Page: 1 of 7 1. IDENTIFICATION OF THE SUBSTANCE AND OF THE COMPANY Dow Corning Corporation South Saginaw Road Midland, Michigan 48686 24 Hour Emergency Telephone: Customer Service: Product Disposal Information: CHEMTREC: (989) 496-5900 (989) 496-6000 (989) 496-6315 (800) 424-9300 MSDS No.: 02375907 Revision Date: 2002/01/17 Generic Description: Silicone Sealant Physical Form: Paste Color: White Odor: Acetic acid odor Note: NFPA = National Fire Protection Association 2. OSHA HAZARDOUS COMPONENTS NFPA Profile: Health 2 Flammability 1 Instability/Reactivity 0 17689-77-9 1.0-5.0 Ethyltriacetoxysilane 4253-34-3 1.0-5.0 Methyltriacetoxysilane The above components are hazardous as defined in 29 CFR 1910.1200. 3. EFFECTS OF OVEREXPOSURE Acute Effects Eye: Oral: Direct contact may cause moderate irritation. May cause moderate irritation. Irritates respiratory passages very slightly. Low ingestion hazard in normal use. Prolonged/Repeated Exposure Effects Oral: Signs and Symptoms of Overexposure Medical Conditions Aggravated by Exposure
Page: 2 of 7 The above listed potential effects of overexposure are based on actual data, results of studies performed upon similar compositions, component data and/or expert review of the product. Please refer to Section 11 for the detailed toxicology information. 4. FIRST AID MEASURES Eye: Oral: Comments: Immediately flush with water for 15 minutes. Get medical attention. Remove from skin and wash thoroughly with soap and water or waterless cleanser. Get medical attention if irritation or other ill effects develop or persist. No first aid should be needed. No first aid should be needed. Treat according to person's condition and specifics of exposure. 5. FIRE FIGHTING MEASURES Flash Point: Autoignition Temperature: Not applicable. Not determined. Flammability Limits in Air: Not determined. Extinguishing Media: Fire Fighting Measures: Unusual Fire Hazards: On large fires use dry chemical, foam or water spray. On small fires use carbon dioxide (CO2), dry chemical or water spray. Water can be used to cool fire exposed containers. Self-contained breathing apparatus and protective clothing should be worn in fighting large fires involving chemicals. Determine the need to evacuate or isolate the area according to your local emergency plan. Use water spray to keep fire exposed containers cool. Hazardous Decomposition Products Thermal breakdown of this product during fire or very high heat conditions may evolve the following hazardous decomposition products: Carbon oxides and traces of incompletely burned carbon compounds. Silicon dioxide. Metal oxides. Formaldehyde. 6. ACCIDENTAL RELEASE MEASURES
Page: 3 of 7 Containment/Clean up: Observe all personal protection equipment recommendations described in Sections 5 and 8. Wipe up or scrape up and contain for salvage or disposal. Clean area as appropriate since some silicone materials, even in small quantities, may present a slip hazard. Final cleaning may require use of steam, solvents or detergents. Dispose of saturated absorbant or cleaning materials appropriately, since spontaneous heating may occur. Local, state and federal laws and regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which federal, state and local laws and regulations are applicable. Sections 13 and 15 of this MSDS provide information regarding certain federal and state requirements. Note: See section 8 for Personal Protective Equipment for Spills. Call Dow Corning Corporation, (989) 496-5900, if additional information is required. 7. HANDLING AND STORAGE Use with adequate ventilation. Product evolves acetic acid (HOAc) when exposed to water or humid air. Provide ventilation during use to control HOAc within exposure guidelines or use respiratory protection. Avoid eye contact. Avoid skin contact. Use reasonable care and store away from oxidizing materials. Keep container closed and store away from water or moisture. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Component Exposure Limits CAS Number Component Name Exposure Limits 17689-77-9 Ethyltriacetoxysilane See acetic acid comments. 4253-34-3 Methyltriacetoxysilane See acetic acid comments. Acetic acid is formed upon contact with water or humid air. Provide adequate ventilation to control exposures within guidelines of OSHA PEL: TWA 10 ppm and ACGIH TLV: TWA 10 ppm, STEL 15 ppm. Engineering Controls Local Ventilation: General Ventilation: Recommended. Recommended. Personal Protective Equipment for Routine Handling Eyes: Suitable Gloves: Use proper protection - safety glasses as a minimum. Wash at mealtime and end of shift. Contaminated clothing and shoes should be removed as soon as practical and thoroughly cleaned before reuse. Chemical protective gloves are recommended. Silver Shield(R). 4H(R). No respiratory protection should be needed.
