Pestgon. Safety Data Sheets April 1, PestgonTermite Call toll-free for an inspection. Did you know Pestgon has a termite divison:

Transcription

1 Pestgon 3612 Ocean Ranch Blvd Oceanside, CA Cell Office Office Fax: Website: Did you know Pestgon has a termite divison: PestgonTermite Call toll-free for an inspection Safety Data Sheets April 1, 2016 Important Disclosure... Page 2 Advion Cockroach Gel Bait...Pages 3-9 Avert Dry Flowable...Pages Avitrol... Pages Bedlam Plus... Pages CB Pages Contrac... Pages Deadline MP... Pages Delta Dust... Pages Demand CS... Pages Eco PCO ACU... Pages Endzone... Pages Essentria IC3...Pages Final...Pages Fumitoxin Tablets...Pages InVict Xpress Granular Bait... Pages Martin s Gopher Bait Pages Maxforce FC Magnum... Pages Maxforce Fly Spot Bait... Pages Maxforce Granular Fly Bait... Pages Niban FG... Pages Onslaught FastCap... Pages Phantom... Pages Precor 2000 Plus... Pages Precor IGR... Pages PTB Phantom Pressurized... Pages Purge III... Pages Pyrethrin Fogger... Pages Pyrocide Pages RCO Omega Gopher Grain Bait... Pages Talstar PL... Pages Termidor SC... Pages Terro PCO... Pages Wasp Freeze... Pages ZP Rodent Oat Bait... Pages

2 Return to Index... Important Disclosure Please read carefully RETAIN FOR YOUR FILES 4/1/2016 RIGHT TO KNOW: Prior to application of pesticides to your property, State law requires that you be given the following information: CAUTION - PESTICIDES ARE TOXIC CHEMICALS. Structural Pest Control Operators are licensed and regulated by the Structural Pest Control Board and apply pesticides which are registered and approved for use by the California Department of Food and Agriculture and the United States Environmental Protection Agency. Registration is granted when the state finds that, based on existing scientific evidence, there are no appreciable risks if proper use conditions are followed or that the risks are outweighed by the benefits. The degree of risk depends upon the degree of exposure; so exposure should be minimized. If, within 24 hours following application, you experience symptoms similar to common seasonal illnesses comparable to the flu, contact your physician or poison control center ( ) and your pest control operator immediately. If rodenticide ingestion occurs, you may experience symptoms of mild shock/bleeding, an anticoagulant reaction. For further information, contact any of the following: Service Information: Pest Control Operator , Pestgon Incorporated Health Information: County Health Department Riverside Orange Application Information: County Ag Commissioner Riverside Orange Los Angeles San Bernardino Los Angeles San Bernardino Regulatory Information: Structural Pest Control Board 2005 Evergreen St., Ste 1500, Sacramento, CA San Diego San Diego TERMS AND NOTICES: The total amount of this contract for any and all pest management service work is due and payable upon receipt of each billing invoice. Only target pests checked on the original contract are included in the Regular Scheduled Service (RSS). Should Pestgon Incorporated fail to comply with specifications of the service contract, they shall be given a thirty (30) day written notice to comply and render satisfactory service, and if, at the end of such thirty-day notice, unsatisfactory conditions persist, customer reserves the right to cancel the contract without further notice. In any case, either party shall give written notice thirty (30) days prior to cancellation date. SERVICE GUARANTEE: The PESTGON INCORPORATED Service Guarantee is a promise to retreat target pests during the term of the service contract, not a guarantee of efficacy or safety. If necessary, PESTGON INCORPORATED agrees to call back during the Service Guarantee period unless otherwise noted and provide retreat service at no extra charge. After the SG period, it will be understood by both parties that target pests are controlled and any other pest management services are chargeable to the customer. Charges for Regular Scheduled Service shall continue uninterrupted by the Service Guarantee unless otherwise agreed. Upon being instructed or advised, either in writing or orally, if the customer fails to make proper preparations and/or corrections for pest management service, Pestgon Incorporated cannot assure satisfactory service and the Service Guarantee will be void. RESPONSIBILITY: Customer agrees to inform PESTGON INCORPORATED of any allergic or pregnant persons occupying the premises prior to any indoor treatment and PESTGON agrees to make reasonable effort to inquire. PESTGON shall take every reasonable precaution to use pest control products labeled to provide the maximum safety required by the United States Environmental Protection Agency in order to protect persons, pets and plants. However, PESTGON is not responsible for their health or wellbeing. Customer agrees to follow all precautionary instructions, written or oral, and to hold pest control operator harmless from any and all claims, damages and expenses arising out of pests and/or pest management services pursuant to this contract. PRIME CONTRACT: In compliance with the Structural Pest Control Board, the California Department of Food and Agriculture and the United States Environmental Protection Agency, this document, even as an addendum, is the prime contract for pest control services by and between PESTGON INCORPORATED and the owners and authorized agents of the property herein addressed. Consent by the Owner (s) or authorized agent (s) and performance by PESTGON of any part of this contract binds this contractual agreement and its terms as the prime contract. No other contractual agreement, attachments or addendum shall have any force to precede, prevail, invalidate, impair or negate this prime contract and its terms. Any changes to this contractual agreement shall be only by written agreement, which is and shall be expressly understood to be an addendum hereto. In case any one or more of the parts or provisions of this contractual agreement shall be invalid, illegal or unenforceable in any respect, the validity, legality and enforceability of the remaining parts and provisions contained herein shall not be in any way invalidated, negated, affected or impaired thereby. PESTICIDE DISCLOSURE NOTICE: California law (8538 Business & Professions Code and California Code of Regulations) requires that we provide you with a pesticide disclosure notice and the following chemical information prior to our initial pest control service. Property Managers, please notify your tenants that there will be ongoing pest control performed on the exterior common areas. If we treat the interior of a unit, we will leave a copy of this pesticide disclosure notice inside the unit for the tenant. CHEMICAL INFORMATION AND APPLICATION RATES PER EPA LABEL INSTRUCTIONS: Advion Cockroach Gel Bait = 0.6% Indoxacarb (S-Enantiomer) EPA Avert Dry Flowable = 0.050% Abamectin B1, EPA Avitrol = 0.5% 4-Aminopyridine, EPA Bedlam Plus Insecticide = 0.4% 3-phenoxybenzyl-(1RS, 3RS, 1RS, 3SR)-2, 2-dimethyl-3-(2- methylprop-1-enyl) cycloproposanecarboxylate, 1.0% N-Ocyl bicycloheptene dicarboximide, Imicloprid 0.05%, EPA CB-80 = 0.5% Pyrethrins, EPA Contrac Rodent Bait = 0.005% Bromadiolone, EPA Deadline M-Ps Snail Bait = 4% Metaldehyde, EPA Delta Dust = 0.05% Deltamethrin, EPA Demand CS = 0.06% Lambda-Cyhalothrin, EPA EcoPCO ACU = 0.1% 2-Phenethyl Propionate, EPA Endzone = 4.4% AceTamiprid EPA Essentria IC3 Insect Concentrate = Rosemary Oil 10%, Geraniol 5%, Wintergreen Oil 37%, White Mineral Oil 40%, Vanilin 3%, EPA Exempt Final All-Weather Blox =.005% Brodifacoum, EPA Fumitoxin = 55% Aluminum Phosphide, EPA InVict Express Granular Bait, Imidacloprid 0.5%, EPA Martins Gopher Grain Bait 50 = 0.5% Strychnine Alkaloid, EPA Maxforce FC Magnum=.05% Fipronl, Maxforce Fly Spot Bait = 10% Imidacloprid, 1-[6-Chloro-3-pyridinyl)methyl], 0.1% Z-9-Tricosene, EPA Niban = 0.5% Orthoboric Acid, EPA Maxforce Granular Fly Bait = Imidacloprid, 1-[(g-chloro-3-pyridinyl)methyl]-N nitro-2-imidazolidin-imine_0.5% Z-9-Tricosene_0.1% EPA Niban = 0.5% Orthoboric Acid, EPA Onslaught FastCap Spider & Scorpion Insecticide = 6.40% Esfenvalerate, 1.60% Prallethrin, 8.0% Piperonyl Butoxide, EPA Phantom Insecticide = 21.45% Chlorfenapyr, EPA Precor 2000 Plus = 0.085% Methoprene, 0.35% pemethrin, 0.3% Phenothrin, 2% N-octylbicycloheptene, dicarboximide, 1.4% Piperonyl butoxide, EPA Precor Plus IGR = 1.2% [S]-Methoprene EPA PTB Phantom II Pressurized = 0.5% ChlorFenapyr.4-bromo-2(4-chlorophenyl)-1-(eThoxymethyl)-5- (trifluorometh- yl)-1h-pyrrole-3-caronitrile, EPA Purge III Insecticide = 0.975% Pyrethrins, 1.950% Piperonyl Butoxide, 3.05% N-octylbicyclopheptene, EPA Pyrethrin Fogger = 0.5% Pyrethrins, 1% Piperonyl Butoxide, technical, 1% N-OctylBicycloheptene Dicarboximide, EPA GA-1 Pyrocide 300 = 3.0% Pyrethrins - 6.0% *Piperonyl butoxide, Technical ** 9.57% N-Octly bicychloheptene dicabonximide, EPA RCO Omega Gopher Grain Bait = 0.5% Strychnine Alkaloid, EPA Talstar PC Granular, 0.2 Bifenthrin, EPA Termidor SC = 9.1% Fipronil, EPA Terro PCO Liquid Ant Bait Stations = 5.40% Sodium Tetraborate Decahydrate (Borax) EPA Wasp-Freeze = 0.129% Allethrin, EPA ZP Rodent Bait = 2% Zinc Phosphide, EPA Pestgon Incorporated, 3612 Ocean Ranch Blvd, Oceanside, CA pestgon@pacbell.net

3 Return to Index... SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 DuPont Advion Cockroach Gel Bait Version 2.2 Revision Date Ref This SDS adheres to the standards and regulatory requirements of the European Union and may not meet the regulatory requirements in other countries. 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Product information Product name Synonyms Use of the Substance/Mixture : DuPont Advion Cockroach Gel Bait : B : Biocidal product Company : DuPont de Nemours South Africa (Pty) Ltd 34 Whiteley Road Block B, 1st Floor Melrose Arch South Africa Telephone : Telefax : Emergency telephone number address : +27 (0) : sds-support@che.dupont.com 2. HAZARDS IDENTIFICATION Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Avoid treating areas that are easily accessible to children and pets. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS-No. EC-No. Registration number Indoxacarb (S-Enantiomer) Classification Concentration [%] T; R25 R43 N; R50/53 0,6 For the full text of the R-phrases mentioned in this Section, see Section FIRST AID MEASURES General advice Inhalation Skin contact : Never give anything by mouth to an unconscious person. : No hazards which require special first aid measures. Is not considered a potential route of exposure. Consult a physician if necessary. : No hazards which require special first aid measures. Wash with water and soap as a precaution. In the case of skin irritation or allergic reactions see a 1/7

4 SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 DuPont Advion Cockroach Gel Bait Version 2.2 Revision Date physician. Ref Eye contact Ingestion : No hazards which require special first aid measures. Hold eye open and rinse slowly and gently with water for minutes. If eye irritation persists, consult a specialist. : No hazards which require special first aid measures. Do not induce vomiting without medical advice. Rinse mouth with water. Consult a physician if necessary. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Extinguishing media which shall not be used for safety reasons Specific hazards during fire fighting Special protective equipment for fire-fighters Further information : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment., Water, Water spray, Foam, Dry chemical, Carbon dioxide (CO2), : High volume water jet, (contamination risk), : Not a fire or explosion hazard. : Wear self-contained breathing apparatus and protective suit. : Prevent fire extinguishing water from contaminating surface water or the ground water system. Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. (on small fires) If area is heavily exposed to fire and if conditions permit, let fire burn itself out since water may increase the area contaminated. Prevent fire extinguishing water from contaminating surface water or the ground water system. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Environmental precautions Methods for cleaning up : Use personal protective equipment. Refer to protective measures listed in sections 7 and 8. : Use appropriate container to avoid environmental contamination. Prevent further leakage or spillage. Do not allow material to contaminate ground water system. Do not flush into surface water or sanitary sewer system. Local authorities should be advised if significant spillages cannot be contained. If the spill area is porous, the contaminated material must be collected for subsequent treatment or disposal. If the product contaminates rivers and lakes or drains inform respective authorities. : Clean-up methods - small spillage For small spills, use cloth or paper towels and place collected material and towels in appropriate container for disposal. Clean-up methods - large spillage Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Sweep up or vacuum up 2/7

5 SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 DuPont Advion Cockroach Gel Bait Version 2.2 Revision Date Ref spillage and collect in suitable container for disposal. Flush away traces with water. Additional advice : Dispose of in accordance with local regulations. 7. HANDLING AND STORAGE Handling Advice on safe handling Advice on protection against fire and explosion : Before using, read the product bulletin. Wear personal protective equipment. Do not get in eyes or mouth or on skin. Do not store or consume food, drink or tobacco in areas where they may become contaminated with this material. Wash hands before breaks and immediately after handling the product. Close container after each use. For personal protection see section 8. : Do not apply this product around electrical equipment due to the possibility of shock hazard. Storage Requirements for storage areas and containers Advice on common storage : Store in original container. Keep in properly labelled containers. Keep tightly closed in a dry and cool place. Store in a place accessible by authorized persons only. Keep out of the reach of children. Keep away from food, drink and animal feedingstuffs. : No special restrictions on storage with other products. Storage temperature : > 3 C Other data : Stable under recommended storage conditions. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Personal protective equipment Respiratory protection : No personal respiratory protective equipment normally required. Hand protection Eye protection Hygiene measures Protective measures : Material: Protective gloves The suitability for a specific workplace should be discussed with the producers of the protective gloves. : Safety glasses with side-shields conforming to EN166 : Regular cleaning of equipment, work area and clothing. Contaminated work clothing should not be allowed out of the workplace. Avoid prolonged contact with eyes, skin and clothing. When using do not eat, drink or smoke. Wash hands before breaks and immediately after handling the product. Keep away from food, drink and animal feedingstuffs. For environmental protection remove and wash all contaminated protective equipment before re-use. Dispose of rinse water in accordance with local and national regulations. : No PPE is specified however, avoid contact with skin, eyes, and clothing. 3/7

