PRODUCT NAME: LEISURE TIME ph BALANCE 1. PRODUCT AND COMPANY IDENTIFICATION 2. HAZARDS IDENTIFICATION MATERIAL SAFETY DATA SHEET

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1 FOR ANY EMERGENCY, 24 HOURS / 7 DAYS, CALL: FOR ALL TRANSPORTATION ACCIDENTS, CALL CHEMTREC : FOR ALL MSDS QUESTIONS & REQUESTS, CALL: (OUTSIDE USA: ) (OUTSIDE USA: ) MSDS (OUTSIDE USA: ) PRODUCT NAME: 1. PRODUCT AND COMPANY IDENTIFICATION Supplier Leisure Time 1400 Bluegrass Lakes Parkway, Alpharetta, GA, United States Telephone: Telefax: Web: REVISION DATE: 06/21/2011 SUPERCEDES: 01/20/2011 MSDS Number: SYNONYMS: None CHEMICAL FAMILY: None DESCRIPTION / USE FORMULA: Manufacturer Advantis Technologies 1400 Bluegrass Lakes Parkway Alpharetta, GA United States of America 2. HAZARDS IDENTIFICATION OSHA Hazard Classification: Mild eye irritant, Mild skin irritant Routes of Entry: Chemical Interactions: Medical Conditions Aggravated: Skin, eyes, ingestion No known interactions No data available REVISION DATE : 06/21/2011 Page 1 of 9

2 Human Threshold Response Data Odor Threshold Not established for product. Irritation Threshold Not established for product. Hazardous Materials Identification System / National Fire Protection Association Classifications Hazard Ratings : Health Flammability Physical / Instability PPI / Special hazard. HMIS NFPA Immediate (Acute) Health Effects Inhalation Toxicity: Skin Toxicity: Eye Toxicity: Ingestion Toxicity: Acute Target Organ Toxicity: Not expected to be an inhalation hazard at ambient conditions. Not expected to be toxic by inhalation. Not expected to be irritating. Skin contact may cause minor irritation consisting of transient redness and/or swelling. This irritant effect would not be expected to result in permanent damage. Contact would be expected to cause minor irritation, consisting of transient redness and swelling. No corneal involvement or visual impairment is expected. Ingestion may cause mild irritation of the gastrointestinal tract and may also cause gastrointestinal discomfort with any or all of the following symptoms: nausea, vomiting or diarrhea. May cause mild skin and eye irritation. Ingestion may cause mild gastrointestinal discomfort. Prolonged (Chronic) Health Effects Carcinogenicity: Reproductive and Developmental Toxicity: Inhalation: Skin Contact: Ingestion: Sensitization: Chronic Target Organ Toxicity: Supplemental Health Hazard Information : This product is not known or reported to be carcinogenic by any reference source including IARC, OSHA, NTP or EPA. Not known or reported to cause reproductive or developmental toxicity. There are no known or reported effects from chronic exposure. There are no known or reported effects from chronic exposure except for effects (if any) similar to those experienced from acute exposure. There are no known or reported effects from chronic ingestion except for effects similar to those experienced from single exposure. This material is not known or reported to be a skin or respiratory sensitizer. There are no known or reported target organ effects from chronic exposure. No additional health information available. REVISION DATE : 06/21/2011 Page 2 of 9

3 3. COMPOSITION / INFORMATION ON INGREDIENTS CAS OR CHEMICAL NAME CAS # % RANGE PHOSPHORIC ACID, DIPOTASSIUM SALT Sodium Phosphate FIRST AID MEASURES Inhalation: Skin Contact: Eye Contact: Ingestion: IF INHALED: Remove individual to fresh air. Seek medical attention if breathing becomes difficult or if respiratory irritation develops. IF ON SKIN: Flush skin with water for 15 minutes. Take off all contaminated clothing. Seek medical attention if irritation develops. IF IN EYES: Flush eyes with plenty of water for at least 15 minutes. Seek medical attention if irritation develops. IF SWALLOWED: Immediately drink water to dilute. Seek medical attention if symptoms develop. Never give anything by mouth to an unconscious person. 5. FIRE FIGHTING MEASURES Flammability Summary (OSHA): Flammable Properties Fire / Explosion Hazards: Extinguishing Media: Fire Fighting Instructions: Hazardous Combustion Products: Product is not known to be flammable, combustible, pyrophoric or explosive. Material will not ignite or burn. Not Applicable. - Choose extinguishing media suitable for surrounding materials. In case of fire, use normal fire-fighting equipment and the personal protective equipment recommended in Section 8 to include a NIOSH approved self-contained breathing apparatus. Carbon monoxide, Carbon dioxide REVISION DATE : 06/21/2011 Page 3 of 9

