SheffCoat. Aqueous Based Coating Systems. Customized Immediate Release and Enteric Film Coating Systems.

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SheffCoat Aqueous Based Coating Systems Customized Immediate Release and Enteric Film Coating Systems www.sheffieldbioscience.com

A Name You Know Can Trust For more than 75 years, we have earned our reputation for reliability and excellence in serving the biotech, pharmaceutical and nutrition markets by delivering unsurpassed product value, enhanced opportunities for supply chain consolidation, and new technology innovation. We bring together our superior products with new innovative solutions and market-driving alternatives to help our customer succeed in today s challenging global marketplace. As part of the Kerry Group, a $6 Billion leader, we can provide you the global technical service, regulatory and application support whether this is in the development process, or trouble-shooting commercial production challenges. We make it our business to exceed our customers expectations every day. We collaborate directly with formulators in the development of new drugs and delivery systems. We understand the requirements and regulations needed to succeed. SheffCoat Benefits Pre-blended, ready-to-use dry clear or colored coatings that optimize performance and efficiency Complete line of cost effective aqueous coating systems Based on industry standard polymers, pigments, and plasticizers that meet all regulatory requirements Applied with standard film coating processes and equipment R&D application labs for custom & collaborative formulation development Match or exceed performance of current coating system Precise color matching of existing coating system and assurance of batch to batch color consistency SheffCoat 2

SheffCoat : The Standard of Comparison Building on 75 years of innovation, commitment and reliability as a world class excipient supplier, Kerry has created a one step, ready-to-use system to match your existing coating and color, while offering a full spectrum of best-in-class, cost effective solutions. SheffCoat film coating systems are based on industry standard, regulatory accepted polymers, pigments and plasticizers that are applied with standard film coating processes and equipment. With our extensive knowledge and experience we can match or exceed the functionality of any competitive coating system as well as custom match or create any desired color. We provide formulation, technical, regulatory and quality support through every step of your development, scale-up and production process. Manufacturing Expertise SheffCoat coating systems are manufactured in Norwich, NY which is a CFR 21-11 Registered Drug Establishment, and Vadodara, India. We are committed to exceeding the cgmp expectations of our pharmaceutical customer base with our extensive quality assurance programs. Each batch is produced in accordance within approved specifications and are GMP/GLP compliant with IPEC guidelines as well as regional requirements globally. Our individual and isolated manufacturing suites have separate air handling systems. We have various blenders allowing for accurate scale-up and enabling batch sizes up to 1, kg. Global Technical Support Our core technical expertise and extensive knowledge in industrial pharmaceutical tablet coating enables us to support our customers in optimizing SheffCoat performance and efficiency. We are available to assist customers with on-site coating trials and problem solve with production issues. Regulatory and Quality Assurance Kerry has a dedicated regulatory group to ensure product compliance to global regulatory requirements. Our regulatory team provides full customer support to customers in every step of the process including regional regulatory agency compliance, vendor forms, and audits to complete formulation changes. Changing to SheffCoat assures seamless changes from your current formulations quality and performance while improving your cost competiveness, and flexibility. *Drug Master Files are available. Individual and Isolated suites have separate air handling systems. Various blenders with liquid addition and high sheer mixing. Accurate scale-up and multiple batch sizes. SheffCoat 3

New Product Formulation When you need something unique, Kerry has the technical and applications expertise and is ready to work with your R&D team to create a unique solution. Our state of the art pilot plants and application labs in the US, Brazil, Turkey, and India are fully equipped to perform tablet functionality testing to ensure our products conform to the highest standards. Our application experts will collaborate with you to develop a customized formulation that will optimize performance and efficiency while using ingredients that meet all regulatory and consumer requirements. Kerry s application technicians can provide solutions to solve coating issues such as: Soft or friable cores Uneven or inconsistent cores Heat sensitive APIs Moisture sensitive APIs Process efficiency requirements Color match sources can include, but are not limited to: Existing Formulations Previously Coated Tablets Pantone Number PDR or On-Line References R&D/Application Support Custom collaborative coating development capabilities Color matching of existing coating system Pilot scale coating trials Extensive knowledge in scale-up into manufacturing Complete tablet functionality testing capabilities Capabilities to match or exceed performance of current coating system SheffCoat 4