6 SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 DuPont Advion Cockroach Gel Bait Version 2.2 Revision Date Ref PHYSICAL AND CHEMICAL PROPERTIES Form : gel, Colour : light tan, Odour : slight, ph : 5,4 at 10 g/l ( 25 C), Method: CIPAC MT 75 Flash point : > 100 C Flammability (solid, gas) Oxidizing properties Explosive properties : Does not sustain combustion. : The product is not oxidizing. : Not explosive Density : 1,123 g/cm3 at 22 C 10. STABILITY AND REACTIVITY Conditions to avoid Materials to avoid Hazardous reactions : Temperature : < 3 C Protect from frost. : No materials to be especially mentioned. : None reasonably foreseeable. No dangerous reaction known under conditions of normal use. Stable at normal temperatures and storage conditions. 11. TOXICOLOGICAL INFORMATION Acute oral toxicity : LD50/ rat: > mg/kgmethod: OECD Test Guideline 425 (Data on the product itself) Information source: Internal study report Acute inhalation toxicity Indoxacarb (S- Enantiomer) Acute dermal toxicity Skin irritation Eye irritation : LC50/ 4 h/ rat female: 4,2 mg/l : LD50/ rat mg/kg Method: OECD Test Guideline 402 (Data on the product itself) Information source: Internal study report : rabbit Result: No skin irritation Method: OECD Test Guideline 404 (Data on the product itself) Information source: Internal study report : rabbit Result: No eye irritation Method: OECD Test Guideline 405 (Data on the product itself) Information source: Internal study report 4/7

7 SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 DuPont Advion Cockroach Gel Bait Version 2.2 Revision Date Ref Sensitisation : Local lymph node test mouse Result: Animal test did not cause sensitization by skin contact. Method: OECD Test Guideline 429 (Data on the product itself) Information source: Internal study report Mutagenicity assessment Indoxacarb (S-Enantiomer) Carcinogenicity assessment Indoxacarb (S- Enantiomer) : Tests on bacterial or mammalian cell cultures did not show mutagenic effects., Did not cause genetic damage in animals. : Did not show carcinogenic effects in animal experiments. Toxicity to reproduction assessment Indoxacarb (S- : Animal testing did not show any effects on fertility. Enantiomer) 12. ECOLOGICAL INFORMATION Elimination information (persistence and degradability) Biodegradability Bioaccumulation : Not readily biodegradable. Estimation based on data obtained on active ingredient. : This mixture contains no substance considered to be persistent, bioaccumulating nor toxic (PBT). This mixture contains no substance considered to be very persistent nor very bioaccumulating (vpvb). Toxicity to fish Indoxacarb (S- Enantiomer) : LC50 / 96 h/ Oncorhynchus mykiss (rainbow trout) : 0,65 mg/l Aquatic toxicity Indoxacarb (S- Enantiomer) : / EC50/ 48 h/ Daphnia magna (Water flea): 0,256 mg/l Chronic toxicity to fish Indoxacarb (S- Enantiomer) : Early Life-Stage/ NOEC/ 90 d/ Oncorhynchus mykiss (rainbow trout): 0,15 mg/l Method: Chronic toxicity to aquatic Invertebrates Indoxacarb (S- Enantiomer) : / NOEC/ 21 d/ Daphnia magna (Water flea): 1 mg/l Further information on ecology Additional ecological information : No data is available on the product itself. Do not apply directly to water, or to areas where surface water is present, or to intertidal areas below the mean high 5/7

8 SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 DuPont Advion Cockroach Gel Bait Version 2.2 Revision Date water mark. Ref DISPOSAL CONSIDERATIONS Product Contaminated packaging : Do not contaminate ponds, waterways or ditches with chemical or used container. Wastes resulting from the use of this product must be disposed of on site or at an approved waste disposal facility. In accordance with local and national regulations. : Dispose of in accordance with local regulations. 14. TRANSPORT INFORMATION Further information : Not dangerous goods in the meaning of ADR/RID, ADNR, IMDG-Code, ICAO/IATA-DGR 15. REGULATORY INFORMATION Labelling according to EC Directives Hazardous components: Indoxacarb (S-Enantiomer) R-phrase(s) : R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S-phrase(s) : S 2 Keep out of the reach of children. S13 Keep away from food, drink and animal feedingstuffs. S35 This material and its container must be disposed of in a safe way. S46 If swallowed, seek medical advice immediately and show this container or label. Special labelling of certain mixtures Sensitising components : To avoid risks to man and the environment, comply with the instructions for use. contains: Indoxacarb (S-Enantiomer) Indoxacarb, (R-enantiomer) May produce an allergic reaction. 16. OTHER INFORMATION Text of R-phrases mentioned in Section 3 R25 Toxic if swallowed. R43 May cause sensitization by skin contact. 6/7

9 SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 DuPont Advion Cockroach Gel Bait Version 2.2 Revision Date Ref R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Further information Before use read DuPont's safety information., Take notice of the directions of use on the label. Registered trademark of E.I. du Pont de Nemours and Company Significant change from previous version is denoted with a double bar. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The above information relates only to the specific material(s) designated herein and may not be valid for such material(s) used in combination with any other materials or in any process or if the material is altered or processed, unless specified in the text. 7/7

10 Return to Index... Safety Data Sheet AVERT DRY FLOWABLE ROACH BAIT Revision date : 2011/07/18 Page: 1/7 Version: 3.2 ( /SDS_CPA_US/EN) 1. Product and Company Identification Company BASF CORPORATION 100 Campus Drive Florham Park, NJ 07932, USA 24 Hour Emergency Response Information CHEMTREC: BASF HOTLINE: HELP Registrant: Whitmire Micro-Gen Research Laboratories, Inc Tree Court Industrial Blvd. St. Louis, MO Substance number: Synonyms: Abamectin B1 2. Hazards Identification Emergency overview CAUTION: KEEP OUT OF REACH OF CHILDREN. KEEP OUT OF REACH OF DOMESTIC ANIMALS. HARMFUL IF SWALLOWED. HARMFUL IF INHALED. HARMFUL IF ABSORBED THROUGH SKIN. Avoid inhalation of dusts. Avoid contact with the skin, eyes and clothing. Wash thoroughly after handling. See Product Label for additional precautionary statements. State of matter: solid Colour: brown Odour: mild Potential health effects Primary routes of exposure: Routes of entry for solids and liquids include eye and skin contact, ingestion and inhalation. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route of entry for liquified gases. Acute toxicity: Relatively nontoxic after single ingestion. Slightly toxic after short-term skin contact. Irritation / corrosion: May cause slight but temporary irritation to the eyes. Contact may result in skin irritation.

11 Safety Data Sheet AVERT DRY FLOWABLE ROACH BAIT Revision date : 2011/07/18 Page: 2/7 Version: 3.2 ( /SDS_CPA_US/EN) Sensitization: Skin sensitizing effects were not observed in animal studies. 3. Composition / Information on Ingredients CAS Number Content (W/W) Chemical name % Abamectin % Proprietary ingredients 4. First-Aid Measures General advice: First aid providers should wear personal protective equipment to prevent exposure. Remove contaminated clothing. Move person to fresh air. If person is not breathing, call 911 or ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or physician for treatment advice. Have the product container or label with you when calling a poison control center or doctor or going for treatment. If inhaled: Remove the affected individual into fresh air and keep the person calm. If on skin: Rinse skin immediately with plenty of water for minutes. If in eyes: Hold eyes open and rinse slowly and gently with water for 15 to 20 minutes. Remove contact lenses, if present, after first 5 minutes, then continue rinsing. If swallowed: Have person sip a glass of water if able to swallow. Do not induce vomiting. Never induce vomiting or give anything by mouth if the victim is unconscious or having convulsions. Note to physician Treatment: Treat symptomatically. 5. Fire-Fighting Measures Flash point: Substance/product is non-flammable. Suitable extinguishing media: dry powder, carbon dioxide, water spray Hazards during fire-fighting: carbon monoxide, carbon dioxide, If product is heated above decomposition temperature, toxic vapours will be released. The substances/groups of substances mentioned can be released in case of fire. Protective equipment for fire-fighting: Firefighters should be equipped with self-contained breathing apparatus and turn-out gear. Further information: Evacuate area of all unnecessary personnel. Contain contaminated water/firefighting water. Do not allow to enter drains or waterways.

12 Safety Data Sheet AVERT DRY FLOWABLE ROACH BAIT Revision date : 2011/07/18 Page: 3/7 Version: 3.2 ( /SDS_CPA_US/EN) 6. Accidental release measures Personal precautions: Take appropriate protective measures. Clear area. Shut off source of leak only under safe conditions. Extinguish sources of ignition nearby and downwind. Ensure adequate ventilation. Wear suitable personal protective clothing and equipment. Environmental precautions: Do not discharge into the subsoil/soil. Do not discharge into drains/surface waters/groundwater. Contain contaminated water/firefighting water. A spill of or in excess of the reportable quantity requires notification to state, local and national emergency authorities. This product is not regulated by CERCLA ('Superfund'). Cleanup: Dike spillage. Sweep/shovel up. Avoid raising dust. Use wet cleaning methods when applicable. Place into suitable containers for reuse or disposal in a licensed facility. Spilled substance/product should be recovered and applied according to label rates whenever possible. If application of spilled substance/product is not possible, then spills should be contained, solidified, and placed in suitable containers for disposal. After decontamination, spill area can be washed with water. Collect wash water for approved disposal. 7. Handling and Storage Handling General advice: RECOMMENDATIONS ARE FOR MANUFACTURING, COMMERCIAL BLENDING, AND PACKAGING WORKERS. PESTICIDE APPLICATORS & WORKERS must refer to the Product Label and Directions for Use attached to the product. Provide good ventilation of working area (local exhaust ventilation if necessary). Keep away from sources of ignition - No smoking. Keep container tightly sealed. Protect against heat. Handle and open container with care. Do not open until ready to use. Once container is opened, content should be used as soon as possible. Provide means for controlling leaks and spills. Follow label warnings even after container is emptied. The substance/ product may be handled only by appropriately trained personnel. Avoid all direct contact with the substance/product. Avoid contact with the skin, eyes and clothing. Avoid inhalation of dusts/mists/vapours. Wear suitable personal protective clothing and equipment. Protection against fire and explosion: The relevant fire protection measures should be noted. Fire extinguishers should be kept handy. Avoid all sources of ignition: heat, sparks, open flame. Avoid extreme heat. Ground all transfer equipment properly to prevent electrostatic discharge. Electrostatic discharge may cause ignition. Storage General advice: Keep only in the original container in a cool, dry, well-ventilated place away from ignition sources, heat or flame. Protect containers from physical damage. Protect against contamination. The authority permits and storage regulations must be observed. Storage incompatibility: General advice: Segregate from incompatible substances. Segregate from foods and animal feeds. Segregate from textiles and similar materials. Storage stability: May be kept indefinitely if stored properly. If an expiry date is mentioned on the packaging/label this takes priority over the statements on storage duration in this safety data sheet. 8. Exposure Controls and Personal Protection Users of a pesticidal product should refer to the product label for personal protective equipment requirements.

13 Safety Data Sheet AVERT DRY FLOWABLE ROACH BAIT Revision date : 2011/07/18 Page: 4/7 Version: 3.2 ( /SDS_CPA_US/EN) Advice on system design: Whenever possible, engineering controls should be used to minimize the need for personal protective equipment. Personal protective equipment RECOMMENDATIONS FOR MANUFACTURING, COMMERCIAL BLENDING, AND PACKAGING WORKERS: Respiratory protection: Wear respiratory protection if ventilation is inadequate. Breathing protection if breathable aerosols/dust are formed. Hand protection: Chemical resistant protective gloves, Protective glove selection must be based on the user's assessment of the workplace hazards. Eye protection: Safety glasses with side-shields. Tightly fitting safety goggles (chemical goggles). Wear face shield if splashing hazard exists. Body protection: Body protection must be chosen depending on activity and possible exposure, e.g. head protection, apron, protective boots, chemical-protection suit. General safety and hygiene measures: RECOMMENDATIONS FOR MANUFACTURING, COMMERCIAL BLENDING, AND PACKAGING WORKERS Wear long sleeved work shirt and long work pants in addition to other stated personal protective equipment. Work place should be equipped with a shower and an eye wash. Handle in accordance with good industrial hygiene and safety practice. Personal protective equipment should be decontaminated prior to reuse. Gloves must be inspected regularly and prior to each use. Replace if necessary (e.g. pinhole leaks). Take off immediately all contaminated clothing. Store work clothing separately. Hands and/or face should be washed before breaks and at the end of the shift. No eating, drinking, smoking or tobacco use at the place of work. Keep away from food, drink and animal feeding stuffs. 9. Physical and Chemical Properties Form: powder Odour: mild Colour: brown ph value: 4.9 ( 1 %(m)) Melting point: not applicable Boiling point: not applicable Relative density: ( 23 C) Bulk density: kg/m3 Vapour density: not determined Solubility in water: insoluble 10. Stability and Reactivity Conditions to avoid: Avoid all sources of ignition: heat, sparks, open flame. Avoid prolonged storage. Avoid electro-static discharge. Avoid contamination. Avoid prolonged exposure to extreme heat. Avoid extreme temperatures. This product may form an explosive mixture if: 1. the dust is suspended in the atmosphere as a dust cloud AND 2. the concentration of the dust is above the lower explosion limit (LEL) AND 3. the limiting oxygen concentration (LOC) is exceeded. Substances to avoid: caustics

