Staples the Office Superstore, LLC. MSDS # 500 Staples Drive Hazard Rating HMIS NFPA Framingham, MA 01702 USA Health Business Phone: 1.800.322.0912 Flammability 24-HR MEDICAL AND DOT EMERGENCIES: 1.800.322.0912 Reactivity Special MATERIAL SAFETY DATA SHEET Complies with ANSI Z400.1 Format SECTION 1: PRODUCT IDENTIFICATION Product: MSDS CODE: 771624, 5/24/2011 This MSDS applies to Product Number: 771624 PRODUCT NAME: Canon CLI-8 Black Remanufactured inkjet Cartridge MODEL #: SIC-R60B DATE ISSUED: 5/25/2011 Article I. Hazard description SECTION 2: HAZARDS IDENTIFICATION Irritant Information pertaining to particular dangers for man and environment: The product has to be labeled due to the calculation procedure of international guidelines. Irritating to eyes. May cause sensitization by skin contact. Classification system: The classification was made according to the latest editions of international substances lists, and expanded upon from company and literature data. NFPA ratings (scale 0-4) Health = 1 Fire = 0 Reactivity = 0 HMIS-ratings (scale 0-4) Health =1 Fire = 0 Reactivity = 0 GHS label elements Warning Warning 3.3/2A - Causes serious eye irritation. 3.4/1 - May cause an allergic skin reaction. Prevention: Avoid breathing dust/fume/gas/mist/vapors/spray. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection.
Response: IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment (see on this label). If skin irritation or rash occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Wash contaminated clothing before reuse. Disposal: Dispose of contents/container in accordance with local/regional/national/international regulations. Chemical characterization SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS Description: Mixture of the substances listed below with nonhazardous additions. Dangerous components: 67-63-0 propan-2-ol Danger: 2.6/2 Warning: 3.3/2A, 3.8/3 56-81-5 glycerol <10% 57-13-6 urea <10% 107-21-1 ethanediol Warning: 64-17-5 Ethanol 3.1.O/4 Danger: 2.6/2 25322-68-3 Polyethylene glycol <5% 55965-84-9 mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl2Hisothiazol- 3-one [EC no. 220-239-6] (3:1) mixture of: 5-chloro-2-methyl-4isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-4-isothiazolin-3-one [EC no. 220-239-6] (3:1) Danger: 3.1.O/3, 3.1.D/3, 3.1.I/3, 3.4.S/1; 3.2/1B <10% <10% <10% 0.002% Warning: 4.1.C/1 SECTION 4: FIRST AID MEASURES 24-HR MEDICAL EMERGENCY PHONE: 1.888.322.0912 Emergency First Aid Procedures: After inhalation: Supply fresh air and to be sure call for a doctor. In case of unconsciousness place patient stably in side position for transportation. After skin contact: Immediately wash with water and soap and rinse thoroughly After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. After swallowing: If symptoms persist consult doctor. SECTION 5: FIRE FIGHTING MEASURES Person-related safety precautions: Not required Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. Protective equipment: No special measures required. SECTION 6: ACCIDENTAL RELEASE MEASURES Measures for environmental protection: Dilute with plenty of water. Do not allow to enter sewers/ surface or ground water. Measures for cleaning/collecting: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Ensure adequate ventilation.
SECTION 7: HANDLING AND STORAGE Handling: Information for safe handling: Ensure good ventilation/exhaustion at the workplace. Prevent formation of aerosols. Information about protection against explosions and fires: No special measures required. Storage: Requirements to be met by storerooms and receptacles: No special requirements. Information about storage in one common storage facility: Not required. Further information about storage conditions: Keep receptacle tightly sealed. SECTION 8: EXPOSURE CONTROLS AND PERSONAL PROTECTION Additional information about design of technical systems: No further data; see item 7. Additional information: The lists that were valid during the creation were used as basis.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES SECTION 10: STABILITY AND REACTIVITY Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. Dangerous reactions No dangerous reactions known. Dangerous products of decomposition: No dangerous decomposition products known. SECTION 11: TOXICOLOGICAL INFORMATION Acute toxicity: Primary irritant effect: On the skin: No irritant effect. On the eye: No irritating effect. Sensitization: Sensitization possible through skin contact.
Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Irritant SECTION 12: ECOLOGICAL INFORMATION General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water. Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. SECTION 13: DISPOSAL CONSIDERATIONS Product: Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. Uncleaned packagings: Recommendation: Disposal must be made according to official regulations. Recommend cleaning agent: Water, if necessary with cleansing agents. SECTION 14: TRANSPORT INFORMATION DOT EMERGENCY 24-HR: 1.888.322.0912 U.S. DOT Class: DOT regulations: Hazard class: - Land transport ADR/RID (cross-border): ADR/RID class: - Maritime transport IMDG: IMDG Class: - Marine pollutant: No Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: - UN "Model Regulation": - SECTION 15: REGULATORY INFORMATION
SECTION 16: OTHER INFORMATION All information contained in this Material Safety Data Sheet is provided to the best of Staples the Office Superstore s knowledge. No warranty is made with respect to this information, expressed or implied, including warranties of merchantability or fitness for a particular purpose. Users are responsible for verifying the information under their own operating conditions to determine whether the products listed in the MSDS are suitable for their intended use. The information contained herein is confidential, intended solely for the user's internal use and may not be provided to any third parties. Users are responsible for compliance with all laws and regulations as may be required by their receipt of the information and use of the products provided with this MSDS.