Spectra in the Lab ATOMS AND PHOTONS

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1 Spectra in the Lab Every chemical element has a unique ``signature'' which can be revealed by analyzing the light it gives off. This is done by spreading the light out into a rainbow of color. It may seem remarkable that we can learn about the composition of distant stars by studying the light they emit. In fact, we can learn a great deal, not only about the chemical elements present, but also about physical conditions. The key is to spread the light out by color, producing a spectrum like the one shown in Fig. 1. This lab explores some of the basic ideas used to analyze spectra. ATOMS AND PHOTONS Fig. 1. A spectrum. The light - in this case, from an ordinary light bulb - has been spread out into a rainbow of color. The scales above and below the spectrum will be explained below. The nature of matter was debated for thousands of years. Suppose you have a chunk of gold, for example, and you start cutting it into smaller and smaller pieces. Can you always cut any piece, even a very small one, into two smaller pieces of gold? Or is there some minimum size a piece of gold can have? We know the answer - the smallest possible piece contains just one atom of gold. Atoms are the building blocks of matter. There are about one hundred different kinds of atoms in the universe - these are known as the chemical elements. The nature of light posed a very similar question: Is light composed of waves or of particles? If light is waves, then one can always reduce the amount of light by making the waves weaker, while if light is particles, there's a minimum amount of light you can have - a single ``particle'' of light. In 1905, Einstein found the answer: light is both! In some situations it behaves like waves, while in others it behaves like particles. This may seem strange and mystical, but it describes the nature of light very well. A wave of light has a wavelength, defined as the distance from one crest of the wave to the next, and written using the symbol. The wavelengths of visible light are quite small: between 400 mm and 650 nm, where 1 nm = 10-9 m is a ``nanometer'' - one billionth of a meter. In Fig. 1, the scale on the bottom shows wavelengths in nanometers; as you can see, red light has a long wavelengths, while blue light has a short wavelengths. A particle of light, known as a photon, has an energy E. The energy of a single photon of visible light is tiny, barely enough to disturb one atom; we use units of ``electron-volts'', abbreviated as ev, to measure the energy of photons. In Fig. 1, the scale on the top shows energies in electron-volts; photons of red light have low energies, while photons of blue light have high energies. The relationship between energy E and wavelength is one of the most basic equations of quantum physics:

2 Here c is the speed of light, and h is known as Planck's constant. Both c and h are constants of nature; they never change. From our point of view, the significance of this equation is that energy E and wavelength are inversely proportional to each other, and the relationship between them is the same in a laboratory on Earth and in the most distant stars and galaxies. SIGNATURES OF THE ELEMENTS As the ideas of quantum physics developed, physicists began to understand another puzzle. A century before, scientists noticed that the light given off by a hot gas or vapor does not form a spectrum of all colors as in Fig. 1; instead, only certain colors are present, and each element produces a unique set of these colors, as shown in Fig. 2. Why do hot atoms behave this way? The answer involves two key ideas: first, each atom contains one or more electrons orbiting a central nucleus; second, in atoms of any given element, only certain orbits are allowed, and a very specific amount of energy is involved when an electron jumps from one orbit to another. Hydrogen: a simple atom with a simple spectrum. Besides the three lines shown here, you may be able to see another in the blue near 410 nm. Helium: slightly more complex than hydrogen, with one yellow line and a number in the blue. Neon: a very large number of lines in the red give neon signs their distinctive pink colors, but notice the two green lines. Argon: the pastel color of argon is due to a wide range of lines throughout the spectrum. Mercury: the strongest line, at 546 nm, gives mercury a greenish color. Fig. 2. When heated, each element produces a unique pattern of spectral ``lines''. Fig. 3 illustrates this for hydrogen, which has only one electron. The allowed orbits of an electron in a hydrogen atom can be numbered using the symbol n, with n = 1 for the orbit closest to the nucleus, n = 2 for the next one out, and so on. For orbit n, the amount of energy required to completely separate the electron

3 from the nucleus is This quantity E n is the energy level of orbit n. For example, an electron in orbit n = 2 requires energy E 2 = 3.4 ev to be separated from the nucleus, while an electron in orbit n = 3 requires only E 3 = 1.51 ev; thus, orbit n = 3 is less tightly bound to the nucleus than orbit n = 2. When an electron jumps down from orbit n = 3 to orbit n = 2, it gives off energy E = E 2 - E 3 = 1.89 ev. This is exactly the energy of the photons which make up the red line of hydrogen in Fig. 2. Likewise, electrons jumping from orbit n = 4 to orbit n = 2 produce the blue-green line, and electrons jumping from orbit n = 5 to orbit n = 2 produce the deep blue line. When an electron jumps from a high-numbered orbit to a low-numbered orbit, the atom emits a photon. Fig. 3. Energy levels (horizontal lines), and downward jumps (arrows) of hydrogen. The wiggly arrows in color represent the photons produced when an electron jumps down from one orbit to another. To save space, the lowest level (n = 1) is not shown. What happens when an electron in a hydrogen atom jumps up to a higher orbit? This takes energy, which has to come from somewhere. One way to supply the energy is with a photon, but the photon has to have exactly the right amount of energy - no more, and no less. So an electron in orbit n = 2 can jump up to orbit n = 3 if it encounters a photon with energy E = E 2 - E 3 = 1.89 ev. When an electron jumps from a lownumbered orbit to a high-numbered orbit, the atom absorbs a photon. Similar processes of emission and absorption are possible with atoms of other elements. For atoms with more than one electron, the physics is more complex, but the basic idea that electrons have only certain allowed orbits still holds. Each element has a different set of allowed orbits, so each element emits or absorbs photons with different energies, so, different wavelengths. This is just what we see in Fig. 2! Molecules also produce spectral lines, but their spectra are much more complex than the spectra of single atoms, and typically show broad bands instead of narrow lines, as in Fig. 4. Fig. 4. A spectrum of air. The bright bands are due to molecular oxygen

