Synthesis of Mesoporous Silica Materials Using the Reactive Urea-formaldehyde Resin Polymerized in situ as Template
|
|
- Kelley Knight
- 7 years ago
- Views:
Transcription
1 Vol. 64, , ACTA CHIMICA SINICA No. 8, * ( ) ( ). BET,...,., / [n( ) n( ) 2]. ; ; ; ; Synthesis of Mesoporous Silica Materials Using the Reactive Urea-formaldehyde Resin Polymerized in situ as Template GUO, Bin LIU, Hui HAO, Zhi-Xian* GAN, Li-Hua XU, Zi-Jie CHEN, Long-Wu (Department of Chemistry, Tongji University, Shanghai ) Abstract A simple one-step procedure was described for the synthesis of mesoporous monolith and composite sphere, in which hydrolyzation of tetraethyl orthosilicate and polymerization of urea with formaldehyde occurred at the same time. The analysis of the liquid nitrogen adsorption demonstrated that the pore sizes of the monoliths and the composite spheres were both uniform. Morphologies of the composite spheres characterized by SEM were smooth or of network, which depended on the relative concentrations of the reactants. As the molar ratio of formaldehyde to urea exceeded the limit of 2.0, the synthesis by varying initial concentration of the reactants yielded the monoliths with controllable pore sizes. From the analysis of the FTIR and DTA, the urea-formaldehyde resin with branched chains in its molecular structure was considered as an inducing agent in the pore formation of the monolith. Keywords mesoporous silica; template; urea-formaldehyde resin; composite powder; monolith [1 5] Mobile MCM- 41 [6],,. ( [7] ),,, [8 10]., [1 6,8 11], * haozhixian@mail.tongji.edu.cn Received June 24, 2005; revised November 8, 2005; accepted December 21, (No ).
2 No , D- D- -L- [12] ; [13] ; ( [14] [15] [16] ). -ZrO 2 -TiO 2, [17]., [18] 4 µm. Arafa [19],..., : (, 98.5%, ); (, 99.7%, ); (, 99.0%, ); (, 37.0% 40.0%,, 38.0% ); (, 36.0% 38.0%,, 37.0% ), ml 50 ml 15 ml (TEOS) 20 ml 50 ml, n(teos) n(hcl) n(h 2 O) n(etoh) h,, 20 min, 20 h., 55, ph min., 70 2 d., 90 2 d,., d. 600, 2 h. 1.3 Thermo Nicolet NEXUS ; CDR-1 ; Micromeritics Tristar 3000 ; Philips XL-30 (20 kv). 2 (U) (TEOS) , (F), 1,. 1 Table 1 Molar ratios of reactants and the weight of composite sphere n( ) n( ) n(teos) /g F 0.0 U 1.0 S F 0.5 U 1.0 S F 1.0 U 1.0 S F 1.5 U 1.0 S F 2.0 U 1.0 S F 3.0 U 1.0 S F 4.0 U 1.0 S F 9.0 U 3.0 S , ,.
3 758 Vol. 64, BET 600 SiO 2 6 nm, 680 m 2 /g, 1.0 cm 3 /g, 50 m 2 /g., 90,. 2 BET ,. 2 BET Table 2 BET characterization data of the monolith silicas synthesized with two different molar ratios of formaldehyde to urea a / nm / (m 2 g 1 ) / (m 2 g 1 ) / (cm 3 g 1 ) F 0.27 U 0.27 S F 0.53 U 0.53 S F 1.0 U 1.0 S F 1.6 U 1.6 S F 0.81 U 0.27 S F 1.6 U 0.53 S F 3.0 U 1.0 S F 4.8 U 1.6 S m 2 /g, cm 3 /g, F 1.0 U S 1.6. Wang [20],. 1 F 1.0 U 1.0 S 1.6 BJH Figure 1 BJH pore size distributions of F 1.0 U 1.0 S 1.6 (a) before calcination; (b) after calcination a 1, ,, 14 nm, 290 m 2 /g, 1.1 cm 3 /g ; ,, nm 5.51 nm, m 2 /g m 2 /g, cm 3 /g cm 3 /g F 1.0 U 1.0 S 1.6 F 4.8 U 1.6 S F 4.8 U 1.6 S 1.6 F 1.0 U 1.0 S 1.6, F 4.8 U 1.6 S 1.6 F 1.0 U 1.0 S 1.6. BET, F 1.0 U 1.0 S m 2 /g, cm 3 /g,. F 4.8 U 1.6 S F 4.8 U 1.0 S 1.6 BJH Figure 2 BJH pore size distributions of F 4.8 U 1.0 S 1.6 (a) before calcination; (b) after calcination 2.2 SEM 3,., F 1.6 U 1.6 S 1.6,., (6 nm), BET.,. F 4.8 U 1.6 S 1.6 ( 1 µm),.
