SAFETY DATA SHEET MARISOL LA. Last changed: 01/12/2012 Replaces date: 01/07/2009

Transcription

1 1 Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Trade name / designation 1.2 Relevant identified uses of the substance or mixture and uses advised against RELEVANT IDENTIFIED USES Degreaser 1.3 Details of the supplier of the safety data sheet NATIONAL MANUFACTURER/IMPORTER Enterprise Maritech AB Address Box 9063 Postal code S Kristianstad Country Sweden [email protected] Internet Telephone Fax Emergency Telephone Number Emergency Phone Type of assistance Opening Hours 112 Giftinformation Dygnet runt 2 Hazards identification 2.1 Classification of the substance or mixture DPD Classification: Most important HSE hazard effects: 2.2 Label elements Xn; R65, R66 Harmful: may cause lung damage if swallowed. Repeated exposure may cause skin dryness or cracking. Harmful EC-Label: No COMPOSITION distillates (petroleum), hydrotreated light (60-90 %) R-PHRASES R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. S-PHRASES S 23 Do not breathe vapour/spray. S24 Avoid contact with skin. S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. 1 / 7

2 2.3 Other 3 Composition/information on ingredients 3.2 Mixtures Ingredient name Reg.No EC No. CAS No. Conc. DPD- CLP-classification (wt%) Classification distillates (petroleum), hydrotreated light % Xn,R65 - R66 Asp. Tox. 1 H304 EUH066 2-(2-butoxyethoxy)ethanol, diethylene glycol monobutyl ether % Xi,R36 Eye Irrit. 2 H319 Full text of R-, H- and EUH-phrases: see section 16. The EUH hazard statements mentioned in CLP-classification are only label elements. 4 First aid measures 4.1 Description of first aid measures INHALATION Fresh air and rest. Keep an eye on the injured person. Get medical attention if any discomfort continues. In the event of breathing difficulties, administer breathing assistance and immediately consult a doctor. INGESTION Rest. DO NOT induce vomiting. Get medical attention immediately. SKIN CONTACT Rinse skin thoroughly with water. Immediately remove contaminated clothing. EYE CONTACT Rinse the eye with water immediately. Get medical attention if any discomfort continues. 4.2 Most important symptoms and effects, both acute and delayed MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED Harmful: may cause lung damage if swallowed. Repeated exposure may cause skin dryness or cracking. 4.3 Indication of any immediate medical attention and special treatment needed INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED Treat symptomatically. 5 Fire-fighting measures 5.1 Extinguishing media SUITABLE EXTINGUISHING MEDIA: Extinguishing agent: carbon dioxide, powder, foam, a wide water jet or water mist. 5.2 Special arising from the substance or mixture SPECIAL HAZARDS The product may accumulate static elctricity. 5.3 Advice for fire-fighters Containers close to fire should be removed or cooled with water. 2 / 7

3 6 Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures PERSONAL PRECAUTIONS Wear necessary protective equipment. 6.2 precautions ENVIRONMENTAL PRECAUTIONS Prevent discharge into the sewage system or the immediate environment. 6.3 Methods and material for containment and cleaning up METHODS AND MATERIAL Bank with sand, earth or other inert absorption agent. Pump up liquid spillage with explosion-proof pump or hand pump, or use suitable absorbent material. 6.4 Reference to other sections REFERENCES See Section 1 for contact in case of emergency. See section 8 for information regarding personal protection. See section 13 for information regarding waste treatment. 7 Handling and Storage 7.1 Precautions for safe handling 7.2 Conditions for safe storage, including any incompatibilities CONDITION FOR SAFE STORAGE, INCLUDING ANY UNCOMPATIBILITIES Keep away from sources of ignition. 7.3 Specific end uses SPECIFIC END USE(S) No information available Store in accordance with regulations for flammable goods. 8 Exposure controls / Personal protection 8.1 Control parameters OEL value Ingredient name CAS no. Range ppm mg/m3 Year Notification 2-(2-butoxyethoxy)ethanol, diethylene glycol monobutyl ether h distillates (petroleum), hydrotreated light 15 min distillates (petroleum), hydrotreated light 8 h R=Toxic for reproduction, H=Skin absorption, K=Carcinogenic, A=Sensitising, T=Upper limit, M=Mutagenic 8.2 Exposure controls EYE PROTECTION Wear approved, tight fitting safety glasses where splashing is probable. HAND PROTECTION Protective gloves (e.g. nitrile) must be used if there is a risk of direct contact or splash. 3 / 7

