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1 1.) Identification of the substance/mixture and of the company/undertaking Trade name EOS CobaltChrome SP2 Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses of the substance or mixture cobalt-based metal powder for manufacture of dental restorations in EOSINT M systems Details of the supplier of the safety data sheet Address Electro Optical Systems Finland Oy Lemminkäisenkatu Turku FINLAND Telephone no (0) / 9147 Fax no (0) Information provided by / telephone +49 (0) 89 / Emergency telephone +49 (0) 89 / (8 am - 5 pm) +49 (0) 89 / (Mo - Thu: 9 am - 12 pm & 1-6 pm; Fr: 1-4 pm) (CET) Advice on Safety Data Sheet Identification of the supplier Address EOS GmbH - Electro Optical Systems Robert-Stirling-Ring Krailing / München GERMANY Telephone no. +49 (0) 89 / Fax no. +49 (0) 89 / ) Hazards identification Classification of the substance or mixture Classification in accordance with Regulation 67/548/EEC or 1999/45/EC R42/43 R53 Label elements Labelling according to Directive 1999/45/CE Hazard symbols Harmful Hazardous component(s) to be indicated on label, contains: cobalt page 1(7)

2 R phrases 42/43 May cause sensitisation by inhalation and skin contact. 53 May cause long-term adverse effects in the aquatic environment. S phrases 22 Do not breathe dust. 24 Avoid contact with skin. 36/37 Wear suitable protective clothing and gloves. 3.) Composition / information on ingredients Chemical characterization cobalt-based powder Hazardous ingredients cobalt EC no Index no CAS no Concentration > 50 < 70 %-b.w. Classification R42/43 R53 Hazard symbols Xn R phrases 42/43-53 chromium EC no Index no. - CAS no Concentration > 10 < 30 %-b.w. Classification - Hazard symbols R phrases - tungsten EC no Index no. - CAS no Concentration > 5 < 10 %-b.w. Classification - Hazard symbols - R phrases - SILICON EC no Index no. - CAS no Concentration > 1 < 5 %-b.w. Classification - Hazard symbols R phrases - 4.) First aid measures General information Remove contaminated clothing and shoes immediately, and launder thoroughly before reusing. After inhalation Remove affected person from the immediate area. Ensure supply of fresh air. Summon a doctor immediately. After skin contact When in contact with the skin, clean with soap and water. Seek medical attention. After eye contact Separate eyelids, wash the eyes thoroughly with water (15 min.). Get medical attention if pain still persists. After ingestion Rinse mouth thoroughly with water. Induce vomiting. Summon a doctor immediately. Never give anything by mouth to an unconscious person. 5.) Fire-fighting measures Suitable extinguishing media special powder against burning metal page 2(7)

3 Extinguishing media that must not be used for safety reasons Water; Carbon dioxide; ABC powder; Foam Special exposure hazards arising from the substance or preparation itself, combustion products, resulting gases In the event of fire, the following can be released: Carbon dioxide (CO2); Carbon monoxide (CO) Special protective equipment for fire-fighters Use self-contained breathing apparatus. Wear protective clothing. Other information Run-off water from fire fighting must not be discharged into drains or enter surface water. 6.) Accidental release measures Personal precautions Refer to protective measures listed in sections 7 and 8. Ensure adequate ventilation. Avoid dust formation. Avoid contact with skin, eyes and clothing. Keep away sources of ignition. Environmental precautions Do not discharge into the drains/surface waters/groundwater. Do not discharge into the subsoil/soil. Methods for cleaning up/taking up Small quantities of spilled material may be collected dry or wet. In large quantities: Take up mechanically; When aspirators are used, make sure that they are equiped with efficient dust filtres (HEPA). 7.) Handling and storage Handling Advice on safe handling Product inherent handling risks must be minimised taking the appropriate measures for protection and preventive actions. The working process should be designed to rule out the release of hazardous substances or skin contact as far it is possible by the state of the art. Provide good ventilation of working area (local exhaust ventilation, if necessary). Avoid contact with skin and eyes. Avoid dust formation. Advice on protection against fire and explosion Dust can form an explosive mixture with air. Take precautionary measures against static charges. Keep away from sources of ignition - refrain from smoking. Storage Requirements for storage rooms and vessels Containers which are opened must be carefully resealed and kept upright to prevent leakage. Always keep in containers of same material as the original one. Advice on storage assembly Do not store together with: Mineral acids; Acids; Fluorine; ammonium nitrate; Hydrazine; performic acid; Phosphorous; selenium; sulphur; Titane plus potassium chlorate Further information on storage conditions Keep container tightly closed and dry in a cool, well-ventilated place. Protect against mechanical damage. page 3(7)

