Safety Data Sheet According to Regulation (EC) No 1907/2006 (REACH)

Transcription

1 Product. No: Specification No: SR type Page 1 of 8 Section 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product Identifier Trade name/designation: Zinc Silver Oxide Battery (SR) 1.2 Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses: Uses advised against: 1.3 Details of the supplier Supplier: Hitachi Maxell, Ltd., Energy Division, MD Dept Address 5, Takumidai, Ono-shi, Hyogo , Japan Telephone Number: 81-(0) Classification of the substance or mixture: Section 2: Hazards identification Classification according to Regulation (EC) No 1272/2008 [CLP/GHS] Additional information: Legal Remark (U.S.A) Improper handling of the battery could lead to distortion, leakage*, overheating, or explosion and cause human injury or equipment trouble. Direct contact with contents leaking from the battery could cause injury such as loss of eyesight. Please strictly observe safety instruction. (*Leakage is defined as an unintended escape of liquid from a battery.) Legal Remark (EU) These batteries are no substances or preparations according to Regulation (EC) No 1907/2006 EC. Instead they have to be regarded as articles, no substances are intended to be released during handling. Therefore there is no obligation to supply a MSDS according to Regulation (EC) 1907/2006, Article 31.

2 Product. No: Specification No: SR type Page 2 of Label elements Labeling according to Regulation (EC) No 1272/2008 Hazard pictograms: Xi: Irritant F: Highly N: Dangerous for Flammable the environment Signal word: Danger Hazard statements: The battery is sealed hermetically. Thus, the ingredients have no hazard potential, except the battery is violated or dismantled. If in case of mistreatment the ingredients are released, a spontaneously flammable gas mixture may be released under certain circumstances (measures according to section 4 to 6). Precautionary statements: Attention: If batteries are treated wrong the danger of burns or bursts occurs. Batteries must not be heated above 100 C or incinerated. The battery contents must not get in contact with water. If the negative electrode gets in contact with water or humidity hydrogen gas is formed, which may inflame spontaneously. 3.1 Description of the mixture: Section 3: Composition/information on ingredients CAS No EC No INDEX No REAC H No % [weight] Name Silver oxide Classification according to 67/548/EEC Maganese dioxide Xn; R20/22; S Graphite Zinc F; R15-17: N; R or less Mercury Repr.Cat. 2: R26; T+; R48/23; N; R Pottassium Hydroxide Xn; R22; C; R Sodium Hydroxide C; R35

3 Product. No: Specification No: SR type Page 3 of 8 Section 4: First Aid Measures 4.1 Description of first aid measures None unless exposed to internal materials. If contents leak, observe the following instructions Eye contact: Immediately rinse the eye with plenty of water and continue for at least 15 minutes. Consult a physician immediately Inhalation: Damaged batteries may release alkaline solution fumes that could cause respiratory irritation. Immediately rinse the mouth with plenty of water and consult a physician Skin contact: Immediately wash the skin with plenty of water. If itchiness or irritation due to chemical burns persists, consult a physician Ingestion: If a battery is swallowed, consult a physician immediately. If the contents come into contact with the mouth, immediately rinse with plenty of water and consult a physician. Section 5: Firefighting measures 5.1 Extinguishing media: Suitable extinguishing media: Any type of extinguisher is effective Unsuitable extinguishing media: n/a 5.2 Special hazards arising from the substance or mixture Hazardous combustion products: 5.3 Advice for fire-fighters: Heat from a fire could cause batteries to explode and release an alkaline solution. Use self-contained breathing apparatus and full protective equipment to avoid inhalation and prevent harmful alkaline fumes from entering the eyes or coming into contact with the skin. Section 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures n/a

4 Specification No: SR type Page 4 of 8 Section 7: Handling and storage 7.1 Precautions for safe handling Protective measures: Do not swallow the battery, touch any liquid that leaks from the battery, short-circuit, charge, expose to open flame, heat, disassemble or deform the battery 7.2 Conditions for safe storage, including any incompatibilities Never store the battery in hot or humid place. Never let the battery come into contact with water. Section 8: Exposure controls/personal protection Under normal conditions (during discharge) release of ingredients does not occur. 8.1 Control parameters Occupational exposure limits: Limit value type (country of origin) Substance name EC-No. CAS-No Limit value Monitoring and observation processes 8.2 Exposure controls Appropriate engineering controls: Not Available Personal protective equipment: Not Available Eye/Face protection: Not Available Skin protection: Not Available Respiratory protection: Not Available Work/Hygienic Practices: Not Available. Section 9: Physical and Chemical Properties Not applicable if closed. 9.1 Information on basic physical and chemical properties Appearance Physical state: Disc Shaped Color: Odor: Odor threshold: Safety relevant basic data ph (20 C): No Data Melting point/range( C): No Data Initial boiling point/range ( C): NoData Decomposition temperature ( C): NoData Flash point ( C): No Data Ignition temperature ( C): No Data Vapor pressure (hpa) at C: No Data