4 6. ACCIDENTAL RELEASE MEASURES Personal Protection for Emergency Situations: Spill Mitigation Procedures Air Release: Water Release: Land Release: Additional Spill Information : Use the personal protective equipment recommended in Section 8 and a NIOSH approved self-contained breathing apparatus. not applicable This material is soluble in water.if the product contaminates rivers and lakes or drains inform respective authorities. Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13).The product should not be allowed to enter drains, water courses or the soil. Stop source of spill as soon as possible and notify appropriate personnel. Utilize emergency response personal protection equipment prior to the start of any response. Evacuate all nonessential personnel. Dispose of spill residues per guidelines under Section 13, Disposal Consideration. 7. HANDLING AND STORAGE Handling: Storage: Do not take internally. Avoid contact with skin, eyes and clothing. Upon contact with skin or eyes, wash off with water. Avoid breathing mist or vapor. Store in a cool, dry place. Isolate from incompatible materials. Keep containers tightly closed when not in use. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Ventilation: No exposure limits exist for the constituents of this product. Additional ventilation beyond that of general exhaust is not normally required. Protective Equipment for Routine Use of Product Skin Protection : Eye Protection: Protective Clothing Type: Wear impervious gloves to avoid skin contact. Use safety glasses with side shields. Impervious Exposure Limit Data CHEMICAL NAME CAS # Name of Limit Exposure REVISION DATE : 06/21/2011 Page 4 of 9

5 No Data Found 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: liquid Form No data. Color: No data. Odor: No data. Molecular Weight: Specific Gravity : C ph : Boiling Point: 100 C 212 F Freezing Point: Melting Point: Density: Bulk Density: Vapor Pressure: Vapor Density: Viscosity: Solubility in Water: Partition coefficient n- octanol/water: Evaporation Rate: Oxidizing: Volatiles, % by vol.: VOC Content HAP Content not applicable not applicable 10. STABILITY AND REACTIVITY not applicable not applicable soluble Stability and Reactivity Summary: Conditions to Avoid: Chemical Incompatibility: Hazardous Decomposition Products: Decomposition Temperature: Stable under normal conditions. High temperatures Strong oxidizing agents Carbon monoxide, Carbon dioxide, Oxides of phosphorus No data 11. TOXICOLOGICAL INFORMATION REVISION DATE : 06/21/2011 Page 5 of 9

6 Product Animal Toxicity Oral LD50 value: LD50 Believed to be > 5,000 mg/kg rat Dermal LD50 value: LD50 Believed to be > 2,000 mg/kg rabbit Inhalation LC50 No data. value: Skin Irritation: May cause mild skin irritation. Eye Irritation: May cause mild eye irritation. Skin Sensitization: This material is not known or reported to be a skin or respiratory sensitizer. Subchronic / Chronic Toxicity: Reproductive and Developmental Toxicity: Mutagenicity: Carcinogenicity: Not known or reported to cause subchronic or chronic toxicity. Not known or reported to cause reproductive or developmental toxicity. Not known or reported to be mutagenic. This product is not known or reported to be carcinogenic by any reference source including IARC, OSHA, NTP or EPA. 12. ECOLOGICAL INFORMATION Overview: REVISION DATE : 06/21/2011 Page 6 of 9

