MATERIAL SAFETY DATA SHEET Goof Off Citrus Liquid. 1. Product and Company Identification

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1 Page: 1 Flammability Health 0 1 Instability 0 Special 1. Product and Company Identification Product Code: 2640 Product Name: Manufacturer Information Company Name: W. M. Barr 2105 Channel Avenue Memphis, TN Phone Number: (901) Emergency Contact: 3E 24 Hour Emergency Contact (800) Information: W.M. Barr Customer Service (800) Web site address: Preparer Name: W.M. Barr EHS Dept (901) Intended Use: Multi-Purpose Remover for grease, tar, ink, paint, adhesive, etc. Synonyms FG701, FG704, FG708, FG712, FG Hazards Identification Emergency Overview Product may have the potential to produce slight eye irritation from direct contact. Date Created: 03/20/2009 Keep away from children. OSHA Regulatory Status: While this material is not classified as hazardous under OSHA regulations, this MSDS contains valuable information critical to the safe handling and proper use of the product. This MSDS should be retained and available for employees and other users of this product. Health Hazards (Acute and Chronic) Material has not been evaluated as a mixture. Hazards listed below are those of the individual ingredients: Acute Eye Contact: t expected to be an eye irritant. Slight irritation may occur. Acute Inhalation: hazards expected. Acute Skin Contact: Skin contact is not expected to produce any adverse effects, if used as directed. Acute Ingestion: significant adverse effects are expected upon ingestion of the product. Chronic Effects: ne known. Target Organs: ne known. Likely routes of exposure: Skin contact, Ingestion. Signs and Symptoms Of Exposure See Potential Health Effects.

2 Page: 2 Medical Conditions Generally Aggravated By Exposure ne Known. 3. Composition/Information on Ingredients CAS # Concentration NA 0.0 % 2. Methyl Soyate % 4. First Aid Measures Emergency and First Aid Procedures Skin: Remove contaminated clothing. Immediately wash skin thoroughly with water and mild soap, if available. Seek medical attention if irritation develops or persists. Eyes: Immediately begin to flush eyes with water, remove any contact lens. Continue to flush the eyes for at least 15 minutes. Seek medical attention. Inhalation: If symptoms are experienced, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Ingestion: If swallowed, do NOT induce vomiting. Seek immediate medical attention. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. te to Physician information. 5. Fire Fighting Measures Flammability Classification: NFPA Class IIIB Flash Pt: > F (93.3 C) Method Used: Setaflash Closed Cup (Rapid Setaflash) Explosive Limits: LEL: UEL: Special Fire Fighting Procedures As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH approved or equivalent) and full protective gear. Containers can build up pressure if exposed to heat (fire). Storage containers exposed to fire should be kept cool with water spray to prevent pressure build-up. Stay away from heads of containers that have been exposed to intense heat or flame. Unusual Fire and Explosion Hazards ne known. Material is thought to have the potential, if soaked in rags, to act as an "oily" rag and could result in spontaneous combustion. Hazardous Combustion Products Carbon monoxide, carbon dioxide. Suitable Extinguishing Media Use alcohol foam, dry chemical, carbon dioxide, or water spray when fighting fires involving this material. Unsuitable Extinguishing Media ne Known.

