Chemistry 110. Dr. Scott A. Showalter. Office Hours: 106 Chemistry Building (Chemistry Building is NOT Whitmore!

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1 Chemistry 110 Dr. Scott A. Showalter Office Hours: 106 Chemistry Building (Chemistry Building is NOT Whitmore!) by appointment courses.chem.psu.edu/chem110fall Lecture Notes can be downloaded and printed at: research.chem.psu.edu/sasgroup/chem110 CH110 FA11 SAS 1

2 Necessary materials 1. Textbook: Brown, LeMay, Bursten, & Murphy; Chemistry: The Central Science, 11 th ed., Required. Note: Half Text ( Volume 1 ) is an option. 2. Fall Chem 110 Student Packet. Required. 3. Wilson Solutions to Exercises in Chemistry, The Central Science, 11 th ed. Highly Recommended. 4. ALEKS system access. Required (this is your homework). 5. Non-text programmable calculator Required. CH110 FA11 SAS 2

3 What is Chemistry 110? 1. From the Course Packet: Chemistry 110 is the first in a two-course sequence in general chemistry. Chemistry impacts every area in our lives: from how our bodies work, to the environment, to new materials, to how we live and work. Our goals for this course are for you to recognize that what happens at the molecular level profoundly affects our macroscopic world and how fun chemistry is. By the end of Chem 110, you will understand conceptually (1) how atoms combind to form molecules; (2) how molecules interact and react with each other; and (3) how the molecular-level structure affects the macroscopic properties. 2. From ME Chemistry 110 expands on what you already know from previous chemistry courses, teaches you some new concepts, introduces you to scientific reasoning, and applies these ideas to important topics regardless of what your major is. It is the key concepts and ideas (the big picture ) that we hope you take from this course (e.g. what you will remember a year from now). They will be foundational for almost any career you choose. CH110 FA11 SAS 3

4 Should you be here? No previous chemistry experience? Chem 101 is a better option; Chem 110 is NOT appropriate for you! Prerequisites for Chem 110 see general course info on website Algebra High school chemistry Chapters 1, 2 in text Familiarity with Chapters 3, 4, 10 NOTE: Chem 110 assumes previous exposure to Chemistry we move very quickly Chem 108 is 1-credit add-on course to Chem 110 for students needing more help (you can add now during the drop/add period) CH110 FA11 SAS 4

5 Who am I? Name: Degrees: Dr. Scott Showalter BS, Cornell University Ph.D., Washington University School of Medicine Hometown: Rochester, NY Job: Assistant Professor of Chemistry Teach and run a research group of seven people including two undergraduate researchers. Research: Biophysical Chemistry: We utilize NMR spectroscopy and other techniques to understand structure-function relationships in medically relevant bio-molecules. CH110 FA11 SAS 5

6 Who are your TAs? If you have been assigned to a section associated with the 3:35 PM lecture: Sarah Black Anthony Cirri Steven Kennedy Carrie Ryan Mike Sennett You are very fortunate to have an excellent group of TAs! Utilize their knowledge to get the most out of this course. Don t let the online homework and quizzes fool you into thinking you don t need them! CH110 FA11 SAS 6

7 Who are YOU? Chem 110 students are an unbelievably diverse group and each lecture tends to have a different bias (major, year in college, etc.). In the next week or so, if you d like (not required), you can me to introduce yourself. I will respond to all such s! sas76@psu.edu Some things you could include: Name Major and year What you want to do when you graduate and get a real job (and whether or not you think chemistry is at all relevant for doing so) Where you re from How much chemistry you had before, how well you did, and how much you liked it Chemistry or science topics you re interested in Why you re taking the class (You have to? Maybe you re actually secretly interested in chemistry? I won t tell ) What do you hope to learn from this class? CH110 FA11 SAS 7

8 My expectations 1. You will take personal responsibility and pride in everything you do for this course. The TAs and I do not give you points: YOU EARN THEM. We are here to help. 2. You will take ownership of this course know the requirements, know and adhere to deadlines, follow procedures and deadlines. The course website, ALEKS, ANGEL, and course packet are excellent resources: utilize them to keep current on course announcements and to find supplemental materials! 3. Be responsible for doing what you need to do to learn and master the material in advance of exams (different for different people), and utilize the numerous available resources. Set up cooperative study groups and do your homework together. There is no curve so you cannot hurt yourself by working with others (which is a stupid mentality anyway). CH110 FA11 SAS 8

