MATERIAL SAFETY DATA SHEET

Transcription

1 PRODUCTS

2 Hazard Classification: Dangerous Goods (Flammable}, Hazardous- Irritant Class: 3 Subclass: Not applicable Poisons Schedule: Not scheduled I 4. FIRST AID MEASURES Poison Information Centres in each State capital city can provide additional assistance for scheduled poisons. Ring Ingestion: Immediately rinse mouth with water. Give water to drink. Do NOT induce vomiting. If vomiting occurs, place victim's face downwards, head lower than hips to prevent vomit entering lungs. Seek immediate medical assistance. Eye Contact: Immediately irrigate with copious quantities of water for at least 15 minutes. Eyelids to be held open. Seek medical assistance if irritation persists. Skin Contact: Wash contaminated skin with water. Inhalation: Remove victim from exposure- avoid becoming a casualty. Remove contaminated clothing and loosen remaining clothing. Allow patient to assume most comfortable position and keep warm. Keep at rest until fully recovered. For all but the most minor symptoms arrange for patient to be seen by a doctor as soon as possible, either on site or at the nearest hospital. Notes to physician: Treat symptomatically and as for excessive consumption of alcoholic drink. I 5. FIRE-FIGHTING MEASURES Specific Hazards: Flammable Fire fighting further advice: Fire fighters to wear self-contained breathing apparatus if risk of exposure to vapour or products of combustion. Suitable extinguishing media: Water fog (or if unavailable fine water spray}, foam, dry agent (carbon dioxide, dry chemical powder). 6. ACCIDENTAL RELEASE MEASURES Contain using sand and soil- prevent runoff into drains and waterways. Use absorbent (soil or sand, inert material, vermiculite). Collect and seal in properly labeled containers for disposal 7. HANDLING AND STORAGE Storage: As for class 3 flammable goods. Store in cool ventilated area away from ignition sources. Handling: Always wash hands after handling prior to eating, drinking, smoking or going to the toilet.

3 IB.EXPOSURECONTROLS/PERSONALPROTECTION National occupational exposure limits. No value assigned for this specific material by the National Occupational Health and Safety Commission (Worksafe Australia) However, Exposure standard for constituent: ethanol, recommended by NOHSC is 1000 ppm (1880 mglm 3 ) TWA. Engineering Measures: Remove all ignition sources. Personal Protection Equipment: No special requirements. I 9. PHYSICAL AND CHEMICAL PROPERTIES Form I Colour I Odour: Thin, clear liquid. Specific Gravity: 0.97 Ref Vapour Density: Not determined Vapour Pressure: Not determined Flash Point: Not determined Flammability Limits: Not determined Autoignition Temp (C): Not determined % Volatile by Volume: 82 Solubility in Water: 100% Melting Point (C): Not applicable Boiling Point (C): Not determined Decamp. Point (C): Not determined Sublimation Point: Not determined ph: Not determined Viscosity: Not determined Evaporation Rate: Not determined I 10. STABILITY AND REACTIVITY Stability: Stable under normal conditions. Compatibility: Incompatible with oxidizing agents. 11. TOXICOLOGICAL INFORMATION Main Symptoms: No adverse health effects expected if the product is handled in accordance with this Safety Data Sheet and the product label. Symptoms that may arise if the product is mishandled are: Acute Ingestion: Swallowing may cause harm to the central nervous system, effects including headaches, dizziness, blurred vision, coma, respiratory arrest. Eye Contact: May irritate and damage eyes. Skin Contact: May irritate on skin contact. Inhalation: May irritate respiratory tract and mucous membranes. May result in headache and nausea. Chronic: Chronic intoxication by swallowing or repeated inhalation. May cause degenerative changes to liver, kidney, hair, gastrointestinal tract and heart muscle.

4 Toxicity Data: No data available for TYRE SHINE. For major component ethanol - Oral LDso (Rat): 7060 mglkg Inhalation LCso (Rat): 38 mgll/10h 12. ECOLOGICAL INFORMATION Eco-toxicity No data available for TYRE SHINE. For major component- Ethanol Toxicity to fish (acute): LCO/Golden Ide >1000 mgii/4bh Toxicity to Daphnia: EC 5 c/daphnia Magna > 1000 mgll/24h Persistence and Deqradability Degree of Elimination - 94% Eradication - Biodegradable Avoid contaminating waterways DISPOSAL CONSIDERATIONS Suitable for disposal at approved land waste site. I 14. TRANSPORT INFORMATION Classified as Dangerous Goods for the purpose of transport by road or rail. Refer to relevant regulations for storage and transport requirements. UN-NO: 1993 CLASS: 3 HAZCHEM CODE: 2 [Y] ERG: 14 PACKING GROUP: Ill Proper shipping name: Flammable Liquid N. 0. S. Segregation Dangerous Goods: Class 1 - Explosives Class Oxidising Agents Class Flammable gases in bulk Class Poisonous gases Class Spontaneous combustible substance Class Organic peroxides Class 7 - Radioactive substances

5 15. REGULA TORY INFORMATION Hazardous according to criteria of Worksafe Australia. Hazard Category Irritant R-phrase(s) R11 Highly Flammable R20122 Harmful by inhalation and if swallowed R36138 Irritating to eyes and skin R66 Repeated exposure may cause skin dryness and cracking S-phrase(s) S7 Keep container tightly closed S16 Keep away from sources of ignition S23 Do not breathe vapour A void contact with skin and eyes S33 Take precautionary measures against static charges S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible) Poisons Schedule (AUST) Toxic Substance (NZ): Not scheduled 16. OTHER INFORMATION Literary Reference: 1. M.S.D.S- Ethanol- CSR- Jan 2003 This MSDS summarises at the date of issue or best knowledge of the health and safety hazard information of the product, and in particular how to safely handle and use the product in the workplace. Since Cosmic Products Australia and its subsidiaries cannot anticipate or control the conditions under which the product may be used, each user must, prior to usage, review this MSDS in the context of how the user intends to handle and use the product in the workplace. If clarification or further information is needed to ensure that an appropriate assessment can be made, the user should contact this company. Our responsibility for product as sold is subject to our standard terms and conditions, a copy of which is sent to our customers and is also available upon request. End of M.S.D.S