SheffCoat Standard Color Collection Colored tablet coatings provide brand recognition and dose discrimination functions, as well as mask the tablet core. Kerry has coatings to meet label requirements, regulatory requirements and stability needs for all regions. We offer a portfolio of off-the-shelf colors that can also be customized to create a distinctive color. Need to precisely match an existing color? We understand the importance and we get it right. Visual and spectrophotometric color match specifications are part of every product. The below are standard collection colors. Contact us for customized colors per your requirements. 11* 111 121* 131 141 151* 161 171 181 191 111* 1121 12* 112 122* 132 142 152* 162 172 182 192 112* 1122 13* 113 123* 133 143 153* 163 173 183 193 113* 1123 14* 114 124* 134 144 154* 164 174 184 194 114* 1124 15* 115 125* 135 145 155* 165 175 185 195 115* 1125 16* 116 126* 136 146 156* 166 176 186 196 116* 1126 *contains Iron Oxide Packaging and Samples All of our samples are shipped with coated placebos and a sufficient quantity of coating powder formulations so you can evaluate the color prior to performing any coating trials. SheffCoat is packaged in a 25kg poly lined, tamper evident boxes. Customized packaging and batch sizes available upon request. Standard sample is.5 kg, but larger samples are available upon request. SheffCoat 5

SheffCoat Immediate Release Offerings: Coatings Overview SheffCoat Immediate Release film coatings allows the customer to select from numerous plasticizers and a wide range of colorants to customize a film coating that is compatible with your API and regional regulatory requirements. We offer a variety of different viscosities and film strengths to exactly match your existing film coating or customize a film coating that will provide superior film performance and adhesion while providing excellent logo definition without compromising disintegration time or other important tablet properties. SheffCoat Pro VLV Low viscosity HPMC SheffCoat HPMC base SheffCoat PVA PVA base Increased processing efficiency, elasticity and better adhesion Industry standard strong smooth coating with good adhesion Increased processing efficiency, adhesion, and moisture protection SheffCoat MP HPMC + PVA Ability to use a wider range of coating temperatures and a smoother appearance SheffCoat PVA+ PVA + lecithin Additional moisture protection SheffCoat PlusC SheffCoat L (Lactose) HPMC + lactose SheffCoat D (polydextrose) HPMC + Polydextrose SheffCoat S (Starch) HPMC + starch SheffCoat HS HPMC + HPC Increased film strength and adhesion SheffCoat HP (High Pigment) SheffCoat System + additional pigment Increase processing efficiency and decreased coating time (heat and moisture exposure) Cost Reduction SheffCoat 6

SheffCoat Optimization Matrix Polymer Moisture Sensitive API - aqueous coating Moisture Sensitive API - alcohol or solvent coating Temperature Sensitive API API sensitive to plasticizer interaction Waxy or poor adhesion cores Soft tablets (herbal formulations) Low Viscosity/ high solids solution Improved Logo Definition Cleaner label Prop 65 Restrictions Titanium dioxide free Natural Pigments Taste or Odor Masking Glossy Finish Gloss topcoat Precoat for friable cores Precoat for enteric coating Aqueous Enteric Coating Alcohol or Solvent Based Coating SheffCoat HPMC X X X X X X X X SheffCoat Pro HPMC X X X X X SheffCoat PVA PVA X X X X X X X X SheffCoat PVA+ SheffCoat HS SheffCoat L SheffCoat D SheffCoat S PVA X HPMC+ HPC X X X X X X HPMC+ Lactose X X HPMC+ Polydextrose X X HPMC+Starch SheffCoat MP HPMC+PVA X X X X Sheff HP (High Pigment) HPMC and/or PVA X SheffCoat ENT Methacrylate copolymer X SheffCoat EC HPMC+ Ethylcellulose X X X SheffCoat 7