9 My expectations (continued) 4. Do not wait until the last minute! That is a sure way to fail, or at the very least fall very far behind and add un-needed stress. 5. Treat everyone with respect at all times everyone is here to learn, do the best that they can, and get the most out of their college experience (even if you don t think so now, you will in 10 years!) Which brings us to Cell Phones: 1. If your cell phone rings in class, one of the TAs or I reserve the right to answer it. 2. I will stop speaking while the call is handled. You and all of your peers will never hear what I may have taught you in the time you choose to waste. 6. The same is true for packing your bags up early; you start packing, I stop talking. And lastly CH110 FA11 SAS 9

10 DON T CHEAT! Cheating is disrespectful of everybody in this room (most importantly yourself) and is not worth the consequences! We (me, the TAs, the proctors) are tech-savvy students and former students who know about all ways to cheat using old tricks and new technology, and we regularly look for such breaches of ethical behavior. Don t think, naively, that you can cheat on a test without getting caught. It s a risk that s not worth taking. While it is not as easy for us to catch you cheating on your online homework and quizzes, remember that they are designed to prepare you for exams and are only as valuable as your integrity makes them. You have been warned. For information regarding the official code of conduct and university academic integrity policy, please see the course website or your Student Packet. CH110 FA11 SAS 10

11 Why study chemistry? Am I ever going to use it? 1. Medicine What fraction of a dose will be bio-available and active? (chemical structure, solubility, equilibrium) 2. Materials and Engineering What materials would you choose to build the various parts of an airplane? (periodicity, chemistry of the elements, reactivity) 3. Energy Which chemicals make the best fuels for a particular purpose? (chemical structure, thermodynamics, reactivity, equilibrium) CH110 FA11 SAS 11

12 Are You an Informed Consumer? 1. The M&M Red Dye Scare was Unnecessary M&Ms never actually contained amaranth, but misinformation caused the product pull 2. Dye production actually created the modern field of chemistry (industrial textiles) 3. Food Dyes remain an interesting problem for chemists to work on: It is easy to make vibrant dyes It is easy to make non-carcinogenic dyes It is hard to make vibrant, non-carcinogenic dyes that don t turn your pee colors too CH110 FA11 SAS 12

13 Are You an Informed Citizen? 1. Coal mining in Pennsylvania and West Virginia has created severe environmental impacts Acid mine drainage results from reaction chemistry that occurs upon wetting metal sulfide mineral deposits. 2. The I-99 Construction project was an environmental disaster right here in State College and it could have been avoide The chemistry of these minerals is known right, Earth and Mineral Scientists? 3. Have you elected policy makers who will make decisions informed by science? CH110 FA11 SAS 13

14 Are You Prepared for YOUR Economy? 1. Do consumers want electric cars? Do they want hydrogen fuel cell cars? No. They want cars that consume less fossil fuel and contribute less to climate change. 2. Where does the electricity or the hydrogen come from? Is it coal? Oil? Natural gas? Uh oh 3. Chemists will participate in securing your energy future What jobs are you training for? CH110 FA11 SAS 14

15 Why study chemistry? Because it is the central science. It is the study of matter & its transformations. In this course you will: Learn the language of chemistry and gain general knowledge Learn to understand how structure affects function Connect microscopic properties to macroscopic properties Learn how energy is stored in molecules and how we can use it Learn modern analytical techniques How do we use scientific reasoning to find the solution to interesting problems and address how well we know them? Course Method: Atoms First Approach Pay attention to the syllabus. We will not move through the book in chapter order! CH110 FA11 SAS 15

16 Lectures On to the administrative stuff also be sure to check ANGEL for information! 1. Read the text AND make an effort to solve suggested book and packet homework problems BEFORE the lecture 2. Print lecture notes and try any blank questions before lecture 3. Go back to your attempts at the homework and fill in missing information after lecture. 4. Take notes! Ask questions! Be ready to answer questions! 5. Practice in-class problem solving 6. Demos will be on the exam. CH110 FA11 SAS 16