14 Safety Data Sheet AVERT DRY FLOWABLE ROACH BAIT Revision date : 2011/07/18 Page: 5/7 Version: 3.2 ( /SDS_CPA_US/EN) Hazardous reactions: The product is chemically stable. No hazardous reactions when stored and handled according to instructions. Decomposition products: Hazardous decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated. Thermal decomposition: Possible thermal decomposition products: carbon monoxide, carbon dioxide Stable at ambient temperature. If product is heated above decomposition temperature toxic vapours may be released. To avoid thermal decomposition, do not overheat. Corrosion to metals: Corrosive effects to metal are not anticipated. Oxidizing properties: Not an oxidizer. 11. Toxicological information Acute toxicity Oral: Type of value: LD50 Species: rat (male/female) Value: > 5,000 mg/kg (other) Inhalation: Type of value: LC50 Not inhalable due to the physico-chemical properties of the product. Dermal: Type of value: LD50 Species: rabbit (male/female) Value: > 2,000 mg/kg (other) Irritation / corrosion Skin: Species: rabbit Result: non-irritant Method: Primary skin irritation test Eye: Species: rabbit Result: non-irritant Method: Primary eye irritation test May cause slight irritation to the eyes. Genetic toxicity Information on: Abamectin Results from a number of mutagenicity studies with microorganisms, mammalian cell culture and mammals are available. Taking into account all of the information, there is no indication that the substance is mutagenic Carcinogenicity Information on: Abamectin

15 Safety Data Sheet AVERT DRY FLOWABLE ROACH BAIT Revision date : 2011/07/18 Page: 6/7 Version: 3.2 ( /SDS_CPA_US/EN) In long-term studies in rats and mice in which the substance was given by feed, a carcinogenic effect was not observed Reproductive toxicity Information on: Abamectin The results of animal studies suggest a fertility impairing effect with high doses Development: Information on: Abamectin Causes developmental effects in animals at high, maternally toxic doses Ecological Information Fish Information on: Abamectin Acute: Oncorhynchus mykiss/lc50 (96 h): mg/l Aquatic invertebrates Information on: Abamectin Acute: Daphnia magna/ec50 (48 h): mg/l Aquatic plants Information on: Abamectin Toxicity to aquatic plants: OECD Guideline 201 static green algae/ec50 (72 h): > 6.1 mg/l Not readily biodegradable (by OECD criteria) Disposal considerations Waste disposal of substance: Pesticide wastes are regulated. If pesticide wastes cannot be disposed of according to label instructions, contact the State Pesticide or Environmental Control Agency or the Hazardous Waste representative at the nearest EPA Regional Office for guidance. Container disposal: Rinse thoroughly at least three times (triple rinse) in accordance with EPA recommendations. Consult state or local disposal authorities for approved alternative procedures such as container recycling. Recommend crushing, puncturing or other means to prevent unauthorized use of used containers. 14. Transport Information Reference Bill of Lading

16 Safety Data Sheet AVERT DRY FLOWABLE ROACH BAIT Revision date : 2011/07/18 Page: 7/7 Version: 3.2 ( /SDS_CPA_US/EN) 15. Regulatory Information Federal Regulations Registration status: Chemical TSCA, US blocked / not listed Crop Protection TSCA, US released / exempt EPCRA 311/312 (Hazard categories): Acute; Chronic 16. Other Information Refer to product label for EPA registration number. Recommended use: insecticide We support worldwide Responsible Care initiatives. We value the health and safety of our employees, customers, suppliers and neighbors, and the protection of the environment. Our commitment to Responsible Care is integral to conducting our business and operating our facilities in a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring the safe and environmentally sound handling of our products, and minimizing the impact of our operations on society and the environment during production, storage, transport, use and disposal of our products. MSDS Prepared by: BASF NA Product Regulations msds@basf.com MSDS Prepared on: 2011/07/18 IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU MAKE TESTS TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR INFORMATION SET FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE USED WITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESSLY UNDERSTAND AND AGREE THAT THE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION FURNISHED BY BASF HEREUNDER ARE GIVEN GRATIS AND BASF ASSUMES NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DESIGNS, DATA AND INFORMATION GIVEN OR RESULTS OBTAINED, ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK. END OF DATA SHEET

17 Return to Index US EPA Reg No : CD PCPA Reg. No US EPA Reg No : CD PCPA Reg. No US EPA Reg No : CD PCPA Reg. No

18 May be harmful if swallowed.

19

20

21

22

23 May be harmful if swallowed.

24

25

26

27

28 Return to Index... SAFETY DATA SHEET Issue Date: 30-Oct-2015 Revision Date: 30-Oct-2015 Version: 1 Product identifier Product Name: Bedlam PLUS EPA Registration Number: Other means of identification Part Code: PRODUCT AND COMPANY IDENTIFICATION Recommended use of the chemical and restrictions on use: Recommended Use: A Liquefied Aerosol Insecticide Spray. Details of the supplier of the safety data sheet Manufacturer Address: McLaughlin Gormley King Company th Avenue North FAX #: (763) Minneapolis, MN Telephone Number: (800) , or (763) Address: mgk-sds@mgk.com Emergency telephone numbers: 24 Hour TRANSPORTATION Emergency: CHEMTREC : (800) International: (703) Hour MEDICAL Emergency: SafetyCall : (888) , or (952) Comments: MGK Hours of operation are 8:00 am to 4:30 pm CST, 14:00 to 22:30 GMT. For MEDICAL EMERGENCIES or PESTICIDE INCIDENTS, call 24 hours a day to (888) , or (952) HAZARDS IDENTIFICATION Classification OSHA Regulatory Status: This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR ). Acute toxicity - Inhalation (Dusts/Mists) Category 4 Skin sensitization Category 1 Flammable aerosol Category 2 Gases under pressure Liquefied gas Label elements WARNING Emergency Overview Hazard statements Page 1 / 9

29 Bedlam PLUS Revision Date: 30-Oct-2015 H280 - Contains gas under pressure; may explode if heated Appearance: Milky white / Milky yellow (Aerosol Non-volatiles) Physical state: Aerosol - Compressed liquefied gas. Odor: Slight, Sweet - Solvent Precautionary Statements - Prevention: P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking P211 - Do not spray on an open flame or other ignition source P251 - Pressurized container: Do not pierce or burn, even after use P261 - Avoid breathing dust/fume/gas/mist/vapors/spray P271 - Use only outdoors or in a well-ventilated area P272 - Contaminated work clothing should not be allowed out of the workplace P280 - Wear protective gloves Precautionary Statements - Response: P321 - Specific treatment (see Section 4/ First Aid). P302 + P352 - IF ON SKIN: Wash with plenty of soap and water P333 + P313 - If skin irritation or rash occurs: Get medical advice/attention P363 - Wash contaminated clothing before reuse P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing P312 - Call a POISON CENTER or doctor/physician if you feel unwell Precautionary Statements - Storage: P410 + P403 - Protect from sunlight. Store in a well-ventilated place P411 - Do not expose to temperatures exceeding 122 F (50 C) Precautionary Statements - Disposal: P501 - Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC): Do not use this product in or on electrical equipment due to the possibility of shock hazard. 3. COMPOSITION/ INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% d-phenothrin (SUMITHRIN ) MGK -264 Insecticide Synergist (n-octyl bicycloheptene dicarboximide) Imidacloprid Isobutane <--->15 * *The exact percentage (concentration) of composition has been withheld as a trade secret. Page 2 / 9

30 Bedlam PLUS Revision Date: 30-Oct-2015 Comments: Ingredients not identified are proprietary or non-hazardous. Values are not product specifications. 4. FIRST AID MEASURES Aspiration pneumonia hazard: Description of first aid measures: Eye contact: Skin Contact: Ingestion: Inhalation: Self-protection of the First Responder: Note to physicians: Hold eye open and rinse slowly and gently with water for minutes. Remove contact lenses, if present, after the first 5minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. Take off contaminated clothing. Rinse skin immediately with plenty of water for minutes. Call a poison control centeror doctor for treatment advice. If swallowed, IMMEDIATELY call a poison control center or doctor for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by a poison control center or a doctor. Never give anything by mouth to an unconscious person. Remove affected person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificialrespiration, preferably mouth-to-mouth if possible. Call a poison control center or doctor for further treatment advice. Remove all sources of ignition. Use personal protective equipment as required. For skin effects, a highly efficient therapeutic agent for Pyrethrin/ Pyrethroid exposure is topical application of tocopherol acetate (Vitamin E). 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media: Caution: Use of water spray when fighting fire may be inefficient. Hazardous combustion products: Carbon monoxide, Carbon dioxide (CO2). Specific hazards arising from the chemical No information available. Explosion data Sensitivity to Mechanical Impact: None. Sensitivity to Static Discharge: None. Protective equipment and precautions for firefighters: In the event of fire and/or explosion do not breathe fumes. NFPA Health hazards 2 Flammability 4 Instability 0 Physical and Chemical Properties * HMIS Health hazards 1 * Flammability 4 Physical hazards 0 Personal protection X Chronic Hazard Star Legend * = Chronic Health Hazard Page 3 / 9

31 Bedlam PLUS Revision Date: 30-Oct ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions: Environmental precautions: Remove all sources of ignition. Evacuate personnel to safe areas. Ensure adequate ventilation, especially in confined areas. Keep people away from and upwind of spill/leak. Use personal protective equipment as required. Prevent further leakage or spillage if safe to do so. Prevent product from entering drains. See Section 12 for additional ecological information. Methods and material for containment and cleaning up Methods for containment: Methods for cleaning up: Prevent further leakage or spillage if safe to do so. Cover powder spill with plastic sheet or tarp to minimize spreading. Dike far ahead of liquid spill for later disposal. Dam up. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Pick up and transfer to properly labeled containers. Soak up with inert absorbent material. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling: Ensure adequate ventilation, especially in confined areas. Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static electricity). Take precautionary measures against static discharges. Use spark-proof tools and explosion-proof equipment. All equipment used when handling the product must be grounded. Use with local exhaust ventilation. Use personal protective equipment as required. Do not breathe dust/fume/gas/mist/vapors/spray. Avoid contact with eyes. Avoid breathing vapors or mists. Contents under pressure. Do not puncture or incinerate cans. Do not stick pin or any other sharp object into opening on top of can. For more information, see product label. Conditions for safe storage, including any incompatibilities Storage Conditions: Keep tightly closed in a dry and cool place. Keep in properly labeled containers. Keep containers tightly closed in a cool, well-ventilated place. For more information, see product label. 8. EXPOSURE CONTROLS/ PERSONAL PROTECTION Control parameters Exposure Guidelines: This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies. Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Supplier OEL Isobutane STEL: 1000 ppm - TWA: 800 ppm TWA: 1900 mg/m 3 NIOSH IDLH Immediately Dangerous to Life or Health Appropriate engineering controls Page 4 / 9

32 Bedlam PLUS Revision Date: 30-Oct-2015 Engineering Controls: Safety showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection: Skin and body protection: Respiratory protection: General Hygiene Considerations: Tight sealing safety goggles. Face protection shield. Wear protective gloves and protective clothing. If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. When using do not eat, drink or smoke. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties: Physical state: Appearance: Odor: Odor threshold: Color (Gardner Scale): Aerosol - Compressed liquefied gas. Milky white / Milky yellow (Aerosol Non-volatiles) Slight, Sweet - Solvent No information available No information available Property: Values: ph: 5.3 Melting point / freezing point: No information available Boiling point / boiling range: No information available Flash point: > 93.3 C / > % in H2O. Test was performed on aerosol Non-Volatile's.. Tag Closed Cup; Test was performed on aerosol Non-Volatile's; Evaporation rate: Flammability (solid, gas): Upper flammability limit (UEL): Lower flammability limit (LEL): Vapor pressure: Vapor density: Specific Gravity: Water solubility: Partition coefficient; n-octanol/ Water: Autoignition temperature: Decomposition temperature: Kinematic viscosity: Dynamic viscosity: Refractive Index: Other Information: No information available No information available No information available No information available No information available No information available No information available No information available No information available No information available No information available No information available C. No information available Test was performed on aerosol Non-Volatile's.. Density: 1.00 g/cm 20.0 C (Aerosol Non-volatiles) Page 5 / 9

33 Bedlam PLUS Revision Date: 30-Oct-2015 VOC Content (%): 12.9 Miscibility/ Solubility: Water: Alcohol Aromatic solvents: Petroleum distillates: Partially miscible Partially miscible Partially miscible Partially miscible 10. STABILITY AND REACTIVITY Reactivity No data available Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous polymerization: Hazardous polymerization does not occur. Conditions to avoid Heat, flames and sparks. Incompatible materials: Incompatible with strong acids and bases. Incompatible with oxidizing agents. Hazardous Decomposition Products Carbon monoxide, Carbon dioxide (CO2). Numerical measures of toxicity - Product Information 11. TOXICOLOGICAL INFORMATION Oral LD50 >5,000 mg/kg (rat) Dermal LD50 >5,000 mg/kg (rabbit) Inhalation LC50 >2.09 mg/l (rat; 4 hours) Eye contact: Non-irritating to eyes. (rabbit). Skin Contact: Slightly irritating. (rabbit). Skin Irritation Index: 0.8 Sensitization: Comment: Carcinogenicity Reproductive toxicity: Developmental Toxicity Teratogenicity: STOT - single exposure: STOT - repeated exposure: Chronic toxicity: Target Organ Effects: Positive. (guinea pig). Some of the above toxicity data was bridged from the insecticide concentrate, that is used in manufacturing this end-use product. This product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARC or NTP. No information available. No information available. No information available. No information available. No information available. Avoid repeated exposure. Central nervous system. Page 6 / 9

