IMDG INTERNATIONAL MARITIME DANGEROUS GOODS CODE. Incorporating Amendment EDITION VOLUME 1

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IMDG INTERNATIONAL MARITIME DANGEROUS GOODS CODE Incorporating Amendment 34-08 2008 EDITION VOLUME 1 INTERNATIONAL MARITIME ORGANIZATION London, 2008

Volume 1 Preamble PART 1 - GENERAL PROVISIONS, DEFINITIONS AND TRAINING Chapter 1.1 General provisions 1.1.0 Introductory note 3 1.1.1 Application and implementation of the Code 3 1.1.2 Conventions 4 1.1.3 Dangerous goods forbidden from transport 8 Chapter 1.2 Chapter 1.3 Chapter 1.4 Definitions, units of measurement and abbreviations 1.2.1 Definitions 9 1.2.2 Units of measurement 16 1.2.3 List of abbreviations 22 Training 1.3.0 Introductory note 24 1.3.1 Training of shore-side personnel 24 Security provisions 1.4.0 Introductory note 29 1.4.1 General provisions for companies, ships and port facilities 29 1.4.2 General provisions for shore-side personnel 29 1.4.3 Provisions for high consequence dangerous goods 30 Chapter 1.5 General provisions concerning class 7 1.5.1 Scope and application 32 1.5.2 Radiation protection programme 33 1.5.3 Quality assurance 33 1.5.4 Special arrangement 33 1.5.5 Radioactive material possessing other dangerous properties 34 1.5.6 Non-compliance 34 PART 2 - CLASSIFICATION Chapter 2.0 Introduction 2.0.0 Responsibilities 37 2.0.1 Classes, divisions, packing groups 37 2.0.2 UN Numbers and Proper Shipping Names 38 2.0.3 Classification of substances, mixtures and solutions with multiple hazards (precedence of hazard characteristics) 39 2.0.4 Transport of samples 41 Chapter 2.1 Class 1 - Explosives 2.1.0 Introductory notes 42 2.1.1 Definitions and general provisions 42 2.1.2 Compatibility groups and classification codes 43 2.1.3 Classification procedure 45

Chapter 2.2 Class 2 - Gases 2.2.0 Introductory notes 2.2.1 Definitions and general provisions 2.2.2 Class subdivisions 2.2.3 Mixtures of gases Chapter 2.3 Class 3 - Flammable liquids 2.3.0 Introductory note 2.3.1 Definitions and general provisions 2.3.2 Assignment of packing group 2.3.3 Determination of flashpoint Chapter 2.4 Class 4 - Flammable solids; substances liable to spontaneous combustion; substances which, in contact with water, emit flammable gases 2.4.0 Introductory note Chapter 2.5 Chapter 2.6 Chapter 2.7 Chapter 2.8 Chapter 2.9 2.4.1 Definition and general provisions 2.4.2 Class 4.1 - Flammable solids, self-reactive substances and solid desensitized explosives 2.4.3 Class 4.2 - Substances liable to spontaneous combustion 2.4.4 Class 4.3 - Substances which, in contact with water, emit flammable gases 2.4.5 Classification of organometallic substances Class 5 - Oxidizing substances and organic peroxides 2.5.0 Introductory note 2.5.1 Definitions and general provisions 2.5.2 Class 5.1 - Oxidizing substances 2.5.3 Class 5.2 - Organic peroxides Class 6 - Toxic and infectious substances 2.6.0 Introductory notes 2.6.1 Definitions 2.6.2 Class 6.1 - Toxic substances 2.6.3 Class 6.2 - Infectious substances Class 7 - Radioactive material 2.7.1 Definitions 2.7.2 Classification Class 8 - Corrosive substances 2.8.1 Definition and properties 2.8.2 Assignment of packing groups Class 9 - Miscellaneous dangerous substances and articles (class 9) and environmentally hazardous substances 2.9.1 Definitions 2.9.2 Assignment to class 9 2.9.3 Environmentally hazardous substances (aquatic environment) Chapter 2.10 Marine pollutants 2.10.1 Definition 2.10.2 General provisions 2.10.3 Classification 50 50 50 51 52 52 52 53 55 55 55 61 62 63 65 65 65 67 80 80 80 84 89 90 113 113 115 115 115 123 123 123 VI

