Safety Data Sheet acc. to OSHA HCS

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1 Safety Data Sheet acc. to OSHA HCS Page 1/7 Printing date 05/16/2015 Reviewed on 05/16/ Identification Product identifier Trade name: URANYL ACETATE 2% SOLUTION (Depleted Uranium) Article number: Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. Application of the substance / the mixture Laboratory chemicals Details of the supplier of the safety data sheet Manufacturer/Supplier: Electron Microscopy Sciences 1560 Industry Road USA-Hatfield, PA Tel: Fax: Information department: Product safety department Emergency telephone number: ChemTrec Contract CCN Hazard(s) identification Classification of the substance or mixture Classification according to Directive 67/548/EEC or Directive 1999/45/EC Not applicable. Information concerning particular hazards for human and environment: The product does not have to be labeled due to the calculation procedure of international guidelines. Classification system: The classification was made according to the latest editions of international substances lists, and expanded upon from company and literature data. Label elements Labelling according to EU guidelines: Observe the general safety regulations when handling chemicals. The product is not subject to identification regulations according to directives on hazardous materials. Hazard-determining components of labeling: Uranylacetat-Dihydrat Classification system: NFPA ratings (scale 0-4) Health = 0 Fire = 0 Reactivity = 0 HMIS-ratings (scale 0-4) HEALTH FIRE REACTIVITY Health = 0 Fire = 0 Reactivity = 0 Other hazards Results of PBT and vpvb assessment PBT: Not applicable. (Contd. on page 2) USA

2 Safety Data Sheet acc. to OSHA HCS Page 2/7 Printing date 05/16/2015 Reviewed on 05/16/2015 Trade name: URANYL ACETATE 2% SOLUTION (Depleted Uranium) vpvb: Not applicable. (Contd. of page 1) 3 Composition/information on ingredients Chemical characterization: Mixtures Description: Mixture of the substances listed below with nonhazardous additions. Dangerous components: Uranylacetat-Dihydrat 2.5% 4 First-aid measures Description of first aid measures General information: No special measures required. After inhalation: Supply fresh air; consult doctor in case of complaints. After skin contact: Generally the product does not irritate the skin. After eye contact: Rinse opened eye for several minutes under running water. After swallowing: If symptoms persist consult doctor. Most important symptoms and effects, both acute and delayed No further relevant information available. Indication of any immediate medical attention and special treatment needed No further relevant information available. 5 Fire-fighting measures Extinguishing media Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. Special hazards arising from the substance or mixture No further relevant information available. Advice for firefighters Protective equipment: No special measures required. 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Not required. Environmental precautions: Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. 7 Handling and storage Precautions for safe handling No special measures required. Information about protection against explosions and fires: No special measures required. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: No special requirements. (Contd. on page 3) USA

3 Safety Data Sheet acc. to OSHA HCS Page 3/7 Printing date 05/16/2015 Reviewed on 05/16/2015 Trade name: URANYL ACETATE 2% SOLUTION (Depleted Uranium) Information about storage in one common storage facility: Not required. Further information about storage conditions: None. Specific end use(s) No further relevant information available. (Contd. of page 2) 8 Exposure controls/personal protection Additional information about design of technical systems: No further data; see item 7. Control parameters Components with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. Additional information: The lists that were valid during the creation were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures: The usual precautionary measures for handling chemicals should be followed. Breathing equipment: Not required. Protection of hands: The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Goggles recommended during refilling. 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: Liquid Color: Yellow Odor: Characteristic Odour threshold: Not determined. ph-value: Not determined. Change in condition Melting point/melting range: Boiling point/boiling range: Undetermined. 100 C (212 F) Flash point: Not applicable. Flammability (solid, gaseous): Not flammable. (Contd. on page 4) USA