34 Bedlam PLUS Revision Date: 30-Oct-2015 Ecotoxicity: Persistence and degradability No information available. 12. ECOLOGICAL INFORMATION Bioaccumulation No information available. Chemical Name d-phenothrin (SUMITHRIN ) Isobutane Partition coefficient; n-octanol/ Water: Other adverse effects: No information available Environmental hazards (EPA): Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance contact your State Water Board or Regional Office of the EPA. Waste treatment methods 13. DISPOSAL CONSIDERATIONS Disposal of wastes: Contaminated packaging: Disposal should be in accordance with applicable regional, national and local laws and regulations. For more information, see product label. For more information, see product label. 14. TRANSPORT INFORMATION DOT (Department of Transportation) UN/ID Number: UN1950 Proper Shipping Name: Aerosols, non-flammable Hazard Class: 2.2 Air (IATA/ ICAO) UN/ID Number: UN1950 Proper Shipping Name: Aerosols, non-flammable Hazard Class: 2.2 Vessel (IMO/ IMDG) UN/ID Number: UN1950 Proper Shipping Name: Aerosols, non-flammable Hazard Class: REGULATORY INFORMATION Page 7 / 9

35 Bedlam PLUS Revision Date: 30-Oct-2015 US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 SARA 311/312 Hazard Categories Acute health hazard Chronic Health Hazard Fire hazard Sudden release of pressure hazard Reactive Hazard No Yes No Yes No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR and 40 CFR ) CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material US State Regulations: California Proposition 65: This product does not contain any Proposition 65 chemicals U.S. EPA Label Information: EPA Registration Number: Difference between SDS and EPA (FIFRA) Pesticide label: This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for Safety Data Sheets (SDS), and for workplace labels of non-pesticide chemicals. The pesticide label also includes other important information, including directions for use. The hazard information required on the pesticide label is reproduced below: Precautionary Statements: International: TSCA DSL/NDSL EINECS/ELINCS ENCS IECSC KECL PICCS AICS Does not comply Does not comply Does not comply Does not comply Complies Does not comply Does not comply Does not comply Page 8 / 9

36 Bedlam PLUS Revision Date: 30-Oct-2015 Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION. Issue Date: 30-Oct-2015 Revision Date: 30-Oct-2015 Revision Note: - New SDS. - GHS - Classification. SDS Prepared By: Address: Disclaimer: Troy Azzivitto, MGK Chemistry Department. mgk-sds@mgk.com The data contained herein are based on information currently available to McLaughlin Gormley King Company and,to the best of our knowledge, are accurate and based on sound expert opinion. Our statements herein, however, are not to betaken as a warranty or representation for which McLaughlin Gormley King Company assumes legal responsibility. End of Safety Data Sheet. Page 9 / 9

37 SAFETY DATA SHEET CB-80 Insecticide SDS # : 6545-A Revision date: Format: NA Version 1.01 Return to Index PRODUCT AND COMPANY IDENTIFICATION Product Identifier Product Name CB-80 Insecticide Other means of identification Product Code(s) 6545-A Synonyms Active Ingredient(s) Pyrethrins and Pyrethroids, Pyrethrum PIPERONYL BUTOXIDE: Butylcarbityl(6-propylpiperonyl) ether, 1,3-Benzodioxole, 5-[[2-(2-butoxyethoxy)ethoxy]methyl]-6-propyl- Piperonyl Butoxide, Pyrethrins Recommended use of the chemical and restrictions on use Recommended Use: Restrictions on Use: Manufacturer Address Emergency telephone number Insecticide Use as recommended by the label FMC Corporation 1735 Market Street Philadelphia, PA (215) (General Information) msdsinfo@fmc.com ( General Information) For leak, fire, spill or accident emergencies, call: / (CHEMTREC - U.S.A.) / (CHEMTREC - Collect - All Other Countries) Medical Emergencies: / (PROSAR - U.S.A. & Canada) / (PROSAR - All Other Countries - Collect) 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR ) Acute toxicity - Inhalation (Dusts/Mists) Category 4 Serious eye damage/eye irritation Category 2 Skin sensitization Category 1 Specific target organ toxicity (single exposure) Category 3 Aspiration toxicity Category 1 Flammable Aerosols Category 2 Page 1 / 9

38 CB-80 Insecticide GHS Label elements, including precautionary statements SDS # : 6545-A Revision date: Version 1.01 Danger EMERGENCY OVERVIEW Hazard Statements H304 - May be fatal if swallowed and enters airways H313 - May be harmful in contact with skin H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation H332 - Harmful if inhaled H335 - May cause respiratory irritation H336 - May cause drowsiness or dizziness Precautionary Statements - Prevention P261 - Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray P264 - Wash face, hands and any exposed skin thoroughly after handling P272 - Contaminated work clothing should not be allowed out of the workplace P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking P211 - Do not spray on an open flame or other ignition source P251 - Do not pierce or burn, even after use P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P337 + P313 - If eye irritation persists: Get medical advice/ attention P302 + P352 - IF ON SKIN: Wash with plenty of water and soap P333 + P313 - If skin irritation or rash occurs: Get medical advice/ attention P363 - Wash contaminated clothing before reuse P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P312 - Call a POISON CENTER or doctor if you feel unwell P301 + P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor P331 - Do NOT induce vomiting Precautionary Statements - Storage P405 - Store locked up P403 + P233 - Store in a well-ventilated place. Keep container tightly closed P410 + P412 - Protect from sunlight. Do not expose to temperatures exceeding 50 C/ 122 F Precautionary Statements - Disposal P501 - Dispose of contents/ container to an approved waste disposal plant Hazards not otherwise classified (HNOC) No hazards not otherwise classified were identified. Other Information May be harmful if swallowed Harmful to aquatic life with long lasting effects 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical name CAS-No Weight % Piperonyl butoxide Pyrethrins Page 2 / 9

39 CB-80 Insecticide SDS # : 6545-A Revision date: Version ,1-Difluoroethane Isopropanol Petroleum distillates, hydrotreated light Synonyms are provided in Section FIRST AID MEASURES Eye Contact Hold eyes open and rinse slowly and gently with water for 15 to 20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for further treatment advice. Skin Contact Take off contaminated clothing. Rinse skin immediately with plenty of water for minutes. Call a poison control center or doctor for further treatment advice. Inhalation Ingestion Most important symptoms and effects, both acute and delayed Indication of immediate medical attention and special treatment needed, if necessary Move to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or doctor for further treatment advice. Immediately call a poison control center or doctor. Do not induce vomiting unless told to do so by a poison control center or doctor. Do not give any liquid to the person. Do not induce vomiting or give anything by mouth to an unconscious person. Central nervous system effects. Treat symptomatically. Contains petroleum distillate. May pose an aspiration pneumonia hazard. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Specific Hazards Arising from the Chemical Explosion data Sensitivity to Mechanical Impact Sensitivity to Static Discharge Protective equipment and precautions for firefighters Foam. Carbon dioxide (CO2). Dry chemical. Water spray. Contents under pressure. Not sensitive. Not sensitive. Isolate fire area. Evaluate downwind. In the event of fire, wear self contained breathing apparatus. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Isolate and post spill area. Remove all sources of ignition. Ventilate the area. Wear suitable protective clothing, gloves and eye/face protection. For personal protection see section 8. If ventilation is not possible wear full protection suit and chemical protective equipment. Other For further clean-up instructions, call FMC Emergency Hotline number listed in Section 1 "Product and Company Identification" above. Environmental Precautions Methods for Containment Methods for cleaning up See Section 12 for additional Ecological Information. Prevent further leakage or spillage if safe to do so. Transfer damaged cartridges or cans to containers for later disposal. Clean and neutralize spill area, tools and equipment by washing with bleach water and soap. Waste must be classified and labeled prior to recycling or disposal. Dispose of waste as indicated in Section 13. Rinsate may be disposed at a waste water treatment plant. Page 3 / 9

40 CB-80 Insecticide SDS # : 6545-A Revision date: Version HANDLING AND STORAGE Handling Storage Incompatible products Do not contaminate other pesticides, fertilizers, water, food, or feed by storage or disposal. BEWARE: Aerosol is pressurized. Keep away from direct sun exposure and temperatures over 130 F. Do not open by force or throw into fire even after use. Do not spray on flames or red-hot objects. Keep in a dry, cool and well-ventilated place. Keep away from open flames, hot surfaces and sources of ignition. Keep out of reach of children and animals. Keep/store only in original container. Strong oxidizing agents. Bases. Powdered earth metals. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Chemical name ACGIH TLV OSHA PEL NIOSH Mexico Pyrethrins TWA: 5 mg/m 3 TWA: 5 mg/m 3 IDLH: 5000 mg/m 3 TWA: 5 mg/m 3 Mexico: TWA 5 mg/m 3 Mexico: STEL 10 mg/m 3 Isopropanol STEL 400 ppm TWA: 200 ppm TWA: 400 ppm TWA: 980 mg/m 3 IDLH: 2000 ppm TWA: 400 ppm TWA: 980 mg/m 3 STEL: 500 ppm STEL: 1225 mg/m 3 Mexico: TWA 400 ppm Mexico: TWA 980 mg/m 3 Mexico: STEL 500 ppm Mexico: STEL 1225 mg/m 3 Chemical name British Columbia Quebec Ontario TWAEV Alberta Pyrethrins TWA: 5 mg/m 3 TWA: 5 mg/m 3 TWA: 5 mg/m 3 TWA: 5 mg/m Isopropanol TWA: 200 ppm STEL: 400 ppm TWA: 200 ppm STEL: 400 ppm Petroleum distillates, hydrotreated light Appropriate engineering controls TWA: 200 mg/m 3 Skin TWA: 400 ppm TWA: 985 mg/m 3 STEL: 500 ppm STEL: 1230 mg/m 3 TWA: 200 ppm TWA: 492 mg/m 3 STEL: 400 ppm STEL: 984 mg/m Engineering measures Apply technical measures to comply with the occupational exposure limits. When working in confined spaces (tanks, containers, etc.), ensure that there is a supply of air suitable for breathing and wear the recommended equipment. Individual protection measures, such as personal protective equipment Eye/Face Protection Skin and Body Protection Hand Protection Respiratory Protection Hygiene measures If there is a potential for exposure to particles which could cause eye discomfort, wear chemical goggles. Wear long-sleeved shirt, long pants, socks, and shoes. Protective gloves If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Respiratory protection must be provided in accordance with current local regulations. Clean water should be available for washing in case of eye or skin contamination. Wash skin prior to eating, drinking, chewing gum or using tobacco. Shower or bathe at the end of working. Remove and wash contaminated clothing before re-use. Launder work clothing separately from regular household laundry. Page 4 / 9

41 CB-80 Insecticide General information SDS # : 6545-A Revision date: Version 1.01 If the product is used in mixtures, it is recommended that you contact the appropriate protective equipment suppliers These recommendations apply to the product as supplied 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Appearance yellow, Aerosolized liquid Physical State Liquid Aerosol Color Yellow Odor Pyrethrins Odor threshold No information available ph No information available Melting point/freezing point Not applicable Boiling Point/Range No information available Flash point 14.4 C / 58 F (Flame extension 5" - no flashback) Evaporation Rate No information available Flammability (solid, gas) No information available Flammability Limit in Air Upper flammability limit: No information available Lower flammability limit: No information available Vapor pressure No information available Vapor density No information available Density 7.29 lb/gal Specific gravity Water solubility No information available Solubility in other solvents No information available Partition coefficient No information available Autoignition temperature No information available Decomposition temperature No information available Viscosity, kinematic No information available Viscosity, dynamic No information available Explosive properties No information available Oxidizing properties No information available Molecular weight No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity Chemical Stability None under normal use conditions. Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous polymerization Conditions to avoid Incompatible materials Hazardous polymerization does not occur. Keep away from open flames, hot surfaces and sources of ignition. Strong oxidizing agents. Bases. Powdered earth metals. Hazardous Decomposition Products Carbon oxides (COx), Hydrogen fluoride, Carbonyl fluoride. Product Information LD50 Oral 2,370 mg/kg (rat) LD50 Dermal > 2000 mg/kg (rabbit) LC50 Inhalation 2.5 mg/l (rat) 11. TOXICOLOGICAL INFORMATION Eye Contact Skin Contact Slightly or non-irritating (rabbit) Slightly or non-irritating (rabbit) Page 5 / 9

42 CB-80 Insecticide Sensitization Sensitizer. SDS # : 6545-A Revision date: Version 1.01 Information on toxicological effects Symptoms Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal. Delayed and immediate effects as well as chronic effects from short and long-term exposure Mutagenicity Piperonyl butoxide ether may affect mammalian liver microsomal detoxification enzymes. n-octyl bicycloheptene dicarboximide was negative in a chromosome aberration assay, Carcinogenicity Not recognized as carcinogenic by Research Agencies (IARC, NTP, OSHA, ACGIH). Reproductive toxicity No information available. Developmental toxicity Isopropanol has been reported to cause teratogenicity in laboratory animals. STOT - single exposure Not classified. STOT - repeated exposure Not classified. Target organ effects Mice fed 0.3 or 0.9% piperonyl butoxide in the diet for 20 days had increased liver weight and other signs of liver toxicity. Male rats given up to 2.4% of piperonyl butoxide in the diet for up to 12 weeks had clinical and histologic signs of liver damage; the highest dose group showed preneoplastic changes, including enlargement of hepatocyte nuclei and multinucleated cells. Kidney damage was also seen. Aspiration hazard No information available. Chemical name ACGIH IARC NTP OSHA Piperonyl butoxide Group Isopropanol Group 3 Ecotoxicity 12. ECOLOGICAL INFORMATION Piperonyl butoxide ( ) Active Ingredient(s) Duration Species Value Units Piperonyl Butoxide LC50 Fish 3.94 ppm LD50 Bee 25 µg/bee LD50 Bobwhite quail >2250 mg/kg LD50 Mallard duck >5620 ppm Persistence and degradability Bioaccumulation No information available. No information available. 13. DISPOSAL CONSIDERATIONS Waste disposal methods Contaminated Packaging Improper disposal of excess pesticide, spray mixture, or rinsate is prohibited. If these wastes cannot be disposed of by use according to label instructions, contact appropriate disposal authorities for guidance. Containers must be disposed of in accordance with local, state and federal regulations. Refer to the product label for container disposal instructions. 14. TRANSPORT INFORMATION DOT Page 6 / 9