5 Specification No: SR type Page 5 of 8 Vapor density (air = 1): No Data Density (g/cm3)at C: No Data Bulk density (kg/m3): No Data Water solubility (20 C in g/l): No Data Solubility(ies): No Data Partition coefficient: No Data N-Octanol/Water (log Po/w): No Data Viscosity, dynamic (mpa s): No Data Physical hazards: 9.2 Other safety information: Properties of explosive atmospheres (mixtures): Gases and vapors: No Data Dusts: No Data Physical chemical properties of nanoparticles: No Data Limiting oxygen concentration: No Data Bulk density: No Data Solubility in different media: No Data Stability in organic solvents and identity of relevant degradation products: No Data Evaporation rate: No Data Conductivity: No Data Surface tension: No Data Dissociation constant in water (pka): No Data Oxidation-reduction Potential: No Data Fat solubility (solvent oil to be specified): No Data Critical temperature: No Data 10.1 Reactivity: 10.2 Chemical stability: Stable 10.3 Possibility of hazardous reactions n/a 10.4 Conditions to avoid: See section Incompatible materials: n/a 10.6 Hazardous decomposition products: n/a Section 10: Stability and reactivity Section 11: Toxicological Information 11.1 Information on toxicological effects: No Data Effect dose / Concentration Acute oral toxicity Acute dermal toxicity Acute inhalative toxicity (gas) Acute inhalative toxicity (vapor) Acute inhalative toxicity (dust/mist) Species Method Time

6 Specification No: SR type Page 6 of 8 Section 12: Ecological information 12.1 Toxicity: No Data Aquatic toxicity Substances Acute (short-term) toxicity Effect dose Exposure time Species Method Evaluation Remark LC50 EC50 IC50 Chronic (long-term) toxicity Effect dose Longterm fish toxicity LC50 Chronic daphnia toxicity EC50 Exposure time Species Method Evaluation Remark Section 13: Disposal considerations 13.1 Waste treatment methods Product/packaging disposal: The battery may be regulated by national or local regulations. Please follow the proper regulations. Electricity remaining in a discarded battery can lead to distortion, leakage, overheating, or explosion if battery comes into contact with other metals, so make sure to cover the (+) and (-) terminals with friction tape or some other insulator before disposal Section 14: Transport Information Alkaline batteries are considered to be dry cell batteries and are unregulated for purposes of transportation by U.S. Department of Translportation (DOT), International Civil Aviation (ICAO), International Air Transport Association (IATA) and the International Maritime Organization (IMO) 14.1 Land transport (CFR 49: DOT):not regulated UN-No: Proper shipping name: Class(es): Packing group: Hazard label(s): Special provision(s): Land transport (ADR/RID/GGVSE): not regulated UN-No: Proper shipping name: Class(es): Classification Code: Packing group: Hazard label(s):

7 Specification No: SR type Page 7 of 8 Special provision(s): Sea transport (IMDG-Code/GGVSee): not regulated UN No: Proper shipping name: Class(es): Packing group: Marine Pollutant: Special provision(s): Air transport (ICAO-IATA/DGR): not regulated UN No: Proper shipping name: Class(es): Packing group: Special provision(s): A123 Section 15: Regulatory Information 15.1 Safety, health and environmental regulations/legislation specific for the mixture EU regulation Authorizations and/or restrictions on use: Authorizations: Restrictions on use: Not to be used by children Other EU regulations: This product is considered an article therefore no MSDS is required National regulations (Germany): Restrictions of occupation: Not to be used by children Storage class VCI: Water hazard class: non-water pollution according to VwVwS Appendix 1 Section 16: Other Information 16.1 Relevant R-, H- and EUH-phrases (number and full text): Xn: Harmful T: Toxic Xi: Irritating O: Oxidising C: Corrosiv N: Dangerous for the enviroment R8: Contact with conbulsive material may case fire R20/22: Harmful by inhalation and if swallowed. R22: Harmful if sswallowed R23: Toxic by Inhalation R33: Danger of cumulatve effects R34: Cuses burns R35: Causes severe burns R 44: Risk of explosion if heated under confinement R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

8 Specification No: SR type Page 8 of 8 The above information is based on the data of which we are aware and is believed to be correct as of the date hereof. Since this information may be applied under conditions beyond our control and with which we may be unfamiliar and since data made available subsequent to the date hereof may suggest modifications of the information, we do not assume any responsibility for the results of its use. This information is furnished upon condition that the person receiving it shall make his own determination of the suitability of the material for his particular purpose.

9 Specification No: SR type Page 9 of 8

10 Trade name: Manganese Dioxide (CR Type) Lithium Batteries Product. No: All CR type coin batteries Print date: 28SEP2011

11 Trade name: Manganese Dioxide (CR Type) Lithium Batteries Product. No: All CR type coin batteries Print date: 28SEP2011

12 Trade name: Manganese Dioxide (CR Type) Lithium Batteries Product. No: All CR type coin batteries Print date: 28SEP2011

13 Trade name: Manganese Dioxide (CR Type) Lithium Batteries Product. No: All CR type coin batteries Print date: 28SEP2011