4 Safety Data Sheet acc. to OSHA HCS Page 4/7 Printing date 05/16/2015 Reviewed on 05/16/2015 Trade name: URANYL ACETATE 2% SOLUTION (Depleted Uranium) Ignition temperature: Decomposition temperature: Not determined. Auto igniting: Product is not selfigniting. Danger of explosion: Product does not present an explosion hazard. Explosion limits: Lower: Upper: Not determined. Not determined. Vapor pressure at 20 C (68 F): 23 hpa (17 mm Hg) Density: Not determined. Relative density Not determined. Vapour density Not determined. Evaporation rate Not determined. Solubility in / Miscibility with Water: Not miscible or difficult to mix. Partition coefficient (n-octanol/water): Not determined. Viscosity: Dynamic: Kinematic: Solvent content: Organic solvents: 0.0 % Water: 98.0 % Not determined. Not determined. Solids content: 4.0 % Other information No further relevant information available. (Contd. of page 3) 10 Stability and reactivity Reactivity Chemical stability Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. Possibility of hazardous reactions No dangerous reactions known. Conditions to avoid No further relevant information available. Incompatible materials: No further relevant information available. Hazardous decomposition products: No dangerous decomposition products known. 11 Toxicological information Information on toxicological effects Acute toxicity: LD/LC50 values that are relevant for classification: Uranylacetat-Dihydrat Oral LD mg/kg (rat) Primary irritant effect: on the skin: No irritant effect. on the eye: No irritating effect. (Contd. on page 5) USA

5 Safety Data Sheet acc. to OSHA HCS Page 5/7 Printing date 05/16/2015 Reviewed on 05/16/2015 Trade name: URANYL ACETATE 2% SOLUTION (Depleted Uranium) (Contd. of page 4) Sensitization: No sensitizing effects known. Additional toxicological information: The product is not subject to classification according to internally approved calculation methods for preparations: When used and handled according to specifications, the product does not have any harmful effects according to our experience and the information provided to us. Carcinogenic categories IARC (International Agency for Research on Cancer) None of the ingredients is listed. NTP (National Toxicology Program) None of the ingredients is listed. OSHA-Ca (Occupational Safety Health Administration) None of the ingredients is listed. 12 Ecological information Toxicity Aquatic toxicity: No further relevant information available. Persistence and degradability No further relevant information available. Bioaccumulative potential No further relevant information available. Mobility in soil No further relevant information available. Additional ecological information: General notes: Water hazard class 3 (Self-assessment): extremely hazardous for water Do not allow product to reach ground water, water course or sewage system, even in small quantities. Danger to drinking water if even extremely small quantities leak into the ground. Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. Other adverse effects No further relevant information available. 13 Disposal considerations Waste treatment methods Recommendation: Smaller quantities can be disposed of with household waste. Uncleaned packagings: Recommendation: Disposal must be made according to official regulations. 14 Transport information UN-Number DOT, ADR, IMDG, IATA UN2910 UN proper shipping name DOT Radioactive material, excepted package-limited quantity of material ADR 2910 Radioactive material, excepted package-limited quantity of material (Contd. on page 6) USA

6 Safety Data Sheet acc. to OSHA HCS Page 6/7 Printing date 05/16/2015 Reviewed on 05/16/2015 Trade name: URANYL ACETATE 2% SOLUTION (Depleted Uranium) (Contd. of page 5) IMDG, IATA RADIOACTIVE MATERIAL, EXCEPTED PACKAGE - LIMITED QUANTITY OF MATERIAL Transport hazard class(es) DOT Class 7 Radioactive material Label 7x ADR Class 7 Radioactive material Label 7X IMDG, IATA Class 7 Radioactive material Environmental hazards: Marine pollutant: No Special marking (ADR): Symbol (fish and tree) Special precautions for user Warning: Radioactive material Danger code (Kemler): 70 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Transport/Additional information: Not applicable. ADR Excepted quantities (EQ) Code: E0 Not permitted as Excepted Quantity IMDG Limited quantities (LQ) 0 Excepted quantities (EQ) Code: E0 Not permitted as Excepted Quantity 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Sara Section 355 (extremely hazardous substances): None of the ingredients is listed. Section 313 (Specific toxic chemical listings): None of the ingredients is listed. TSCA (Toxic Substances Control Act): water, distilled, conductivity or of similar purity (Contd. on page 7) USA

7 Safety Data Sheet acc. to OSHA HCS Page 7/7 Printing date 05/16/2015 Reviewed on 05/16/2015 Trade name: URANYL ACETATE 2% SOLUTION (Depleted Uranium) Proposition 65 Chemicals known to cause cancer: None of the ingredients is listed. Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed. Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. Chemicals known to cause developmental toxicity: None of the ingredients is listed. (Contd. of page 6) Carcinogenic categories EPA (Environmental Protection Agency) None of the ingredients is listed. TLV (Threshold Limit Value established by ACGIH) Uranylacetat-Dihydrat A1 NIOSH-Ca (National Institute for Occupational Safety and Health) Uranylacetat-Dihydrat Product related hazard informations: Observe the general safety regulations when handling chemicals. The product is not subject to identification regulations according to directives on hazardous materials. Hazard-determining components of labeling: Uranylacetat-Dihydrat Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Date of preparation / last revision 05/16/2015 / - USA