43 CB-80 Insecticide UN/ID no Proper Shipping Name Hazard class TDG UN/ID no SDS # : 6545-A Revision date: Version oz. Container: UN lb. Cylinder: UN oz. Container: Consumer Commodity 13 lb. Cylinder: Compressed gas, flammable, n.o.s. (1,1-Difluoroethane, Isopropyl alcohol) 17 oz. Container: ORM-D 13 lb. Cylinder: oz. Container: UN lb. Cylinder: UN1954 Proper Shipping Name 17 oz. Container: Aerosols 13 lb. Cylinder: Compressed gas, flammable, n.o.s. (1,1-Difluoroethane, Isopropyl alcohol) Hazard class 2.1 ICAO/IATA UN/ID no Proper Shipping Name Hazard class 17 oz. Container: 9 13 lb. Cylinder: 2.1 IMDG/IMO UN/ID no 17 oz. Container: ID lb. Cylinder: UN oz. Container: Consumer Commodity 13 lb. Cylinder: Compressed gas, flammable, n.o.s. (1,1-Difluoroethane, Isopropyl alcohol) 17 oz. Container: UN lb. Cylinder: UN1954 Proper Shipping Name 17 oz. Container: Aerosols 13 lb. Cylinder: Compressed gas, flammable, n.o.s. (1,1-Difluoroethane, Isopropyl alcohol) Hazard class 2.1 U.S. Federal Regulations 15. REGULATORY INFORMATION SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372: SARA 311/312 Hazard Categories Acute health hazard Chronic health hazard Fire hazard Sudden release of pressure hazard Reactive Hazard Yes Yes Yes No No Clean Water Act This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR and 40 CFR ): Chemical name Pyrethrins CWA - Reportable Quantities 1 lb CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302): Chemical name Hazardous Substances RQs Extremely Hazardous RQ Substances RQs Pyrethrins lb RQ 1 lb final RQ RQ kg final RQ FIFRA Information Page 7 / 9

44 CB-80 Insecticide SDS # : 6545-A Revision date: Version 1.01 This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: CAUTION Contains petroleum distillates. Causes moderate eye irritation. Harmful if swallowed, inhaled, or absorbed through skin. Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals. US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations This product does not contain any substances regulated by state right-to-know regulations International Inventories Component Piperonyl butoxide ( 4 ) Pyrethrins ( 0.5 ) 1,1-Difluoroethane ( ) Isopropanol ( ) Petroleum distillates, hydrotreated light ( 5-15 ) TSCA (United States) DSL (Canada) EINECS/ELI NCS (Europe) ENCS (Japan) China (IECSC) KECL (Korea) PICCS (Philippines) AICS (Australia) X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Mexico - Grade Serious risk, Grade 3 WHMIS Hazard Class A - Compressed gases B5 - Flammable aerosol D1B - Toxic materials D2B - Toxic materials 16. OTHER INFORMATION NFPA Health Hazards 2 Flammability 3 Instability 0 Special Hazards - HMIS Health Hazards 2 Flammability 3 Physical hazard 0 Personal Protection X Revision date: Revision note Format Change Page 8 / 9

45 CB-80 Insecticide SDS # : 6545-A Revision date: Version 1.01 Disclaimer FMC Corporation believes that the information and recommendations contained herein (including data and statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information provided herein relates only to the specified product designated and may not be applicable where such product is used in combination with any other materials or in any process. Use of this product is regulated by the U.S. Environmental Protection Agency (EPA). It is a violation of Federal law to use this product in a manner inconsistent with its labeling. Further, since the conditions and methods of use are beyond the control of FMC Corporation, FMC corporation expressly disclaims any and all liability as to any results obtained or arising from any use of the products or reliance on such information. Prepared By: FMC Corporation FMC Logo - Trademark of FMC Corporation 2015 FMC Corporation. All Rights Reserved. End of Safety Data Sheet Page 9 / 9

46 CONTRAC ALL-WEATHER BLOX SAFETY DATA SHEET ACCORDING TO REGULATION: OSHA Hazard Communication Standard 29 CFR DATE OF ISSUE: January PRODUCT AND COMPANY IDENTIFICATION Product Identifier: CONTRAC ALL-WEATHER BLOX EPA Registration Number: Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses: Anticoagulant Rodenticide - Ready to use Uses advised against: Use only for the purpose described above MANUFACTURER/SUPPLIER: Bell Laboratories, Inc Kinsman Blvd. Madison, WI 53704, USA sds@belllabs.com Phone: Medical or Vet Emergency: or Spill or Transportation Emergency: (CHEMTREC) 2. HAZARD IDENTIFICATION Classification according to Regulation OSHA (d): Not classified Return to Index PREPARED BY: CAR See Section 15 for information on FIFRA applicable safety, health, and environmental classifications. 3. COMPOSITION/INFORMATION ON INGREDIENTS Component CAS No. % By weight Bromadiolone [3-[3-(4 -Bromo-[1,1 -biphenyl]-4-yl)-3-hydroxy-1-phenylpropyl]-4- hydroxy-2h-1-benzopyran-2-one] % Inert and Non-Hazardous Ingredients Proprietary % 4. FIRST AID MEASURES Description of first aid measures Ingestion: Call physician or emergency number immediately. Have person sip a glass of water if able to swallow. Do not induce vomiting unless instructed by physician. Inhalation: Not applicable. Eye contact: Hold eye open and rinse slowly with water for minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. If irritation develops, obtain medical assistance. Skin contact: Take off contaminated clothing. Rinse skin immediately with plenty of water for minutes. If irritation develops, obtain medical assistance. Most important symptoms and effects, both acute and delayed Ingestion of excessive quantities may cause nausea, vomiting, loss of appetite, extreme thirst, lethargy, diarrhea, bleeding. Advice to physician: If ingested, administer Vitamin K 1 intramuscularly or orally as indicated for bishydroxycoumarin overdoses. Repeat as necessary as based upon monitoring of prothrombin times. Advice to Veterinarian: For animals ingesting bait and/or showing poisoning signs (bleeding or elevated prothrombin times), give Vitamin K 1. If needed, check prothrombin times every 3 days until values return to normal (up to 30 days). In severe cases, blood transfusions may be needed. Trade Name: Contrac All-Weather Blox Date Created: January 2015 Supplier: Bell Laboratories, Inc. Page 1 of 4

47 5. FIRE-FIGHTING MEASURES Extinguishing media Suitable Extinguishing Media: water, foam or inert gas. Unsuitable Extinguishing Media: None known. Special hazards arising from the mixture: High temperature decomposition or burning in air can result in the formation of toxic gases, which may include carbon monoxide and traces of bromine and hydrogen bromide. Advice for firefighters: Wear protective clothing and self-contained breathing apparatus. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures: Gloves should be worn when handling the bait. Collect spillage without creating dust. Environmental precautions: Do not allow bait to enter drains or water courses. Where there is contamination of streams, rivers or lakes contact the appropriate environment agency. Methods and materials for containment and cleaning up For Containment: Sweep up spilled material immediately. Place in properly labeled container for disposal or re-use. For Cleaning Up: Wash contaminated surfaces with detergent. Dispose of all wastes in accordance with all local, regional and national regulations. Reference to other sections: Refer to Sections 7, 8 & 13 for further details of personal precautions, personal protective equipment and disposal considerations. 7. HANDLING AND STORAGE Precautions for safe handling: Do not handle the product near food, animal foodstuffs or drinking water. As soon as possible, wash hands thoroughly after applying bait and before eating, drinking, chewing gum, using tobacco, or using the toilet. Conditions for safe storage, including any incompatibilities: Store only in original container in a cool, dry place, inaccessible to pets and wildlife. Do not contaminate water, food or feed by storage or disposal. Keep containers closed and away from other chemicals. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Established Limits Component OSHA ACGIH Other Limits Bromadiolone Not Established Not Established Not Established Appropriate Engineering Controls: Not required Occupational exposure limits: Not established Personal Protective Equipment: Respiratory protection: Not required Eye protection: Not required Skin protection: Shoes plus socks, and waterproof gloves. Hygiene recommendations: Wash thoroughly with soap and water after handling. Trade Name: Contrac All-Weather Blox Date Created: January 2015 Supplier: Bell Laboratories, Inc. Page 2 of 4

48 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Appearance/Color: Blue wax block Odor: Sweet grain-like Odor Threshold: Not applicable, odor not associated with a hazardous material. ph: Not applicable, Contrac All-Weather Blox is not dispersible with water. Melting point: Not applicable to rodenticide bait Boiling point: Not applicable to rodenticide bait Flash point: Not applicable, Contrac All-Weather Blox does not contain components classified as flammable. Evaporation rate: Not applicable, Contrac All-Weather Blox is a solid. Upper/lower flammability or explosive limits: Not applicable, Contrac All-Weather Blox does not contain components classified as flammable or explosive. Vapor Pressure: Vapor Density: Not applicable to rodenticide bait NA: Contrac All-Weather Blox is a solid Relative Density: C Solubility (water): Not water soluble Solubility (solvents): Not applicable to rodenticide bait Partition coefficient: n- Not applicable to rodenticide bait octanol/water: Auto-ignition temperature: Not applicable, Contrac All-Weather Blox does not contain components classified as flammable. Decomposition temperature: Not applicable to rodenticide bait Viscosity: Not applicable, Contrac All-Weather Blox is not a liquid. 10. STABILITY AND REACTIVITY Reactivity: Stable when stored in original container in a cool, dry location. Chemical stability: Stable when stored in original container in a cool, dry location. Possibility of hazardous reactions: Refer to Hazardous decomposition products Conditions to avoid: Avoid extreme temperatures (below 0 C or above 40 C). Incompatible materials: Avoid strongly alkaline materials. Hazardous decomposition products: High temperature decomposition or burning in air can result in the formation of toxic gases, which may include carbon monoxide and traces of bromine and hydrogen bromide. 11. TOXICOLOGICAL INFORMATION Information on toxicological effects Acute Toxicity LD50, oral (ingestion): >5000 mg/kg (rats) (Bromadiolone Rat LD50 oral: 0.70 mg/kg bw). LD50, dermal (skin contact): > 5001 mg/kg (rats) (Bromadiolone rabbit LD50 dermal: 1.71 mg/kg bw). LC50, inhalation: Contrac All-Weather Blox is a wax block and therefore exposure by inhalation is not relevant. Skin corrosion/irritation: Not irritating to skin. Serious eye damage/irritation: Not irritating to eyes. Respiratory or skin sensitization: Dermal sensitization: Not a Sensitizer (Guinea pig maximization test). Germ cell mutagenicity: Contrac All-Weather Blox contains no components known to have a mutagenetic effect. Carcinogenicity: Contrac All-Weather Blox contains no components known to have a carcinogenetic effect. Components NTP IARC OSHA Bromadiolone Not listed Not listed Not listed Reproductive Toxicity: Contrac All-Weather Blox: No data Aspiration Hazard: Not applicable. Contrac All-Weather Blox is a wax block. Target Organ Effects: Reduced blood clotting ability. 12. ECOLOGICAL INFORMATION Ecotoxicity Effects: This product is extremely toxic to fish, birds and other wildlife. Dogs and predatory and scavenging mammals and birds might be poisoned if they feed upon animals that have eaten this bait. Do not apply this product directly to water or to areas where surface water is present or to intertidal areas below the mean high water mark. Runoff also may be hazardous to aquatic organisms in water adjacent to treated areas. Do not contaminate water when disposing of equipment wash water or rinsate. Persistence and degradability: Contrac All-Weather Blox is inherently biodegradable. Bioaccumulative potential: Not determined for Contrac All-Weather Blox. Bromadiolone water solubility is extremely low (< 0.1mg/l). Mobility in Soil: Not determined for Contrac All-Weather Blox. Mobility of bromadiolone in soil is considered to be limited. Other adverse effects: None. Trade Name: Contrac All-Weather Blox Date Created: January 2015 Supplier: Bell Laboratories, Inc. Page 3 of 4

