ThyssenKrupp Metallurgie

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1 Supplier: THYSSENKRUPP Metallurgie Altendorfer Straße 120 D Essen Tel: +49-(0) Fax: +49-(0) Product name: SILICON CARBIDE Gültig ab Fassung Nr. 02 Ausdruck : Identification of the substance/preparation and of the company/undertaking: 1.1 Identification of the substance or preparation: Black Silicon Carbide 1.2 Company/undertaking identification: Altendorfer Straße 120 D Essen Tel: Fax: Contact Person: Mr. Mis 1.4 Emergency call: Poison control Center Mainz, Tel.: / Fax:: Composition/Information of ingredients: Chemical characterisation: SiC % CAS-Nr.: EINECS-Nr.: Dangerous Contents: 3. Hazards identification: Eyes: May cause mechanical irritation Skin: Can cause mild irritation Inhalation: Can cause mild upper respiration tract irritation. Prolonged or repeated inhalation may cause lung damage; Cancer hazard Ingestion: Can cause mild irritation Chemical ingredient and possible processing hazards: Chronic exposure to crystalline silica in excess of permissible limits can result in fibrotic lung disease (silcosis). Inhalation studies in experimental animals at doses in excess of the PEL for crystalline silica have resulted in lung tumors. Other routes of administration(intrapleural, intrathoracic) have also resulted in the formation of tumors (lymphoid tumors, adenocarcinomas). Crystalline silica is listed on the NTP and listed as carcinogenic to humans by IARC (Group 1) Silicon carbide dust may cause mild irritation of upper respiratory tract on acute overexposure. Chronic

2 overexposure to particulates of respirable size may cause lung inflammation, difficult breathing, chest pain coughing, and pneumoconiosis or possible fibrotic changes in the lungs. Dust containing carbon can cause eye, mucous membrane, and upper respiratory tract irritation. Overexposure to dust containing carbon can cause scarring of the lungs. Chronic exposure to inert dusts of silicon can cause increased airways resistance and contribute to chronic bronchitis. Intratracheal administration of silicon in rabbits produced significant pulmonary lesions. High exposures to iron oxide dust or fume can cause x-ray changes (siderosis or iron pigmentation) in the lungs as a result of long-term exposure. Siderosis is a benign condition and is not associated with pulmonary fibrosis (scarring of the lung). Ingestion of high levels of iron oxide can cause gastrointestinal irritation, bleeding and systematic toxicity. Aluminium dust/fines and fumes are a low risk by inhalation and should be treated as a nuisance dust as specified by the ACGIH. Hazard description: Medical conditions aggravated by exposure to the product: Asthma, chronic lung disease and skin rashes. Information pertaining to particular dangers for man and environment: See item 11 Classification system: The classification was made according to the latest editions of the EU-lists, and expanded upon from company and literature data. 4. First Aid measures: In case of inhalation: Remove to fresh air; check for clear airway, breathing, and presence of pulse. Provide cardiopulmonary resuscitation for persons without pulse or respiration. Consult a physician. In case of having swallowed the product: Dilute by drinking large amounts of water. Do not induce vomiting. Never give anything by mouth to a convulving or unconscious person. Consult a physician. In case of contact with the eyes: Flush eyes with plenty of water of at least 15 minutes. Consult a physician In case of skin contact: Wash with soap and water for at least 15 minutes. Consult a physician if irritation persists. 5. Fire-Fighting measures: Suitable extinguishing agents: Use fire fighting methods and materials that are appropriate for surrounding fire. Protective equipment: Wear self-contained respiratory protective device. Wear fully protective suit.

3 6. Accidental release measures: Personal precautions: Avoid formation of dust Environmental precautions: No special measures required Methods for cleaning up: Pick up mechanically 7. Handling and Storage: Storage: The product is not flammable; No special requirements Requirements to be met by storerooms and receptacles: No special requirements Handling: Prevent formation of dust. Provide suction extractors if dust is formed 8. Exposure controls/ personal protection: Additional information about design of technical systems No further data; see item 7. ACGIH TLV: 10 mg/m^3 OSHA PEL: 15*; 5** mg/m^3 * total dust ** respirable fraction Quartz (SiO2) ACGIH TLV : 0,1 mg/m^3 OSHA : 0,1 **, 0,3* mg/m^3 Aluminium OSHA : 15 total ; 5 respirable mg/m^3 TLV : 10 dust, 5 fume mg/m^3 General protective equipment: - General protective and hygienic measures The usual precautionary measures for handling chemicals should be followed Breathing equipment: Use suitable respiratory protective device in case of insufficient ventilation Short term filter device: Filter NIOSH N 95 Protection of hands: Impervious gloves Eye protection: Safety glasses 9. Physical and chemical properties: General information: Form: Solid in various forms

4 Colour: Black Odor: Odorless Other Information: Melting point: Not determined Boiling point: Not determined Flash Point: Not applicable Auto igniting: Product is not self igniting Danger of explosion: Product does not present an explosion hazard Density: at 20 C: 3,208 g/cm^3 Water: Insoluble Organic solvents: 0,0 % Solid contents: 100 % 10. Stability and reactivity: Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications Reactions: No dangerous reactions known Dangerous products of decomposition: No dangerous decomposition products known Additional information: Non-corrosive 11. Toxicological Information: Acute toxicity:- Primary irritant effect:- On the skin: May cause mild irritation On the eye:: May cause mechanical irritation Inhalation: Can cause mild upper respioratory tract iirritation Ingestion: Can cause mild irritation Additional toxicological information: The product is not subject to classification according to the calculation method of the General EU Classification Guidelines for the Preparations as issued in the latest version. 12. Ecological Information: General notes: Generally not hazardous for water 13. Disposal Information: Product:- Recommendation: Collect in containers, bags, or covered dumpster boxes. If reuse of orrecycling is not possible, material may be disposed of at an industrial landfill.

5 Uncleaned packagings: Recommendation: Disposal must be made according to official regulations 14. Transport information: U.S.A.DOT: Not regulated- Enter the proper freight classification MSDS Number, and Product name on the shipping paperwork Canadian TDG Hazard Class & PIN: Not regulated Marine pollutant: No 15. Regulatory Information: U.S. federation Regulations: TSCA STATUS: All components of this product are listed on the TSCA inventory CERCLA REPORTABLE QUANTITY: None SARA TITLE III: Section 302 Extremely Hazardous Substances : None Section 313 Toxic Categories: Aluminium (fume/dust) 16. Others: In reference to Title VI of the Clean Air Act 1990, this material does not contain nor was it manufactured using ozone-depleting chemicals California Proposition 65: Quartz (Silica, crystalline) is known to the State of California to cause cancer Markings according to EU guidelines: The product is not subject to identification regulations under EU Directives and the Ordinance on Hazardous Materials (GefStoffV) Water hazard class: Generally not hazardous for water International Regulations: CANADIAN DOMESTIC SUBSTANCES LIST: All components of this product are listed on the Canadian DSL. AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES: All components of this product are listed on the AICS. Disclaimer: This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationsship

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