Hazardous Waste Management January 25, 2016 Laboratory Use Orientation and Safety Seminar

Transcription

1 Hazardous Waste Management January 25, 2016 Laboratory Use Orientation and Safety Seminar

2 Context Toxic Substances and Hazardous and Nuclear Wastes Control Act of 1990 (RA 6969) It has been recognized that the public and the environment are at risk in the use or exposure to chemicals as well as the long term damage brought about by careless handling or disposal of hazardous wastes harvardmodelcongress.org

3 Context DChE Laboratory is an EMB-registered HazWaste Generator DChE Lab-WMS approved in August 2011 harvardmodelcongress.org

4 Hazardous Waste Management Anticipate Minimize Contain Label Dispose

5 Anticipate Your Waste

6 Waste Classification Non-hazardous waste Solids Sharp solids (e.g. broken glass) Non-sharp solids Office waste (e.g. paper) Liquids 6

7 Waste Classification Hazardous waste waste that exhibits one or more of the following characteristics 7

8 Waste Management Plan Must be submitted BEFORE being allowed to work in the laboratory Expected wastes to be generated and corresponding amounts Type of waste container to be used Inform adviser/labcom of any changes in WMP in cases of unexpected developments on the course of experimentation 8

9 WMP Template LAB FORM 4A Waste Management Plan Department of Chemical Engineering, University of the Philippines Diliman This form is to be accomplished for the application for the ChE Laboratory Use Permit. Attach a printed copy of this form to LAB FORM 1. Please submit an e- copy to hseofficerdche@gmail.com. TITLE OF THE RESEARCH: Name of Activity Waste generated (One waste per row) Quantity Concentration Type Proposed Action (Hazardous*/ (kg) (if applicable) On-site Treatment and Disposal Storage for 3 rd Party Collection Non-Hazardous) Prepared by: Name/s Degree and Program of Study Signature & Date Endorsed by: Approved by: Printed Name and Signature of Adviser & Date Julie Anne D. del Rosario, HSE Officer 9

10 WMP Template LAB FORM 4A Waste Management Plan Department of Chemical Engineering, University of the Philippines Diliman This form is to be accomplished for the application for the ChE Laboratory Use Permit. Attach a printed copy of this form to LAB FORM 1. Please submit an e- copy to hseofficerdche@gmail.com. TITLE OF THE RESEARCH: Name of Activity Waste generated (One waste per row) Quantity Concentration Type Proposed Action (Hazardous*/ (kg) (if applicable) On-site Treatment and Disposal Storage for 3 rd Party Collection Non-Hazardous) Prepared by: Name/s Degree and Program of Study Signature & Date Endorsed by: Approved by: Printed Name and Signature of Adviser & Date Julie Anne D. del Rosario, HSE Officer 10

11 WMP Template LAB FORM 4A Waste Management Plan Department of Chemical Engineering, University of the Philippines Diliman This form is to be accomplished for the application for the ChE Laboratory Use Permit. Attach a printed copy of this form to LAB FORM 1. Please submit an e- copy to hseofficerdche@gmail.com. TITLE OF THE RESEARCH: Name of Activity Waste generated (One waste per row) Quantity Concentration Type Proposed Action (Hazardous*/ (kg) (if applicable) On-site Treatment and Disposal Storage for 3 rd Party Collection Non-Hazardous) Prepared by: Name/s Degree and Program of Study Signature & Date Endorsed by: Approved by: Printed Name and Signature of Adviser & Date Julie Anne D. del Rosario, HSE Officer 11

12 WMP Template LAB FORM 4A Waste Management Plan Department of Chemical Engineering, University of the Philippines Diliman This form is to be accomplished for the application for the ChE Laboratory Use Permit. Attach a printed copy of this form to LAB FORM 1. Please submit an e- copy to hseofficerdche@gmail.com. TITLE OF THE RESEARCH: Name of Activity Waste generated (One waste per row) Quantity Concentration Type Proposed Action (Hazardous*/ (kg) (if applicable) On-site Treatment and Disposal Storage for 3 rd Party Collection Non-Hazardous) Prepared by: Name/s Degree and Program of Study Signature & Date Endorsed by: Approved by: Printed Name and Signature of Adviser & Date Julie Anne D. del Rosario, HSE Officer 12

