Material Safety Data Sheet

Transcription

1 1. Product & Company Identification Product LiPo Battery Manufacturer: Conrad Electronic SE Model: LiPo 150 mah/3,7v/15 C Nominal capacity: 150 mah Nominal voltage: 3,7 V Address: Klaus-Conrad-Strasse 1, D Hirschau Telephone: Date of issue: Composition/information on ingredients Component Range % by Wt. CAS No. Lithium Cobaltate Graphite Polypropylene Poly(tetrafuoroethylene) Polyethylene Sodium carboxymethyl cellulose 0, Lithium hexafluorophosphate Ethylene carbonate Nickel 2, Copper Aluminium Page 1 of 6

2 3. Hazard Identification Hazard Class Miscellaneous dangerous article. Emergency overview None special measures need. Routes of entry Skin, eye contact and ingestion Health hazards These chemicals are contained in a sealed can. Potential for exposure should not exist unless the battery leaks, is exposed to high temperatures or is mechanically, physically, or electrically abused. This could result in the release of toxic or corrosive materials. Skin contact: Irritation may occur following exposure to a leaking battery. Eye contact: Irritation may occur following exposure to a leaking battery. Ingestion: Irritation to the internal/external mouth area. Environment hazards found. Explosion hazards Explosion may occur when the battery is short circuit or throwed in fire or exposured to high heat. 4. First aid measures Skin contact None under normal use conditions. If exposure to a leaking battery, immediately flush skin with plenty of soap and water. Remove contaminated clothing and shoes. Wash clothing before reuse. Get medical attention if irritation develops. Eye contact None under normal use conditions. If exposure to a leaking battery. immediately flush eyes with plenty of water, lifting tipper and lower eyelids occasionally. Get medical attention if irritation persists. Inhalation None under normal use conditions. If exposure to a leaking battery, remove to fresh air, get medical attention for any breathing difficulty Ingestion Wash out mouth thoroughly with water and give plenty of water to drink. Get medical attention. Page 2 of 6

3 5. Fire fighting measures Types of hazard Battery is not a flammable article. Hazardous combustion products Exploding in fire could release hydrogen fluoride and toxic fume Fire fighting measures Dry chemical. foam, carbon dioxide or sand. Special Information If possible, remove from fighting area. In the event of a fire, wear full protective clothing and self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. 6. Accidental release measures Earth or sand should be used to absorb the exudation. seal leaking battery and earth in a heavy duty polythene bag and dispose according to local regulations. 7. Handling and storage Handling Do not short circuit or expose to temperatures above the temperature rating of battery. Do not over-recharge, over-discharge, force discharge, immerse, puncture or crush. Storage Store in a dry and cool place but prevent condensation on cells or batteries. Elevated temperatures can result in shortened battery life and degrade performance. 8. Exposure controls, personal protection Occupat ional exposure limits (8-Hour TWAs:) Lithium cobaltages as (Co) (Dusts and fumes) mg/m3 (OSHA), 0.02 mg/m3 (ACGIH) Graphite (Natural) - 15 mppcf (OSHA), 2 mg/m3 for all forms of graphite except graphite fibers (ACGIH), 4 mg/m3 total dust, 2mg/m3 respirable fraction (China) Polypropylene - 5 mg/m3 total dust (China) Polyethylene -15 mg/m3 total dust, 5 mg/m3 respirable fraction (OSHA), 10 mg/m3 total dust, 3 mg/m3 respirable fraction (ACGIH), 5 mg/m3 total dust (China) Nickel -1 mg/m3'(osha), 1.5 mg/m3 inhalable fraction (ACGIH), 1 mg/m3 Nickel and isoluble compounds, 0,5 mg/m3 soluble compounds (China) Copper mg/m3 dusts and mists (OSHA/ACGIH), 1 mg/m3 dust, 0.2 mg/m3 fume (China) Aluminum - 15 mg/m3 total dust and 5 mg/m3 respirable fraction (OSHA), 10 mg/m3 dusts (ACGIH), 4 mg/m3 Aluminium and aluminium alloys total dust, 3 mg/m3 Aluminium oxide total dust (China) Other ingredients: None established Inspect measures Atomic absorption spectrometry, X-ray fluorescence spectroscopy. Page 3 of 6

