Creation Date 29.11.96 Revision Date 29.11.96 Revision Number 2 Page 1 of 6 1 PRODUCT NAME: BAQUA OUT PRODUCT CODE: 20 08 591 005 2 COMPOSITION/INFORMATION ON INGREDIENTS Chemical characterisation: Chelating Agent Product Code: 06175 EEC-No: 200-573-9 INGREDIENTS CAS No. Hazard symbols R-Phrases Concentration Ethylene diamine tetra acetic acid tetra sodium salt 64-02-8 Xn R22-R36 75.. 100% 3 HAZARDS IDENTIFICATION Harmful if swallowed. Irritating to eyes. 4 FIRST-AID MEASURES Eye Contact Skin Contact Inhalation Ingestion Immediately irrigate with eyewash solution or clean water, holding the eyelids apart, for at least 10 minutes. Obtain immediate medical attention. Wash immediately with water followed by soap and water. If symptoms develop, obtain medical attention. Remove patient from exposure. Obtain medical attention if ill effects occur. Provided the patient is conscious, wash out mouth with water and give 200-300 ml (half a pint) of water to drink. Do not induce vomiting. Obtain immediate medical attention. Information for Physicians Treatment Symptomatic treatment and supportive therapy as indicated. 5 FIRE-FIGHTING MEASURES Special hazards Protective Equipment Extinguishing Agents Not classed as flammable. The material may form flammable dust clouds in air. If involved in a fire, it may emit noxious and toxic fumes. Suitable respiratory protection. Water spray or foam.
Creation Date 29.11.96 Revision Date 29.11.96 Revision Number 2 Page 2 of 6 6 ACCIDENTAL RELEASE MEASURES Personal precautions Environmental precautions Methods for cleaning up Ensure suitable personal protection during removal of spillages. Do not allow to enter drains, sewers of water courses. Spillages or uncontrolled discharges into water courses must be alerted to the National Rivers Authority. Clear up spillages. Protect against dust. Transfer to a container for disposal. Wash the spillage area clean. 7 HANDLING AND STORAGE Handling Safe handling advice Measures to prevent fire and explosions Storage Requirements for storage rooms Recommended materials: Unsuitable materials: Materials not to be stored together Avoid inhalation of high concentrations of dusts. Avoid contact with skin and eyes. Keep locked up and out of reach of children. Keep away from food, drink and animal feeding stuffs. Keep away from heat and sources of ignition. Keep only in the original container in a cool, well ventilated place. Keep out of reach of children and away from food. Keep away from strong acids, oxidising agents. Polyethylene Metals; copper; aluminium; zinc. Strong oxidising agents, acids 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Additional information on technical system design Technical measures Personal protection Respiratory protection Eye protection Hand protection Body protection Where engineering controls are not fitted or inadequate wear suitable respiratory protective equipment.
Creation Date 29.11.96 Revision Date 29.11.96 Revision Number 2 Page 3 of 6 9 PHYSICAL AND CHEMICAL PROPERTIES Form powder Colour white Odour almost odourless Boiling Point Melting Point > 400 C Flash Point > 100 C Flammability (solid, gas) Auto Ignition Temperature Explosion limits (lower) (upper) Critical data Density : Solubility Solubility in/with water approx. 800 mg/l at : 20 C Solubility Insoluble in/with most organic solvents ph-value (qual.) (quant.) 11.. 12 (aqueous solution) at (... C) Partition coeff. Not available at :... C Oxidising properties Not oxidising Explosive properties 10 STABILITY AND REACTIVITY Stability Stable under normal conditions. Hazardous reactions (materials to avoid) May react with acids, oxidising agents. Incompatible materials: strong acids, oxidising agents. 11 TOXICOLOGICAL INFORMATION ACUTE TOXICITY (LETHAL DOSES) LD50 Oral (rat) ACUTE TOXICITY (IRRITATION, SENSITISATION, ETC.) Dose : 1000.. 2000 mg/kg Inhalation - Symptoms: Skin Contact - Symptoms Eye Contact - Symptoms Ingestion - Symptoms Dust may be irritant to the upper respiratory tract. May cause skin irritation. Irritating to eyes. Harmful if swallowed.
Creation Date 29.11.96 Revision Date 29.11.96 Revision Number 2 Page 4 of 6 12 ECOLOGICAL INFORMATION ELIMINATION Degradability :. MOBILITY Solubility in water Results: The substance is soluble in water. ECOTOXICITY Toxicity to fish: LC50 Bluegill Sunfish Dose Test parameter Period Assessment : 486mg/l : Mortality : 96 hours : Low toxicity to fish BIOCHEMICAL OXYGEN DEMAND BOD :. COD :. Water pollution class : (WGK2) - (official classification) 13 DISPOSAL CONSIDERATION Bury on an authorised landfill site or incinerate under approved controlled conditions, using incinerators suitable for the disposal of noxious chemical waste. Disposal should be in accordance with local, state or national legislation.
Creation Date 29.11.96 Revision Date 29.11.96 Revision Number 2 Page 5 of 6 14 TRANSPORT INFORMATION Road transport ADR/RID Maritime transport IMDG Air transport ICAO/IATA dangerous substance as defined in the above regulations Class: 8 No/letter: 52/c UN No: 3259 Technical name: Hazard substance 1 : AMINES. SOLID, CORROSIVE, N.O.S. Ethylene diamine tetra acetic acid tetra sodium salt. dangerous substance as defined in the above regulations Class : 8 UN No: 3259 PG: III EmS No. 8-15/8-07 Marine pollutant: No Proper shipping name: AMINES. SOLID, CORROSIVE, N.O.S. Hazard substance 1 : Ethylene diamine tetra acetic acid tetra sodium salt. IMDG Code Page: 8109-2 MFAG No. (first): 760 dangerous substance as defined in the above regulations Class : 8 UN/ID No: 3259 / PG: III Technical name: AMINES. SOLID, CORROSIVE, N.O.S. Hazard substance 1 : Ethylene diamine tetra acetic acid tetra sodium salt. 15 REGULATORY INFORMATION Classification according to EEC directives Classification : HARMFUL Hazard labels: R-phrases: S-phrases: (xn) Harmful (R22) Harmful if swallowed (R36) Irritating to eyes (S2) Keep out of reach of children. (S13) Keep away from food, drink and animal feeding stuffs. (S22) Do not breathe dust. (S26) In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. (S46) If swallowed, seek medical advice immediately and show this container or label. Hazardous ingredients - Ethylene diamine tetra acetic acid tetra sodium salt National regulatory information.
Creation Date 29.11.96 Revision Date 29.11.96 Revision Number 1 Page 6 of 6 16 OTHER INFORMATION This data sheet was prepared in accordance with Directive 91/155/EEC. BAQ OUT is a trade mark of ZENECA Limited. The information and recommendations in this publication are to the best of our knowledge, information and belief, accurate at the date of publication. Nothing herein is to be construed as a warranty, express or implied. In all cases it is the responsibility of the users to determine the applicability of such information or the suitability of any products for their own particular purposes. ZENECA Biocides is part of a subsidiary of ZENECA Group PLC (Registered in England No. 2723534).