8 Safety data sheet according to 1907/2006/EC, Article 31 Page 1/7 Printing date Revision: Identification of the substance/mixture and of the company/undertaking Product identifier Trade name: URANYL ACETATE 2% SOLUTION (Depleted Uranium) Article number: Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. Application of the substance / the mixture Laboratory chemicals Details of the supplier of the safety data sheet Manufacturer/Supplier: Electron Microscopy Sciences 1560 Industry Road USA-Hatfield, PA Tel: Fax: ProSciTech Pty Ltd 11 Carlton Street, Kirwan QLD 4817 Australia Telephone Number: (07) :30am - 5:00pm, Monday to Friday (excluding Public Holidays) Emergency Contact: (07) :30am - 5:00pm, Monday to Friday (excluding Public Holidays) Emgrid Australia Pty. Ltd. P.O. Box 118 The Patch VIC 3792 Australia Tel: Fax: Website: Further information obtainable from: Product safety department Emergency telephone number: ChemTrec Contract CCN Hazards identification Classification of the substance or mixture Classification according to Directive 67/548/EEC or Directive 1999/45/EC Not applicable. Information concerning particular hazards for human and environment: The product does not have to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version. Classification system: The classification is according to the latest editions of the EU-lists, and extended by company and literature data. Label elements Labelling according to EU guidelines: Observe the general safety regulations when handling chemicals. The product is not subject to identification regulations under EU Directives and the Ordinance on Hazardous Materials (German GefStoffV). Hazard-determining components of labelling: Uranylacetat-Dihydrat Other hazards Results of PBT and vpvb assessment PBT: Not applicable. (Contd. on page 2) AU

9 Safety data sheet according to 1907/2006/EC, Article 31 Page 2/7 Printing date Revision: Trade name: URANYL ACETATE 2% SOLUTION (Depleted Uranium) vpvb: Not applicable. (Contd. of page 1) 3 Composition/information on ingredients Chemical characterisation: Mixtures Description: Mixture of substances listed below with nonhazardous additions. Dangerous components: Uranylacetat-Dihydrat 2.5% Additional information: For the wording of the listed risk phrases refer to section First aid measures Description of first aid measures General information: No special measures required. After inhalation: Supply fresh air; consult doctor in case of complaints. After skin contact: Generally the product does not irritate the skin. After eye contact: Rinse opened eye for several minutes under running water. After swallowing: If symptoms persist consult doctor. Most important symptoms and effects, both acute and delayed No further relevant information available. Indication of any immediate medical attention and special treatment needed No further relevant information available. 5 Firefighting measures Extinguishing media Suitable extinguishing agents: CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam. Special hazards arising from the substance or mixture No further relevant information available. Advice for firefighters Protective equipment: No special measures required. 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Not required. Environmental precautions: Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. 7 Handling and storage Precautions for safe handling No special measures required. Information about fire - and explosion protection: No special measures required. (Contd. on page 3) AU

10 Safety data sheet according to 1907/2006/EC, Article 31 Page 3/7 Printing date Revision: Trade name: URANYL ACETATE 2% SOLUTION (Depleted Uranium) Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: No special requirements. Information about storage in one common storage facility: Not required. Further information about storage conditions: None. Specific end use(s) No further relevant information available. (Contd. of page 2) 8 Exposure controls/personal protection Additional information about design of technical facilities: No further data; see item 7. Control parameters Ingredients with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. Additional information: The lists valid during the making were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures: The usual precautionary measures are to be adhered to when handling chemicals. Respiratory protection: Not required. Protection of hands: The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Goggles recommended during refilling 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: Liquid Colour: Yellow Odour: Characteristic Odour threshold: Not determined. ph-value: Not determined. Change in condition Melting point/melting range: Undetermined. Boiling point/boiling range: 100 C Flash point: Not applicable. (Contd. on page 4) AU