13 WMP Template LAB FORM 4A Waste Management Plan Department of Chemical Engineering, University of the Philippines Diliman This form is to be accomplished for the application for the ChE Laboratory Use Permit. Attach a printed copy of this form to LAB FORM 1. Please submit an e- copy to hseofficerdche@gmail.com. TITLE OF THE RESEARCH: Name of Activity Waste generated (One waste per row) Quantity Concentration Type Proposed Action (Hazardous*/ (kg) (if applicable) On-site Treatment and Disposal Storage for 3 rd Party Collection Non-Hazardous) Prepared by: Name/s Degree and Program of Study Signature & Date Endorsed by: Approved by: Printed Name and Signature of Adviser & Date Julie Anne D. del Rosario, HSE Officer 13

14 Minimize

15 Why minimize waste? Reduce costs Increase process efficiency and productivity Reduce present and future regulatory burdens Improve workplace safety Improve environmental quality Maintain or improve institutional image

16 How can you minimize waste? Plan ahead Order only the amount needed Avoid storing excess chemicals Share unneeded chemicals Keep chemicals properly labeled

17 Instructional Laboratory Reagents to be used in the experiments are to be prepared by the instructors. Chemical wastes generated during experiments are to placed in designated containers located in the instructional laboratories. Enter amount/concentration of waste in the waste logbook provided by the instructor. Call the attention of your instructor if there are any unused chemicals left after experiment 17

18 Contain 18

19 Waste Containers Material must be compatible with waste Examples: Acids and bases: do NOT store in metal Hydrofluoric acid: do NOT store in glass Gasoline/solvents: do NOT store in lightweight polyethylene containers Do NOT completely fill container; allow some space above (~10%) Secondary containment 19

20 Waste Storage Do NOT place waste containers on: Floor Fume hood Sink Always ensure that containers are capped properly at all times Place incompatible chemical wastes as far apart from each other as possible 20

21 Waste Storage 21

22 Compatibility 22

23 Label 23

24 UPD Chemical Engineering Laboratory HAZARDOUS WASTE Waste Label Waste Information HW Class Name of the hazardous waste class as specified in Container Information HW Description HW Number Characteristic Form Volume Packaging date Capacity Material DAO Table 1-1 Name of the hazardous waste description as specified in DAO Table 1-1 Code of the hazardous waste description as specified in DAO Table 1-1 Toxic, Corrosive, Flammable, Explosive, Reactive, and/or Infectious Liquid, Solid, or Sludge Volume of the hazardous waste contained in the container Date on which the hazardous waste is packed in the container (when the container is 90% full or upon collection) Maximum capacity or volume of the container Material of construction of the container 24

25 Hazardous Waste Number Excerpt from DAO Table 1-1: 25

26 Waste Logbook Laboratory: Room: Adviser/s: Name of student Date Chemical name Amount (kg ) Conc. (kg/l, if applicable) Waste number (refer to DAO) When container is nearly full (90%) or when container is collected, tabulate the total amounts (contents and concentration if applicable) on the last row/s 26

27 Waste symbols To be attached to the waste container Definitions given in DAO Will be provided by the department 27

28 Dispose 28

29 Down the sink with copious water 29

30 Documentation 30

31 LAB FORM 4B Lab Form 4B: Waste Management Report Waste Management Report Department of Chemical Engineering, University of the Philippines Diliman This form is to be accomplished for the application for ChE Laboratory Clearance. Please attach approved LAB FORM 4A: Waste Management Plan For the e-copy, please retain all rows in this document. Submit via to For the printed copy, please hide rows without inputs. B HW No. HW Class HW Nature HW Cataloguing B201 B202 B203 B206 B208 B299 Acid Wastes Sulfuric Acid Hydrochloric Acid Nitric Acid Mixture of Sulfuric and Hydrochloric Acid Organic Acid Other Acid Wastes Unknown Acid Wastes HW Generated Quantity Unit 31

32 Waste Management Report Contents of report shall be verified by the Research Lab Head, and reviewed by the HSE Officer. Data on the reports, waste logbook and waste container labels should be consistent 32

33 References National Academy of Sciences, Prudent Practices in the Laboratory Handling and Disposal of Chemicals. Stanford University EH&S Chemical Waste Program. UC San Diego, How to store and dispose of hazardous chemical waste. University of Kentucky, Laboratory waste disposal. UP Diliman Department of Chemical Engineering, Laboratory Waste Management System. UT Tyler EH&S, Laboratory Waste Management Guidelines. 34

34 Thank You! Any questions? 35