Page: 4 of 7 Suitable Respirator: None should be needed. Personal Protective Equipment for Spills Eyes: Inhalation/Suitable Respirator: Use proper protection - safety glasses as a minimum. Wash at mealtime and end of shift. Contaminated clothing and shoes should be removed as soon as practical and thoroughly cleaned before reuse. Chemical protective gloves are recommended. No respiratory protection should be needed. Precautionary Measures: Avoid eye contact. Avoid skin contact. Use reasonable care. Comments: Product evolves acetic acid (HOAc) when exposed to water or humid air. Provide ventilation during use to control HOAc within exposure guidelines or use respiratory protection. Note: These precautions are for room temperature handling. Use at elevated temperature or aerosol/spray applications may require added precautions. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical Form: Paste Color: White Odor: Acetic acid odor Specific Gravity @ 25 C: 1.03 Viscosity: Not determined. Freezing/Melting Point: Not determined. Boiling Point: Not determined. Vapor Pressure @ 25 C: Not determined. Vapor Density: Not determined. Solubility in Water: Not determined. ph: Not determined. Volatile Content: Not determined. Note: The above information is not intended for use in preparing product specifications. Contact Dow Corning before writing specifications. 10. STABILITY AND REACTIVITY Chemical Stability: Hazardous Polymerization: Conditions to Avoid: Materials to Avoid: Stable. Hazardous polymerization will not occur. Oxidizing material can cause a reaction. Water, moisture, or humid air can cause hazardous vapors to form as described in Section 8.
Page: 5 of 7 11. TOXICOLOGICAL INFORMATION Special Hazard Information on Components 12. ECOLOGICAL INFORMATION Environmental Fate and Distribution Complete information is not yet available. Environmental Effects Complete information is not yet available. Fate and Effects in Waste Water Treatment Plants Complete information is not yet available. Ecotoxicity Classification Criteria Hazard Parameters (LC50 or EC50) High Medium Low Acute Aquatic Toxicity (mg/l) <=1 >1 and <=100 >100 Acute Terrestrial Toxicity <=100 >100 and <= 2000 >2000 This table is adapted from "Environmental Toxicology and Risk Assessment", ASTM STP 1179, p.34, 1993. This table can be used to classify the ecotoxicity of this product when ecotoxicity data is listed above. Please read the other information presented in the section concerning the overall ecological safety of this material. 13. DISPOSAL CONSIDERATIONS RCRA Hazard Class (40 CFR 261) When a decision is made to discard this material, as received, is it classified as a hazardous waste? No State or local laws may impose additional regulatory requirements regarding disposal. Call Dow Corning Corporate Environmental Management, (989) 496-6315, if additional information is required. 14. TRANSPORT INFORMATION DOT Road Shipment Information (49 CFR 172.101) Not subject to DOT. Ocean Shipment (IMDG) Not subject to IMDG code. Air Shipment (IATA)
Page: 6 of 7 Not subject to IATA regulations. Call Dow Corning Transportation, (989) 496-8577, if additional information is required. 15. REGULATORY INFORMATION Contents of this MSDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200. TSCA Status: All chemical substances in this material are included on or exempted from listing on the TSCA Inventory of Chemical Substances. EPA SARA Title III Chemical Listings Section 302 Extremely Hazardous Substances: Section 304 CERCLA Hazardous Substances: Section 312 Hazard Class: Acute: Yes Chronic: No Fire: No Pressure: No Reactive: No Section 313 Toxic Chemicals: None present or none present in regulated quantities. Supplemental State Compliance Information California Warning: This product contains the following chemical(s) listed by the State of California under the Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65) as being known to cause cancer, birth defects or other reproductive harm. None known. Massachusetts 7631-86-9 7.0-13.0 Silica, amorphous New Jersey
Page: 7 of 7 70131-67-8 > 60.0 Dimethyl siloxane, hydroxy-terminated 7631-86-9 7.0-13.0 Silica, amorphous 17689-77-9 1.0-5.0 Ethyltriacetoxysilane 4253-34-3 1.0-5.0 Methyltriacetoxysilane Pennsylvania 70131-67-8 > 60.0 Dimethyl siloxane, hydroxy-terminated 7631-86-9 7.0-13.0 Silica, amorphous 16. OTHER INFORMATION Prepared by: Dow Corning Corporation These data are offered in good faith as typical values and not as product specifications. No warranty, either expressed or implied, is hereby made. The recommended industrial hygiene and safe handling procedures are believed to be generally applicable. However, each user should review these recommendations in the specific context of the intended use and determine whether they are appropriate. (R) indicates Registered Trademark