PART 3 - DANGEROUS GOODS LIST, SPECIAL PROVISIONS AND EXCEPTIONS See Volume 2 PART 4 - PACKING AND TANK PROVISIONS Chapter 4.1 Use of packagings, including intermediate bulk containers (IBCs) and large packagings 4.1.0 Definitions 129 4.1.1 General provisions for the packing of dangerous goods in packagings, including IBCs and large packagings 129 4.1.2 Additional general provisions for the use of IBCs 132 4.1.3 General provisions concerning packing instructions 133 4.1.4 List of packing instructions 136 Packing instructions concerning the use of packagings (except IBCs and large packagings) 136 Packing instructions concerning the use of IBCs 186 Packing instructions concerning the use of large packagings 190 4.1.5 Special packing provisions for goods of class 1 193 4.1.6 Special packing provisions for goods of class 2 194 4.1.7 Special packing provisions for organic peroxides (class 5.2) and self-reactive substances of class 4.1 195 4.1.8 Special packing provisions for infectious substances of category A (class 6.2, UN 2814 and UN 2900) 197 4.1.9 Special packing provisions for class 7 197 Chapter 4.2 Chapter 4.3 Use of portable tanks and multiple-element gas containers (MEGCs) 4.2.0 Transitional provisions 200 4.2.1 General provisions for the use of portable tanks for the transport of substances of class 1 and classes 3 to 9 200 4.2.2 General provisions for the use of portable tanks for the transport of non-refrigerated liquefied gases 204 4.2.3 General provisions for the use of portable tanks for the transport of refrigerated liquefied gases of class 2 205 4.2.4 General provisions for the use of multiple-element gas containers (MEGCs) 206 4.2.5 Portable tank instructions and special provisions 207 Portable tank instructions 209 Portable tank special provisions 216 4.2.6 Additional provisions for the use of road tank vehicles 218 Use of bulk containers 4.3.1 General provisions 219 4.3.2 Additional provisions applicable to bulk goods of classes 4.2, 4.3, 5.1, 6.2. 7 and 8 220 PART 5 - CONSIGNMENT PROCEDURES Chapter 5.1 General provisions 5.1.1 Application and general provisions 5.1.2 Use of overpacks and unit loads 5.1.3 Empty uncleaned packagings or units 5.1.4 Mixed packing 5.1.5 General provisions for class 7 5.1.6 Packages packed into a cargo transport unit 225 225 225 226 226 228 VII

Chapter 5.2 Chapter 5.3 Chapter 5.4 Marking and labelling of packages including IBCs 5.2.1 Marking of packages including IBCs 5.2.2 Labelling of packages including IBCs Placarding and marking of cargo transport units 5.3.1 Placarding 5.3.2 Marking of cargo transport units Documentation 5.4.1 Dangerous goods transport documentation 5.4.2 Container/vehicle packing certificate 5.4.3 Documentation required aboard the ship 5.4.4 Other required information and documentation 5.4.5 Multimodal Dangerous Goods Form 229 232 238 239 242 247 247 248 248 PART 6 - CONSTRUCTION AND TESTING OF PACKAGINGS, INTERMEDIATE BULK CONTAINERS (IBCs), LARGE PACKAGINGS, PORTABLE TANKS, MULTIPLE-ELEMENT GAS CONTAINERS (MEGCs) AND ROAD TANK VEHICLES Chapter 6.1 Provisions for the construction and testing of packagings (other than for class 6.2 substances) Chapter 6.2 Chapter 6.3 Chapter 6.4 6.1.1 Applicability and general provisions 6.1.2 Code for designating types of packagings 6.1.3 Marking 6.1.4 Provisions for packagings 6.1.5 Test provisions for packagings Provisions for the construction and testing of pressure receptacles, aerosol dispensers, small receptacles containing gas (gas cartridges) and fuel cell cartridges containing liquefied flammable gas 6.2.1 General provisions 6.2.2 Provisions for UN pressure receptacles 6.2.3 Provisions for non-un pressure receptacles 6.2.4 Provisions for aerosol dispensers, small receptacles containing gas (gas cartridges) and fuel cell cartridges containing liquefied flammable gas Provisions for the construction and testing of packagings for class 6.2 infectious substances of category A 6.3.1 General 6.3.2 Test provisions for packagings 6.3.3 Test report 6.3.4 Marking 6.3.5 Test provisions for packagings Provisions for the construction, testing and approval of packages and material of class 7 6.4.1 [reserved] 6.4.2 General provisions 6.4.3 Additional provisions for packages transported by air 6.4.4 Provisions for excepted packages 6.4.5 Provisions for industrial packages 6.4.6 Provisions for packages containing uranium hexafluoride 255 256 258 260 268 274 277 287 288 290 290 290 290 291 295 295 296 296 296 297 VIII