11 Safety data sheet according to 1907/2006/EC, Article 31 Page 4/7 Printing date Revision: Trade name: URANYL ACETATE 2% SOLUTION (Depleted Uranium) Flammability (solid, gaseous): Not applicable. Ignition temperature: Decomposition temperature: Not determined. Self-igniting: Product is not selfigniting. Danger of explosion: Product does not present an explosion hazard. Explosion limits: Lower: Upper: Vapour pressure at 20 C: 23 hpa Not determined. Not determined. Density: Not determined. Relative density Not determined. Vapour density Not determined. Evaporation rate Not determined. Solubility in / Miscibility with water: Not miscible or difficult to mix. Partition coefficient (n-octanol/water): Not determined. Viscosity: Dynamic: Kinematic: Not determined. Not determined. Solvent content: Organic solvents: 0.0 % Water: 98.0 % VOC (EC) 0.00 % Solids content: 4.0 % Other information No further relevant information available. (Contd. of page 3) 10 Stability and reactivity Reactivity Chemical stability Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. Possibility of hazardous reactions No dangerous reactions known. Conditions to avoid No further relevant information available. Incompatible materials: No further relevant information available. Hazardous decomposition products: No dangerous decomposition products known. 11 Toxicological information Information on toxicological effects Acute toxicity: LD/LC50 values relevant for classification: Uranylacetat-Dihydrat Oral LD mg/kg (rat) (Contd. on page 5) AU

12 Safety data sheet according to 1907/2006/EC, Article 31 Page 5/7 Printing date Revision: Trade name: URANYL ACETATE 2% SOLUTION (Depleted Uranium) (Contd. of page 4) Primary irritant effect: on the skin: No irritant effect. on the eye: No irritating effect. Sensitisation: No sensitising effects known. Additional toxicological information: The product is not subject to classification according to the calculation method of the General EU Classification Guidelines for Preparations as issued in the latest version. When used and handled according to specifications, the product does not have any harmful effects to our experience and the information provided to us. 12 Ecological information Toxicity Aquatic toxicity: No further relevant information available. Persistence and degradability No further relevant information available. Bioaccumulative potential No further relevant information available. Mobility in soil No further relevant information available. Additional ecological information: General notes: Water hazard class 3 (German Regulation) (Self-assessment): extremely hazardous for water Do not allow product to reach ground water, water course or sewage system, even in small quantities. Danger to drinking water if even extremely small quantities leak into the ground. Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. Other adverse effects No further relevant information available. 13 Disposal considerations Waste treatment methods Recommendation Smaller quantities can be disposed of with household waste. Uncleaned packaging: Recommendation: Disposal must be made according to official regulations. 14 Transport information UN-Number ADG, IMDG, IATA UN2910 UN proper shipping name ADG 2910 RADIOACTIVE MATERIAL, EXCEPTED PACKAGE - LIMITED QUANTITY OF MATERIAL IMDG, IATA RADIOACTIVE MATERIAL, EXCEPTED PACKAGE - LIMITED QUANTITY OF MATERIAL (Contd. on page 6) AU

13 Safety data sheet according to 1907/2006/EC, Article 31 Page 6/7 Printing date Revision: Trade name: URANYL ACETATE 2% SOLUTION (Depleted Uranium) Transport hazard class(es) ADG (Contd. of page 5) Class 7 Radioactive material. Label 7X IMDG, IATA Class 7 Radioactive material. Environmental hazards: Marine pollutant: No Special marking (ADG): Symbol (fish and tree) Special precautions for user Warning: Radioactive material. Danger code (Kemler): 70 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Transport/Additional information: Not applicable. ADG Limited quantities (LQ) 0 Excepted quantities (EQ) Code: E0 Not permitted as Excepted Quantity Transport category 4 Tunnel restriction code E IMDG Limited quantities (LQ) 0 Excepted quantities (EQ) Code: E0 Not permitted as Excepted Quantity 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Australian Inventory of Chemical Substances All ingredients are listed. Standard for the Uniform Scheduling of Medicines and Poisons None of the ingredients is listed. Labelling according to EU guidelines: Observe the general safety regulations when handling chemicals. The product is not subject to identification regulations under EU Directives and the Ordinance on Hazardous Materials (German GefStoffV). Hazard-determining components of labelling: Uranylacetat-Dihydrat Chemical safety assessment: A Chemical Safety Assessment has not been carried out. AU (Contd. on page 7)

14 Safety data sheet according to 1907/2006/EC, Article 31 Page 7/7 Printing date Revision: Trade name: URANYL ACETATE 2% SOLUTION (Depleted Uranium) (Contd. of page 6) 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. AU