4 No / SEM Figure 3 SEM images of the samples prepared by varying initial molar ratios of formaldehyde to urea (a) F 1.6 U 1.6 S 1.6 powders before calcination; (b) F 4.8 U 1.6 S 1.6 powders before calcination; (c) F 4.8 U 1.6 S 1.6 monolith before calcination; (d) F 1.6 U 1.6 S 1.6 powders after calcination; (e) F 4.8 U 1.6 S 1.6 powders after calcination; (f) F 4.8 U 1.6 S 1.6 monolith after calcination F 1.6 U 1.6 S 1.6 F 4.8 U 1.6 S 1.6,. BET,. F 4.8 U 1.6 S 1.6 3c,, FT-IR cm 1 N H O H, (Si OH) (CH 2 OH) cm 1 Si O Si [19], F 1.0 U 1.0 S 1.6, ( 1 ), 90%,, cm 1 C N, [21] cm 1 (CH 2 OH) [22,23],,,.,, 1 n( ) n( ) Figure 4 IR spectra of the composite monoliths prepared by varying the molar ratio of formaldehyde to urea 2.4 DTA 5, 100. F 0.0 U 1.0 S 1.6, F.50 U 1.0 S 1.6 F 1.0 U 1.0 S , [18,19]. F 2.0 U 1.0 S 1.6, F 3.0 U 1.0 S 1.6, F 4.0 U 1.0 S 1.6,, 300,.,
5 760 Vol. 64, 2006,. 5 Figure 5 DTA of the composite monoliths prepared by varying the molar ratio of formaldehyde to urea 3,., BET,,.,,,,..,. 3 Stein, A.; Melde, B. J.; Schroden, R. C. Adv. Mater. 2000, 12, De Vos, D. E.; Dams, M.; Sels, B. F.; Jacobs, P. A. Chem. Rev. 2002, 102, Stein, A. Adv. Mater. 2003, 15, Kresge, C. T.; Leonowicz, M. E.; Roth, W. J.; Vartuli, J. C.; Beck, J. S. Nature 1992, 359, Yao, N.; Xiong, G.-X.; He, M.-Y.; Sheng, W.-S.; Yang, W.-S.; Bao, X.-H. Chem. Mater. 2002, 14, Schulz-Ekloff, G.; Rathousky, J.; Zukal, A. J. Inorg. Mater. 1999, 1, Che, S.; Kamiya, S.; Terasaki, O.; Tatsumi, T. J. Am. Chem. Soc. 2001, 123, Zhao, D.-Y.; Yang, P.-D.; Melosh, N. Adv. Mater. 1998, 10, El-Safty, S. A.; Hanaoka, T. Chem. Mater. 2004, 16, Wei, Y.; Jin, D.-L.; Ding, T.-Z.; Shih, W.-H.; Liu, X.-H.; Stephen, Z. D. C.; Fu, Q. Adv. Mater. 1998, 10, Pang, J.-B.; Qiu, K.-Y.; Wei, Y. Microporous Mesoporous Mater. 2000, 40, Ogasawara, W.; Shenton, W.; Davis, S. A.; Mann, S. Chem. Mater. 2000, 12, Pedroni, V.; Schulz, P. C.; Gschaider de Ferreira, M. E.; Morini, M. A. Colloid Polym. Sci. 2000, 278, Coradin, T.; Livage, J. J. Sol-Gel Sci. Technol. 2003, 26, Yang, J.-J.; Zuo, Y.-M. Chem. J. Chin. Univ. 2000, 21, 1852 (in Chinese). (,,, 2000, 21, 1852.) 18 Guo, R.; Yu, J.-G.; Zhao, L.; Zhao, X.-J. Acta Chim. Sinica 2004, 62, 493 (in Chinese). (,,,,, 2004, 62, 493.) 19 Arafa, I. M.; Fares, M. M.; Barham, A. S. Eur. Polym. J. 2004, 40, Wang, X.-Z.; Li, W.-H.; Zhu, G.-S.; Qiu, S.-L.; Zhao, D.-Y.; Zhong, B. Microporous Mesoporous Mater. 2004, 71, Ye, S.; Ran, Q.-Y.; Wu, W.-Z.; Mao, X.-W. Thermochim. Acta 1995, 253, Haase, F.; Sauer, J. J. Am. Chem. Soc. 1995, 117, Minopoulou, E.; Dessipri, E.; Chryssikos, G. D.; Gionis, V.; Paipetis, A.; Panayiotou, C. Int. J. Adhes. Adhes. 2003, 23, 473. References 1 Sayari, A. Chem. Mater. 1996, 8, Corma, A. Chem. Rev. 1997, 97, (A DING, W. F.; DONG, H. Z.)
Pore development of thermosetting phenol resin derived mesoporous carbon through a commercially nanosized template
Materials Science and Engineering A 473 (2008) 153 157 Pore development of thermosetting phenol resin derived mesoporous carbon through a commercially nanosized template Zhihong Tang a,b, Yan Song a,,
More informationSynthesis, characterization and application of a novel mercapto- and new kind of
SUPPLEMENTARY MATERIAL Synthesis, characterization and application of a novel mercapto- and new kind of polyaminophenol-bifunctionalized MCM-41 for dispersive micro solid phase extraction of Ni(II) prior
More informationOil absorption in mesoporous silica particles
Processing and Application of Ceramics 4 [4] (2010) 265 269 Oil absorption in mesoporous silica particles Radislav Filipović 1,2,*, Dragica Lazić 1, Mitar Perušić 1, Ivan Stijepović 3 1 Faculty of Technology,
More informationNano-pore structure characterization of shales using gas adsorption and mercury intrusion techniques
Available online www.jocpr.com Journal of Chemical and Pharmaceutical Research, 2014, 6(4):850-857 Research Article ISSN : 0975-7384 CODEN(USA) : JCPRC5 Nano-pore structure characterization of shales using
More informationSynthesis of mesoporous Zr-P-Al materials with high BET specific surface area without calcination
Advanced Materials Research Vols. 287-290 (2011) pp 2094-2101 Online available since 2011/Jul/04 at www.scientific.net (2011) Trans Tech Publications, Switzerland doi:10.4028/www.scientific.net/amr.287-290.2094
More informationHexagonal to Mesocellular Foam Phase Transition in Polymer-Templated Mesoporous Silicas
Langmuir 2000, 16, 8291-8295 8291 Hexagonal to Mesocellular Foam Phase Transition in Polymer-Templated Mesoporous Silicas John S. Lettow, Yong Jin Han, Patrick Schmidt-Winkel, Peidong Yang, Dongyuan Zhao,
More informationSupporting Information
Supporting Information Wiley-VCH 2005 69451 Weinheim, Germany Magnetic Nanoparticle-Capped Mesoporous Silica Nanorod-Based Stimuli-Responsive Controlled Release Delivery System** Supratim Giri, Brian G.
