Page 1/6 1 Identification of the substance/mixture and of the company/undertaking Product identifier Article number: A2499 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. Application of the substance / the mixture Chemical analytics Laboratory chemical Details of the supplier of the safety data sheet Manufacturer/Supplier: AppliChem GmbH Tel.: +49 (0)6151 93570 Ottoweg 4 Fax.: +49 (0)6151 935711 D-64291 Darmstadt msds@applichem.com Further information obtainable from: Dept. Compliance Emergency telephone number: +49(0)6151 93570 (Inside normal buisness hours) * 2 Hazards identification Classification of the substance or mixture Met. Corr.1 H290 May be corrosive to metals. Eye Dam. 1 H318 Causes serious eye damage. Label elements GHS label elements The product is classified and labelled according to the Globally Harmonised System (GHS). Hazard pictograms GHS05 Signal word Danger Hazard-determining components of labelling: hydrogen chloride Hazard statements H290 May be corrosive to metals. H318 Causes serious eye damage. Precautionary statements P390 Absorb spillage to prevent material damage. P406 Store in corrosive resistant container /container with a corrosion resistant inner liner. Other hazards Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. (Contd. on page 2)
Page 2/6 (Contd. of page 1) * 3 Composition/information on ingredients Chemical characterisation: Mixtures Description: aqeous solution Dangerous components: 7647-01-0 hydrogen chloride Met. Corr.1, H290; Skin Corr. 1B, H314; STOT SE 3, H335 >3-4% 4 First aid measures Description of first aid measures General information: Immediately remove any clothing soiled by the product. After inhalation: Supply fresh air; consult doctor in case of complaints. After skin contact: Immediately rinse with water. If skin irritation continues, consult a doctor. After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. After swallowing: Rinse out mouth. make victim drink water (maximum of 2 drinking glasses) Do not attempt to neutralize. If symptoms persist consult doctor. Information for doctor: Most important symptoms and effects, both acute and delayed No further relevant information available. Indication of any immediate medical attention and special treatment needed No further relevant information available. 5 Firefighting measures Extinguishing media Suitable extinguishing agents: Use fire extinguishing methods suitable to surrounding conditions. Special hazards arising from the substance or mixture No further relevant information available. Advice for firefighters Protective equipment: No special measures required. 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Not required. Environmental precautions: Dilute with plenty of water. Do not allow product to reach sewage system or any water course. Methods and material for containment and cleaning up: Absorb with liquid-binding material (AppliSorb). Clean up affected area. Dispose of the material collected according to regulations. Reference to other sections No dangerous substances are released. * 7 Handling and storage Handling: Precautions for safe handling No special measures required. Information about fire - and explosion protection: No special measures required. (Contd. on page 3)
Page 3/6 Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: No special requirements. Information about storage in one common storage facility: Not required. Further information about storage conditions: None. Recommended storage temperature: 15-25 C Storage class: 8 B Specific end use(s) No further relevant information available. (Contd. of page 2) 8 Exposure controls/personal protection Additional information about design of technical facilities: No further data; see item 7. Control parameters Ingredients with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. Additional information: The lists valid during the making were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures: The usual precautionary measures are to be adhered to when handling chemicals. Respiratory protection: Use suitable respiratory protective device in case of insufficient ventilation. Filter ABEK Protection of hands: The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. For the permanent contact gloves made of the following materials are suitable: Nitrile rubber, NBR Recommended thickness of the material: 0,11 mm Value for the permeation: Level 480 Min. As protection from splashes gloves made of the following materials are suitable: Nitrile rubber, NBR Recommended thickness of the material: 0,11 mm Value for the permeation: Level 480 Min. Eye protection: Safety glasses 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: Fluid Colour: Colourless Odour: Odourless ph-value at 20 C: 0,3 Change in condition Melting point/melting range: Undetermined. Boiling point/boiling range: Undetermined. Flash point: Not applicable. (Contd. on page 4)