4 8.) Exposure controls / personal protection Exposure limit values cobalt CAS no EC no Cobalt TWA 0,1 mg/m³ Cobalt compounds Co TWA 0,1 mg/m³ chromium CAS no EC no Chromium TWA 0,5 mg/m³ tungsten CAS no EC no Tungsten: soluble TWA 1 mg/m³ STEL 3 mg/m³ Tungsten: insoluble TWA 5 mg/m³ STEL 10 mg/m³ SILICON CAS no EC no Silicon total inhalable dust TWA 10 mg/m³ Silicon respirable dust TWA 4 mg/m³ Exposure controls Personal protective equipment Respiratory protection If workplace exposure limits are exceeded, a respiration protection approved for this particular job must be worn. In case of dust formation, take appropriate measures for breathing protection in the event workplace threshold values are not specified. Respirator HEPA Hand protection In case of intensive contact, wear protective gloves (EN 374). Before use, the protective glove should be page 4(7)

5 tested in any case for its specific work-station suitability (i.e. mechanical resistance, product compatibility and antistatic properties). Adhere to the manufacturer s instructions and information relating to the use, storage, care and replacement of protective gloves. Protective gloves shall be replaced immediately when physically damaged or worn. Design operations thus to avoid permanent use of protective gloves. Eye protection Safety glasses with side protection shield (EN 166) Skin protection Normal chemical work clothing. General protective and hygiene measures Do not eat, drink or smoke during work time. Keep away from foodstuffs and beverages. Wash hands before breaks and after work. Avoid contact with eyes and skin. Do not inhale dust. Remove soiled or soaked clothing immediately. Provide eye wash fountain in work area. Have emergency shower available. 9.) Physical and chemical properties General information Form Colour Odour Powder grey odourless Important health, safety and environmental information Changes in physical state Flash point Fire promoting Properties Oxidizing no data available no data available not oxidizing Density Value 4,5-5,7 g/cm³ Solubility in water 10.) Stability and reactivity insoluble Conditions to avoid Heat, naked flames and other ignition sources. Spontaneously inflammable when finely dispersed. Hydrogen gas is released upon contact with mineral acids and may form explosive compounds with air. Materials to avoid Mineral acids; Acids; Fluorine; ammonium nitrate; Hydrazine; performic acid; Phosphorous; selenium; Sulphur; Titane plus potassium chlorate Hazardous decomposition products No hazardous decomposition products known. Because of the thermal load in the process chamber new phases can be generated. 11.) Toxicological information Acute toxicity Acute oral toxicity LD50 > 7000 mg/kg rat page 5(7)

6 Acute dermal toxicity Acute inhalational toxicity No data available. No data available. Experience in practice Inhalation of dusts may irritate the respiratory tract. Eye contact may cause mechanical irritation through dust particles. Possibility of sensitisation through skin contact. Sensitisation possible through inhalation. Other information (chapter 11.) Product specific toxicological data are not known. 12.) Ecological information Ecotoxicity Fish toxicity LC50 > 100 mg/l Brachydanio rerio Duration of exposure 96 h Daphnia toxicity LC50 3,2 mg/l Daphnia magna Duration of exposure 48 h Algae toxicity IC50 0,05-0,26 mg/l Selenastrum capricornutum Duration of exposure 72 h Other information Do not discharge product unmonitored into the environment. 13.) Disposal considerations Product Allocation of a waste code number, according to the European Waste Catalogue, should be carried out in agreement with the regional waste disposal company. Packaging Residuals must be removed from packaging and when emptied completely disposed of in accordance with the regulations for waste removal. Incompletely emptied packaging must be disposed of in the form of disposal specified by the regional disposer. 14.) Transport information Other information (chapter 14.) The product is not defined under national/international road, rail, sea and air transport regulations as a hazardous material. page 6(7)

7 15.) Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU regulations Council Directive 96/82/EC on the control of major-accident hazards involving dangerous substances Annex I, part 1 + 2: not mentioned. With regard to possibly appropriate decomposition products see Chapter ) Other information s of key data used to compile the data sheet: EC Directive 67/548/EC resp. 99/45/EC as amended in each case. Regulation (EC) No 1907/2006 (REACH), 1272/2008 (CLP) as amended in each case. EC Directives 2000/39/EC, 2006/15/EC, 2009/161/EC National Threshold Limit Values of the corresponding countries as amended in each case. Transport regulations according to ADR, RID, IMDG, IATA as amended in each case. The data sources used to determine physical, toxic and ecotoxic data, are indicated directly in the corresponding chapter. Relevant R-phrases (chapter 3): 42/43 May cause sensitisation by inhalation and skin contact. 53 May cause long-term adverse effects in the aquatic environment. Department issuing safety data sheet UMCO Umwelt Consult GmbH Georg-Wilhelm-Str. 183 b, D Hamburg Tel.: / Fax: / This information is based on our present state of knowledge. However, it should not constitute a guarantee for any specific product properties and shall not establish a legally valid relationship. page 7(7)

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