More informationSUPPLEMENTARY INFORMATION. An ionic liquid template approach to graphene-carbon. xerogel composites for supercapacitors with enhanced.
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2014 SUPPLEMENTARY INFORMATION An ionic liquid template approach to graphene-carbon
More informationE. Marenna a, E. Santacesaria b, P. Pernice a, M. Di Serio b, A. Aronne a
UNIVERSITA DEGLI STUDI DI NAPOLI FEDERICO II SYNTHESIS VIA SOL-GEL OF Nb 2 O 5 SiO 2 CATALYSTS FOR EPOXIDATION REACTIONS E. Marenna a, E. Santacesaria b, P. Pernice a, M. Di Serio b, A. Aronne a a Dipartimento
More informationAppendix A. Fig. 1 Nitrogen adsorption for Activated Carbon from Norit
Appendix A Summary Report Surface Area BET Surface Area: 1555.9551 m²/g Langmuir Surface Area: 1992.1415 m²/g Pore Volume Single point adsorption total pore volume of pores 0.619747 cm³/g t-plot micropore
More informationEffect of surface area, pore volume and particle size of P25 titania on the phase transformation of anatase to rutile
Indian Journal of Chemistry Vol. 48A, October 2009, pp. 1378-1382 Notes Effect of surface area, pore volume and particle size of P25 titania on the phase transformation of anatase to rutile K Joseph Antony
More informationAnalysis of nitrogen and carbon tetrachloride adsorption isotherms and pore size distribution for siliceous MCM-41 synthesized from rice husk silica
ORIGINAL ARTICLE Analysis of nitrogen and carbon tetrachloride adsorption isotherms and pore size distribution for siliceous MCM-41 synthesized from rice husk silica Siriluk Chiarakorn 1, Nurak Grisdanurak
More informationSupporting Information. Rational design of Au nanorods assemblies for highly sensitive and selective SERS detection of prostate specific antigen
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2015 Supporting Information Rational design of Au nanorods assemblies for highly sensitive and selective
More informationIn Situ DNA-Templated Synthesis of Silver Nanoclusters for Ultrasensitive and Label-Free Electrochemical Detection of MicroRNA
Supporting Information for In Situ DNA-Templated Synthesis of Silver Nanoclusters for Ultrasensitive and Label-Free Electrochemical Detection of MicroRNA Cuiyun Yang, Kai Shi, Baoting Dou, Yun Xiang,*
More informationSynthesis of titanium dioxide nanostructures and their effects on current-voltage (I-V) performance in dye sensitized solar cells
International Journal of ChemTech Research CODEN (USA): IJCRGG ISSN : 0974-4290 Vol.6, No.13, pp 5220-5225, November 2014 MESCon 2014 [4th -5 th September 2014] National Conference on Material for Energy
More informationTextural Characteristics of Activated Carbons Prepared from Oil Palm Shells Activated with ZnCl 2 and Pyrolysis Under Nitrogen and Carbon Dioxide
Journal of Physical Science, Vol. 19(2), 93 104, 2008 93 Textural Characteristics of Activated Carbons Prepared from Oil Palm Shells Activated with ZnCl 2 and Pyrolysis Under Nitrogen and Carbon Dioxide
More informationPreparation and characterization of mesoporous Titanium-silica and zirconia-silica mixed oxides
Preparation and characterization of mesoporous Titanium-silica and zirconia-silica mixed oxides R. G. Rodríguez Avendaño, J.A. de los Reyes Universidad A. Metropolitana, Departamento de Ingeniería de Procesos
More informationMISCIBILITY AND INTERACTIONS IN CHITOSAN AND POLYACRYLAMIDE MIXTURES
MISCIBILITY AND INTERACTIONS IN CHITOSAN AND POLYACRYLAMIDE MIXTURES Katarzyna Lewandowska Faculty of Chemistry Nicolaus Copernicus University, ul. Gagarina 7, 87-100 Toruń, Poland e-mail: reol@chem.umk.pl
More informationSynthesis and Characterization of MnO 2 Nanoparticles using Co-precipitation Technique
International Journal of Chemistry and Chemical Engineering. ISSN 2248-9924 Volume 3, Number 3 (2013), pp. 155-160 Research India Publications http://www.ripublication.com Synthesis and Characterization
More informationElectronic Supplementary Information for: Macroscopic samples of polystyrene with ordered three-dimensional nanochannels
Electronic Supplementary Information for: Macroscopic samples of polystyrene with ordered three-dimensional nanochannels Huiming Mao and Marc A. Hillmyer* Department of Chemistry University of Minnesota
