ULTRAVIEW UNIVERSAL DAB CHROMOGEN
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1 SECTION 1. IDENTIFICATION Product name : Mat.-No./ Genisys-No. : Manufacturer or supplier's details Company name of supplier : Roche Diagnostics - Address : 9115 Hague Road Indianapolis IN Telephone : Emergency telephone number: In case of emergencies: : CHEMTREC (U.S. or Canada) (International) Recommended use of the chemical and restrictions on use Restrictions on use : For professional users only. SECTION 2. HAZARDS IDENTIFICATION GHS Classification Carcinogenicity : Category 1B GHS Label element Hazard pictograms : Signal word Hazard statements Precautionary statements : Danger : H350 May cause cancer. : Prevention: P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. Response: P308 + P313 IF exposed or concerned: Get medical advice/ attention. Storage: P405 Store locked up. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant. 1 / 12
2 Other hazards None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Hazardous components Chemical Name CAS-No. Concentration (%) Polyethylene glycol >= 5 - < 10 biphenyl-3,3',4,4'-tetrayltetraammonium tetrachloride >= < 1 SECTION 4. FIRST AID MEASURES General advice If inhaled In case of skin contact In case of eye contact If swallowed Most important symptoms and effects, both acute and delayed Notes to physician : Move out of dangerous area. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended. : Move to fresh air. If unconscious place in recovery position and seek medical advice. If symptoms persist, call a physician. : If on skin, rinse well with water. : Immediately flush eye(s) with plenty of water. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. : Keep respiratory tract clear. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. Take victim immediately to hospital. Rinse mouth with water. : May cause cancer. : The first aid procedure should be established in consultation with the doctor responsible for industrial medicine. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. 2 / 12
3 Unsuitable extinguishing media Specific hazards during firefighting Hazardous combustion products Further information Special protective equipment for firefighters : High volume water jet : No information available. : No hazardous combustion products are known : Standard procedure for chemical fires. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. : Wear self-contained breathing apparatus for firefighting if necessary. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up : Use personal protective equipment. Refer to protective measures listed in sections 7 and 8. : Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. : Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal. SECTION 7. HANDLING AND STORAGE Advice on protection against fire and explosion Advice on safe handling Conditions for safe storage : Normal measures for preventive fire protection. : Do not breathe vapours/dust. Avoid exposure - obtain special instructions before use. Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Dispose of rinse water in accordance with local and national regulations. : Keep container tightly closed in a dry and well-ventilated place. Observe label precautions. Electrical installations / working materials must comply with the technological safety standards. 3 / 12
4 SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Hazardous components without workplace control parameters Components CAS-No. Value type (Form of exposure) Polyethylene glycol TWA (aerosol) Components biphenyl-3,3',4,4'- tetrayltetraammonium tetrachloride Engineering measures CAS-No Control parameters / Permissible Basis concentration 10 mg/m3 US WEEL Personal protective equipment Respiratory protection Hand protection : In the case of vapour formation use a respirator with an approved filter. Material : Protective gloves Remarks Eye protection Skin and body protection Hygiene measures : The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. This recommendation is only valid for the product mentioned in the safety data sheet and provided by us and for the application specified by us. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time. The suitability for a specific workplace should be discussed with the producers of the protective gloves. : Eye wash bottle with pure water Tightly fitting safety goggles : impervious clothing Choose body protection according to the amount and concentration of the dangerous substance at the work place. : When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES 4 / 12
5 Appearance Colour Odour Odour Threshold ph Melting point/range Boiling point/boiling range Flash point Evaporation rate Flammability (solid, gas) Upper explosion limit Lower explosion limit Vapour pressure Relative vapour density Relative density Density Solubility(ies) Partition coefficient: n- octanol/water Auto-ignition temperature Decomposition temperature Viscosity Explosive properties Oxidizing properties : liquid : colourless : none : neutral : does not flash : The product is not flammable. : The substance or mixture is not classified as oxidizing. SECTION 10. STABILITY AND REACTIVITY Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products : No dangerous reaction known under conditions of normal use. : Stable under normal conditions. : Reacts with the following substances: Oxidizing agents No decomposition if stored and applied as directed. : Carbon oxides 5 / 12