15 Safety Data Sheet acc. to OSHA HCS Page 1/8 Printing date 05/16/2015 Reviewed on 05/16/ Identification Product identifier Trade name: URANYL ACETATE 2% SOLUTION (Depleted Uranium) Article number: Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. Application of the substance / the mixture Laboratory chemicals Details of the supplier of the safety data sheet Manufacturer/Supplier: Electron Microscopy Sciences 1560 Industry Road USA-Hatfield, PA Tel: Fax: Information department: Product safety department Emergency telephone number: ChemTrec Contract CCN Hazard(s) identification Classification of the substance or mixture GHS08 Health hazard STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure. GHS07 Acute Tox. 4 H302 Harmful if swallowed. Acute Tox. 4 H332 Harmful if inhaled. Skin Irrit. 2 H315 Causes skin irritation. Classification according to Directive 67/548/EEC or Directive 1999/45/EC Not applicable. Information concerning particular hazards for human and environment: The product does not have to be labeled due to the calculation procedure of international guidelines. Classification system: The classification was made according to the latest editions of international substances lists, and expanded upon from company and literature data. Label elements Labelling according to EU guidelines: Observe the general safety regulations when handling chemicals. The product is not subject to identification regulations according to directives on hazardous materials. Hazard-determining components of labeling: Uranylacetat-Dihydrat (Contd. on page 2) CA

16 Safety Data Sheet acc. to OSHA HCS Page 2/8 Printing date 05/16/2015 Reviewed on 05/16/2015 Trade name: URANYL ACETATE 2% SOLUTION (Depleted Uranium) Classification system: NFPA ratings (scale 0-4) (Contd. of page 1) Health = 0 Fire = 0 Reactivity = 0 HMIS-ratings (scale 0-4) HEALTH FIRE REACTIVITY Health = 0 Fire = 0 Reactivity = 0 Other hazards Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. 3 Composition/information on ingredients Chemical characterization: Mixtures Description: Mixture of the substances listed below with nonhazardous additions. Dangerous components: Uranylacetat-Dihydrat 1-5% 4 First-aid measures Description of first aid measures General information: No special measures required. After inhalation: Supply fresh air; consult doctor in case of complaints. After skin contact: Generally the product does not irritate the skin. After eye contact: Rinse opened eye for several minutes under running water. After swallowing: If symptoms persist consult doctor. Most important symptoms and effects, both acute and delayed No further relevant information available. Indication of any immediate medical attention and special treatment needed No further relevant information available. 5 Fire-fighting measures Extinguishing media Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. Special hazards arising from the substance or mixture No further relevant information available. Advice for firefighters Protective equipment: No special measures required. 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Not required. Environmental precautions: Do not allow to enter sewers/ surface or ground water. (Contd. on page 3) CA

17 Safety Data Sheet acc. to OSHA HCS Page 3/8 Printing date 05/16/2015 Reviewed on 05/16/2015 Trade name: URANYL ACETATE 2% SOLUTION (Depleted Uranium) Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. (Contd. of page 2) 7 Handling and storage Precautions for safe handling No special measures required. Information about protection against explosions and fires: No special measures required. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: No special requirements. Information about storage in one common storage facility: Not required. Further information about storage conditions: None. Specific end use(s) No further relevant information available. 8 Exposure controls/personal protection Additional information about design of technical systems: No further data; see item 7. Control parameters Components with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. Additional information: The lists that were valid during the creation were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures: The usual precautionary measures for handling chemicals should be followed. Breathing equipment: Not required. Protection of hands: The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Goggles recommended during refilling. CA (Contd. on page 4)

18 Safety Data Sheet acc. to OSHA HCS Page 4/8 Printing date 05/16/2015 Reviewed on 05/16/2015 Trade name: URANYL ACETATE 2% SOLUTION (Depleted Uranium) (Contd. of page 3) 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: Liquid Color: Yellow Odor: Characteristic Odour threshold: Not determined. ph-value: Not determined. Change in condition Melting point/melting range: Undetermined. Boiling point/boiling range: 100 C Flash point: Not applicable. Flammability (solid, gaseous): Not flammable. Ignition temperature: Decomposition temperature: Not determined. Auto igniting: Product is not selfigniting. Danger of explosion: Product does not present an explosion hazard. Explosion limits: Lower: Upper: Vapor pressure at 20 C: 23 hpa Not determined. Not determined. Density: Not determined. Relative density Not determined. Vapour density Not determined. Evaporation rate Not determined. Solubility in / Miscibility with Water: Not miscible or difficult to mix. Partition coefficient (n-octanol/water): Not determined. Viscosity: Dynamic: Kinematic: Solvent content: Organic solvents: 0.0 % Water: 98.0 % Not determined. Not determined. Solids content: 4.0 % Other information No further relevant information available. 10 Stability and reactivity Reactivity Chemical stability Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. Possibility of hazardous reactions No dangerous reactions known. (Contd. on page 5) CA