More informationControlling Gold Nanoparticles with Atomic Precision: Synthesis and Structure Determination
Controlling Gold Nanoparticles with Atomic Precision: Synthesis and Structure Determination Huifeng Qian Department of Chemistry, Carnegie Mellon University, USA Advisor: Prof. Rongchao Jin Background
More informationInfluence of temperature and ph on the morphology and the color of the CoAl 2 O 4 prepared by sol gel method
Influence of temperature and ph on the morphology and the color of the CoAl 2 O 4 prepared by sol gel method Y. El Jabbar 1, R. El Ouatib 1*, L. Er-Rakho 1 and B. Durand 2 1 Laboratoire de Physico-Chimie
More informationSupporting information
Supporting information Ultrafast room-temperature NH 3 sensing with positively-gated reduced graphene oxide field-effect transistors Ganhua Lu 1, Kehan Yu 1, Leonidas E. Ocola 2, and Junhong Chen 1 * 1
More informationLuisa Palumbo Dipartimento di Chimica IFM - NIS Centre of Excellence Università di Torino
Conversion of Methanol to Hydrocarbons: spectroscopic characterization of carbonaceous species formed over H-ZSMH ZSM-5 Luisa Palumbo Dipartimento di Chimica IFM - NIS Centre of Excellence Università di
More informationFacile Synthesis of ZnO Nanoparticles and Their Photocatalytic Activity
2004 Bull. Korean Chem. Soc. 2014, Vol. 35, No. 7 Soo-Keun Lee et al. http://dx.doi.org/10.5012/bkcs.2014.35.7.2004 Facile Synthesis of ZnO Nanoparticles and Their Photocatalytic Activity Soo-Keun Lee,
More informationDemonstration of sub-4 nm nanoimprint lithography using a template fabricated by helium ion beam lithography
Demonstration of sub-4 nm nanoimprint lithography using a template fabricated by helium ion beam lithography Wen-Di Li*, Wei Wu** and R. Stanley Williams Hewlett-Packard Labs *Current address: University
More informationAsian Journal on Energy and Environment
As. J. Energy Env. 2005, 6(04), 193-201 Asian Journal on Energy and Environment ISSN 1513-4121 Available online at www.asian-energy-journal.info Synthesis,Characterization and Application of Single and
More informationSPECTROSCOPIC STUDIES ON DEGRADATION OF POLY N,N'-METHYLENE BISACRYLAMIDE
Int. J. Chem. Sci.: 8(4), 2010, 2795-2800 SPECTROSCOPIC STUDIES ON DEGRADATION OF POLY N,N'-METHYLENE BISACRYLAMIDE V. SRIDHAR *, S. KALAHASTI a, B. SANJEEVA RAO b, S. INDIRA, K. GOPALA KISHAN RAO c and
More informationTishreen University Journal for Research and Scientific Studies - Basic Sciences Series Vol. ( ) No. ( )
Tishreen University Journal for Research and Scientific Studies Basic Sciences Series Vol. No. BET XRF (XRD) (XRF) K (H O ) X.R.D, BET, X.R.F ١٠٥ Tishreen University Journal for Research and Scientific
More informationSYNTHESIS AND STRUCTURAL PROPERTIES OF Al 2 O 3 -ZrO 2 NANO COMPOSITE PREPARED VIA SOLUTION COMBUSTION SYNTHESIS
IMPACT: International Journal of Research in Engineering & Technology (IMPACT: IJRET) ISSN(E): 2321-8843; ISSN(P): 2347-4599 Vol. 2, Issue 3, Mar 2014, 145-152 Impact Journals SYNTHESIS AND STRUCTURAL
More informationJournal of Colloid and Interface Science
Journal of Colloid and Interface Science 323 (2008) 326 331 Contents lists available at ScienceDirect Journal of Colloid and Interface Science www.elsevier.com/locate/jcis Layer-by-layer assembly of TiO
More informationRus Mahayuni Abdul Rahman, Mohamad Deraman, Mohd Hafizuddin Jumali, Ramli Omar, Masliana Muslimin, Mazliza Mohtar and Astimar Abdul Aziz
POROUS CARBON PELLETS FROM KOH TREATED SELF-ADHESIVE CARBON GRAINS FROM OIL PALM EMPTY FRUIT BUNCH: EFFECT OF KOH WEIGHT PERCENTAGES AND PELLETIZING COMPRESSION FORCE Rus Mahayuni Abdul Rahman, Mohamad
More informationIonic conductivity study on electron beam irradiated polyacrylonitrile polyethylene oxide gel
Ionic conductivity study on electron beam irradiated polyacrylonitrile polyethylene oxide gel Ma Yi-Zhun ( ) a)b), Pang Li-Long( ) a)b), Zhu Ya-Bin( ) a)b), Wang Zhi-Guang( ) a), and Shen Tie-Long( ) a)b)
More informationNian Gong, PhD. Department of Anesthesiology & Perioperative Care
Nian Gong, PhD Department of Anesthesiology & Perioperative Care University of California, Irvine 837 Health Sciences Road, Gillespie Building 3226A, Irvine, CA 92697 Telephone/Fax: (949) 824-7222; Email:
