT INFORMATION 14.1 UN number CFR : UN / 8

7 Health Instability SAFETY DATA SHEET 14.2 UN proper shipping name CFR : ETHANOL SOLUTION 14.3 Transport hazard class(es) CFR : Packing group CFR Packing group : II Classification Code : F1 Hazard Identification Number : 33 Labels : 3 SECTION 15. REGULATORY INFORMATION California Prop 65 : This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects. SECTION 16. OTHER INFORMATION Further information NFPA: Flammability HMIS III: 3 HEALTH FLAMMABILITY 3 PHYSICAL HAZARD 0 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Revision Date : The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information re- 7 / 8

8 lates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. US / Z8 8 / 8