19 Safety Data Sheet acc. to OSHA HCS Page 5/8 Printing date 05/16/2015 Reviewed on 05/16/2015 Trade name: URANYL ACETATE 2% SOLUTION (Depleted Uranium) Conditions to avoid No further relevant information available. Incompatible materials: No further relevant information available. Hazardous decomposition products: No dangerous decomposition products known. (Contd. of page 4) 11 Toxicological information Information on toxicological effects Acute toxicity: LD/LC50 values that are relevant for classification: Uranylacetat-Dihydrat Oral LD mg/kg (rat) Primary irritant effect: on the skin: No irritant effect. on the eye: No irritating effect. Sensitization: No sensitizing effects known. Additional toxicological information: The product is not subject to classification according to internally approved calculation methods for preparations: When used and handled according to specifications, the product does not have any harmful effects according to our experience and the information provided to us. Carcinogenic categories IARC (International Agency for Research on Cancer) None of the ingredients is listed. NTP (National Toxicology Program) None of the ingredients is listed. OSHA-Ca (Occupational Safety Health Administration) None of the ingredients is listed. 12 Ecological information Toxicity Aquatic toxicity: No further relevant information available. Persistence and degradability No further relevant information available. Bioaccumulative potential No further relevant information available. Mobility in soil No further relevant information available. Additional ecological information: General notes: Water hazard class 3 (Self-assessment): extremely hazardous for water Do not allow product to reach ground water, water course or sewage system, even in small quantities. Danger to drinking water if even extremely small quantities leak into the ground. Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. Other adverse effects No further relevant information available. CA (Contd. on page 6)

20 Safety Data Sheet acc. to OSHA HCS Page 6/8 Printing date 05/16/2015 Reviewed on 05/16/2015 Trade name: URANYL ACETATE 2% SOLUTION (Depleted Uranium) (Contd. of page 5) 13 Disposal considerations Waste treatment methods Recommendation: Smaller quantities can be disposed of with household waste. Uncleaned packagings: Recommendation: Disposal must be made according to official regulations. 14 Transport information UN-Number DOT, TDG, IMDG, IATA UN2910 UN proper shipping name DOT Radioactive material, excepted package-limited quantity of material TDG 2910 Radioactive material, excepted package-limited quantity of material IMDG, IATA RADIOACTIVE MATERIAL, EXCEPTED PACKAGE - LIMITED QUANTITY OF MATERIAL Transport hazard class(es) DOT Class 7 Radioactive material Label 7x TDG (Transport dangerous goods): Class 7 Radioactive material Label 7X IMDG, IATA Class 7 Radioactive material Environmental hazards: Marine pollutant: No Special marking (TDG): Symbol (fish and tree) Special precautions for user Warning: Radioactive material Danger code (Kemler): 70 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Transport/Additional information: Not applicable. TDG Excepted quantities (EQ) Code: E0 Not permitted as Excepted Quantity (Contd. on page 7) CA

21 Safety Data Sheet acc. to OSHA HCS Page 7/8 Printing date 05/16/2015 Reviewed on 05/16/2015 Trade name: URANYL ACETATE 2% SOLUTION (Depleted Uranium) IMDG Limited quantities (LQ) 0 Excepted quantities (EQ) Code: E0 Not permitted as Excepted Quantity (Contd. of page 6) UN "Model Regulation": UN2910, Radioactive material, excepted package-limited quantity of material, 7X 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Sara Section 355 (extremely hazardous substances): None of the ingredients is listed. Section 313 (Specific toxic chemical listings): None of the ingredients is listed. TSCA (Toxic Substances Control Act): water, distilled, conductivity or of similar purity Proposition 65 Chemicals known to cause cancer: None of the ingredients is listed. Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed. Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. Chemicals known to cause developmental toxicity: None of the ingredients is listed. Carcinogenic categories EPA (Environmental Protection Agency) None of the ingredients is listed. TLV (Threshold Limit Value established by ACGIH) Uranylacetat-Dihydrat A1 NIOSH-Ca (National Institute for Occupational Safety and Health) Uranylacetat-Dihydrat Canadian substance listings: Canadian Domestic Substances List (DSL) water, distilled, conductivity or of similar purity Canadian Ingredient Disclosure list (limit 0.1%) None of the ingredients is listed. Canadian Ingredient Disclosure list (limit 1%) None of the ingredients is listed. Product related hazard informations: Observe the general safety regulations when handling chemicals. (Contd. on page 8) CA

