The Periodic Table. Bromfield Honors Chemistry
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1 The Periodic Table Bromfield Honors Chemistry
2 Write your answers in your notebook What is a trend? What are some patterns or trends you have observed?
3 Periodic Law Historical development Chemical Periodicity Periodic table Features of modern table Mendeleev Moseley Valence electrons Periods Groups Electronegativity Electron Configurations Alkali metals Atomic Size Ionic Size Periodic Trends Ionization Energy Electron Affinity Alkaline Earth Metals Transition Metals Chalcogens Halogens Noble Gases
4 Modern Periodic Table Periods horizontal rows Numbered 1-7 (corresponds to n)
5 Modern Periodic Table Groups vertical columns Numbered 1-18
6 Valence Electrons The outermost electrons in an atom
7 Valence Electrons The outermost electrons in an atom The electrons in the highest occupied s and p orbitals
8 Valence Electrons The outermost electrons in an atom The electrons in the highest occupied s and p orbitals Varies from 1 to 8
9 Valence Electrons The outermost electrons in an atom The electrons in the highest occupied s and p orbitals Varies from one to eight # of valence electrons = group number or group number - 10
10 How many valence electrons? Li C N Ar O Mg
11 Lewis dot diagrams One dot for each valence electron Li N O C Ar Mg
12 s, p, d and f blocks
13 Representative Elements Elements in the s and p blocks Aka Main group elements
14 Elements of the f block Often called the rare earths or inner transition metals Lanthanides Actinides Many are radioactive
15 Alternative Periodic Tables
16 Alternative Periodic Tables
17 Alternative Periodic Tables
18 Alternative Periodic Tables
19 Alternative Periodic Tables
20 Alternative Periodic Tables
21 Modern Periodic Table Video Most of the elements in the periodic table are metals!
22 Classes of elements Metals Typically solids Exception: mercury Lustrous Good conductors Malleable Ductile Nonmetals May be solid, liquid or gas Solids are brittle Nonconductors
23 Metalloids Have properties of metals and nonmetals
24 Group 1 Alkali Metals Most reactive metals Must be stored under oil Not found as free elements in nature Soft can be cut with a knife Reactions with water
25 Alkali Metals 1 valence electron Typically form +1 ions
26 Group 2 Alkaline Earth Metals
27 Group 2 Alkaline Earth Metals Less reactive than alkali metals
28 Group 2 Alkaline Earth Metals Less reactive than alkali metals Not found as free elements in nature
29 Group 2 Alkaline Earth Metals Less reactive than alkali metals Not found as free elements in Have 2 valence electrons
30 Group 2 Alkaline Earth Metals Less reactive than alkali metals Not found as free elements in nature Have 2 valence electrons Typically form +2 ions
31 Transition metals Groups 3-12
32 Transition metals Compounds of transition metals are often highly colored
33 Transition metals Many transition metals can form several cations Ex. Cr 6+, Cr 3+
34 Hemoglobin a metalloprotein! Deoxyhemoglobin (in veins) Oxyhemoglobin (near the heme) In arteries
35 Group 16 Chalcogens 6 valence electrons Tend to form -2 anions Aka oxygen family Periodic Videos: Selenium
36 Group 17 Halogens The most reactive nonmetals Periodic Videos: Fluorine
37 Group 17 Halogens The most reactive nonmetals 7 valence electrons Tend to form -1 anions
38 Group 17 Halogens The most reactive nonmetals 7 valence electrons Tend to form -1 anions Form diatomic molecules F 2, I 2, Cl 2, Br 2
39 Halogens
40 Group 18 Noble Gases Non-reactive gases Open University: Noble Gases 8 valence electrons Completely filled sublevels Don t tend to gain or lose electrons Basically don t form compounds
41 Group 18 Noble Gases Non-reactive gases 8 valence electrons Completely filled sublevels Don t tend to gain or lose electrons Basically don t form compounds
42 Organizing information By the mid-1800 s, about 70 elements were known
43 Organizing information By the mid-1800 s, about 70 elements were known Similarities of certain elements Coinage elements: copper, silver, gold
44 Organizing information By the mid-1800 s, about 70 elements were known Similarities of certain elements Coinage elements: copper, silver, gold Halogens ( salt-maker ): chlorine, bromine, iodine
45 Organizing information By the mid-1800 s, about 70 elements were known Similarities of certain elements Coinage elements: copper, silver, gold Halogens ( salt-maker ): chlorine, bromine, iodine Alkali metals: lithium, sodium, potassium
46 Early attempts at organizing Döbereiner s triads
47 Early attempts at organizing Döbereiner s triads Newland s Law of Octaves
48 Dmitri Mendeleev ( )
49 Dmitri Mendeleev ( ) 1869 published first periodic table of the elements
50 Dmitri Mendeleev ( ) 1869 published first periodic table of the elements Listed all known elements in order of increasing atomic mass
51 Dmitri Mendeleev ( ) 1869 published first periodic table of the elements Arranged rows so that elements with similar properties were side by side
52 Dmitri Mendeleev ( ) 1869 published first periodic table of the elements Arranged rows so that elements with similar properties were side by side (even if out of order by mass)
53 Dmitri Mendeleev ( ) Left blanks in table if no element with appropriate property was known
54 Dmitri Mendeleev ( ) Left blanks in table if no element with appropriate property was known This led to very accurate predictions of scandium, germanium and gallium
55 Henry Moseley ( ) Used x-ray diffraction data on the elements to determine the nuclear charge
56 Henry Moseley ( ) Used x-ray diffraction data on the elements to determine the nuclear charge Realized that the properties of the elements are related to atomic number
57 Henry Moseley ( ) Rearranged the periodic table based on atomic number
58 Glenn Seaborg Rearranged the periodic table by putting the lanthanides and actinides under the main body of the table Video
59 The Periodic Law When elements are arranged according to increasing atomic number, there is a regular and repeating pattern in their chemical and physical properties.
60 The Special 7 Elements that exist as diatomic molecules H 2 O 2 N 2 F 2 Cl 2 I 2 Br 2
61 The Special 7 Elements that exist as diatomic molecules H 2 O 2 N 2 F 2 Cl 2 I 2 Other elemental molecules: P 4 S 8 Br 2
62 Exceptional Electron Configurations Some elements have electron configurations that don t follow the arrowfilling diagram Ex. Cu Expected: Actual:
63 Exceptional Electron Configurations Some elements have electron configurations that don t follow the arrowfilling diagram Why? Special stability associated with half-filled or fully filled sublevels
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