3 Page: 3 6. Accidental Release Measures Steps To Be Taken In Case Material Is Released Or Spilled Isolate the immediate area. Prevent unauthorized entry. Eliminate all sources of ignition in area and downwind of the spill area. Stay upwind, out of low areas, and ventilate closed spaces before entering. All equipment used when handling this product must be grounded or non-sparking. Do not touch or walk through spilled material. Stop leak if you can do so without risk. Prevent entry into waterways, sewers, or confined areas. A vapor suppressing foam may be used to reduce vapors. Absorb or cover with dry earth, sand, or other non-combustible material and transfer to compatible containers. For large spills, dike ahead of the spill. 7. Handling and Storage Precautions To Be Taken in Handling "Empty" containers retain product residue (liquid and/or vapor) and can be dangerous. As with all chemicals, avoid contact with eyes, skin, and clothing. Avoid prolonged contact with skin. Wash thoroughly after handling. Rags contaminated with product may have the potential for spontaneous combustion, as other "oily rags", and presents a fire hazard. Rags contaminated with product should be stored in approved UL listed of FM approved, covered containers. Rags should be allowed to dry before being disposed of. Precautions To Be Taken in Storing Do not store in direct sunlight. Keep container tightly closed when not in use. Store in a cool, dry place. Do not store near flames or at elevated temperatures. 8. Exposure Controls/Personal Protection CAS # OSHA PEL ACGIH TLV Other Limits NA 2. Methyl Soyate Respiratory Equipment (Specify Type) When used by the consumer following directions for use and with adequate ventilation, respiratory protection should not be needed. Eye Protection At a minimum, wear safety glasses with side shields. If the material is used in a manner where splashing of liquid is possible, chemical goggles or a face shield should be worn to prevent eye contact. Protective Gloves When used under normal cleaning conditions and as directed, skin protection is generally not required, Individuals with sensitive skin and individuals with repeated or prolonged skin contact with product should wear chemical resistant gloves, such as nitrile rubber. Other Protective Clothing Various application methods can dictate use of additional protective safety equipment, such as impermeable aprons, etc., to minimize exposure. Ventilation When used as directed, ventilation is normally not required when handling or using this product to keep exposure to airborne contaminants below the exposure limit. Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Use with adequate ventilation to prevent buildup of vapors. If strong odor is noticed or you experience slight dizziness, headache, nausea or eye-watering -- STOP -- ventilation is inadequate. Leave area immediately and move to fresh air.

4 Page: 4 Work/Hygienic/Maintenance Practices Wash hands thoroughly after use and before eating, drinking, or smoking. Do not eat, drink, or smoke in the work area. Discard any clothing or other protective equipment that cannot be decontaminated. A source of clean water should be available in the work area for flushing of eyes and skin. 9. Physical and Chemical Properties Physical States: [ ] Gas [ X ] Liquid [ ] Solid Melting Point: NP Boiling Point: F (215.6 C) F (361.7 C) Autoignition Pt: Flash Pt: > F (93.3 C) Method Used: Setaflash Closed Cup (Rapid Setaflash) Explosive Limits: LEL: UEL: Specific Gravity (Water = 1): Density: LB/GL Bulk density: Vapor Pressure (vs. Air or mm Hg): Vapor Density (vs. Air = 1): > 1 Evaporation Rate (vs Butyl < 1 Acetate=1): Solubility in Water: t soluble. Percent Volatile: < 2.0 % by weight. Heat Value: Particle Size: Corrosion Rate: ph: NP Appearance and Odor Transparent, slight orange color and citrus fragrance. 10. Stability and Reactivity Stability: Unstable [ ] Stable [ X ] Conditions To Avoid - Instability ne known. Incompatibility - Materials To Avoid Strong oxidizers, acids, and alkalis. Hazardous Decomposition Or Byproducts Oxides of carbon, carbon monoxide Possibility of Hazardous Reactions: Will occur [ ] Will not occur [ X ] Conditions To Avoid - Hazardous Reactions ne known. 11. Toxicological Information This product has not been tested as a whole. Information below will be for the primary ingredient (~98% of total mixture). Acute Toxicity: LD50 Oral Rats >17.4 g/kg

5 Page: 5 Skin Corrosion/Irritation: A 24-hr human patch test produced very mild irritation. Serious Eye Damage/Irritation: The application of undiluted material to a rabbit's eye produced only mild transient irritation. Respiratory or Skin Sensitization: There is a moderate potential for skin sensitization. Aspiration Hazard: Chronic Toxicological Effects This product has not been tested as a whole. Information below will be for the primary ingredient (~98% of total mixture). Germ Cell Mutagenicity: Reproductive Toxicity: STOT-Single Exposure: STOT-Repeated Exposure: Carcinogenicity/Other Information data available. CAS # NTP IARC ACGIH OSHA NA 2. Methyl Soyate Ecological Information This material has not been tested as a whole. The information below is for the primary ingredient (~98% of total mixture). Toxicity: LC50 >1000 mg/l for 96-hour period with Fathead Minnows. Persistence and Degradability: Readily biodegradable. Bioaccumulative Potential: Mobility in Soil: Other Adverse Effects: ne known.