More informationTreatment of oily wastewater produced from refinery processes using flocculation and ceramic membrane filtration
Separation and Purification Technology 32 (2003) 93/98 www.elsevier.com/locate/seppur Treatment of oily wastewater produced from refinery processes using flocculation and ceramic membrane filtration Jing
More informationResearch on Semantic Web Service Composition Based on Binary Tree
, pp.133-142 http://dx.doi.org/10.14257/ijgdc.2015.8.2.13 Research on Semantic Web Service Composition Based on Binary Tree Shengli Mao, Hui Zang and Bo Ni Computer School, Hubei Polytechnic University,
More informationProduction and Characterisation of Activated Carbons made from Coffee Industry Residues
Production and Characterisation of Activated Carbons made from Coffee Industry Residues João Valente Nabais *1, Peter Carrott 1, M.M.L. Ribeiro Carrott 1, Vânia Luz 1, Angel Ortiz 2 1 Universidade de Évora,
More informationSupporting Information
Supporting Information Fabrication of Fluoropolymer Microtubes via RAFT Copolymerization of N,N -Methylene Bisacrylamide Gel Fibers and Fluoromonomer Qi Li, [a, b] Yi Wang, [a] and Liming Tang* [a] asia_201500035_sm_miscellaneous_information.pdf
More informationAdsorption Characteristics of MOF-199 And MOF-5 Prepared Using Renewable Template
The 3rd National Graduate Conference (NatGrad5), Universiti Tenaga Nasional, Putrajaya Campus, 8-9 April 5. Adsorption Characteristics of MOF-99 And MOF-5 Prepared Using Renewable Template N.S Jamaludin
More informationBET Surface Area Analysis of Nanoparticles
OpenStax-CNX module: m38278 1 BET Surface Area Analysis of Nanoparticles Nina Hwang Andrew R. Barron This work is produced by OpenStax-CNX and licensed under the Creative Commons Attribution License 3.0
More informationHigh and Low Bandgap Polyfluorene Copolymers for Organic Solar Cells Xiwen Chen
High and Low Bandgap Polyfluorene Copolymers for Organic Solar Cells Xiwen Chen Senior Research Scientist Commonwealth Scientific and Industrial Research Organsation (CSIRO) Outlines Electron Transport
More informationPULLING OUT OPINION TARGETS AND OPINION WORDS FROM REVIEWS BASED ON THE WORD ALIGNMENT MODEL AND USING TOPICAL WORD TRIGGER MODEL
Journal homepage: www.mjret.in ISSN:2348-6953 PULLING OUT OPINION TARGETS AND OPINION WORDS FROM REVIEWS BASED ON THE WORD ALIGNMENT MODEL AND USING TOPICAL WORD TRIGGER MODEL Utkarsha Vibhute, Prof. Soumitra
More informationThis chapter gives a brief outline of the experimental techniques used for the
CHAPTER II Experimental Techniques This chapter gives a brief outline of the experimental techniques used for the characterization of catalysts and the test of catalyst activity in this study. 2.1 Thermo-gravimetric
More informationControlling the Pore Size and Morphology of Mesoporous Silica
Linköping Studies in Science and Technology Licentiate Thesis No. 1451 Controlling the Pore Size and Morphology of Mesoporous Silica Emma M. Johansson LIU-TEK-LIC-2010:22 Nanostructured Materials Division
More informationFacile Synthesis and Luminescence Properties of Silica Submicron Rods. Jie CHEN, Ye SHENG, Ke-Yan ZHENG, Mei-Qi CHANG, Hui ZHANG, Hai-Feng ZOU *
International Conference on Material Science and Application (ICMSA 2015) Facile Synthesis and Luminescence Properties of Silica Submicron Rods Jie CHEN, Ye SHENG, Ke-Yan ZHENG, Mei-Qi CHANG, Hui ZHANG,
More informationSYNTHESIS OF AMORPHOUS SiO X NANOSTRUCTURES. 1. Introduction
SYNTHESIS OF AMORPHOUS SiO X NANOSTRUCTURES J. Y. LAO, J. G. WEN, D. Z. WANG, Z. F. REN Department of Physics, Boston College, 140 Commonwealth Avenue Chestnut Hill, Massachusetts 02467, United States
More informationTexture characteristic of membrane materials ASAP, BET
Texture characteristic of membrane materials ASAP, BET Theory Specific surface (surface area) is used for the characterization of many materials. There are various techniques how measure the specific surface
More informationStudy on Wet Etching of AAO Template
Study on Wet Etching of AAO Template Guofeng Hu, Haiming Zhang, Wenwen Di & Tingting Zhao School of Science, Tianjin Polytechnic University, Tianjin 300160, China E-mail: hugf2009@163.com Abstract The
More informationOpaline Photonic Crystals: How Does Self-Assembly Work?