6 SECTION 11. TOXICOLOGICAL INFORMATION Acute toxicity Product: Acute oral toxicity : Acute toxicity estimate: > 5,000 mg/kg Method: Calculation method Acute dermal toxicity : Acute toxicity estimate: > 5,000 mg/kg Method: Calculation method Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity : LD50 Oral (Rat): > 50,000 mg/kg : Acute toxicity estimate: > 30 mg/l Method: Expert judgement : LD50 Dermal (Rabbit): > 20,000 mg/kg Skin corrosion/irritation Remarks: This information is not available. Remarks: This information is not available. Serious eye damage/eye irritation Remarks: This information is not available. Remarks: This information is not available. Respiratory or skin sensitisation Skin sensitisation: Respiratory sensitisation: Germ cell mutagenicity Germ cell mutagenicity - : In vitro tests showed mutagenic effects Assessment 6 / 12
7 Carcinogenicity May cause cancer. Carcinogenicity - Assessment : Presumed to have carcinogenic potential for humans IARC OSHA NTP No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. Reproductive toxicity STOT - single exposure Assessment: The substance or mixture is not classified as specific target organ toxicant, single exposure. Assessment: The substance or mixture is not classified as specific target organ toxicant, single exposure. STOT - repeated exposure Assessment: The substance or mixture is not classified as specific target organ toxicant, repeated exposure. Assessment: The substance or mixture is not classified as specific target organ toxicant, repeated exposure. Aspiration toxicity No data available 7 / 12
8 No data available SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Product: Ecotoxicology Assessment Toxicity Data on Soil Other organisms relevant to the environment : Not expected to adsorb on soil. Toxicity to fish Ecotoxicology Assessment Acute aquatic toxicity Chronic aquatic toxicity Toxicity Data on Soil Other organisms relevant to the environment : LC50: > 100 mg/l Exposure time: 96 h : This product has no known ecotoxicological effects. : This product has no known ecotoxicological effects. : Not expected to adsorb on soil. Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 32 mg/l aquatic invertebrates Exposure time: 24 h Ecotoxicology Assessment Toxicity Data on Soil Other organisms relevant to the environment : Not expected to adsorb on soil. Persistence and degradability No data available Bioaccumulative potential No data available Mobility in soil No data available Other adverse effects Product: Ozone-Depletion Potential : Regulation: 40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I Substances Remarks: This product neither contains, nor was manufac- 8 / 12
9 tured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). Adsorbed organic bound halogens (AOX) : Remarks: Not applicable SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues Contaminated packaging : Do not contaminate ponds, waterways or ditches with chemical or used container. Send to a licensed waste management company. : Empty remaining contents. Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers. SECTION 14. TRANSPORT INFORMATION International Regulation IATA-DGR Not regulated as a dangerous good IMDG-Code Not regulated as a dangerous good Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. National Regulations 49 CFR Not regulated as a dangerous good SECTION 15. REGULATORY INFORMATION TSCA list : Not relevant EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards : Chronic Health Hazard 9 / 12
10 SARA 302 SARA 313 : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Clean Air Act This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 12 (40 CFR 61). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR , Subpart F). The following chemical(s) are listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR ): Polyethylene glycol % Clean Water Act This product does not contain any Hazardous Substances listed under the U.S. CleanWater Act, Section 311, Table 116.4A. This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act, Section 311, Table This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section 307 Massachusetts Right To Know Pennsylvania Right To Know New Jersey Right To Know No components are subject to the Massachusetts Right to Know Act. water % Polyethylene glycol % water % Polyethylene glycol % California Prop 65 This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. The components of this product are reported in the following inventories: REACH : Not in compliance with the inventory : Polyethylene glycol : biphenyl-3,3',4,4'-tetrayltetraammonium tetrachloride : Brij 35 : disodium disulphite 10 / 12
11 : Citric acid monohydrate : Gentamicin, sulfate (salt) CH INV : Not in compliance with the inventory TSCA : Not On TSCA Inventory : Gentamicin, sulfate (salt) DSL : This product contains the following components that are not on the Canadian DSL nor NDSL. : Gentamicin, sulfate (salt) AICS : Not in compliance with the inventory NZIoC ENCS : On the inventory, or in compliance with the inventory : Not in compliance with the inventory : water : biphenyl-3,3',4,4'-tetrayltetraammonium tetrachloride ISHL : Not in compliance with the inventory : water : biphenyl-3,3',4,4'-tetrayltetraammonium tetrachloride KECI : Not in compliance with the inventory : biphenyl-3,3',4,4'-tetrayltetraammonium tetrachloride PICCS IECSC : On the inventory, or in compliance with the inventory : On the inventory, or in compliance with the inventory Inventories 11 / 12
12 Health Instability SAFETY DATA SHEET AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA) SECTION 16. OTHER INFORMATION Further information NFPA: Flammability HMIS III: 0 0 HEALTH 0 FLAMMABILITY 0* 1 PHYSICAL HAZARD 0 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Revision Date : The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. US / EN 12 / 12
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