6 Page: Disposal Considerations Waste Disposal Method Dispose in accordance with applicable local, state, and federal regulations. 14. Transport Information LAND TRANSPORT (US DOT) DOT Proper Shipping Name Paint Related Material, t Regulated LAND TRANSPORT (Canadian TDG) Additional Transport Information For D.O.T. information, contact W.M. Barr Technical Services at Canadian Chemical Lists 15. Regulatory Information CAS # Canadian NPRI Canadian IDL NA 2. Methyl Soyate Canadian WHMIS Classification data available. US EPA SARA Title III CAS # Sec.302 (EHS) Sec.304 RQ Sec.313 (TRI) Sec.110 NA 2. Methyl Soyate US EPA CAA, CWA, TSCA CAS # EPA CAA EPA CWA NPDES EPA TSCA CA PROP 65 NA 2. Methyl Soyate Inventory Canadian Regulatory Lists: Canadian NPRI: Canadian IDL: Canadian National Pollutant Release Inventory Canadian Ingredient Disclosure List SARA (Superfund Amendments and Reauthorization Act of 1986) Lists: Sec.302: EPA SARA Title III Section 302 Extremely Hazardous Chemical with TPQ. * indicates LB TPQ if not volatile. Sec.304: EPA SARA Title III Section 304: CERCLA Reportable + Sec.302 with Reportable Quantity. ** indicates statutory RQ. Sec.313: EPA SARA Title III Section 313 Toxic Release Inventory. te: -Cat indicates a member of a chemical category. Sec.110: EPA SARA 110 Superfund Site Priority Contaminant List TSCA (Toxic Substances Control Act) Lists: Inventory: Chemical Listed in the TSCA Inventory. 5A(2): Chemical Subject to Significant New Rules (SNURS) 6A: Commercial Chemical Control Rules 8A: Toxic Substances Subject To Information Rules on Production 8A CAIR: Comprehensive Assessment Information Rules - (CAIR) 8A PAIR: Preliminary Assessment Information Rules - (PAIR) 8C: Records of Allegations of Significant Adverse Reactions 8D: Health and Safety Data Reporting Rules 8D TERM: Health and Safety Data Reporting Rule Terminations 12(b): tice of Export

7 Page: 7 Other Important Lists: CWA NPDES: CAA HAP: CAA ODC: EPA Clean Water Act NPDES Permit Chemical EPA Clean Air Act Hazardous Air Pollutant CA PROP 65: California Proposition 65 EPA Clean Air Act Ozone Depleting Chemical (1=CFC, 2=HCFC) International Regulatory Lists: EPA Hazard Categories: This material meets the EPA 'Hazard Categories' defined for SARA Title III Sections 311/312 as indicated: [ ] Yes [X] Acute (immediate) Health Hazard [ ] Yes [X] Chronic (delayed) Health Hazard [ ] Yes [X] Fire Hazard [ ] Yes [X] Sudden Release of Pressure Hazard [ ] Yes [X] Reactive Hazard Regulatory Information This product has been classified according to the hazard criteria of the Controlled Products Regulations. 16. Other Information Company Policy or Disclaimer The information contained herein is presented in good faith and believed to be accurate as of the effective date shown above. This information is furnished without warranty of any kind. Employers should use this information only as a supplement to other information gathered by them and must make independent determination of suitability and completeness of information from all sources to assure proper use of these materials and the safety and health of employees. Any use of this data and information must be determined by the user to be in accordance with applicable federal, state and local laws and regulations.