17 Info About Lecture Notes Lecture notes will start with a page like this one to reinforce the syllabus: Prepare for Recitation September 1 st ALEKS Prep Assignment due August 26 th ALEKS Objective 1 due August 30 th ANGEL Quiz 1, September 1 st Lecture 1: August 22 nd (Course Introduction) Lecture 2: August 24 th Lecture 3: August 26 th Lecture 4: August 29 th Read: Ch. 1; Ch ; Ch ; Ch Additional Preparation*: BLB 1: 17; Packet 1: 1-5 BLB 2: 4,31; Packet 2: 1,2,3 BLB 5: 3,25,28; BLB 6: 4,25,27; Packet 6: 1-5 *ALEKS work is necessary but not sufficient for exam level preparation! Do not neglect the packet! CH110 FA11 SAS 17

18 Info About Lecture Notes Lectures will contain practice problems like this one that will reflect the style and difficulty of exam questions: An unknown liquid has a density of 2.14 g/ml. How many ml would a 6.42 g sample of this liquid occupy? A) 3.00x10-3 ml B) 2.14 ml C) 3.00 ml D) 6.42 ml E) 2.14x10 3 ml Try to work these problems before lecture. I will work the problem in class and if you have trouble with it, seeing where my approach is different from yours may help. CH110 FA11 SAS 18

19 Homework and Quizzes Homework Your syllabus and my lecture notes contain suggested problems to work. Your graded homework is done online through ALEKS the Tuesday before each recitation (Your TA will explain.) TAs will hold office hours regularly in the Chemistry Resource Room (211 Whitmore) if you need help. Quizzes Quizzes are administered online through ANGEL and are open only on the Thursday to which they are assigned. Recitation Recitation is there to help you learn problem solving skills necessary to perform to your full potential on exams. You will complete a brief in-recitation query problem to vet your attendance. CH110 FA11 SAS 19

20 Did You Learn to Study in High School? No? I Didn t Think So! Welcome to college. You aren t in high school anymore. You and all of your peers are smart We aim to hold you to a higher standard There is no shame in getting help Assistance with note taking, reading comprehension, test anxiety, and time management is available We will organize guided study groups that offer free tutoring to all students CH110 FA11 SAS 20

21 Fall 2011 Chem 110 Grading Midterm Exam 1 17% Monday September 19, 6:30 PM Midterm Exam 2 17% Monday October 10, 6:30 PM Midterm Exam 3 17% Monday November 7, 6:30 PM Final Exam 29% Scheduled by the Registrar closer to the end of the semester. Total Emphasis for Exams: 80% Note the dates of these exams NOW Recitation Queries 5% ANGEL Quizzes 7.5% ALEKS Homework 7.5% Total Coursework Grade 20% EXTRA CREDIT POSSIBLE 1% There is no extra credit beyond the ALEKS completion bonus. Do not waste your time asking for any. CH110 FA11 SAS 21

22 Fall 2011 Chem 110 Grading Minimum scores for letter grades A/A- 90% 180 pts B+/B/B- 80% 160 pts C+/C 69% 138 pts D 57% 114 pts There will be no curve. Do not waste your time asking for one. The TAs and I do not control your grade: YOU DO! 20% of your grade comes from quizzes and homework that you have total control over and have every opportunity to score 100% on. You can earn 2 bonus points (1% course grade bonus) simply by completing the ALEKS material in its entirety. CH110 FA11 SAS 22

23 Lecture options All lecture options are M/W/F in Forum 108 Dr. Mary Bojan, 8:00 AM Dr. Ben Lear, 9:05 AM Dr. Linlin Jensen, 10:10 AM Dr. Squire Booker, 11:15 AM Dr. Tae-Hee Lee, 2:30 PM Dr. Scott Showalter, 3:35 PM Dr. Alan Benesi, 4:40 PM You are permitted to attend any lecture you wish, which will help resolve one-time conflicts that may arise. You are strongly encouraged to attend your assigned lecture as this is the only one your assigned TA will attend and we all have slightly different styles! CH110 FA11 SAS 23