Viscosity, cps 16 14 12 1 8 6 4 2 SheffCoat Viscosities 1 12 14 16 18 2 22 24 % solids SheffCoat SheffCoat PVA SheffCoat D SheffCoat HP SheffCoat Pro SheffCoat MP SheffCoat PVA+ SheffCoat HS Viscosity, cps 14 12 1 8 6 4 2 She Coat Viscosities - PVA based 1 12 14 16 18 2 22 24 % solids She Coat She Coat PVA She Coat MP She Coat PVA+ 12 1 8 Free Film Strength kg/mm 6 4 2 SheffCoat SheffCoat HP SheffCoat HS SheffCoat D SheffCoat MP SheffCoat Pro SheffCoat PVA SheffCoat PVA+ Free Film Elasticity mm/mm 8 7 6 5 4 3 2 1 SheffCoat SheffCoat HP SheffCoat HS SheffCoat D SheffCoat MP SheffCoat Pro SheffCoat PVA SheffCoat PVA+ cc/mm3/day.16.14.12.1.8.6.4.2 Free Film Moisture Transmission SheffCoat SheffCoat HS SheffCoat MP SheffCoat PVA SheffCoat PVA+ Placebo s were coated to 3% weight gain. PEG was used as the plasticizer. SheffCoat 8

The Original SheffCoat The most basic film coating; widely used across the pharmaceutical industry for decades SheffCoat HPMC base Numerous plasticizers available; plasticizers chosen to be compatible with API and regional regulatory requirements, or label requirements Wide range of colors available; chosen to be compatible with API and regional regulatory requirements, or customers preferences Different viscosities and molecular weights available SheffCoat is equivalent in performance and appearance to other HPMC coatings on the market Film Performance SheffCoat film coating system provide exact matches to competitive products with comparable formula and functionality without comprimising important film attributes. 25 Film Performance 1.4 Film Elasticity 2 1.2 g/.1" 15 mm/.1" 1.8 1.6 5.4.2 Competitor SheffCoat Competitor SheffCoat 12 Coated Tablet Disintegration Time 1 8 minutes 6 4 2 Competitor SheffCoat SheffCoat 9

SheffCoat PVA Applied with 2% solids spray suspensions for improved efficiency over HPMC Superior film coating to HPMC SheffCoat PVA PVA base Ideal slip for bottle packaging equipment and blister pack machines No change in tablet dissolution and compared to HPMC Excellent adhesion properties SheffCoat PVA+ PVA + lecithin SheffCoat PVA+ provides the same benefits of a traditional PVA coating but contains lecithin for additional moisture protection. Film Performance cps 15 13 11 9 7 5 3 1-1 Viscosity of Aqueous Dispersions 1 2 3 % solids in dispersion HPMC Coating SheffCoat PVA Competitive PVA.9.8.7.6.5.4.3.2.1 Moisture transmission (cc/mm3/day) HPMC/HPC SheffCoat PVA Competitive PVA SheffCoat 1

SheffCoat Pro HPMC Based Coating Platform SheffCoat Pro is a low viscosity HPMC film coating that provides increased processing efficiency, elasticity and adhesion over traditional HPMC systems. It can be sprayed at a significantly lower temperature than PVA and HPMC allowing for increased energy savings and making it ideal for heat sensitive APIs. SheffCoat Pro is an ideal high efficiency coating when PVA based coatings cannot be used due to regulatory requirements, process temperature, or plasticizer considerations. Applied at 25% solids (up to twice as fast as traditional HPMC systems) Utilizes VLV a low viscosity HPMC without the brittle characteristics of E3. SheffCoat VLV Pro Low Dow viscosity VLV HPMC Adhesive and elastic coating with good appearance and excellent logo definition Considered a trouble shooting coating Sprayable at lower temperatures allowing for increased energy savings and ideal for heat sensitive APIs SheffCoat 11

SheffCoat HS HPMC Based Coating Platform with Increased Film Elasticity and Adhesion Some tablets have softer cores and may need a very durable coating with increased adhesion in order to ensure the tablet core does not erode during the coating process. There are also certain APIs that are extremely sensitive to moisture. The addition of HPC provides improved film characteristics to overcome these issues. SheffCoat HPMC base HPC adds film elasticity and adhesion HPC may also increase viscosity at higher usage rates, slightly lowering solids content of spray suspension increase film elasticity increase adhesion to core SheffCoat HS (High Strength) HPMC + HPC (Hydroxypropyl cellulose) SheffCoat 12

