SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : Other means of identification : Not applicable. Recommended use : Air Freshener Restrictions on use : Reserved for industrial and professional use. Product dilution information : Product is sold ready to use. Company : Ecolab Co. 515 Tomken Road Mississauga, Ontario Canada L4W 2X5 1-8-352-5326 Emergency telephone number : 1-8-328-26 (US/Canada), 1-651-222-5352 (outside US) Issuing date : 6/11/214 SECTION 2: HAZARDS IDENTIFICATION Physical and chemical hazards : Not flammable or combustible. Potential Health Effects Eyes Skin Ingestion Inhalation Chronic Exposure SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS Pure substance/mixture : Mixture Chemical Name CAS-No. Concentration: (%) starch 95-25-8 5-1 aluminium oxide 1344-28-1 1-5 SECTION 4: FIRST AID MEASURES In case of eye contact In case of skin contact If swallowed If inhaled Protection of first-aiders : Rinse with plenty of water. : Rinse with plenty of water. : Rinse mouth. Get medical attention if symptoms occur. : Get medical attention if symptoms occur. : No special precautions are necessary for first aid responders. 975573-3 1 / 7
Notes to physician : No specific measures identified. See toxicological information (Section 11) SECTION 5: FIREFIGHTING MEASURES Suitable extinguishing media Unsuitable extinguishing media Specific hazards during firefighting Hazardous combustion products Special protective equipment for firefighters Specific extinguishing methods Risk of explosion. : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. : None known. : Not flammable or combustible. : Decomposition products may include the following materials: Carbon oxides nitrogen oxides (NOx) Sulphur oxides Oxides of phosphorus : Use personal protective equipment. : Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. : Not available. SECTION 6: ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up : Refer to protective measures listed in sections 7 and 8. : No special environmental precautions required. : Stop leak if safe to do so. Contain spillage, and then collect with noncombustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Flush away traces with water. For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. SECTION 7: HANDLING AND STORAGE Advice on safe handling : Wash hands after handling. For personal protection see section 8. Conditions for safe storage : Keep out of reach of children. Store in suitable labeled containers. Storage temperature : -5 C to 5 C SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters 975573-3 2 / 7
Components CAS-No. Form of exposure Permissible concentration Basis starch 95-25-8 1 mg/m3 CAD AB OEL 1 mg/m3 CAD BC OEL VME (total 1 mg/m3 OEL (QUE) starch 95-25-8 1 mg/m3 ACGIH 5 mg/m3 NIOSH REL (Respirable) (total) 1 mg/m3 NIOSH REL (Total 15 mg/m3 OSHA Z1 5 mg/m3 OSHA Z1 (respirable fraction) aluminium oxide 1344-28-1 1 mg/m3 CAD AB OEL VME (total 1 mg/m3 OEL (QUE) 1 mg/m3 CAD BC OEL (Respirable) aluminium oxide 1344-28-1 1 mg/m3 ACGIH (Respirable fraction) (Total 15 mg/m3 OSHA Z1 (respirable fraction) 5 mg/m3 OSHA Z1 Engineering measures : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Personal protective equipment Eye protection Hand protection Skin protection Respiratory protection Hygiene measures : No special protective equipment required. : No special protective equipment required. : No special protective equipment required. : No personal respiratory protective equipment normally required. : Wash hands before breaks and immediately after handling the product. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Appearance : powder Colour : white Odour : Perfumes, fragrances ph : 7., 1 % Flash point : Not applicable. Odour Threshold Melting point/freezing point 975573-3 3 / 7
Initial boiling point and boiling range Evaporation rate Flammability (solid, gas) Upper explosion limit Lower explosion limit Vapour pressure Relative vapour density Relative density : 1. Water solubility Solubility in other solvents Partition coefficient: n- octanol/water Auto-ignition temperature Thermal decomposition Viscosity, kinematic Explosive properties Oxidizing properties Molecular weight VOC SECTION 1: STABILITY AND REACTIVITY Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products : Stable under normal conditions. : No dangerous reaction known under conditions of normal use. : None known. : None known. : Decomposition products may include the following materials: Carbon oxides nitrogen oxides (NOx) Sulphur oxides Oxides of phosphorus SECTION 11: TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Inhalation, Eye contact, Skin contact Potential Health Effects Eyes Skin Ingestion 975573-3 4 / 7
Inhalation Chronic Exposure Experience with human exposure Eye contact Skin contact Ingestion Inhalation Toxicity Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Carcinogenicity Reproductive effects Germ cell mutagenicity Teratogenicity STOT - single exposure STOT - repeated exposure Aspiration toxicity Components Acute oral toxicity : aluminium oxide LD5 rat: > 1, mg/kg SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity Environmental Effects : This product has no known ecotoxicological effects. Product Toxicity to fish Toxicity to daphnia and other aquatic invertebrates Toxicity to algae Persistence and degradability 975573-3 5 / 7
Bioaccumulative potential Mobility in soil Other adverse effects SECTION 13: DISPOSAL CONSIDERATIONS Disposal methods Disposal considerations : Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility. : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not reuse empty containers. SECTION 14: TRANSPORT INFORMATION The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport. Land transport (TDG) Not dangerous goods Sea Transport (IMDG/IMO) Not dangerous goods SECTION 15: REGULATORY INFORMATION WHMIS Classification : Not considered a WHMIS controlled product. This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR. NPRI Components Canadian PBT Chemicals : aluminium oxide : This product contains the following components on the DSL that are classified as Persistent, Bioaccumulative and/or Toxic (PBT) under CEPA: octamethylcyclotetrasiloxane The components of this product are reported in the following inventories: 197/26 (EU) : Switzerland. New notified substances and declared preparations : Switzerland. Federal Health Agency, Giftliste 1 (Stoffe) United States TSCA Inventory : On TSCA Inventory 975573-3 6 / 7
Health Instability SAFETY DATA SHEET Canadian Domestic Substances List (DSL) : All components of this product are on the Canadian DSL. Australia. Industrial Chemical (Notification and Assessment) Act : New Zealand. Inventory of Chemicals (NZIoC), as published by ERMA New Zealand : Japan. ENCS - Existing and New Chemical Substances Inventory : Japan. ISHL - Inventory of Chemical Substances (METI) : Korea. Korean Existing Chemicals Inventory (KECI) : On the inventory, or in compliance with the inventory Philippines Inventory of Chemicals and Chemical Substances (PICCS) : China Inventory of Existing Chemical Substances : SECTION 16: OTHER INFORMATION NFPA: Flammability HMIS III: HEALTH FLAMMABILITY PHYSICAL HAZARD Special hazard. = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Issuing date : 6/11/214 version : 1. Prepared by : Regulatory Affairs 1-8-352-5326 REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the MSDS. The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. 975573-3 7 / 7