Opaline Photonic Crystals: How Does Self-Assembly Work? David J. Norris Chemical Engineering & Materials Science, University of Minnesota 1μm silica spheres See: D. J. Norris, E. G. Arlinghaus, L. Meng,
More informationPhase Characterization of TiO 2 Powder by XRD and TEM
Kasetsart J. (Nat. Sci.) 42 : 357-361 (28) Phase Characterization of TiO 2 Powder by XRD and TEM Kheamrutai Thamaphat 1 *, Pichet Limsuwan 1 and Boonlaer Ngotawornchai 2 ABSTRACT In this study, the commercial
More informationZurich Open Repository and Archive
University of Zurich Zurich Open Repository and Archive Winterthurerstr. 190 CH-8057 Zurich http://www.zora.uzh.ch Year: 2011 Correlation of nitrogen sorption and confocal laser scanning microscopy for
More informationCharacterization of surface and porous properties of synthetic hybrid lamellar silica
Characterization of surface and porous properties of synthetic hybrid lamellar silica Gilles TOUSSAINT a*, Miguel Angel RODRIGUEZ b, Rudi CLOOTS c, Juan RUBIO d, Fausto RUBIO e, Bénédicte VERTRUYEN f,
More informationSynthesis and characterization of ordered mesoporous silica nanoparticles with tunable physical properties by varying molar composition of reagents
African Journal of Pharmacy and Pharmacology Vol. 5(21), pp. 242-241, 8 December, 211 Available online at http://www.academicjournals.org/ajpp DOI: 1.5897/AJPP11.592 ISSN 1996-816 211 Academic Journals
More informationSupporting Information. Phosphorus-, nitrogen- and carbon- containing polyelectrolyte complex:
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 S1 Supporting Information Phosphorus-, nitrogen- and carbon- containing polyelectrolyte complex:
More informationSurface Area and Porosity
Surface Area and Porosity 1 Background Techniques Surface area Outline Total - physical adsorption External Porosity meso micro 2 Length 1 Å 1 nm 1 µm 1 1 1 1 1 mm macro meso micro metal crystallite 1-1
More informationProgram 2014 Tsinghua-Sanya Workshop on Big Data: Opportunities, Challenges and Innovations Dec. 27 Dec. 30, 2014 Sanya, China
Program 2014 Tsinghua-Sanya Workshop on Big Data: Opportunities, Challenges and Innovations Dec. 27 Dec. 30, 2014 Sanya, China Dec 27, Saturday 09:00 am - 09:30 am Opening Ceremony 09:30 am - 10:20 am
More informationStructural, Photocatalytic Activity and Photovoltaic Properties of Mesoporous Anatase Titania Nanopowders Prepared by Hydrothermal Method
Structural, Photocatalytic ctivity and Photovoltaic Properties of Mesoporous natase Titania Nanopowders Prepared by Hydrothermal Method Sorapong Pavasupree 1,2, Jaturong Jitputti 1, Supachai Ngamsinlapasathian
More informationSupporting Information
Supporting Information Simple and Rapid Synthesis of Ultrathin Gold Nanowires, Their Self-Assembly and Application in Surface-Enhanced Raman Scattering Huajun Feng, a Yanmei Yang, a Yumeng You, b Gongping
More informationDEVELOPMENT OF ECO-FRIENDLY FLAME RETARDANT FABRIC USING PHOSPHOROUS BASED INTUMESCENCES CHEMISTRY
DEVELOPMENT OF ECO-FRIENDLY FLAME RETARDANT FABRIC USING PHOSPHOROUS BASED INTUMESCENCES CHEMISTRY Subhas Ghosh 1 and Vikas Joshi 2 1,2 Textile Science Laboratory, College of Technology, Eastern Michigan
More informationInternational Journal of Advanced Engineering Research and Studies E-ISSN2249 8974
Review Article DEVELOPMENT OF HIGH SURFACE AREA ACTIVATED CARBON FROM WASTE MATERIAL B. S. Patil, K. S. Kulkarni Address for Correspondence Chemical Engineering Department, BVDUCOE, Pune, Maharashtra.
More informationPreparation and Capacitive Properties of Nitrogen-Enriched Hierarchical Porous Carbon
Int. J. Electrochem. Sci., 7 (2012) 7587-7599 International Journal of ELECTROCHEMICAL SCIENCE www.electrochemsci.org Preparation and Capacitive Properties of Nitrogen-Enriched Hierarchical Porous Carbon
More informationA metal-free polymeric photocatalyst for hydrogen production from water under visible light
A metal-free polymeric photocatalyst for hydrogen production from water under visible light Xinchen Wang, Kazuhiko Maeda, Arne Thomas, Kazuhiro Takanabe, Gang Xin, Johan M. Carlsson, Kazunari Domen, Markus
More informationHow To Make A Molecular Encoder And Decoder
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Supporting information Molecular Encoder - Decoder Based on Assembly of Graphene with Dye-labeled
More informationInvestigation the Protective Performance of Organic Coatings with Different Breakage Degree Using EIS United to SOM Neural Network
Int. J. Electrochem. Sci., 8 (213) 1895-192 International Journal of ELECTROCHEMICAL SCIENCE www.electrochemsci.org Investigation the Protective Performance of Organic Coatings with Different Breakage
More informationDevelopment of porous materials for hydrogen storage
Development of porous materials for hydrogen storage Shinji Oshima, Osamu Kato, Takeshi Kataoka, Yoshihiro Kobori, Michiaki Adachi Hydrogen & New Energy Research Laboratory Nippon Oil Corporation 8, Chidoricho,
More informationImprovements of calcium oxide based sorbents for multiple CO2 capture cycles
Improvements of calcium oxide based sorbents for multiple CO2 capture cycles Laetitia Vieille, Alexandre Govin, Philippe Grosseau To cite this version: Laetitia Vieille, Alexandre Govin, Philippe Grosseau.