4 TYPES OF SPECTRA (O 2 ), molecular nitrogen (N 2 ), and other molecules. Examining different kinds of light with a spectroscope reveals a wide variety of spectra. The appearance of a spectrum tells us something about the physical conditions which produce the light. For example, a continuous spectrum, like the one at the top of Fig. 5, is a featureless rainbow of color. This kind of spectrum is the hallmark of ``black-body'' radiation (so-called because a black object, heated until it glows, emits this kind of light). A hot solid, liquid, or very dense gas produces a continuous spectrum; while a wide range of wavelengths are always present, the overall color of the light depends on the temperature. For example, a bar of iron heated in a fire glows dull red; if heated more it glows orange, and if heated well beyond its melting point it shines with a brilliant blue-white light. In contrast, an emission spectrum, like the one in the middle of Fig. 5, consists of bright lines or bands on a dark background. Emission spectra are produced when atoms of a low-density gas are ``excited'' - in effect, heated - by an electrical current, ultraviolet radiation, or some other source of energy. Excited atoms have electrons in high orbits, and these emit photons with specific wavelengths when they jump back down to lower orbits (as explained above). Neon signs produce emission spectra; so do objects like the Lagoon Nebula (M8) and the Ring Nebula (M57). Continuous spectrum: a smooth gradation of color, with no distinct features. Emission spectrum: bright lines on dark background. Absorption spectrum: dark lines superimposed on a continuous spectrum. Fig. 5. Basic types of spectra. The absorption spectrum is shown in black & white because the subtle dark lines are hard to reproduce in color. Finally, an absorption spectrum, like the spectrum of sunlight shown in the bottom of Fig. 5, consists of dark lines or bands on top of a continuous spectrum. Absorption spectra are produced when light from a hot object travels through a cooler, low-density gas. When a photon with exactly the right wavelength encounters an atom of the cool gas, it is absorbed and its energy used to kick an electron into a higher orbit; if enough atoms of gas are present, all the photons of that wavelengths are absorbed, while photons with other wavelengths get through. The atmospheres of stars produce absorption spectra. An element produces bright and dark lines with the same wavelengths. For example, hydrogen has three prominent lines with wavelengths of 434 nm, 486 nm, and 656 nm; these appear dark if the hydrogen is absorbing light, and bright if it is emitting light, but the same three wavelengths are seen in either case.

5 In some situations, we find spectra which mix different kinds of features: for example, a continuous spectrum with bright emission lines superimposed. Some stars, as they age, produce continuous spectra with dark absorption lines and bright emission lines; this is usually a sign that the star is ejecting gas in a stellar wind. EXPERIMENTS WITH SPECTRA In the lab, we will show you how to use a simple spectroscope, and how you can use it to measure wavelengths accurately. You will then have a chance to view different types of spectra to learn how to use the spectroscope to analyze the chemical nature of the source. We will set up several different discharge tubes, in which various elements are excited electrically. You will be asked to identify these elements by looking at the light they produce using your spectroscope. The elements in question will be among those featured in Fig. 2. We will also set up a light source which produces a bright spectral line, and ask you to measure the wavelength of this line. Once you've done this, you can identify the element involved by looking at the table printed on your spectrometer. Finally, look a the spectrum of the fluorescent room lights. How would you describe the spectrum you see? Can you identify the kind of gas used in the tubes? WEB RESOURCES Blank charts for spectra Use this chart to sketch spectra of different light sources. If you see lines or other features, place them at the appropriate wavelength using the scale, and list the wavelengths you measure. REVIEW QUESTIONS What is the energy level E 6 for an electron in orbit n = 6 of hydrogen, and how much energy is given off if this electron jumps to orbit n = 2? What kind of light does a hydrogen atom give off when an electron jumps from an orbit with n > 1 down to orbit n = 1? Is this light visible, or invisible? WORKSHEET: SPECTRA IN THE LAB On your worksheet, use colored pencils to sketch the spectrum you see from each of the light sources provided. Use thicker or darker pencil lines to represent brighter spectral lines. Label each spectrum with the type of spectrum you see (continuous, emission, absorption, or some mixture of these); if the spectrum shows emission lines, identify the gas and write its name beside your sketch on your worksheet. As described above, use your spectrograph to look at the fluorescent lights in the lab room. Comparing the emission lines that you see with Fig. 3 in this handout, what is the main gas in fluorescent lights? Go to the entrance to PSB from the makai parking lot and look at the entrance light just outside the doors. Sketch this spectrum and note the wavelength of the most prominent feature. Is there any connection with any of the other light sources you have looked at?

6 Alan Stockton Last modified: February 23,