7 13. DISPOSAL CONSIDERATIONS CARE MUST BE TAKEN TO PREVENT ENVIRONMENTAL CONTAMINATION FROM THE USE OF THE MATERIAL. THE USER OF THE MATERIAL HAS THE RESPONSIBILITY TO DISPOSE OF UNUSED MATERIAL, RESIDUES AND CONTAINERS IN COMPLIANCE WITH ALL RELEVANT LOCAL, STATE AND FEDERAL LAWS AND REGULATIONS REGARDING TREATMENT, STORAGE AND DISPOSAL FOR HAZARDOUS AND NONHAZARDOUS WASTES. Waste Disposal Summary : Disposal Methods : If this product becomes a waste, it will be a nonhazardous waste. As a nonhazardous waste, it should be disposed of in accordance with local, state and federal regulations. 14. TRANSPORT INFORMATION Land (US DOT): Water (IMDG): Not Regulated NOT REGULATED AS A DOT HAZARDOUS MATERIAL NOT REGULATED AS A HAZARDOUS MATERIAL, Air (IATA): NOT REGULATED AS A HAZARDOUS MATERIAL, Emergency Response Guide Number: Not applicable 15. REGULATORY INFORMATION UNITED STATES: Toxic Substances Control Act (TSCA): EPA Pesticide Registration Number: FIFRA Listing of Pesticide Chemicals (40 CFR 180): The components of this product are listed on the TSCA Inventory of Existing Chemical Substances. Not registered in the US under FIFRA. Superfund Amendments and Reauthorization Act (SARA) Title III: Hazard Categories Sections 311 / 312 (40 CFR 370.2): Health Physical Immediate (Acute) Health Hazard None Emergency Planning & Community Right to Know (40 CFR 355, App. A): Extremely Hazardous Substance Section Threshold Planning Quantity: ZUS_SAR302 TPQ (threshold planning quantity) REVISION DATE : 06/21/2011 Page 7 of 9

8 Reportable Quantity (49 CFR , Appendix): ZUS_CERCLA Reportable quantity ZUS_SAR302 Reportable quantity Supplier Notification Requirements (40 CFR ), 313 Reportable Components ZUS_SAR313 De minimis concentration Clean Air Act Toxic ARP Section 112r: CAA 112R Clean Air Act Socmi: HON SOC Clean Air Act VOC Section 111: CAA 111 Clean Air Act Haz. Air Pollutants Section 112: ZUS_CAAHAP ZUS_CAAHRP CAA AP State Right-to-Know Regulations Status of Ingredients Pennsylvania: CAS # ZUSPA_RTK COMPONENT NAME New Jersey: CAS # ZUSNJ_RTK COMPONENT NAME Massachusetts: CAS # ZUSMA_RTK California Proposition 65: CAS # ZUSCA_P65 COMPONENT NAME COMPONENT NAME REVISION DATE : 06/21/2011 Page 8 of 9

9 WHMIS Hazard Classification: 16. OTHER INFORMATION MSDS REVISION STATUS : SECTIONS REVISED: 2 Major References : Available upon request. THIS MATERIAL SAFETY (MSDS) HAS BEEN PREPARED IN COMPLIANCE WITH THE FEDERAL OSHA HAZARD COMMUNICATION STANDARD, 29 CFR THE INFORMATION IN THIS MSDS SHOULD BE PROVIDED TO ALL WHO WILL USE, HANDLE, STORE, TRANSPORT, OR OTHERWISE BE EXPOSED TO THIS PRODUCT. THIS INFORMATION HAS BEEN PREPARED FOR THE GUIDANCE OF PLANT ENGINEERING, OPERATIONS AND MANAGEMENT AND FOR PERSONS WORKING WITH OR HANDLING THIS PRODUCT. ARCH CHEMICALS BELIEVES THIS INFORMATION TO BE RELIABLE AND UP TO DATE AS OF THE DATE OF PUBLICATION BUT, MAKES NO WARRANTY THAT IT IS. ADDITIONALLY, IF THIS MSDS IS MORE THAN THREE YEARS OLD, YOU SHOULD CONTACT ARCH CHEMICALS MSDS CONTROL AT THE PHONE NUMBER ON THE FRONT PAGE TO MAKE CERTAIN THAT THIS DOCUMENT IS CURRENT.. REVISION DATE : 06/21/2011 Page 9 of 9

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