More informationProperties and Characterization of Modified HZSM-5 Zeolites
Journal of Natural Gas Chemistry 12(2003)56 62 Properties and Characterization of Modified HZSM-5 Zeolites Renqing Lü 1, Hejin Tangbo 1, Qiuying Wang 2, Shouhe Xiang 1 1. Institute of New Catalytic Materials,
More informationChiral Polymers and Their Advantages
Synthesis and Properties of Chiral Donor-embedded Polybinaphthalenes for onlinear Optical Applications Guy Koeckelberghs a, Sonja Sioncke b, Thierry Verbiest b, André Persoons b and Celest Samyn a * Laboratory
More informationANALYSIS OF SILVER S ADSORPTION ON CALCINED VERDE- LODO CLAY
ANALYSIS OF SILVER S ADSORPTION ON CALCINED VERDE- LODO CLAY M. L. CANTUARIA 1, A. F. ALMEIDA NETO 1, E. S. NASCIMENTO 1, O. A. A. DOS SANTOS 2 and M. G. A. VIEIRA 1 1 University of Campinas, Chemical
More informationFull terms and conditions of use: http://www.tandfonline.com/page/terms-and-conditions
This article was downloaded by: [Lanzhou Institute of Geology] On: 27 February 2013, At: 01:00 Publisher: Taylor & Francis Informa Ltd Registered in England and Wales Registered Number: 1072954 Registered
More informationAN ENHANCED BINARY ANTI-COLLISION ALGORITHM OF BACKTRACKING IN RFID SYSTEM
Progress In Electromagnetics Research B, Vol. 4, 263 271, 2008 AN ENHANCED BINARY ANTI-COLLISION ALGORITHM OF BACKTRACKING IN RFID SYSTEM X.-L. Shi, X.-W. Shi, Q.-L. Huang, and F. Wei National Key Laboratory
More informationSYNTHESIS AND STRUCTURAL STUDIES OF MCM-41 AND SBA-15 TYPE MESOPOROUS SILICATES
SYNTHESIS AND STRUCTURAL STUDIES OF MCM-41 AND SBA-15 TYPE MESOPOROUS SILICATES Ph.D. Theses Solymár Edit University of Szeged Department of Applied and Environmental Chemistry Szeged 2005 Scientific supervisors:
More informationThis is the Pre-Published Version.
This is the Pre-Published Version. Photocatalytic Conversion of NO using TiO 2 -NH 3 Catalysts in Ambient Air Environment F. B. Li 1,2, X. Z. Li 1*, C.H. Ao 1, M. F. Hou 2 and S.C. Lee 1 1 Department of
More informationFacile Synthesis of Mn-Doped ZnO Porous Nanosheets as Anode Materials for Lithium Ion Batteries with a Better Cycle Durability
Wang et al. Nanoscale Research Letters (2015) 10:280 DOI 10.1186/s11671-015-0983-3 NANO EXPRESS Facile Synthesis of Mn-Doped ZnO Porous Nanosheets as Anode Materials for Lithium Ion Batteries with a Better
More informationFourth SIGHAN Workshop on Chinese Language Processing
Fourth SIGHAN Workshop on Chinese Language Processing (IJCNLP 2005) Jeju Island, Korea 14-15 October 2005 ISBN: 978-1-62748-367-4 Printed from e-media with permission by: Curran Associates, Inc. 57 Morehouse
More informationCRIOCM2015 International Symposium on. Advancement of Construction Management and Real Estate
CRIOCM2015 International Symposium on Advancement of Construction Management and Real Estate (23 rd 25 th October 2015, Hangzhou, China) Call for paper (2 nd Announcement) China is on a unique path to
More informationComparative crystal structure determination of griseofulvin: Powder X-ray diffraction versus single-crystal X-ray diffraction
Article Analytical Chemistry October 2012 Vol.57 No.30: 3867 3871 doi: 10.1007/s11434-012-5245-5 SPECIAL TOPICS: Comparative crystal structure determination of griseofulvin: Powder X-ray diffraction versus
More informationCoating of TiO 2 nanoparticles on the plasma activated polypropylene fibers
Coating of TiO 2 nanoparticles on the plasma activated polypropylene fibers Renáta Szabová*, Ľudmila Černáková, Magdaléna Wolfová, Mirko Černák a Department of Plastics and Rubber, Institute of Polymer
More informationEffects of aging on the kinetics of nanocrystalline anatase crystallite growth
Materials Chemistry and Physics 95 (2006) 275 279 Effects of aging on the kinetics of nanocrystalline anatase crystallite growth Hsing-I Hsiang, Shih-Chung Lin Department of Resources Engineering, National
More informationPreparation of Activated Carbon with High Surface Area from Pistacia Aatlantica Shell
Preparation of Activated Carbon with High Surface Area from Pistacia Aatlantica Shell Azadeh Tadjarodi*, Heydar Ghawami Department of Chemistry, Iran University of Science and Technology, Tehran, Iran
More informationXRF and nitrogen adsorption studies of acid-activated palygorskite
Clay Minerals, (2010)45, 145 156 XRF and nitrogen adsorption studies of acid-activated palygorskite JUNPING ZHANG 1,2,QINWANG 1,HAOCHEN 3 AND AIQIN WANG 1,2, * 1 Center of Eco-material and Eco-Chemistry,
More informationCharacterization of surfaces by AFM topographical, mechanical and chemical properties
Characterization of surfaces by AFM topographical, mechanical and chemical properties Jouko Peltonen Department of physical chemistry Åbo Akademi University Atomic Force Microscopy (AFM) Contact mode AFM
More informationCeramic Processing Research
Journal of Ceramic Processing Research. Vol. 8, No. 3, pp. 177~183 (2007) J O U R N A L O F Ceramic Processing Research Preparation of echinoid-like aggregated hematite particles by forced hydrolysis with