49 13. DISPOSAL CONSIDERATIONS Do not contaminate water, food or feed by storage or disposal. Pesticide Storage: Store only in original container in a cool, dry place inaccessible to children and pets. Keep containers closed and away from other chemicals. Pesticide Disposal: Wastes resulting from the use of this product may be placed in trash or delivered to an approved waste disposal facility. Container Handling: Non-refillable container. Do not reuse or refill this container. [Plastic:] Offer for recycling or reconditioning; or puncture and dispose of in a sanitary landfill; or by incineration. In most states, burning is not allowed. [Paper:] Dispose of empty container by placing in trash, at an approved waste disposal facility or by incineration. In most states, burning is not allowed. 14. TRANSPORT INFORMATION UN number: Not regulated UN proper shipping name: Not regulated Transport hazard class(es): Not regulated Packing group : Not regulated Environmental Hazards DOT Road/Rail: Not considered hazardous for transportation via road/rail. DOT Maritime: Not considered hazardous for transportation by vessel. DOT Air: Not considered hazardous for transportation by air. Freight Classification: LTL Class 60 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC code: Not applicable Special precautions for user: None 15. REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture: FIFRA: This pesticide product is regulated by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non-pesticide chemicals. The safety, health, environmental, and hazard information required on the pesticide label is listed below and reflected throughout this SDS. The pesticide label also includes other important information, including directions for use. Signal Word: CAUTION Precautionary Statements: Contains the anticoagulant Bromadiolone which may cause bleeding if ingested. Harmful if swallowed or absorbed through the skin. Keep away from children, domestic animals and pets. Do not get in eyes, on skin or on clothing. Potential Health Effects: Eye Contact: May cause irritation Skin Contact: Non-irritating to the skin Ingestion: Harmful if swallowed TSCA: All components are listed on the TSCA Inventory or are not subject to TSCA requirements CERCLA/SARA 313: Not listed CERCLA/SARA 302: Not listed 16. OTHER INFORMATION For additional information, please contact the manufacturer noted in Section 1. NFPA Health: 1 (caution) Flammability: 0 (will not burn) Reactivity: 0 (stable) Specific Hazard: None HMIS Health: 2 (moderate) Flammability: 0 (minimal) Reactivity: 0 (minimal) Protective Equipment: B Disclaimer: The information provided in this Safety Data Sheet has been obtained from sources believed to be reliable. Bell Laboratories, Inc. provides no warranties; either expressed or implied, and assumes no responsibility for the accuracy or completeness of the data contained herein. This information is offered for your consideration and investigation. The user is responsible to ensure that they have all current data, including the approved product label, relevant to their particular use. Trade Name: Contrac All-Weather Blox Date Created: January 2015 Supplier: Bell Laboratories, Inc. Page 4 of 4

50 SAFETY DATA SHEET 1. Identification Product identifier Other means of identification SDS number 305 QAD Number Synonym(s) Recommended use Recommended restrictions Product registration number EPA Pest Control Products Act (Canada) Deadline Bullets Deadline M-Ps * Deadline T&O * Deadline M-Ps Mini Pellets * Deadline Ornamental Mollusicide Keep out of the Reach of Children! Keep away from dogs! WHMIS: Manufacturer/Importer/Supplier/Distributor information Manufacturer Company name AMVAC Chemical Corporation Address 4100 E Washington Blvd Los Angeles, CA USA Telephone AMVAC Chemical Corp AMVAC Chemical Corp (FAX) Website CustServ@Amvac-Chemical.com Emergency phone number Medical CHEMTREC (USA+Canada) Product Use CHEMTREC (Outside USA) Return to Index 2. Hazard(s) identification Physical hazards Health hazards Environmental hazards OSHA defined hazards Label elements Not classified. Acute toxicity, inhalation Serious eye damage/eye irritation Reproductive toxicity Not classified. Not classified. Category 4 Category 2B Category 2 Signal word Hazard statement Precautionary statement Prevention Response Storage Disposal Warning Causes eye irritation. Wash hands thoroughly after handling. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Store away from incompatible materials. Dispose of contents/container in accordance with local/regional/national/international regulations. Material name: Deadline Bullets Version #: 01 Issue date: SDS US 1 / 8

51 Hazard(s) not otherwise classified (HNOC) Supplemental information None known. United States Environmental Protection Agency Labeling Requirements: This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non-pesticide chemicals. The hazard information required on the pesticide label is reproduced below. The pesticide label also includes other important information, including directions for use. HAZARDS TO HUMANS AND DOMESTIC ANIMALS. CAUTION. Harmful if swallowed. Avoid breathing dust. May cause eye irritation. Avoid contact with eyes, skin, and clothing. This pesticide may be fatal to children and dogs or other animals if eaten. Keep out of reach of children and pets, poultry and livestock. Keep children, dogs and other pets out of treated areas. ENVIRONMENTAL HAZARDS 3. Composition/information on ingredients Mixtures Chemical name For terrestrial uses, do not apply directly to water, or to areas where surface water is present or to intertidal areas below the mean high water mark. Do not contaminate water when disposing of equipment washwater or rinsate. Common name and synonyms CAS number % Other components Mixture 96 Metaldehyde First-aid measures Inhalation Skin contact Eye contact Ingestion Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed General information 5. Fire-fighting measures Suitable extinguishing media Remove victim to fresh air and keep at rest in a position comfortable for breathing. Oxygen or artificial respiration if needed. Do not use mouth-to-mouth method if victim inhaled the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Call a POISON CENTER or doctor/physician if you feel unwell. Take off contaminated clothing and wash before reuse. Wash off immediately with plenty of water. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Immediately flush eyes with plenty of water for at least 15 minutes. Continue rinsing. Remove contact lenses, if present and easy to do. Call a physician or poison control center immediately. Call a physician or poison control center immediately. Rinse mouth. Drink 1 or 2 glasses of water. Do not induce vomiting without advice from poison control center. Have physician determine if patient s condition allows induction of vomiting or evacuation of stomach. Never give anything by mouth to a victim who is unconscious or is having convulsions. Based on animal toxicity information for metaldehyde, it is anticipated that this material would be harmful upon ingestion and that direct contact may elicit mild eye and skin irritation. Overexposure to metaldehyde may cause excessive salivation, vomiting, nausea, acetonuria (odor of acetone on breath), convulsions, increased body temperature, depression of medullary respiratory and vasomotor control centers and coma. May be fatal. [Note: Because of the low amounts of metaldehyde in the product, it is unlikely the victim can be exposed to sufficient quantities of metaldehyde to have coma or death induced.] Overexposure may aggravate preexisting conditions associated with the kidney, liver, and brain. According to manufacturer of Metaldehyde Technical communication, gastric lavage with a 2.5% solution of sodium bicarbonate-powdered charcoal and prevention of acidosis by sodium bicarbonate may be needed. Administration of Diazepam or Clonidine 20 minutes after ingestion of 1000 mg/kg of Metaled by mice delayed the onset of symptoms and reduced mortality. This is equivalent to 0.6 lb of product ingested for a 10 kg child. Therefore, Diazepam and Clonidine may be appropriate antidotes to reduce the symptomatology of Metaldehyde ingestion. For acute inhalation overexposure, the patient should be monitored as respiratory failure may occur 24 to 48 hours after exposure. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. In the case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Material name: Deadline Bullets Version #: 01 Issue date: SDS US 2 / 8

52 Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire fighting equipment/instructions General fire hazards None known. During fire, gases hazardous to health may be formed. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. In the event of fire, cool tanks with water spray. Water runoff can cause environmental damage. May form combustible dust concentrations in air. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Environmental precautions Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate personal protective equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS/SDS. Stop the flow of material, if this is without risk, to prevent entry into waterways, sewer, basements or confined areas. Collect spillage. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. For waste disposal, see section 13 of the SDS. Avoid release to the environment. Contact local authorities in case of spillage to drain/aquatic environment. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid discharge into drains, water courses or onto the ground. 7. Handling and storage Precautions for safe handling Conditions for safe storage, including any incompatibilities Keep out of the reach of children. Keep away from food, drink and animal feedstuffs. Minimize dust generation and accumulation. Avoid breathing dust. Use only outdoors or in a well-ventilated area. Avoid contact with skin. Avoid contact with eyes. Avoid prolonged exposure. Wear appropriate personal protective equipment recommended in section 8. Wash thoroughly after handling. Wash contaminated clothing before reuse. Observe good industrial hygiene practices. Avoid release to the environment. Do not empty into drains. Keep container tightly closed. Store in a cool, dry place out of direct sunlight. Store in a well-ventilated place. 8. Exposure controls/personal protection Occupational exposure limits US. ACGIH Threshold Limit Values Material Type Value Deadline Bullets Biological limit values Exposure guidelines Appropriate engineering controls TWA No biological exposure limits noted for the ingredient(s). Dust exposure limit. 0.5 mg/m3 Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Wear a full-face respirator, if needed. Skin protection Hand protection Other Respiratory protection Thermal hazards General hygiene considerations To prevent skin contact use suitable protective gloves. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. Not applicable. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Red, blue or buff colored pellet Physical state Solid. Material name: Deadline Bullets Version #: 01 Issue date: SDS US 3 / 8

53 Odor Form Color Odor threshold ph Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Pellets. Red, blue or buff. Aldehyde odor Not available. Not available. Not available. Not available. Not available. Not available. Not available. Upper/lower flammability or explosive limits Flammability limit - lower Not available. (%) Flammability limit - upper (%) Explosive limit - lower (%) Explosive limit - upper (%) Vapor pressure Not available. Not available. Not available. Vapor density 6.06 (air = 1). Relative density Solubility(ies) Solubility (water) Auto-ignition temperature Decomposition temperature Viscosity Other information Bulk density 1.90E+00 mm 24 C (active ingredient). Not available C for active ingredient. Not available. Not available. Not available lb/ft3 Specific gravity Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products The product is stable and non-reactive under normal conditions of use, storage and transport. Material is stable under normal conditions. Hazardous polymerization does not occur. Avoid conditions which create dust. Contact with incompatible materials. Avoid heat, sparks, open flames and other ignition sources. Strong oxidizing agents. Acetaldehyde can be formed by decomposition of Metaldehyde. Decomposition by burning may result in carbon monoxide and other toxic fumes and vapors of unknown composition. 11. Toxicological information Information on likely routes of exposure Inhalation Prolonged inhalation may be harmful. Skin contact Slight skin irritant. Eye contact Causes mild eye irritation. Ingestion However, ingestion is not likely to be a primary route of occupational exposure. Material name: Deadline Bullets Version #: 01 Issue date: SDS US 4 / 8

54 Symptoms related to the physical, chemical and toxicological characteristics Information on toxicological effects Acute toxicity Product Deadline Bullets Acute Exposed individuals may experience eye tearing, redness, and discomfort. Based on animal toxicity information for metaldehyde, it is anticipated that this material would be harmful upon ingestion and that direct contact may elicit mild eye and skin irritation. Overexposure to metaldehyde may cause excessive salivation, vomiting, nausea, acetonuria (odor of acetone on breath), convulsions, increased body temperature, depression of medullary respiratory and vasomotor control centers and coma. May be fatal. [Note: Because of the low amounts of metaldehyde in the product, it is unlikely the victim can be exposed to sufficient quantities of metaldehyde to have coma or death induced.] Causes mild eye irritation. Species Test Results Dermal LD50 Rabbit > 5050 mg/kg (EPA Tox Cat IV). Inhalation LC50 Rat > 2.48 mg/l, 4 hours (EPA Tox Cat IV). Oral LD50 Rat > 5000 mg/kg (EPA Tox Cat IV). * Estimates for product may be based on additional component data not shown. Skin corrosion/irritation Irritation Corrosion - Skin Deadline Bullets Serious eye damage/eye irritation Eye / Kay and Calandra class - Intact Deadline Bullets Respiratory or skin sensitization Respiratory sensitization Skin sensitization Sensitization Deadline Bullets Germ cell mutagenicity Carcinogenicity Causes slight skin irritation. Causes mild eye irritation. Not a respiratory sensitizer., (EPA Tox Cat IV). Result: Slightly irritating, (EPA Tox Cat iv). Result: Mild irritant. This product is not expected to cause skin sensitization. Result: Not a skin sensitizer. Species: Guinea pig No evidence of mutagenicity with in vitro testing. No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Acetaldehyde, a decomposition product of Metaldehyde, has been listed as carcinogenic in the IARC monographs and by the NTP. Acetaldehyde is present at less than 0.01% in the product. None of the components found in appreciable quantities has been found to be carcinogenic by IARC, NTP, or OSHA. OSHA Specifically Regulated Substances (29 CFR ) Not listed. Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Chronic effects 12. Ecological information Ecotoxicity No evidence of reproductive toxicity has been observed. No evidence of teratogenicity in laboratory animals. Not classified. Not classified. Not an aspiration hazard. Overexposure may aggravate preexisting conditions associated with the kidney, liver, and brain. No information is available about the potential of this material to produce adverse environmental effects. This product may be fatal to dogs, other pests, and wild animals if eaten. May be toxic to water inhabitants. Do not contaminate water bodies. Material name: Deadline Bullets Version #: 01 Issue date: SDS US 5 / 8

55 Persistence and degradability Bioaccumulative potential Mobility in soil Other adverse effects No data is available on the degradability of this product. No data available. No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Disposal instructions Local disposal regulations Hazardous waste code Waste from residues / unused products Contaminated packaging 14. Transport information DOT Not regulated as dangerous goods. IATA Not regulated as dangerous goods. IMDG Not regulated as dangerous goods. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information US federal regulations Collect and reclaim or dispose in sealed containers at licensed waste disposal site according to all applicable regulations. Dispose of contents/container in accordance with all applicable local/regional/national/international regulations. Dispose in accordance with all applicable regulations. The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Dispose of in accordance with all applicable regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Empty containers should be taken to an approved waste handling site for recycling or disposal according to all applicable regulations. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Not established. This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR This product is registered under EPA/FIFRA Regulations. It is a violation of Federal Law to use this product in any manner inconsistent with its labeling. Read and follow all label directions. This product is excluded from listing requirements under EPA/TSCA. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Metaldehyde (CAS ) SARA 304 Emergency release notification Listed. Not regulated. OSHA Specifically Regulated Substances (29 CFR ) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous chemical SARA 313 (TRI reporting) Not regulated. Yes Material name: Deadline Bullets Version #: 01 Issue date: SDS US 6 / 8

