1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER Product Name: Other name(s): SODIUM METABISULPHITE (ALL GRADES) Sodium metabisulfite; Sodium pyrosulphite; Disodium pyrosulphite; SMB powder; Grape guards; Sodium disulphite; AASOD33500; Birlasulf; Metabisulfito de sodio. Recommended Use of the Chemical and Restrictions on Use Preservative for foods; antioxidant. Supplier: Ixom Operations Pty Ltd ABN: 51 600 546 512 Street Address: Level 8, 1 Nicholson Street East Melbourne Victoria 3002 Australia Telephone Number: +61 3 9906 3000 Emergency Telephone: 1 800 033 111 (ALL HOURS) Please ensure you refer to the limitations of this Safety Data Sheet as set out in the "Other Information" section at the end of this Data Sheet. 2. HAZARDS IDENTIFICATION Not classified as Dangerous Goods by the criteria of the Australian Dangerous Goods Code (ADG Code) for transport by Road and Rail; NON-DANGEROUS GOODS. This material is hazardous according to Safe Work Australia; HAZARDOUS CHEMICAL. Classification of the chemical: Acute Oral Toxicity - Category 4 Eye Damage - Category 1 SIGNAL WORD: DANGER Hazard Statement(s): H302 Harmful if swallowed. H318 Causes serious eye damage. Precautionary Statement(s): Prevention: P102 Keep out of reach of children. P264 Wash hands thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P280 Wear protective gloves / protective clothing / eye protection / face protection. Response: P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P330 Rinse mouth. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor/physician. Product Name: SODIUM METABISULPHITE (ALL GRADES) Issued: 14/01/2013 Page 1 of 6
Disposal: P501 Dispose of contents and container in accordance with local, regional, national, international regulations. Other Hazards: AUH031 Contact with acids liberates toxic gas. Poisons Schedule (SUSMP): S5 Caution. 3. COMPOSITION AND INFORMATION ON INGREDIENTS Components CAS Number Proportion Hazard Codes Sodium metabisulfite 7681-57-4 100% H302 H318 4. FIRST AID MEASURES For advice, contact a Poisons Information Centre (e.g. phone Australia 131 126; New Zealand 0800 764 766) or a doctor. Inhalation: Remove victim from area of exposure - avoid becoming a casualty. Remove contaminated clothing and loosen remaining clothing. Allow patient to assume most comfortable position and keep warm. Keep at rest until fully recovered. Seek medical advice if effects persist. Skin Contact: If skin contact occurs, remove contaminated clothing and wash skin with running water. If irritation occurs seek medical advice. Eye Contact: Immediately wash in and around the eye area with large amounts of water for at least 15 minutes. Eyelids to be held apart. Remove clothing if contaminated and wash skin. Urgently seek medical assistance. Transport promptly to hospital or medical centre. Ingestion: Rinse mouth with water. If swallowed, do NOT induce vomiting. Give a glass of water. Seek immediate medical assistance. Indication of immediate medical attention and special treatment needed: Treat symptomatically. Can cause corneal burns. 5. FIRE FIGHTING MEASURES Suitable Extinguishing Media: Not combustible, however, if material is involved in a fire use: Fine water spray, normal foam, dry agent (carbon dioxide, dry chemical powder). Specific hazards arising from the chemical: Non-combustible material. Special protective equipment and precautions for fire-fighters: Decomposes on heating emitting toxic fumes, including those of sulfur dioxide. Fire fighters to wear self-contained breathing apparatus and suitable protective clothing if risk of exposure to products of decomposition. 6. ACCIDENTAL RELEASE MEASURES Product Name: SODIUM METABISULPHITE (ALL GRADES) Issued: 14/01/2013 Page 2 of 6
Emergency procedures/environmental precautions: Clear area of all unprotected personnel. If contamination of sewers or waterways has occurred advise local emergency services. Personal precautions/protective equipment/methods and materials for containment and cleaning up: Wear protective equipment to prevent skin and eye contact and breathing in dust. Work up wind or increase ventilation. Cover with damp absorbent (inert material, sand or soil). Sweep or vacuum up, but avoid generating dust. Collect and seal in properly labelled containers or drums for disposal. Wash area down with excess water. 7. HANDLING AND STORAGE This material is a Scheduled Poison S5 and must be stored, maintained and used in accordance with the relevant regulations. Precautions for safe handling: Avoid skin and eye contact and breathing in dust. Avoid handling which leads to dust formation. Keep out of reach of children. Conditions for safe storage, including any incompatibilities: Store in a cool, dry, well ventilated place and out of direct sunlight. Store away from foodstuffs. Store away from incompatible materials described in Section 10. Keep containers closed when not in use - check regularly for spills. