BORYGO EKO car radiator fluid

Transcription

1 1. Identification of preparation and of the company: Product name Product use The BORYGO EKO fluid can be applied to the internal combustion engine cooling system. Manufacturer Boryszew ERG S. A. ul. 15 Sierpnia 106; Sochaczew tel fax Responsible person Emergency telephone number ext. number 222 Mon.-Fri. operating hours: ( ) or 112, Hazards identification: Potential health effects: The product is not classified as posing risk to human health. Potential environmental effects: The product is not classified as posing risk to environment. 3. Composition/ information on ingredients: Mixture of propylene glycol, water and corrosion inhibitors. hazardous substances: Name of substance Concentration [%] CAS Number EC Number Classification Disodium tetraborate, anhydrous borax < T; Rep. Kat.2 R First-aid measures: General information If any of the symptoms occur seek medical attention immediately. Show physician product label, or packaging. Inhalation: Not expected to present an inhalation hazard. Skin contact: Not expected to present a skin hazard. Eye contact: Issue date: Updating date: Page 1 of 6

2 Check for and remove contact lenses. Keeping victim s eyes opened flush them with water for At least 15 minutes. Seek medical attention if symptoms persist. Ingestion: If large quantity swallowed, give lukewarm water (1/2 litre) if victim completely conscious/alert. Do not induce vomiting. Seek emergency medical attention. 5. Fire fighting measures: Fire extinguishing media: - CO 2, - dry chemicals, - water spray, - alcohol-resistant foam. Inappropriate fire extinguishing media: Solid streams of water. Unusual fire and explosion hazards: Heat from fire can generate flammable vapour. Fine sprays/mists may be combustible at temperatures below normal flash point. When mixed with air and expose to ignition source, vapours can burn in open space or explode if confined. Vapours May be heavier than air. Container may burst under intense heat. Incomplete combustion may produce carbon monoxide and other toxic gases. Special fire fighting procedure: Wear positive pressure self-contained breathing apparatus (SCBA) and gas-tight suit. Additional information: Make bystanders leave fire area. Cool fire expose containers with water spray and remove them from fire area if it can be done without risk. When spilled, it may cause slipping. Prevent contaminated water and extinguishing agents from entering waterways. 6. Accidental release measures: Personal precautions: Make bystanders leave hazard area. Ensure good ventilation. Wear protective clothing. Environmental precautions: Stop leak if possible without personal risk. Remove all sources of ignition. Prevent the product from entering waterways, surface waters, ground waters. Notify proper local authorities if big quantities of the product were released or environmental contamination occurred. Procedures for cleaning/removing: Embank and pump over into marked containers big quantities of the released product. Small amounts: take up with non-flammable absorbent material and collect in the marked, tightly sealed container for disposal. Rinse off the affected area with water. Place damaged packaging In a container for disposal. Remove as recommended in p Handling and storage: Handling Observe industrial safety and health regulations related to dealing with chemicals. Use in well-ventilated place Issue date: Updating date: Page 2 of 6

3 Wear suitable protective clothing Do not eat, drink or smoke while working with the product Keep away from fire and sources of ignitron. Storage Store in tightly sealed, suitably marked containers. Store in a well-ventilated place. Do not allow smoking, eating or using open fire in the storage place. Prevent from contact with flammable substances or oxidants. Do not expose to direct sunrays. The product should not be subjected to temperature higher than 40 C. When spilled, it may cause slipping. 8. Exposure control/personal protection: Additional recommendations regarding civil engineering system: Provide adequate ventilation in storage rooms and workplaces. Other requirements see p. 7. Personal protective equipment: Wash hands after working with the product and before each break in work. Keep away from food, drink or feed. Immediately change contaminated clothing. Do not eat, drink or smoke while working with the product. Respiratory tract protection: Gas mask is required whenever vapours/sprays occur. Hand protection: Wear chemical resistant gloves such as: Neoprene. The exact breakthrough time must be provided. Eye protection: Use splash goggles when eye contact due to splashing or spraying liquid is possible. Skin protection: Approved clothing, rubber overall and rubber boots. Technical measures: No special technical measures to be applied. 9. Physical and chemical properties: Form Colour Odour clear, homogeneous liquid green slight ph 7,5-11,0 Freezing point ( C), max -35 Boiling point ( C), min 106 Density, min. Solubility in water Other solvents 1,045 g/cm 3 (20 C) Vapour density * < 0,1 mm Hg (21 0 C) Autoignition temperature ( C)* > 371 all-water soluble aliphatic alcohols, aldehydes, ketones, acetic acid, pyridine, aromatic carbohydrates, ethers Issue date: Updating date: Page 3 of 6

4 Explosive limits * lower limit 2,4% upper limit 17,4% Thermal decomposition ( C)* approx Vapour density relative to air * 2,6 (air = 1; o C) Viscosity (25 o C)* 46mPa s Vapour pressure (20 o C)* Partition coefficient logp (w/o) Ignition temperature ( o C)* * propylene glycol 0,2 mbr -0,92 approx Stability and reactivity: Stability: The product remains stable under recommended use and storage conditions. Substances to be avoided: Strong oxidizing agents, strong alkalis, strong acids, isocyanides. Conditions to be avoided: High temperatures, open flame, sources of ignitron Decomposition products: Carbon Monoxide (II) and other toxic vapours. 11. Toxicological information: Acute toxicity lethal doses: LD 50 (ingestion, rat)=23000 mg/kg* LD 50 (skin, rabbit)= 20800mg/kg* Health hazards: After inhalation: Low risk of poisoning due to low volatility and toxicity of the product. After skin-contact: Not a skin irritant. After eye-contact: May cause minor eye irritation. After swallowing: The product is slightly dangerous to human heath after swallowing large quantities. * propylene glycol 12. Ecological information: Environmental toxicity: Crustacea Dafnia magna: EC 50 /48h > mg/l * Issue date: Updating date: Page 4 of 6

5 Fish Cyprinodon : LC 50 /96h = mg/l* Algae EC 50 /72h >19000 mg/l * Biodegradation: BOD- biological oxygen demand (28 days) = 87-92%* Biodegradable: log P(o/w) -0,92; Bioconcentration factor < 1* Prevent the product from entering waterways, surface water, ground water, sewage system. * propylene glycol 13. Disposal Considerations: Do not empty into sewage system. Do not allow entering into surface water or ground water. The product can be biodegradable in alkaline solution (ph>8). Do not burn used containers. Waste classification: Antifreeze fluids other than those listed in Collect waste material and forward to recycling or combustion in suitable facilities. Dealing with containers: Multiple-use containers are recommended. Forward used containers to local recycling centres. 14. Transport information: ADR/ADNR/RID Road & Rail Transport, IATA, MDG Air & Sea Transport: The product is not classified as dangerous goods. 15. Regulatory information: Label include the following: - identification of preparation manufacturer ( name of company, address, telephone number), - quantity of preparation in container (amount, volume). Safety phrases: S 2 - Keep out of the reach of children S 28 - After contact with skin, wash immediately with plenty of lukewarm water Legislation: Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. COMMISSION DECISION of 3 May 2000replacing Decision 94/3/EC establishing a list of wastes pursuant to Article 1(a) of Council Directive75/442/EEC on waste and Council Decision 94/904/EC establishing a list of hazardous waste pursuant to Article 1(4) of Council Directive 91/689/EEC on hazardous waste. Issue date: Updating date: Page 5 of 6

6 16. Other information: Risk phrases referring to the preparation ingredients see p. 3: R 60 May impair fertility, R 61 - May cause harm to the unborn child. Issue date: Updating date: Page 6 of 6