Chapter 6.5 Chapter 6.6 Chapter 6.7 6.4.7 Provisions for Type A packages 297 6.4.8 Provisions for Type B(U) packages 298 6.4.9 Provisions for Type B(M) packages 300 6.4.10 Provisions for Type C packages 300 6.4.11 Provisions for packages containing fissile material 301 6.4.12 Test procedures and demonstration of compliance 302 6.4.13 Testing the integrity of the containment system and shielding and evaluating criticality safety 303 6.4.14 Target for drop tests 303 6.4.15 Test for demonstrating ability to withstand normal conditions of transport 303 6.4.16 Additional tests for Type A packages designed for liquids and gases 304 6.4.17 Tests for demonstrating ability to withstand accident conditions of transport 304 6.4.18 Enhanced water immersion test for Type B(U) and Type B(M) packages containing more than 10 5 A 2 and Type C packages 305 6.4.19 Water leakage test for packages containing fissile material 305 6.4.20 Tests for Type C packages 305 6.4.21 Tests for packagings designed to contain uranium hexafluoride 306 6.4.22 Approvals of package designs and materials 306 6.4.23 Applications for approval and approvals for radioactive material transport 306 6.4.24 Transitional measures for class 7 312 Provisions for the construction and testing of intermediate bulk containers (IBCs) 6.5.1 General requirements 314 6.5.2 Marking 316 6.5.3 Construction requirements 318 6.5.4 Testing, certification and inspection 319 6.5.5 Specific provisions for IBCs 320 6.5.6 Test provisions for IBCs 326 Provisions for the construction and testing of large packagings 6.6.1 General 333 6.6.2 Code for designating types of large packagings 333 6.6.3 Marking 333 6.6.4 Specific provisions for large packagings 334 6.6.5 Test provisions for large packagings 336 Provisions for the design, construction, inspection and testing of portable tanks and multiple-element gas containers (MEGCs) 6.7.1 Application and general provisions 340 6.7.2 Provisions for the design, construction, inspection and testing of portable tanks intended for the transport of substances of class 1 and classes 3 to 9 340 6.7.3 Provisions for the design, construction, inspection and testing of portable tanks intended tor the transport of non-refrigerated liquefied gases of class 2 353 6.7.4 Provisions for the design, construction, inspection and testing of portable tanks intended for the transport of refrigerated liquefied gases of class 2 363 6.7.5 Provisions for the design, construction, inspection and testing of multiple-element gas containers (MEGCs) intended for the transport of non-refngerated gases 372 IX