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Sodium metabisulfite: 8hr TWA = 5 mg/m 3 As published by Safe Work Australia Workplace Exposure Standards for Airborne Contaminants. TWA - The time-weighted average airborne concentration of a particular substance when calculated over an eight-hour working day, for a five-day working week. These Workplace Exposure Standards are guides to be used in the control of occupational health hazards. All atmospheric contamination should be kept to as low a level as is workable. These workplace exposure standards should not be used as fine dividing lines between safe and dangerous concentrations of chemicals. They are not a measure of relative toxicity. Appropriate engineering controls: Ensure ventilation is adequate to maintain air concentrations below Workplace Exposure Standards. Avoid generating and breathing in dusts. Use with local exhaust ventilation or while wearing dust mask. Keep containers closed when not in use. Individual protection measures, such as Personal Protective Equipment (PPE): The selection of PPE is dependent on a detailed risk assessment. The risk assessment should consider the work situation, the physical form of the chemical, the handling methods, and environmental factors. OVERALLS, SAFETY SHOES, CHEMICAL GOGGLES, GLOVES, DUST MASK. Product Name: SODIUM METABISULPHITE (ALL GRADES) Page 3 of 6 Issued: 14/01/2013
Wear overalls, chemical goggles and impervious gloves. Avoid generating and inhaling dusts. If determined by a risk assessment an inhalation risk exists, wear a dust mask/respirator meeting the requirements of AS/NZS 1715 and AS/NZS 1716. Always wash hands before smoking, eating, drinking or using the toilet. Wash contaminated clothing and other protective equipment before storage or re-use. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Solid Colour: White Odour: Characteristic Molecular Formula: Na2 O5 S2 Solubility: Soluble in water. Specific Gravity: 1.48 Relative Vapour Density (air=1): Not available Vapour Pressure (20 C): Not available Flash Point ( C): Not available Flammability Limits (%): Not available Autoignition Temperature ( C): Not available Solubility in water (g/l): 640 @20 C Melting Point/Range ( C): ca. 150 Decomposition Point ( C): >150 ph: 4.0-5.0 (50g/water, 20 C) 10. STABILITY AND REACTIVITY Reactivity: Chemical stability: Possibility of hazardous reactions: Conditions to avoid: Contact with acids liberates toxic gas. Slowly oxidized on exposure to air and moisture. None known. Avoid exposure to heat. Incompatible materials: Incompatible with acids, and oxidising agents. Hazardous decomposition products: Sulfur dioxide. 11. TOXICOLOGICAL INFORMATION No adverse health effects expected if the product is handled in accordance with this Safety Data Sheet and the product label. Symptoms or effects that may arise if the product is mishandled and overexposure occurs are: Ingestion: Eye contact: Skin contact: Swallowing can result in nausea, vomiting, diarrhoea, and abdominal pain. A severe eye irritant. Contamination of eyes can result in permanent injury. Contact with skin may result in irritation. May cause skin sensitisation in sensitive individuals. Repeated or prolonged skin contact may lead to allergic contact dermatitis. Inhalation: Product Name: SODIUM METABISULPHITE (ALL GRADES) Page 4 of 6 Breathing in dust may result in respiratory irritation. May cause respiratory sensitisation in sensitive individuals, producing asthma-like symptoms. Issued: 14/01/2013
Acute toxicity: Oral LD50 (rat): 1540 mg/kg. Chronic effects: Sodium metabisulfite can sensitise the respiratory tract of allergic persons. 12. ECOLOGICAL INFORMATION Ecotoxicity 96hr LC50 (fish): Avoid contaminating waterways. 150-220 mg/l (S. gairdnerii) 13. DISPOSAL CONSIDERATIONS Disposal methods: Refer to Waste Management Authority. Dispose of contents and container in accordance with local, regional, national, international regulations. 14. TRANSPORT INFORMATION Road and Rail Transport Not classified as Dangerous Goods by the criteria of the Australian Dangerous Goods Code (ADG Code) for transport by Road and Rail; NON-DANGEROUS GOODS. Marine Transport Not classified as Dangerous Goods by the criteria of the International Maritime Dangerous Goods Code (IMDG Code) for transport by sea; NON-DANGEROUS GOODS. Air Transport Not classified as Dangerous Goods by the criteria of the International Air Transport Association (IATA) Dangerous Goods Regulations for transport by air; NON-DANGEROUS GOODS. 15. REGULATORY INFORMATION Classification: This material is hazardous according to Safe Work Australia; HAZARDOUS CHEMICAL. Classification of the chemical: Acute Oral Toxicity - Category 4 Eye Damage - Category 1 Hazard Statement(s): H302 Harmful if swallowed. H318 Causes serious eye damage. Poisons Schedule (SUSMP): S5 Caution. This material is listed on the Australian Inventory of Chemical Substances (AICS). 16. OTHER INFORMATION Supplier Safety Data Sheet; not dated. Product Name: SODIUM METABISULPHITE (ALL GRADES) Page 5 of 6 Issued: 14/01/2013
This safety data sheet has been prepared by Ixom Operations Pty Ltd Toxicology & SDS Services. Reason(s) for Issue: Revised Primary SDS Alignment to GHS requirements This SDS summarises to our best knowledge at the date of issue, the chemical health and safety hazards of the material and general guidance on how to safely handle the material in the workplace. Since Ixom Operations Pty Ltd cannot anticipate or control the conditions under which the product may be used, each user must, prior to usage, assess and control the risks arising from its use of the material. If clarification or further information is needed, the user should contact their Ixom representative or Ixom Operations Pty Ltd at the contact details on page 1. Ixom Operations Pty Ltd's responsibility for the material as sold is subject to the terms and conditions of sale, a copy of which is available upon request. Product Name: SODIUM METABISULPHITE (ALL GRADES) Issued: 14/01/2013 Page 6 of 6