4 Engineering controls General ventilation under normal use conditions. Inhalation protection In fire situations, use self-contained breathing apparatus. Eye protection Safety glasses are recommended during handling. Skin protection In the event of leakave wear gloves. Other protection In the event of leakage, wear chemical apron, Keep batteries away from children. 9. Chemical and Physical Properties Appearance and odor Block battery cell ph N/A Melting point N/A Boiling point ( C) N/A Density (water = 1) Relative vapour density (Air =1) N/A Vapour pressure (kpa) N/A Heat of combustion (kj/mol) N/A Critical temperature ( C) N/A Critical pressure (MPa) N/A Octanol/water partition coefficient as log Pow N/A Flash point ( C) Auto-ignition temperature ( C) N/A Solubility N/A Upper explosive limits %/V/V) N/A Lower explosive limits %/V/V) N/A Main purpose Other properties 2,5 Power supply for equipment or device N/A 10. Stability and reactivity Stability Stable under ordinary conditions of use and storage. Incompatibilities Oxidisine agents, acids, alkalis. water. Conditions to avoid High heat or incinerate. Deform. Mutilate. Crush. Pierce, Disassemble. Short circuit. Expose over a long period to humid conditions. Hazardous polymerizat ion Wll not occur. Hazardous decomposition Toxic fumes. Page 4 of 6

5 11. Toxicological information Acute toxicity For Polypropylene, Intravenous, rat: Dose >99mg/kg For Sodium carboxymethyl cellulose, Oral, rat: LD50 = mg/kg For Ethylene Carbonate, Oral, rat: LD50 = 10 g/kg. Other ingredients: None established. Effects of long-term or repeated exposure lrritativity Irritability Mutagenicity For Sodium carboxymethyl cellulose, adverse reproductive effects have occurred in experimental. Teratogenicity For Poly(tetrafluoroethylene), Equivocal tumorigenic agent: Implant, rat: TDLo = 80 mg/kg. Implant, mouse: TDLo =1140mg/kg Carcinogenicity Nickel (listed as Nickel compounds) is listed in NTP as "Suspect carcinogen" and IARC Category as "Group 1 carcinogen". Other ingredients are not listed in IARC Category. Other Toxicity. 12. Ecological information Ecological toxicity Biodegradability Degradability Bioaccumulation Others 13. Disposal information Disposal measures Do not incinerate, or expose the battery to high heat or fire. Such abuse can result in loss of seal, leakage, and/or battery explosion. Dispose according with appropriate local regulations. Notes Page 5 of 6

6 14. Transport Information UN No. UN3480 Proper Shipping Name Lithium ion batteries Hazard class Class 9, miscellaneous Packing Group II Notes Lithium ion rechargeable batteries are regulated during shipment by the Department ot Transportation (USDOT) and United Nation (International) requirements. If it meets the requirement of each test in the UN Manual of Tests and Criteria, Part III, subsection 38.3 (UN38.3 tests) and all other requirements of PI 965 such as preventing short circuit. 1.2m drop test and so on, it is not subject to other provisions of IATA DGR, 51st edition. 15. Regulatory information Domestic authority regulations: Regulations on safety Administration of Dangerous Chemicals (Jan 26,2002), The article is listed in GB and GB Abroad regulations: The article is listed in of CFR, USA and sujected to the Recommendations on the Transport of Dangerous Goods Model Regulations, IATA DGR and IMDG Code. Nickel and Copper are listed in TSCA, DSL, CERCLA and inventory of EC. All other ingredients are listed in TSCA, DSL, inventory of EC, but not listed in CERCLA. 16. Disclaimer Disclaimer: This MSDS conforms to the requirements of ISO This MSDS is offered to you in good faith as accurate. We have reviewed any information contained in this data sheet which we received from sources outside our company. We believe that information to be correct but cannot guarantee its accuracy or completeness. Health and safety precautions in this data sheet may not be adequate for all individuals and/or situations. Ii is the user's obligation to evaluate and use this product safely and to comply with all applicable laws and regulations. No statement made in this data sheet shall be construed as a permission or recommendatio for the use cif any product in a manner that might infringe existing patents. No warranty is made, either express or implied. Page 6 of 6