The Roesky Working Group: Facilities, Collaborations, and Science

Transcription

1 The Roesky Working Group: Facilities, Collaborations, and Science, KIT Universität des Landes Baden-Württemberg und nationales Großforschungszentrum in der Helmholtz-Gemeinschaft

2 Team

3

4 Invited Speakers Polly Arnold, University of Edinburgh, UK Isabelle Billard, IPHC/DRS, Strasbourg, France William J. Evans, UC Irvine, USA Sophie M. Guillaume, Université de Rennes, France Peter C. Junk, Monash University, Clayton, Australia Arndt Simon, MPI, Stuttgart, Germany 33 Other Lectures 150 Participants

5 Expertise: Research Background Strong background in the synthesis of organometallic and coordination compounds. Catalysis: Hydroamination Polymerization We do not handle radioactive material but we cooperate with the INE and the ITU in Karlsruhe.

6 Equipment Facilities State of the art equipment for handling air stable to highly air sensitive compounds Different kinds of Schlenk lines Glove boxes

7 Instrumentation Facilities NMR Single Crystal X-ray diffraction

8 Instrumentation Facilities IR and Raman Spectroscopy Elemental Analysis

9 Facilities Instrumentation Mass spectroscopy (EI and ESI) HPLC

10 Collaborations Collaborations with French Groups Long term collaboration in the field of polymerization Dr. Sophie Guillaume: Université de Rennes 1 Polymerization Prof. Laurent Maron: Université Paul Sabatier Theory 4 Joint Publications since submitted

11 Collaborations Collaborations in the field of Nuclear Waste Disposal Collaboration with the Institut für Nukleare Entsorgung, KIT and the Universität Heidelberg Dr. Melissa A. Denecke EXAFS Dr. Andreas Geist Actinide(III) / lanthanide(iii) separation 02NUK012 Prof. Dr. Petra J. Panak TRLFS 1 Joint Publication since submitted

12 Science Sc Y La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu

13 Science: An Overview Lanthanides Homogenous catalysis: Hydroamination Polymerization Cluster und porous strucrtures (MOF): Magnetism Luminescens Metal-to-metal-bonds t t l Nuclear waste disposal

14 Science Ca Sr Ba

15 Science: An Overview Alkaline Earth Metals Homogenous catalysis: Hydroamination Metal-to-metal-bonds

16 Science Zn

17 Science: An Overview Zinc Homogenous catalysis: Hydroamination Polymerization Metal-to-metal-bonds t t l

18 Science Au

19 Science: An Overview Gold Heterogenous catalysis Metal-to-metal-bonds Luminescens

20 The First Main-Group-Lanthanide Metal-to-Metal bonds 1/4 [( 5 -C 5 5 Me 5 )Al] 4 + [( -C 5 Me 5 ) 2 Eu] Eu Al d: Al-Eu (10) Å space group P1 R 1 = wr 2 = M. T. Gamer,, S. N. Konchenko, P. Nava, R. Ahlrichs Angew. Chem., Int. Ed. 2006, 45,

21 The first Molecular Polyphosphide of the Rare-Earth Elements P 4 Sm + 2 P P P S. N. Konchenko, N. A. Pushkarevsky, M. T. Gamer, R. Köppe, H. Schnöckel, J. Am. Chem. Soc. 2009, 131,

22 The first Polyphosphide Triple-decker Complexes of the Rare-Earth Elements Fe P P P P P THF Sm III DIP N N N THF DIP First mixed d /f metals triple-decker complex T. Li, J. Wiecko, N. A. Pushkarevsky, M. T. Gamer, R. Köppe, S. N. Konchenko, M. Scheer, An Angew. Chem. Int. Ed. 2011, 50,