22 Safety Data Sheet acc. to OSHA HCS Page 8/8 Printing date 05/16/2015 Reviewed on 05/16/2015 Trade name: URANYL ACETATE 2% SOLUTION (Depleted Uranium) (Contd. of page 7) The product is not subject to identification regulations according to directives on hazardous materials. Hazard-determining components of labeling: Uranylacetat-Dihydrat Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Date of preparation / last revision 05/16/2015 / - Abbreviations and acronyms: IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent Acute Tox. 4: Acute toxicity, Hazard Category 4 Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2 STOT RE 2: Specific target organ toxicity - Repeated exposure, Hazard Category 2 CA

23 Safety data sheet according to 1907/2006/EC, Article 31 Page 1/7 Printing date Revision: SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Trade name: URANYL ACETATE 2% SOLUTION (Depleted Uranium) Article number: Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. Application of the substance / the mixture Laboratory chemicals 1.3 Details of the supplier of the safety data sheet Manufacturer/Supplier: Electron Microscopy Sciences 1560 Industry Road USA-Hatfield, PA Tel: Fax: Further information obtainable from: Product safety department 1.4 Emergency telephone number: ChemTrec Contract CCN SECTION 2: Hazards identification 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 GHS07 Acute Tox. 4 H302 Harmful if swallowed. Acute Tox. 4 H332 Harmful if inhaled. Skin Irrit. 2 H315 Causes skin irritation. 2.2 Label elements Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. Hazard pictograms GHS07 Signal word Warning Hazard-determining components of labelling: Uranylacetat-Dihydrat Hazard statements H302+H332 Harmful if swallowed or if inhaled. H315 Causes skin irritation. Precautionary statements P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P280 Wear protective gloves/protective clothing/eye protection/face protection. P321 Specific treatment (see on this label). P362 Take off contaminated clothing and wash before reuse. (Contd. on page 2) GB

24 Safety data sheet according to 1907/2006/EC, Article 31 Page 2/7 Printing date Revision: Trade name: URANYL ACETATE 2% SOLUTION (Depleted Uranium) (Contd. of page 1) P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. 2.3 Other hazards Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. SECTION 3: Composition/information on ingredients 3.2 Chemical characterisation: Mixtures Description: Mixture of substances listed below with nonhazardous additions. Dangerous components: CAS: EINECS: Uranylacetat-Dihydrat Acute Tox. 2, H300; Acute Tox. 2, H330; STOT RE 2, H373; Aquatic Chronic 2, H % SECTION 4: First aid measures 4.1 Description of first aid measures General information: No special measures required. After inhalation: Supply fresh air; consult doctor in case of complaints. After skin contact: Generally the product does not irritate the skin. After eye contact: Rinse opened eye for several minutes under running water. After swallowing: If symptoms persist consult doctor. 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable extinguishing agents: CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam. 5.2 Special hazards arising from the substance or mixture No further relevant information available. 5.3 Advice for firefighters Protective equipment: No special measures required. SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Not required. 6.2 Environmental precautions: Do not allow to enter sewers/ surface or ground water. 6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). 6.4 Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. GB (Contd. on page 3)

25 Safety data sheet according to 1907/2006/EC, Article 31 Page 3/7 Printing date Revision: Trade name: URANYL ACETATE 2% SOLUTION (Depleted Uranium) (Contd. of page 2) SECTION 7: Handling and storage 7.1 Precautions for safe handling No special measures required. Information about fire - and explosion protection: No special measures required. 7.2 Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: No special requirements. Information about storage in one common storage facility: Not required. Further information about storage conditions: None. 7.3 Specific end use(s) No further relevant information available. SECTION 8: Exposure controls/personal protection Additional information about design of technical facilities: No further data; see item Control parameters Ingredients with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. Additional information: The lists valid during the making were used as basis. 8.2 Exposure controls Personal protective equipment: General protective and hygienic measures: The usual precautionary measures are to be adhered to when handling chemicals. Respiratory protection: Not required. Protection of hands: The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Goggles recommended during refilling SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties General Information Appearance: Form: Liquid Colour: Yellow Odour: Characteristic Odour threshold: Not determined. ph-value: Not determined. (Contd. on page 4) GB