24 Overview of Chem 110 Overall Key Themes Structure affects function Connect macroscopic to microscopic Study of energy Problem solving skills Course Method: Atoms First Approach Chapter 1: Matter and Measurement Chapter 2: Atoms, Molecules and Ions Chapter 6: Structure of the Atom Chapter 7: Properties of the Atom Chapter 8: Bonding Between Atoms Chapter 9: Structure of Molecules Chapters 10, 11, 13: Properties of Molecules Chapters 3, 4, 10: Reactions Between Molecules Chapters 5, 15: Rules Governing Reactions CH110 FA11 SAS 24

25 Exam 1 Concepts You Should Know: Chapter 2: Nomenclature What do the numbers on the periodic table mean? How do we name common ions, acids, etc.? Chapter 3: Chemical Formulas What is mass percent? What is a mole? What is molecular weight? What are the empirical formula and the molecular formula of a compound? Chapter 6: Energy, Atoms, Orbitals, and the Origins of the Periodic Table What is the relationship between photons, their wavelength, their frequency, and their energy? How does all that stuff about photons help chemists to understand the nature of atoms? What is an orbital? How is it defined? What is the electron configuration of an atom? How do I represent it? How do the shape, size, and number of orbitals help me to understand the periodic table? CH110 FA11 SAS 25

26 Exam 1 Concepts You Should Know: Chapter 7: Periodic Trends What are ionization energy, electron affinity, and electronegativity? What are the trends in atomic size? How are the sizes of atoms and ions related? How do these show up in the periodic table? Chapter 8: Bonding and Lewis Structures What are the three types of bonding? How do we describe bonding in ionic solids? How is covalent bonding described in terms of enthalpy, strength, bond order, etc.? What is a Lewis structure? What do we learn about a molecule when we see that it has more than one Lewis structure? How do you use the octet rule and its violations to help predict Lewis structures? CH110 FA11 SAS 26

27 Exam 2 Concepts You Should Know: Chapter 3: Chemical Formulas Again How do we determine the composition of a compound from the various chemical formulas? What is combustion analysis? Chapter 25: Organic Molecules What are the properties of hydrocarbons? What do the functional groups we learned about look like and how do they affect properties? Chapter 9: Bonding and Geometry What are the shapes of the electron domain and molecular geometries we have studied? What is molecular polarity and how is it determined by shape? What are sigma and pi bonds? How do hybrid orbitals relate to molecular shape and bond angles? Chapter 11: Intermolecular Forces What are the IMFs we have learned about? How do IMFs impact boiling and melting points? CH110 FA11 SAS 27

28 Exam 3 Concepts You Should Know: Chapter 10: Gases What are the properties of ideal gases? What is the partial pressure of a gas in a mixture? How does kinetic molecular theory connect the microscopic properties of gases with observables? How are real gases different from ideal gases? Chapter 18: Atmospheric Chemistry What reactions occur in the atmosphere? How do Chem 110 concepts show up in the atmosphere and environment? Chapter 11: Intermolecular Forces What is heat capacity? What are the properties of liquids? How do you use phase diagrams? Chapter 13: (Aqueous) Solutions What are electrolytes and how do we calculate the concentration of chemicals in solution? What is meant by solubility and saturation? What are colligative properties? CH110 FA11 SAS 28

29 Final Concepts You Should Know: Chapter 3: Chemical Equations How do I balance a chemical equation? What is the percent yield of a reaction? Chapter 4: Chemical Reactions What are precipitation reactions? What are metathesis reactions? What are redox reactions in particular and what are oxidation numbers? What are net ionic equations and spectator ions? Chapter 5: Thermochemistry What is enthalpy and the enthalpy of a reaction? What is heat of formation? How do bond enthalpies relate to both of these? What is Hess s Law? Chapter 15: Chemical Equilibrium What is an equilibrium constant? How do you use an ICE table to calculate equilibrium constants or concentrations? What is LeChâtlier s principle? CH110 FA11 SAS 29

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