Material Safety Data Sheet

Transcription

1 1. Chemical Product and Company Identification Product Name : AQUAMICRON Supplier : Manufacturer : API Corporation 2-3-4, Nihonbashi, Chuo-ku, Tokyo, Japan Tel Fax In case of emergency : Call Supplier / Manufacturer 2. Composition/Data on Components Substance/Preparation : Preparation Chemical name CAS No. % EC Number Symbol R-Phrases Methanol T,F R11-23/24/25-39/23/ 24/25 Propylene carbonate < Xi R36 2-Ethylaminoethanol < Xi R21/22 Ethandiol < Xn R22 Complex bound sulphur dioxide Iodine Xn R20/ Hazards Identification Physical/Chemical Hazards International Highly Flammable, Toxic liquid US Domestic Flammable liquid Classification system The classification is in line with current EC lists, IATA and US DOT 49CFR(10/01/0 1) regulations. It is expanded, however, by information from technical literature and by information furnished by supplier companies. 4. First-aid Measures General information Instantly remove any clothing soiled by the product. Remove breathing apparatus only after soiled clothing has been completely removed. In case of irregular breathing or respiratory arrest provide artificial respiration. After inhalation Supply fresh air or oxygen; call for doctor. In case of unconsciousness bring patient into stable side position for transport. After skin contact Instantly wash with water and soap and rinse thoroughly. After eye contact Rinse opened eye for at least 15 minutes under running water. Then consult doctor. After swallowing Drink copious amounts of water and provide fresh air. Instantly call for doctor. Issued on February 1,2003 Page 1 of 6

2 5. Fire-fighting Measures Suitable extinguishing agents CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol-resistant foam. For safety reasons unsuitable extinguishing agents Water with a full water jet. Special hazards caused by the material, its products of combustion or resulting gases: Formation of toxic gases is possible during heating or in case of fire. Nitrogen oxides (NOx) Sulphur dioxide (SO2) Carbon dioxide (CO2) Protective equipment: Put on breathing apparatus. 6. Accidental Release Measures Person-related safety precautions: Wear protective equipment. Keep unprotected persons away. Measures for environmental protection: Do not allow to enter drainage system, surface or ground water. Measures for cleaning/collecting: Absorb with liquid-binding non combustible material (e.g. sand). Send for recovery or disposal in suitable containers. Dispose of contaminated material as waste according to item 13. Ensure adequate ventilation. Additional information: See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal. 7. Handling and Storage Handling Information for safe handling: Ensure good ventilation/exhaustion at the workplace. Keep away from heat and direct sunlight. Open and handle container with care. Work only in fume cupboard. Information about protection against explosions and fires: Keep ignition sources away - Do not smoke. Protect against electrostatic charges. Keep breathing equipment ready. Storage Requirements to be met by storerooms and containers: Suitable storage temperature 15 C to 25 C Further information about storage conditions: Store in cool, dry conditions in well sealed containers. Store in the dark. 8. Exposure Controls/Personal Protection Additional information about design of technical systems: No further data; see item 7. Components with limit values that require monitoring at the workplace: OES Short-term value: 333 mg/m³, 250 ppm Long-term value: 266 mg/m³, 200 ppm Sk, ILV Ethandiol OES Short-term value: 104** mg/m³ Issued on February 1,2003 Page 2 of 6

3 Long-term value: 10* 52** mg/m³ *particulate, IOELV, Sk **vapour, IOELV, Sk iodine OES Short-term value: 1.1 mg/m³, 0.1 ppm Personal protective equipment General protective and hygienic measures Keep away from foodstuffs, beverages and food. Take off immediately all contaminated clothing Wash hands during breaks and at the end of the work. Store protective clothing separately. Avoid contact with the eyes. Avoid contact with the eyes and skin. Apply solvent resistant skin protection preparation before beginning work. Breathing equipment: In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer exposure use breathing apparatus that is independent of circulating air. Protection of hands: The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Tightly sealed safety glasses. Body protection: Light weight protective clothing 9. Physical and Chemical Properties General Information Form: Fluid Colour: Yellow to Reddish brown Odour: Recognizable Change in condition Melting point/melting range: Not determined Boiling point/boiling range: Not determined Flash point: 15.8 C (closed cup) Self-inflammability: Product is not selfigniting. Danger of explosion: Product is not explosive. However, formation of explosive air/steam mixtures is possible. Density at 20 C 1.0 g/cm³ Solubility in / Miscibility with Water: Fully miscible Viscosity: dynamic at 20 C: mpas 10. Stability and Reactivity Thermal decomposition / conditions to be avoided: Stable (at room temperature) for 5 years Dangerous reactions No dangerous reactions known Dangerous products of decomposition: No dangerous decomposition products known Issued on February 1,2003 Page 3 of 6