Chapter 6.8 Provisions for road tank vehicles 6.8.1 General 6.8.2 Road tank vehicles for long international voyages for substances of classes 3 to 9 378 6.8.3 Road tank vehicles for short international voyages 378 378 Chapter 6.9 Provisions for the design, construction, inspection and testing of bulk containers 6.9.1 Definitions 6.9.2 Application and general provisions 382 6.9.3 Provisions for the design, construction, inspection and testing of freight containers used as bulk containers 382 6.9.4 Provisions for the design, construction and approval of bulk containers other than freight containers 383 382 PART 7 - PROVISIONS CONCERNING TRANSPORT OPERATIONS Chapter 7.1 Stowage 7.1.1 General provisions 387 7.1.2 Stowage in relation to living quarters 388 7.1.3 Stowage in relation to undeveloped films and plates, and mailbags 389 7.1.4 Stowage of marine pollutants 389 7.1.5 Stowage in relation to foodstuffs 389 7.1.6 Stowage of solutions and mixtures 389 7.1.7 Stowage and handling of goods of class 1 389 7.1.8 Stowage of goods of class 2 394 7.1.9 Stowage of goods of class 3 395 7.1.10 Stowage of goods of classes 4.1, 4.2 and 4.3 395 7.1.11 Stowage of goods of class 5.1 397 7.1.12 Stowage of goods of class 5.2 397 7.1.13 Stowage of goods of class 6.1 398 7.1.14 Stowage of goods of class 7 398 7.1.15 Stowage of goods of class 8 400 7.1.16 Stowage of goods of class 9 401 Chapter 7.2 Segregation 7.2.1 General 404 7.2.2 Segregation of packages 407 7.2.3 Segregation of cargo transport units on board container ships 409 Illustrations of segregation of cargo transport units on board container ships 410 Illustrations of segregation of cargo transport units on board hatchless container ships 418 7.2.4 Segregation of cargo transport units on board roll-on/roll-off ships 432 Illustrations of segregation of cargo transport units on board ro-ro ships 432 7.2.5 Segregation in shipborne barges and on board barge-carrying ships... 439 7.2.6 Segregation between bulk materials possessing chemical hazards and dangerous goods in packaged form 439 7.2.7 Segregation of goods of class 1 441 7.2.8 Segregation provisions for goods of class 4.1 and class 5.2 443 7.2.9 Segregation for goods of class 7 443

Chapter 7.3 Chapter 7.4 Special provisions in the event of an incident and fire precautions involving dangerous goods 7.3.1 General 7.3.2 General provisions in the event of incidents 7.3.3 Special provisions for incidents involving infectious substances 7.3.4 Special provisions for incidents involving radioactive material 7.3.5 General fire precautions 7.3.6 Special fire precautions for class 1 7.3.7 Special fire precautions for class 2 7.3.8 Special fire precautions for class 3 7.3.9 Special fire precautions and fire fighting for class 7 Transport of cargo transport units on board ships 7.4.1 Applicability 7.4.2 General provisions for cargo transport units 7.4.3 Fumigated units 7.4.4 Stowage of cargo transport units in cargo spaces other than ro-ro cargo spaces 7.4.5 Stowage of cargo transport units in ro-ro cargo spaces 7.4.6 Transport of dangerous goods of class 1 in cargo transport units... Chapter 7.5 Packing of cargo transport units Chapter 7.6 Chapter 7.7 Chapter 7.8 7.5.1 General provisions for cargo transport units 7.5.2 Packing of cargo transport units 7.5.3 Empty cargo transport units Transport of dangerous goods in shipborne barges on barge-carrying ships 7.6.1 Applicability 7.6.2 Definitions 7.6.3 Permitted shipments 7.6.4 Barge loading 7.6.5 Stowage of shipborne barges 7.6.6 Ventilation and condensation 7.6.7 Fire protection 7.6.8 Transport of goods of class 1 in shipborne barges Temperature control provisions 7.7.1 Preamble 7.7.2 General provisions 7.7.3 Methods of temperature control 7.7.4 Special provisions for self-reactive substances (class 4.1) and organic peroxides (class 5.2) 7.7.5 Special provisions applicable to the transport of substances stabilized by temperature control (other than self-reactive substances and organic peroxides) 7.7.6 Special provisions for flammable gases or liquids having a flashpoint of less than 23 C c.c. transported under temperature control 7.7.7 Special provisions for vehicles transported on ships 7.7.8 Approval Transport of wastes 7.8.1 Preamble 7.8.2 Applicability 7.8.3 Transboundary movements under the Basel Convention 7.8.4 Classification of wastes 448 448 448 449 449 450 450 450 450 451 451 452 452 452 454 455 455 455 456 456 456 457 457 457 457 458 459 459 460 461 461 462 462 462 463 463 463 463 XI

Chapter 7.9 Exemptions, approvals and certificates 7.9.1 Exemptions 465 7.9.2 Approvals (including permits, authorizations or agreements) and certificates 465 7.9.3 Contact information for the main designated national competent authorities 465