56 Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR ) Not regulated. Safe Drinking Water Act (SDWA) US state regulations Not regulated. US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) Not listed. US. Massachusetts RTK - Substance List Metaldehyde (CAS ) US. New Jersey Worker and Community Right-to-Know Act Metaldehyde (CAS ) US. Pennsylvania Worker and Community Right-to-Know Law Metaldehyde (CAS ) US. Rhode Island RTK Not regulated. US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Canada Domestic Substances List (DSL) No Canada United States & Puerto Rico Non-Domestic Substances List (NDSL) Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date References Version # 01 Further information ACGIH : American Conference of Governmental Industrial Hygienists CERCLA: Comprehensive Environmental Response, Compensation, and Liability Act EPA: Environmental Protection Agency FIFRA: Federal Insecticide, Fungicide, and Rodenticide Act IARC: International Agency for Research on Cancer NTP: National Toxicology Program OSHA: Occupational Safety and Health Agency SARA: Superfund Amendments and Reauthorization Act TSCA: Toxic Substances Control Act DOT: Department of Transportation IMDG: International Maritime Dangerous Goods IATA: International Air Transport Association Not available. HMIS ratings Health: 2* Flammability: 0 Physical hazard: 0 NFPA ratings Health: 2 Flammability: 0 Instability: 0 No No Material name: Deadline Bullets Version #: 01 Issue date: SDS US 7 / 8

57 Disclaimer Revision Information AMVAC Chemical Corporation cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. This information is provided for the limited guidance to the user. While AMVAC believes that the information is, as of the date hereof, reliable, it is the user s responsibility to determine the suitability of the information for its purposes. The user is advised not to construe the information as absolutely complete since additional information may be necessary or desirable when particular, exceptional, or variable conditions or circumstances exist (like combinations with other materials), or because of applicable regulations. No express or implied warranty of merchantability or fitness for a particular purpose or otherwise is made hereunder with respect to the information or the product to which the information relates AMVAC Chemical Corporation. All Rights Reserved. AMVAC, Deadline, Deadline Bullets, Deadline M-Ps, and the Beaker Logo are trademarks owned by AMVAC Chemical Corporation. Chemtrec is a trademark of the American Chemistry Council, Inc. HMIS is a trademark of the American Coatings Association. NFPA is a trademark of the National Fire Protection Association, Inc. ACGIH is a trademark of the American Conference of Governmental Industrial Hygienists. Product and Company Identification: Synonyms Composition / Information on Ingredients: Ingredients Physical & Chemical Properties: Multiple Properties Toxicological Information: Toxicological Property Data Transport Information: Proper Shipping Name/Packing Group Regulatory Information: United States HazReg Data: North America GHS: Classification Material name: Deadline Bullets Version #: 01 Issue date: SDS US 8 / 8

58 Bayer Environmental Science SAFETY DATA SHEET Return to Index DELTADUST INSECTICIDE 1/11 Version 4.0 / USA Revision Date: 10/06/ Print Date: 10/07/2015 SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Product identifier Trade name Product code (UVP) DELTADUST INSECTICIDE SDS Number EPA Registration No Relevant identified uses of the substance or mixture and uses advised against Use Restrictions on use Information on supplier Supplier Responsible Department Emergency telephone no. Emergency Telephone Number (24hr/ 7 days) Product Information Telephone Number Insecticide See product label for restrictions. Bayer Environmental Science 2 T.W. Alexander Drive Research Triangle PK, NC United States SDSINFO.BCS-NA@bayer.com SECTION 2: HAZARDS IDENTIFICATION Classification in accordance with regulation HCS 29CFR This material is not hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29CFR Other hazards No other hazards known. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Component Name CAS-No. Concentration % by weight Deltamethrin Crystalline quartz (respirable) Calcium carbonate

59 Bayer Environmental Science SAFETY DATA SHEET DELTADUST INSECTICIDE 2/11 Version 4.0 / USA Revision Date: 10/06/ Print Date: 10/07/2015 SECTION 4: FIRST AID MEASURES Description of first aid measures General advice Inhalation Skin contact Eye contact Ingestion When possible, have the product container or label with you when calling a poison control center or doctor or going for treatment. Move to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a physician or poison control center immediately. Take off contaminated clothing and shoes immediately. Wash off immediately with plenty of water for at least 15 minutes. Call a physician or poison control center immediately. Hold eye open and rinse slowly and gently with water for minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a physician or poison control center immediately. Call a physician or poison control center immediately. Rinse out mouth and give water in small sips to drink. DO NOT induce vomiting unless directed to do so by a physician or poison control center. Never give anything by mouth to an unconscious person. Do not leave victim unattended. Most important symptoms and effects, both acute and delayed Symptoms To date no symptoms are known. Indication of any immediate medical attention and special treatment needed Treatment Appropriate supportive and symptomatic treatment as indicated by the patient's condition is recommended. There is no specific antidote. SECTION 5: FIREFIGHTING MEASURES Extinguishing media Suitable Unsuitable Advice for firefighters Special protective equipment for fire-fighters Further information Flash point Autoignition temperature Carbon dioxide (CO2), Dry chemical, Foam, Water None known. Firefighters should wear NIOSH approved self-contained breathing apparatus and full protective clothing. Keep out of smoke. Fight fire from upwind position. Cool closed containers exposed to fire with water spray. Do not allow run-off from fire fighting to enter drains or water courses. Contain the spread of the fire-fighting media. not applicable no data available

60 Bayer Environmental Science SAFETY DATA SHEET DELTADUST INSECTICIDE 3/11 Version 4.0 / USA Revision Date: 10/06/ Print Date: 10/07/2015 Lower explosion limit Upper explosion limit Explosivity Dust explosion class not applicable not applicable no data available no data available SECTION 6: ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Precautions Methods and materials for containment and cleaning up Methods for cleaning up Additional advice Keep unauthorized people away. Isolate hazard area. Avoid contact with spilled product or contaminated surfaces. Avoid dust formation. Sweep up or vacuum up spillage and collect in suitable container for disposal. Clean contaminated floors and objects thoroughly, observing environmental regulations. Use personal protective equipment. Do not allow to enter soil, waterways or waste water canal. Reference to other sections Information regarding safe handling, see section 7. Information regarding personal protective equipment, see section 8. Information regarding waste disposal, see section 13. SECTION 7: HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Hygiene measures Handle and open container in a manner as to prevent spillage. Maintain exposure levels below the exposure limit through the use of general and local exhaust ventilation. Wash hands thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco, using the toilet or applying cosmetics. Remove Personal Protective Equipment (PPE) immediately after handling this product. Before removing gloves clean them with soap and water. Remove soiled clothing immediately and clean thoroughly before using again. Wash thoroughly and put on clean clothing. Conditions for safe storage, including any incompatibilities Requirements for storage areas and containers Store in a cool, dry place and in such a manner as to prevent cross contamination with other crop protection products, fertilizers, food, and feed. Store in original container and out of the reach of children, preferably in a locked storage area.

61 Bayer Environmental Science SAFETY DATA SHEET DELTADUST INSECTICIDE 4/11 Version 4.0 / USA Revision Date: 10/06/ Print Date: 10/07/2015 SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Components CAS-No. Control parameters Update Basis Deltamethrin mg/m3 OES BCS* (TWA) Crystalline quartz (respirable) (Respirable fraction.) mg/m3 (TWA) ACGIH Crystalline quartz (respirable) (Respirable dust.) Crystalline quartz (respirable) (Respirable dust.) Crystalline quartz (respirable) (Respirable dust.) Crystalline quartz (respirable) Crystalline quartz (respirable) Crystalline quartz (respirable) (Respirable dust.) Crystalline quartz (respirable) (Total dust.) Crystalline quartz (respirable) (Respirable.) Crystalline quartz (respirable) (Total dust.) Crystalline quartz (respirable) (Respirable.) Calcium carbonate (Respirable.) Calcium carbonate (Total) Calcium carbonate (Respirable fraction.) Calcium carbonate (Total dust.) mg/m3 (REL) mg/m3 (TWA) mg/m3 (TWA) ug/m3 (AN ESL) ug/m3 (ST ESL) mg/m3 (TWA PEL) mg/m3 (TWA PEL) mg/m3 (TWA) mg/m3 (TWA) millions of particles per cubic foot of air (TWA) mg/m3 (REL) mg/m3 (REL) mg/m3 (PEL) mg/m3 (PEL) 2010 NIOSH 1989 OSHA Z1A TN OEL TX ESL TX ESL US CA OEL US CA OEL 2000 Z Z Z NIOSH 2010 NIOSH OSHA Z OSHA Z1 Calcium carbonate mg/m OSHA Z1A

62 Bayer Environmental Science SAFETY DATA SHEET DELTADUST INSECTICIDE 5/11 Version 4.0 / USA Revision Date: 10/06/ Print Date: 10/07/2015 (Respirable fraction.) (TWA) Calcium carbonate (Total dust.) mg/m3 (TWA) Calcium carbonate mg/m3 (Total dust.) (TWA) Calcium carbonate mg/m3 (Respirable fraction.) (TWA) Calcium carbonate ug/m3 (AN ESL) Calcium carbonate ug/m3 (ST ESL) *OES BCS: Internal Bayer CropScience "Occupational Exposure Standard" Exposure controls 1989 OSHA Z1A TN OEL TN OEL TX ESL TX ESL Personal protective equipment In normal use and handling conditions please refer to the label and/or leaflet. In all other cases the following recommendations would apply. Respiratory protection When respirators are required, select NIOSH approved equipment based on actual or potential airborne concentrations and in accordance with the appropriate regulatory standards and/or industry recommendations. Hand protection Eye protection Skin and body protection General protective measures Chemical resistant nitrile rubber gloves Safety glasses or Goggles Wear long-sleeved shirt and long pants and shoes plus socks. Follow manufacturer's instructions for cleaning/maintaining PPE. If no such instructions for washables, use detergent and warm/tepid water. Keep and wash PPE separately from other laundry. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Physical State Odor Odour Threshold ph Vapor Pressure Vapor Density (Air = 1) Bulk density white powder weak characteristic no data available no data available no data available no data available ca lb/ft³(loose)

63 Bayer Environmental Science SAFETY DATA SHEET DELTADUST INSECTICIDE 6/11 Version 4.0 / USA Revision Date: 10/06/ Print Date: 10/07/2015 Evapouration rate Boiling Point Melting / Freezing Point Water solubility Minimum Ignition Energy Decomposition temperature Partition coefficient: n- octanol/water Viscosity Flash point Autoignition temperature Lower explosion limit Upper explosion limit Explosivity Dust explosion class not applicable not applicable not applicable soluble no data available no data available no data available not applicable not applicable no data available not applicable not applicable no data available no data available SECTION 10: STABILITY AND REACTIVITY Reactivity Thermal decomposition Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products no data available Stable under recommended storage conditions. No hazardous reactions known. no data available Strong acids no data available SECTION 11: TOXICOLOGICAL INFORMATION Exposure routes Immediate Effects Skin contact, Eye contact

64 Bayer Environmental Science SAFETY DATA SHEET DELTADUST INSECTICIDE 7/11 Version 4.0 / USA Revision Date: 10/06/ Print Date: 10/07/2015 Skin May be harmful if absorbed through skin. Information on toxicological effects Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity Skin irritation Eye irritation Sensitisation Assessment repeated dose toxicity LD50 (rat) > 5,050 mg/kg LC50 (rat) > 26.1 mg/l Exposure time: 4 h Determined in the form of dust. LC50 (rat) > 100 mg/l Exposure time: 1 h Determined in the form of dust. Extrapolated from the 4 hr LC50. LD50 (rabbit) > 2,020 mg/kg No skin irritation (rabbit) No eye irritation (rabbit) Non-sensitizing. (guinea pig) Deltamethrin caused neurobehavioral effects and/or neuropathological changes in animal studies. The toxic effects of Deltamethrin are related to transient hyperactivity typical for pyrethroid neurotoxicity. Assessment mutagenicity Deltamethrin was not mutagenic or genotoxic in a battery of in vitro and in vivo tests. Assessment carcinogenicity Deltamethrin was not carcinogenic in lifetime feeding studies in rats and mice. ACGIH Crystalline quartz (respirable) Group A2 NTP Crystalline quartz (respirable) IARC Deltamethrin Overall evaluation: 3 Crystalline quartz (respirable) Overall evaluation: 1 OSHA None. Assessment toxicity to reproduction Deltamethrin did not cause reproductive toxicity in a two-generation study in rats. Assessment developmental toxicity Deltamethrin caused developmental toxicity only at dose levels toxic to the dams. The developmental effects seen with Deltamethrin are related to maternal toxicity.

65 Bayer Environmental Science SAFETY DATA SHEET DELTADUST INSECTICIDE 8/11 Version 4.0 / USA Revision Date: 10/06/ Print Date: 10/07/2015 Further information Only acute toxicity studies have been performed on the formulated product. The non-acute information pertains to the active ingredient(s). SECTION 12: ECOLOGICAL INFORMATION Toxicity to fish Toxicity to aquatic invertebrates LC50 (Oncorhynchus mykiss (rainbow trout)) mg/l Exposure time: 96 h The value mentioned relates to the active ingredient deltamethrin. EC50 (Daphnia magna (Water flea)) mg/l Exposure time: 48 h The value mentioned relates to the active ingredient deltamethrin. Toxicity to aquatic plants Biodegradability EC50 (Algae) > 9.1 mg/l Exposure time: 96 h The value mentioned relates to the active ingredient deltamethrin. Deltamethrin: not rapidly biodegradable Koc Deltamethrin: Koc: Bioaccumulation Deltamethrin: Bioconcentration factor (BCF) 1,400 Does not bioaccumulate. Mobility in soil Environmental precautions Deltamethrin: Immobile in soil Do not apply directly to water, to areas where surface water is present or to intertidal areas below the mean high water mark. Do not contaminate surface or ground water by cleaning equipment or disposal of wastes, including equipment wash water. Apply this product as specified on the label. SECTION 13: DISPOSAL CONSIDERATIONS Waste treatment methods Product Contaminated packaging Pesticide, spray mixture or rinse water that cannot be used according to label instructions may be disposed of on site or at an approved waste disposal facility. Follow advice on product label and/or leaflet. Triple rinse containers. Dispose of empty container in a sanitary landfill or by incineration, or, if allowed by State/Provincial and local authorities, by burning. If burned, stay out of smoke. Follow advice on product label and/or leaflet.