4 11. Toxicological Information Acute toxicity: LD/LC50 values that are relevant for classification: Oral LD mg/kg (rat) LDLo 143 mg/kg (man) Dermal LD mg/kg (rbt) Propylene carbonate Oral LD mg/kg (rat) Dermal LD50 > mg/kg (rbt) Inhalative LC50/4 h > 5000 mg/l (rat) Ethandiol Oral LD mg/kg (rat) Dermal LD50 > 2000 mg/kg (rbt) Inhalative LC50/4 h mg/l (rat) ethylaminoethanol Oral LD mg/kg (rat) Dermal LD mg/kg (rbt) Primary irritant effect: on the skin: Caustic effect on skin and mucous membranes. on the eye: Strong caustic effect. Sensitization: No sensitizing effect known. Additional toxicological information: The product shows the following dangers according to the calculation method of the General EC Classification Guidelines for Preparations as issued in the latest version: Poisonous Corrosive Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of oesophagus and stomach. Listings USA TSCA (Toxic Substances Control Act) Propylene carbonate ethylaminoethanol Ethandiol iodine 12. Ecological Information Ecotoxical effects: Aquatic toxicity: EC50/48h >10000 mg/l (Daphnia magna) LC50/96h mg/l (Pimephales promelas) General notes: Water hazard class 1 (German Regulation) (Self-assessment): low hazard to waters. Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system. 13. Disposal Considerations Product: Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. Remove in accordance with the local official recommendations. European waste catalogue Issued on February 1,2003 Page 4 of 6

5 laboratory chemicals, consisting of or containing dangerous substances, including mixtures of laboratory chemicals Uncleaned packagings: Recommended cleaning agent: Water, if necessary with cleaning agent. 14. Transport Information US Air and US Ground Transport US DOT 49CFR 173.2, 49CFR (c)(10)(i), 49CFR (page189) Hazard Class : 3/6.1 UN number: 1230 Packing group: II Correct technical name: Methanol mixture Land transport ADR/RID ADR/RID Class: 3/6.1 Methanol mixture Hazard Index Number: 336 Substance Index Number: 1230 Packaging group: II Label Designation of goods: 1230 Methanol mixture Maritime transport IMDG: IMDG Class: 3/6.1 UN Number: 1230 Label Packaging group: II EMS Number: 3-07 Marine pollutant: No Correct technical name: Methanol mixture Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: 3/6.1 UN/ID Number: 1230 Label Packaging group: II Correct technical name: Methanol mixture Transport/Additional information: Regulatory Information Designation according to EC guidelines: The product has been classified and labeled in accordance with EC Directives / Ordinance on Hazardous Materials (GefStoffV) and US DOT 49CFR(10/01/01). Code letter and hazard designation of product: International T Toxic F Highly flammable US Domestic F Flammable Hazard-determining components of labeling: Methanol Risk phrases: 11 Highly flammable. 23/24/25 Toxic by inhalation, in contact with skin and if swallowed. 36 Irritating to eyes. 39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed. Safety phrases: 7/9 Keep container tightly closed and in a well-ventilated place. 16 Keep away from sources of ignition - No smoking. Issued on February 1,2003 Page 5 of 6

6 20 When using do not eat or drink. 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). 60 This material and its container must be disposed of as hazardous waste. 16. Other Information This data is based on our present knowledge. However, it shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Relevant R-phrases 11 Highly flammable. 20/21 Harmful by inhalation and in contact with skin. 21/22 Harmful in contact with skin and if swallowed. 22 Harmful if swallowed. 23/24/25 Toxic by inhalation, in contact with skin and if swallowed. 36 Irritating to eyes. 39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed. 50 Very toxic to aquatic organisms. Issued on February 1,2003 Page 6 of 6