More informationSBO3 acntb s. NANOFORCE Next generation nano-engineered Polymer-Steel/CNT Hybrids. Lightweight and multi-functional. aligned Carbon Nanotube bundles
NANOFORCE Next generation nano-engineered Polymer-Steel/CNT Hybrids SBO3 acntb s Lightweight and multi-functional aligned Carbon Nanotube bundles Jin Won (Maria) Seo User Committee Meeting Nanoforce, 7
More informationNovel Method for Solid Phase Peptide Synthesis Using Microwave Energy
Novel Method for Solid Phase Peptide Synthesis Using Microwave Energy Jonathan M. Collins, Michael J. Collins, Rebecca C. Steorts CEM Corporation, Matthews, NC 28106-0200, U.S.A. Presented at American
More informationHydrogen Adsorption on Nanoporous Biocarbon
Hydrogen Adsorption on Nanoporous Biocarbon Mikael Wood, Jacob Burress, Cintia Lapilli, Peter Pfeifer, Parag Shah, Galen Suppes University of Missouri-Columbia Phillip Parilla, Anne Dillon National Renewable
More informationFederal Institute for Materials Research and Testing
Federal Institute for Materials Research and Testing CERTIFIED REFERENCE MATERIAL FOR THE GAS ADSORPTION BAM-PM-101 Material: SiO 2 with specific surface area (BET) of 0.177 0.004 m² g -1 Mean of means
More informationBentonite Hydration observed by Wet-Mode Electron Microscopy (ESEM), AFM force measurements
Bentonite Hydration observed by Wet-Mode Electron Microscopy (ESEM), AFM force measurements F. Friedrich, G. Darbha, D. Schild, F. Huber, F. Quinto, M. Lagos, T. Schäfer INSTITUTE FOR NUCLEAR WASTE DISPOSAL
More informationSupplementary Information. Primary amino acid lithium salt as a catalyst for asymmetric Michael addition of isobutyraldehyde with β-nitroalkenes.
This journal is (c) The Royal Society of Chemistry 8 Supplementary Information Primary amino acid lithium salt as a catalyst for asymmetric Michael addition of isobutyraldehyde with β-nitroalkenes. Atsushi
More informationvii TABLE OF CONTENTS CHAPTER TITLE PAGE DECLARATION DEDICATION ACKNOWLEDGEMENT ABSTRACT ABSTRAK
vii TABLE OF CONTENTS CHAPTER TITLE PAGE DECLARATION DEDICATION ACKNOWLEDGEMENT ABSTRACT ABSTRAK TABLE OF CONTENTS LIST OF TABLES LIST OF FIGURES LIST OF SYMBOLS / ABBREVIATIONS LIST OF APPENDICES ii iii
More informationDevelopment of a Web-based Information Service Platform for Protected Crop Pests
Development of a Web-based Information Service Platform for Protected Crop Pests Chong Huang 1, Haiguang Wang 1 1 Department of Plant Pathology, China Agricultural University, Beijing, P. R. China 100193
More informationDensity functional theory model for calculating pore size distributions: pore structure of nanoporous catalysts
Advances in Colloid and Interface Science Ž. 76 77 1998 203 226 Density functional theory model for calculating pore size distributions: pore structure of nanoporous catalysts Peter I. Ravikovitch a, Gary
More informationAPPLICATION OF MODIFIED CALCIUM SORBENTS IN CARBONATE LOOPING
Physicochem. Probl. Miner. Process. 50(1), 2014, 217 224 www.minproc.pwr.wroc.pl/journal/ Physicochemical Problems of Mineral Processing ISSN 1643-1049 (print) ISSN 2084-4735 (online) Received May 30,
More informationEffect of ph on the Size of Gold Nanoparticles
International Journal of Electronic and Electrical Engineering. ISSN 0974-2174, Volume 7, Number 2 (2014), pp. 159-164 International Research Publication House http://www.irphouse.com Effect of ph on the
More informationChemical Engineering Journal
Chemical Engineering Journal 155 (2009) 493 498 Contents lists available at ScienceDirect Chemical Engineering Journal journal homepage: www.elsevier.com/locate/cej Dispersibility in organic solvents of
More informationAdsorption. December 2014
Adsorption December 2014 1 Nanosized objects have a large surface area Dividing the size of an object by 2... doubles the accessible surface 2 Adsorption Absorption Absorption is a phenomenon that occurs
More informationZhejiang University SPIE Student Chapter Annual Report September 2014
Zhejiang University SPIE Student Chapter Annual Report September 2014 2014 Chapter Officers President: Kai Hu Vice President: Lingchen Huang Secretary: Yingchen Wu Treasurer: Jinyang Liu Advisor: Prof.
More informationCharacterization of nickel based catalysts supported by different oxides and prepared by sol gel method
Characterization of nickel based catalysts supported by different oxides and prepared by sol gel method Mourad Halouane 1, Ouzna Kheffache 2, Saliha Menad 1, Djamila Halliche 2 1 Laboratoire de Recherche
More informationElement of same atomic number, but different atomic mass o Example: Hydrogen
Atomic mass: p + = protons; e - = electrons; n 0 = neutrons p + + n 0 = atomic mass o For carbon-12, 6p + + 6n 0 = atomic mass of 12.0 o For chlorine-35, 17p + + 18n 0 = atomic mass of 35.0 atomic mass
More informationAnalytical Services. Part number Measurement Description. Single-Point BET with Nitrogen 06000-1N. Multi-Point BET With Nitrogen 06000-3N
06000-1N 06000-3N Single-Point BET with Nitrogen Multi-Point BET With Nitrogen Single-point BET specific surface area (P/Po = 0.3) by nitrogen adsorption at 77K. Dynamic flow method unless otherwise requested.
More information