4 RESPIRATORY PROTECTION If necessary, respirator with A filter (brown). OEL value, in accordance with applicable regulations. 9 Physical and chemical Properties 9.1 Information on basic physical and chemical properties PHYSICAL STATE Liquid. COLOUR Light yellow. ODOUR Weak SOLUBILITY Emulsable in water. Parameter Value/unit Method/reference Observation ph consentrate ph in solution Melting point Freezing point Initial boiling point and boiling range C Flash point > 70 C Evaporation rate Flammability (solid, gas) Flammability limits Explotion limits % Vapour pressure Vapour density Relative density Partition coefficient Auto-ignition temprature Decomposition temprature Viscosity 9.2 Other safety information Parameter Value/unit Method/reference Observation Density 825 kg/m³ Note no. Comments 10 Stability and Reactivity 10.1 Reactivity REACTIVITY No information on specific properties or Chemical stability CHEMICAL STABILITY Stable under recommended storage and handling conditions Possibility of hazardous reactions POSSIBILITY OF HAZARDOUS REACTIONS No dangerous reactions known. 4 / 7

5 10.4 Conditions to avoid CONDITIONS TO AVOID Avoid sources of sparking (smoking, fire, static electricity). SAFETY DATA SHEET 10.5 Incompatible materials INCOMPATIBLE MATERIALS Avoid contact with strong oxidisers Hazardous decomposition products: HAZARDOUS DECOMPOSITION PRODUCTS No hazardous decomposition products. 11 Toxicological information 11.1 Toxicological effects ACUTE TOXICITY - ORAL May cause nausea and vomiting. Aspiration during vomiting or ingestion may cause chemical pneumonia. ACUTE TOXICITY - DERMAL Defats the skin. Protracted or repeated exposure may cause drying and cracking of the skin. ACUTE TOXICITY - INHALATION May cause headache and nausea. SERIOUS EYE DAMAGE/IRRITATION May cause smarting. 12 Ecological information 12.1 Toxicity 12.2 Persistence and degradability DEGRADABILITY The component surfactants are easily biodegradable according to Regulation (EC) No 648/2004 on detergents Bioaccumulative potential ACCUMULATION Bioaccumulation improbable Mobility in soil MOBILITY No information available 12.5 Results of PBT and vpvb assessment RESULT OF PBT AND VPVB ASSESSMENT No information available 12.6 Other adverse effects Not regarded as dangerous for the environment. 5 / 7

6 13 Disposal considerations 13.1 Waste treatment methods GENERAL REGULATIONS Treat as dangerous waste. The company is member of REPA. Empty and cleaned packaging is sent for recycling. CATEGORY OF WASTE EWC code is only a suggestion, final consumer selects a suitable EWC code (EWC) (EWC) 14 Transport information Classified as Dangerous Goods: No Land transport (ADR/RID) 14.1 UN-No Packing 14.3 Class(es) Hazard label(s) 14.5 Hazard ID: Tunnel restriction code Inland water ways transport (ADN) 14.1 UN-No Packing 14.3 Class(es) Enviromentally hazardous in tank-vessels 14.5 Sea transport (IMDG) 14.1 UN-No Packing 14.3 Class(es) Sub Risk: IMDG Code segregation Marine pollutant EMS: 14.5 Air transport (ICAO-TI / IATA-DGR) 14.1 UN-No Packing 14.3 Class(es) Hazard label(s) / 7

7 15 Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture 15.2 Chemical Safety Assessment no data available SAFETY DATA SHEET 16 Other information Indication of changes Indication of changes Version Rev. date Responsible Changes /12/2012 A Clean Partner Int. AB 1,2,3,4,5,6,7,8,9,10,11,12,13,14,15,16 VENDOR NOTES Regulation (EC) No 648/2004 on detergents: Aliphatic hydrocarbons > 30 % Non-ionic surfactants < 5 % LIST OF RELEVANT R-PHRASES R36 Irritating to eyes. R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. LIST OF RELEVANT H-STATEMENTS H304 May be fatal if swallowed and enters airways. H319 Causes serious eye irritation. EUH066 Repeated exposure may cause skin dryness or cracking. SDS IS PREPARED BY Enterprise A Clean Partner International AB Address Box 623 Postal code S Alingsås Country Sweden [email protected] Internet Telephone +46(0) Fax +46(0) / 7