Page 4/6 Danger of explosion: Product does not present an explosion hazard. Density at 20 C: 1,02 g/cm³ Solubility in / Miscibility with water: Viscosity: Dynamic: Kinematic: Fully miscible. Not determined. Not determined. Solvent content: Organic solvents: 0,0 % Other information No further relevant information available. (Contd. of page 3) * 10 Stability and reactivity Reactivity No further relevant information available. Chemical stability Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. Possibility of hazardous reactions No dangerous reactions known. Conditions to avoid No further relevant information available. Incompatible materials: No further relevant information available. Hazardous decomposition products: No dangerous decomposition products known. * 11 Toxicological information Information on toxicological effects Acute toxicity Primary irritant effect: Skin corrosion/irritation No irritant effect. Serious eye damage/irritation No irritating effect. Respiratory or skin sensitisation No sensitising effects known. Additional toxicological information: When used and handled according to specifications, the product does not have any harmful effects to our experience and the information provided to us. The substance is not subject to classification according to the latest version of the EU lists. Harmful * 12 Ecological information Toxicity Aquatic toxicity: No further relevant information available. Persistence and degradability No further relevant information available. Behaviour in environmental systems: Bioaccumulative potential No further relevant information available. Mobility in soil No further relevant information available. Additional ecological information: General notes: Must not reach sewage water or drainage ditch undiluted or unneutralised. Generally not hazardous for water Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. (Contd. on page 5)
Page 5/6 Other adverse effects No further relevant information available. (Contd. of page 4) 13 Disposal considerations Waste treatment methods Recommendation Must not be disposed together with household garbage. Do not allow product to reach sewage system. Uncleaned packaging: Recommendation: Disposal must be made according to official regulations. Recommended cleansing agents: Water, if necessary together with cleansing agents. 14 Transport information UN-Number ADR, IMDG, IATA UN1789 UN proper shipping name ADR, IMDG, IATA HYDROCHLORIC ACID Transport hazard class(es) ADR Class 8 (C1) Corrosive substances. IMDG, IATA Class 8 Corrosive substances. Packing group ADR, IMDG, IATA III Environmental hazards: Not applicable. Special precautions for user Warning: Corrosive substances. Stowage Category E Transport in bulk according to Annex II of Marpol and the IBC Code Transport/Additional information: Not applicable. ADR Limited quantities (LQ) 5L Excepted quantities (EQ) Code: E1 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 1000 ml Transport category 3 Tunnel restriction code E IMDG Limited quantities (LQ) 5L (Contd. on page 6)
Page 6/6 (Contd. of page 5) Excepted quantities (EQ) Code: E1 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 1000 ml UN "Model Regulation": UN 1789 HYDROCHLORIC ACID, 8, III * 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture GHS label elements The product is classified and labelled according to the Globally Harmonised System (GHS). Hazard pictograms GHS05 Signal word Danger Hazard-determining components of labelling: hydrogen chloride Hazard statements H290 May be corrosive to metals. H318 Causes serious eye damage. Precautionary statements P390 Absorb spillage to prevent material damage. P406 Store in corrosive resistant container /container with a corrosion resistant inner liner. Directive 2012/18/EU Named dangerous substances - ANNEX I hydrogen chloride Chemical safety assessment: A Chemical Safety Assessment has not been carried out. * 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Relevant phrases H290 May be corrosive to metals. H314 Causes severe skin burns and eye damage. H335 May cause respiratory irritation. Department issuing SDS: Dept. Compliance Contact: Mr. Th. Stöckle Abbreviations and acronyms: RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail) ICAO: International Civil Aviation Organisation ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) PBT: Persistent, Bioaccumulative and Toxic vpvb: very Persistent and very Bioaccumulative Met. Corr.1: Corrosive to metals Category 1 Skin Corr. 1B: Skin corrosion/irritation Category 1B Eye Dam. 1: Serious eye damage/eye irritation Category 1 STOT SE 3: Specific target organ toxicity (single exposure) Category 3 * Data compared to the previous version altered.