26 Safety data sheet according to 1907/2006/EC, Article 31 Page 4/7 Printing date Revision: Trade name: URANYL ACETATE 2% SOLUTION (Depleted Uranium) Change in condition Melting point/melting range: Undetermined. Boiling point/boiling range: 100 C Flash point: Not applicable. Flammability (solid, gaseous): Not applicable. Ignition temperature: Decomposition temperature: Not determined. Self-igniting: Product is not selfigniting. Danger of explosion: Product does not present an explosion hazard. Explosion limits: Lower: Upper: Vapour pressure at 20 C: 23 hpa Not determined. Not determined. Density: Not determined. Relative density Not determined. Vapour density Not determined. Evaporation rate Not determined. Solubility in / Miscibility with water: Not miscible or difficult to mix. Partition coefficient (n-octanol/water): Not determined. Viscosity: Dynamic: Kinematic: Not determined. Not determined. Solvent content: Organic solvents: 0.0 % Water: 98.0 % VOC (EC) 0.00 % Solids content: 4.0 % 9.2 Other information No further relevant information available. (Contd. of page 3) SECTION 10: Stability and reactivity 10.1 Reactivity 10.2 Chemical stability Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications Possibility of hazardous reactions No dangerous reactions known Conditions to avoid No further relevant information available Incompatible materials: No further relevant information available Hazardous decomposition products: No dangerous decomposition products known. GB (Contd. on page 5)

27 Safety data sheet according to 1907/2006/EC, Article 31 Page 5/7 Printing date Revision: Trade name: URANYL ACETATE 2% SOLUTION (Depleted Uranium) (Contd. of page 4) SECTION 11: Toxicological information 11.1 Information on toxicological effects Acute toxicity: LD/LC50 values relevant for classification: Uranylacetat-Dihydrat Oral LD mg/kg (rat) Primary irritant effect: on the skin: No irritant effect. on the eye: No irritating effect. Sensitisation: No sensitising effects known. Additional toxicological information: The product is not subject to classification according to the calculation method of the General EU Classification Guidelines for Preparations as issued in the latest version. When used and handled according to specifications, the product does not have any harmful effects to our experience and the information provided to us. SECTION 12: Ecological information 12.1 Toxicity Aquatic toxicity: No further relevant information available Persistence and degradability No further relevant information available Bioaccumulative potential No further relevant information available Mobility in soil No further relevant information available. Additional ecological information: General notes: Water hazard class 3 (German Regulation) (Self-assessment): extremely hazardous for water Do not allow product to reach ground water, water course or sewage system, even in small quantities. Danger to drinking water if even extremely small quantities leak into the ground Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable Other adverse effects No further relevant information available. SECTION 13: Disposal considerations 13.1 Waste treatment methods Recommendation Smaller quantities can be disposed of with household waste. Uncleaned packaging: Recommendation: Disposal must be made according to official regulations. SECTION 14: Transport information 14.1 UN-Number ADR, IMDG, IATA UN2910 (Contd. on page 6) GB

28 Safety data sheet according to 1907/2006/EC, Article 31 Page 6/7 Printing date Revision: Trade name: URANYL ACETATE 2% SOLUTION (Depleted Uranium) (Contd. of page 5) 14.2 UN proper shipping name ADR 2910 RADIOACTIVE MATERIAL, EXCEPTED PACKAGE - LIMITED QUANTITY OF MATERIAL IMDG, IATA RADIOACTIVE MATERIAL, EXCEPTED PACKAGE - LIMITED QUANTITY OF MATERIAL 14.3 Transport hazard class(es) ADR Class 7 Radioactive material. Label 7X IMDG, IATA Class 7 Radioactive material Environmental hazards: Marine pollutant: No Special marking (ADR): Symbol (fish and tree) 14.6 Special precautions for user Warning: Radioactive material. Danger code (Kemler): Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Transport/Additional information: Not applicable. ADR Limited quantities (LQ) 0 Excepted quantities (EQ) Code: E0 Not permitted as Excepted Quantity Transport category 4 Tunnel restriction code E IMDG Limited quantities (LQ) 0 Excepted quantities (EQ) Code: E0 Not permitted as Excepted Quantity UN "Model Regulation": UN2910, RADIOACTIVE MATERIAL, EXCEPTED PACKAGE - LIMITED QUANTITY OF MATERIAL, 7X SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture No further relevant information available Chemical safety assessment: A Chemical Safety Assessment has not been carried out. GB (Contd. on page 7)

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