CO 2 is an Emerging Raw Material in Polymer Industry (CIAC s Effort in CO 2 based Polymers)

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1 O 2 is an Emerging Raw Material in Polymer Industry (IA s Effort in O 2 based Polymers) Xianhong Wang Key Lab of Polymer Ecomaterials(KLPE) hangchun Institute of Applied hemistry(ia), hinese Academy of Sciences Key Laboratory of Polymer Ecomaterials, IA, hinaese Academy of Sciences

2 Main ontents 1. O 2 based plastics and its applications 2. O 2 Based Polyols and its commercial application

3 O 2 Polymer hemistry Beyond a raw material, a link between polymer and environment (overcome bottleneck of biodegradable polymer industry) 5. Regiochemistry 1. activity 3. ether segment 2. Product selectivity 4. Molecular weight Key issues 6. stereochemistry 7. side-chain chemistry high activity and selectivity catalyst to overcome inertness of O 2 performance adjustment of as-polymerized PP

1. O 2 based Plastics and its applications IA s RET, catalyst for industry Rare earth coordination ternary catalyst(ret) (ZnEt 2 /polyol/re) (8h, 100g PP/g cat.

4 1. O 2 based Plastics and its applications IA s RET, catalyst for industry Rare earth coordination ternary catalyst(ret) (ZnEt 2 /polyol/re) (8h, 100g PP/g cat., P: 5-8% (Mn, kg/mol; Tg, 35 0 ) Patents: US6,815,529B2(2004), JP Patent( ), and 8 patents Publications: Journal of Polymer Science Part A-Polymer hemistry, 2001, 39(16): ; 2006, 44(18): ; 2008, 46(13): Polymer, 2003, 44(6): ; 2003, 44(19): ; 2006, 47(21):

5 Hard but continuous industry effort since : Pilot line in Innermongolier Mengxi Group(cement kiln O 2 ) a milestone in PP industry, a. 500 ton PP produced Inoue visited 2004 and : hina ational offshore Oil ompany, 5000 ton line (suspended since Jun. 2012) Life cycle analysis from SK Innovation O 2 emission per kg polymer PS PET PE PP PP PP is a. half O 2 emission of PE 2012: Zhejiang Bangfeng Plastics 30,000 ton line( coal power plant O 2 )

Scale production of PO2 biodegradable plastics, aquired certificate from BPI since 2011 BPI certificate creates opportunity for large scale

6 Scale production of PO2 biodegradable plastics, aquired certificate from BPI since 2011 BPI certificate creates opportunity for large scale application of O 2 plastics Plastics bag line(po2 bag now sold in US) PO 2 resin and plastics bag acquired BPI certificate(antong Huasheng plastics o.)

7 ew applications: 1) Surgical Dressing Pilot line for surgical dressing Registration ertificate since 2006

ew applications: 2) Resilient biodegradable foam buffering or cushioning for electronics and car interior 2011: water-foaming PP: 30-35 times(d<0.07g/cm3), pore density: 5.

8 ew applications: 2) Resilient biodegradable foam buffering or cushioning for electronics and car interior 2011: water-foaming PP: times(d<0.07g/cm3), pore density: cells/cm 3, low poor resilience). 2014: O 2 foaming PP: 10 times, good resilience Tensile EVA PP EPP ompr. Resil. Resilient foam: cell size: m density 13 of 25

9 ew applications: 3) biodegradable mulch film Discarded awful LLDPE mulching film, reduction of production 150,000 tons/a in Jilin province, the whole country: 2.5m tons/a Requirements: Low cost, thin film(8um), heat preserve, water conservation 14 of 25

10 2.O 2 Based Polyols and its commercial application Poly(ether-carbonate) ols from O 2 and Propylene oxide Terminals ether carbonate yclic P M n <2000g/mol;.U. >70%; Activity>1.0kg/g at.

11 Utilization of Polyols O 2 Isocyanate Polyol Polyurethane 2012: 7.5 Million Tons; 2018:10.4 Million Tons

12 Zn OR l Zn Zn Zn o o o o OR l OH OR l H H H Re Re X Our catalyst: Rare earth metal doped DM

13 IA:Zno-DM/diacid system Mn:2000 g/mol, O 2 %: 20-35wt% onversion of PO versus reaction time using PPG and sebacic acid (SA) as chain transfer agent 5-10 h,1kg polyol /g cat MW1500(O 2 :15-35wt%)

14 Zno-DM/triacid system o Zn o H OR l Zn l Zn l OR H OR H o Zn OH o onversion of PO, U and W pc versus reaction time at 80,4MPa with 180mg DM, 11g BTA.

15 Application of Polyols A 10,000 ton/a line is under construction in antong, hina, focusing on market in leather slurry and shoe industry, while future market on car industry, scheduled to run on Dec, 25, 2015.

16 Water-borne adhesive from O 2 based polyol O 2 polyol(mn=1,500,67%carboante)as soft segment to afford water borne adhesive(solid content: 46%, IA-WAT210), now used in automotive upholstery(benz 212, HQ-7, Audi-A3) hangchun Faway-Johnson s products using IA WAT 210 Benz 212 door panel AudiA3 door handrail HQ7 storage box

17 Toughening of PP foam PU based on O 2 polyol (PO 2 PU) PP 0.035g/cm 3 low Melt Strength of PP leading to irresilent foam 闭孔开孔 resilience:36%,0.08g/cm Raising Melt Strength of PP Biodegradable PU PO 2 PU HDI

18 Thank you for your omments!

19 Professor Xianhong Wang Key Lab of Polymer Ecomaterials(KLPE) hangchun Institute of Applied hemistry(ia), hinese Academy of Sciences mail

Dispersions for the adhesive industry Innovative raw materials for numerous applications

Dispersions for the adhesive industry Innovative raw materials for numerous applications Not all are the same! These days, almost all industries are dependent on innovative adhesive technologies. Modern