SheffCoat PlusC Systems HPMC Based Coating Platform with Improved Processing Efficiency and Less Cost The need for higher than 15% solids spray suspension is desired when faster processing times are needed because the tablets cannot have prolonged exposure to heat and moisture.the addition of a carbohydrate provides the increased processing efficiency without using PVA. SheffCoat HPMC base replace some HPMC with less viscous material, to enable faster coating with higher solids increase sprayability to 18-2% carbohydrates are widely used /widely approved excellent logo definition SheffCoat L (Lactose) HPMC + lactose SheffCoat D (polydextose) HPMC + Polydextrose Creates adequate film and is low cost alternative to HPMC Excellent logo definition SheffCoat S (Starch) HPMC + Starch SheffCoat 13

SheffCoat MP HPMC Based Coating Platform with Improved Processing Efficiency and Film It is possible to increase processing efficiency of a basic HPMC formulation while maintaining film strength and adhesion.instead of replacing HPMC with a carbohydrate, a high performing film forming polymer such as PVA is used in combination. SheffCoat HPMC base increase processing efficiency increase moisture protection SheffCoat MP (Mixed Polymer) HPMC + PVA Provides the benefits of HPMC while providing higher solid and better elasticity Ability to coat at lower temperatures than PVA PVA allows for higher solids in spray suspension faster processing times PVA provides increased elasticity over HPMC SheffCoat High Pigment Systems HPMC Based Coating Platform with Increase Pigment Loading Increasing the levels of pigment in the formulation provides greater efficiency while maintaining the the film performance. SheffCoat HPMC base decrease in material used less coating time less exposure to heat and moisture SheffCoat SheffCoat HP (High Pigment HP Systems) HPMC Polymer + + additional pigment An increase in pigment load translates to theoretical 1/3 decrease in coating weight gain and processing time to achieve same visual effect Suitable for most tablet cores Elasticity and adhesion is maintained SheffCoat 14

SheffCoat Enteric Film Coatings SheffCoat ENT is a functional delayed release or enteric film coating that releases the API at a specific ph and/or area of the digestive tract. Complete ready-to-spray powder formulations SheffCoat ENT Methylmethacrylate Copolymers Consistent and reproducible delayed release performance Targeted drug delivery for applications including tablets, granules, and beads ph Dependent Release Solubilizes at ph 5.5 Variety of plasticizers available Film Performance Release of ASA from enterically coated cores 12 1 8 % Dis 6 Acid Phase 4 2-12 minutes Buffer Phase 12-21- minutes 5 1 15 2 Time in Minutes 15. 1. 95. 9. 85. 8. 75. 7. 65. 6. % tablets passing modified USP test 4 5 6 7 8 9 1 % weight gain of SheffCoat ENT SheffCoat 15

Americas 34 Millington Road Beloit, WI USA Tel: 68-363-12 Asia Pacific 8 Biomedical Grove #2-1/4 Neuros Singapore 138665 Tel: +65-6715-34 Fax: +65-6464-24 4th Floor, Building No. 92 1122 Qin Zhou Bei Road Caohejing Hi-Tech Park Shanghai 2233 Peoples Republic of China China Tel: +86-21-54265333 Fax: +86-21-5426535 Europe, MIddle East and Africa Millennium Business Park, Osberstown, Naas, Co. Kildare, Ireland Tel: +353()45911563 Tel: +353()45911616 Tel: +353(-)45911564 India Unit 114-115-116, 1st Floor Midas Building Sahar Plaza, J B Nagar, Andheri Kurla Road, Mumbai, Maharashtra, 459 India Tel: +91-22-4157 Sheffield and SheffCoat are trademarks of Kerry Group. Please note that the information herein is believed to be accurate and complete. However, no warranty or guarantee whatsoever is made or is to be implied with respect to such information or with respect to any other product, method, performance or apparatus referred herein. Nothing herein shall be construed as a recommendation to use, manufacture, sell or act in violation of any intellectual property rights or legal requirements. Sheffield Bio-Science is a trademark of Kerry Group. Latin America Av. Mercedes Benz 46 - Distrito Industrial Cep - 1354-75 Campinas, Sao Paulo Brazil Tel: +55-19-3765-5 Fax: +55-19-3765-518 Visit us at www.sheffieldbioscience.com MC/Coating/8215 MC-SheffCoat-8/212