66 Bayer Environmental Science SAFETY DATA SHEET DELTADUST INSECTICIDE 9/11 Version 4.0 / USA Revision Date: 10/06/ Print Date: 10/07/2015 RCRA Information Characterization and proper disposal of this material as a special or hazardous waste is dependent upon Federal, State and local laws and are the user's responsibility. RCRA classification may apply. SECTION 14: TRANSPORT INFORMATION 49CFR Not dangerous goods / not hazardous material IMDG UN number 3077 Class 9 Packaging group III Marine pollutant Proper shipping name IATA UN number 3077 Class 9 Packaging group III Environm. Hazardous Mark Proper shipping name YES ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (DELTAMETHRIN MIXTURE) YES ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (DELTAMETHRIN MIXTURE ) This transportation information is not intended to convey all specific regulatory information relating to this product. It does not address regulatory variations due to package size or special transportation requirements. Freight Classification: INSECTICIDES OR FUNGICIDES, N.O.I., OTHER THAN POISON SECTION 15: REGULATORY INFORMATION EPA Registration No US Federal Regulations TSCA list Crystalline quartz (respirable) Calcium carbonate US. Toxic Substances Control Act (TSCA) Section 12(b) Export Notification (40 CFR 707, Subpt D) None. SARA Title III - Section Notification and Information None. SARA Title III - Section Toxic Chemical Release Reporting None.

67 Bayer Environmental Science SAFETY DATA SHEET DELTADUST INSECTICIDE 10/11 Version 4.0 / USA Revision Date: 10/06/ Print Date: 10/07/2015 US States Regulatory Reporting CA Prop65 This product contains a chemical known to the State of California to cause cancer. Crystalline quartz (respirable) This product does not contain any substances known to the State of California to cause reproductive harm. US State Right-To-Know Ingredients Crystalline quartz (respirable) MN Calcium carbonate MN Canadian Regulations Canadian Domestic Substance List None. Environmental CERCLA None. Clean Water Section 307 Priority Pollutants None. Safe Drinking Water Act Maximum Contaminant Levels None. EPA/FIFRA Information: This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information required on the pesticide label: Signal word: Hazard statements: Caution! May be harmful if absorbed through skin. Avoid contact with skin, eyes and clothing. Wash thoroughly with soap and water after handling. SECTION 16: OTHER INFORMATION Abbreviations and acronyms 49CFR Code of Federal Regulations, Title 49 ACGIH US. ACGIH Threshold Limit Values CAS-Nr. Chemical Abstracts Service number EINECS European inventory of existing commercial substances ELINCS European list of notified chemical substances IARC US. IARC Monographs on Occupational Exposures to Chemical Agents IATA International Air Transport Association IMDG International Maritime Dangerous Goods

68 Bayer Environmental Science SAFETY DATA SHEET DELTADUST INSECTICIDE 11/11 Version 4.0 / USA Revision Date: 10/06/ Print Date: 10/07/2015 N.O.S. NTP OECD TDG TWA UN WHO Not otherwise specified US. National Toxicology Program (NTP) Report on Carcinogens Organization for Economic Co-operation and Development Transportation of Dangerous Goods Time weighted average United Nations World health organisation NFPA 704 (National Fire Protection Association): Health - 1 Flammability - 0 Instability - 0 Others - none HMIS (Hazardous Materials Identification System, based on the Third Edition Ratings Guide) Health - 0 Flammability - 0 Physical Hazard - 0 PPE - 0 = minimal hazard, 1 = slight hazard, 2 = moderate hazard, 3 = severe hazard, 4 = extreme hazard Reason for Revision: The following sections have been revised: Section 15: Regulatory information. Revision Date: 10/06/2015 This information is provided in good faith but without express or implied warranty. The customer assumes all responsibility for safety and use not in accordance with label instructions. The product names are registered trademarks of Bayer.

69 Safety Data Sheet Return to Index DEMAND CS Insecticide Date: Replaces: 6/12/2015 1/28/ PRODUCT IDENTIFICATION Product identifier on label: DEMAND CS Insecticide Product No.: A12690A Use: Manufacturer: Insecticide Syngenta Crop Protection, LLC Post Office Box Greensboro NC Manufacturer Phone: Emergency Phone: HAZARDS IDENTIFICATION Classifications: Signal Word (OSHA): Hazard Statements: Inhalation: Category 4 Skin Sensitizer: Category 1B Specific Target Organ Toxicity: Repeated Category 2 Specific Target Organ Toxicity: Drowsiness Category 3 Specific Target Organ Toxicity: Respiratory Irritation Category 3 Warning May cause an allergic skin reaction Harmful if inhaled May cause respiratory irritation May cause drowsiness or dizziness May cause damage to organs Hazard Symbols: Precautionary Statements: Do not breathe mist, vapors, spray. Use only outdoors or in a well-ventilated area. Contaminated work clothing must not be allowed out of the workplace. Wear protective gloves, protective clothing, eye protection. If on skin: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center, doctor or Syngenta if you feel unwell. See Section 4 First Aid Measures. Wash contaminated clothing before reuse. Page 1 of 9

70 Safety Data Sheet DEMAND CS Insecticide Date: Replaces: 6/12/2015 1/28/2015 Store locked up. Dispose of contents and container in accordance with local regulations. Other Hazard Statements: May cause temporary itching, tingling, burning or numbness of exposed skin, called paresthesia. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name Common Name CAS Number Xylene Xylene <1% 1,2,4-Trimethylbenzene 1,2,4-Trimethylbenzene <2.5% Cumene Cumene <1% Ingredients not precisely identified are proprietary or non-hazardous. Values are not product specifications. Concentration 1,2-Propanediol Propylene Glycol Trade Secret Petroleum Solvent Petroleum Solvent Trade Secret Other ingredients Other ingredients Trade Secret >85.8% [1a(S*),3a(Z)]-cyano(3- phenoxyphenyl)methyl-3-(2-chloro-3,3,3- trifluoro-1-propenyl)-2,2- dimethylcyclopropanecarboxylate Lambda-Cyhalothrin % 4. FIRST AID MEASURES Have the product container, label or Safety Data Sheet with you when calling Syngenta ( ), a poison contol center or doctor, or going for treatment. Ingestion: Eye Contact: Skin Contact: Inhalation: If swallowed: Call Syngenta ( ), a poison control center or doctor immediately for treatment advice. Do not give any liquid to the person. Do not induce vomiting unless told to do so after calling or by a poison control center or doctor. Do not give anything by mouth to an unconscious person. If in eyes: Hold eye open and rinse slowly and gently with water for minutes. Remove contact lenses, if present, after 5 minutes, then continue rinsing eye. Call Syngenta ( ), a poison control center or doctor for treatment advice. If on skin or clothing: Take off contaminated clothing. Rinse skin immediately with plenty of water for minutes. Call Syngenta ( ), a poison control center or doctor for treatment advice. If inhaled: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call Syngenta ( ), a poison control center or doctor for further treatment advice. Most important symptoms/effects: Allergic skin reaction Drowsiness or dizziness Respiratory irritation Indication of immediate medical attention and special treatment needed: There is no specific antidote if this product is ingested. Treat symptomatically. Persons suffering a temporary allergic reaction may respond to treatment with antihistamines or steroid creams and/or systemic steroids. Page 2 of 9

71 Safety Data Sheet DEMAND CS Insecticide Date: Replaces: 6/12/2015 1/28/2015 Skin contact paresthesia effects (itching, tingling, burning or numbness) are transient, lasting up to 24 hours. Treat symptomatically. Contains petroleum distillate - vomiting may cause aspiration pneumonia. 5. FIRE FIGHTING MEASURES Suitable (and unsuitable) extinguishing media: Use dry chemical, foam or CO2 extinguishing media. If water is used to fight fire, dike and collect runoff. Specific Hazards: During a fire, irritating and possibly toxic gases may be generated by thermal decomposition or combustion. Special protective equipment and precautions for firefighters: Wear full protective clothing and self-contained breathing apparatus. Evacuate nonessential personnel from the area to prevent human exposure to fire, smoke, fumes or products of combustion. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment, and emergency procedures: Follow exposure controls/personal protection outlined in Section 8. Methods and materials for containment and cleaning up: Control the spill at its source. Contain the spill to prevent from spreading or contaminating soil or from entering sewage and drainage systems or any body of water. Clean up spills immediately, observing precautions in Protective Equipment Section. Cover entire spill with absorbing material and place into compatible disposal container. Scrub area with hard water detergent (e.g. commercial products such as Tide, Joy, Spic and Span). Pick up wash liquid with additional absorbent and place into compatible disposal container. Once all material is cleaned up and placed in a disposal container, seal container and arrange for disposition. 7. HANDLING AND STORAGE Precautions for safe handling: Store the material in a well-ventilated, secure area out of reach of children and domestic animals. Do not store food, beverages or tobacco products in the storage area. Prevent eating, drinking, tobacco use, and cosmetic application in areas where there is a potential for exposure to the material. Wash thoroughly with soap and water after handling. Conditions for safe storage, including any incompatibilities: Store locked up. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION THE FOLLOWING RECOMMENDATIONS FOR EXPOSURE CONTROLS/PERSONAL PROTECTION ARE INTENDED FOR THE MANUFACTURE, FORMULATION AND PACKAGING OF THIS PRODUCT. FOR COMMERCIAL APPLICATIONS AND/OR ON-FARM APPLICATIONS CONSULT THE PRODUCT LABEL. Occupational Exposure Limits: Chemical Name OSHA PEL ACGIH TLV Other Source Xylene 100 ppm TWA 100 ppm TWA; 150 ppm STEL 100 ppm TWA NIOSH 1,2,4-Trimethylbenzene Not Established 25 ppm TWA 25 ppm TWA NIOSH Cumene 50 ppm TWA (skin) 50 ppm TWA Not Established Not Applicable Page 3 of 9

72 Safety Data Sheet DEMAND CS Insecticide Date: Replaces: 6/12/2015 1/28/2015 Propylene Glycol Not Established Not Established 10 mg/m³ TWA AIHA Petroleum Solvent Not Established Not Established 100 mg/m³ (19 ppm) TWA Manufacturer Other ingredients Not Applicable Not Applicable Not Applicable Not Applicable Lambda-Cyhalothrin Not Established Not Established 0.04 mg/m³ TWA (skin) Syngenta Appropriate engineering controls: Use effective engineering controls to comply with occupational exposure limits (if applicable). Individual protection measures: Ingestion: Prevent eating, drinking, tobacco usage and cosmetic application in areas where there is a potential for exposure to the material. Wash thoroughly with soap and water after handling. Eye Contact: Where eye contact is likely, use chemical splash goggles. Skin Contact: Where contact is likely, wear chemical-resistant gloves (such as barrier laminate, butyl rubber, nitrile rubber or Viton), coveralls, socks and chemical-resistant footwear. Stringent housekeeping measures are necessary to prevent translocation of the material from contaminated work surfaces to uncontaminated surfaces (railings, doors, etc.). Unprotected contact with such translocated material can result in paresthesia effects (see Section 11). Inhalation: A combination particulate/organic vapor respirator should be used until effective engineering controls are installed to comply with occupational exposure limits, or until exposure limits are established. Use a NIOSH approved respirator with an organic vapor (OV) cartridge or canister with any R, P or HE filter. Use a self-contained breathing apparatus in cases of emergency spills, when exposure levels are unknown, or under any circumstances where air-purifying respirators may not provide adequate protection. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Off-white liquid Odor: Slight odor/typical aromatic solvent Odor Threshold: Not Available ph: 7.3 (1% w/w dilution in deionized water) Melting point/freezing point: Not Applicable Initial boiling point and boiling range: 212 F Flash Point (Test Method): Flammable Limits (% in Air): Flammability: > 212 F (Setaflash) Not Available Not Applicable Vapor Pressure: Lambda-Cyhalothrin 1.5 x 10(-9) 68 F (20 C) Vapor Density: Not Available Relative Density: 68 F (20 C) Solubility (ies): Lambda-Cyhalothrin mg/l Partition coefficient: n-octanol/water: Not Available Page 4 of 9

73 Safety Data Sheet DEMAND CS Insecticide Date: 6/12/2015 Replaces: 1/28/2015 Autoignition Temperature: Not Available Decomposition Temperature: Not Available Viscosity: Not Available Other: None 10. STABILITY AND REACTIVITY Reactivity: Not reactive. Chemical stability: Stable under normal use and storage conditions. Possibility of hazardous reactions: Will not occur. Conditions to Avoid: None known. Incompatible materials: None known. Hazardous Decomposition Products: None known. 11. TOXICOLOGICAL INFORMATION Health effects information Likely routes of exposure: Symptoms of exposure: Dermal, Inhalation Drowsiness or dizziness, Respiratory irritation Delayed, immediate and chronic effects of exposure: Allergic skin reaction, Drowsiness or dizziness, Respiratory system effects, Paresthesia Numerical measures of toxicity (acute toxicity/irritation studies (finished product)) Ingestion: Oral (LD50 Rat) : > 5000 mg/kg body weight Dermal: Inhalation: Eye Contact: Dermal (LD50 Rat) : Inhalation (LC50 Rat) : Non-Irritating (Rabbit) > 2000 mg/kg body weight > 4.62 mg/l Skin Contact: Skin Sensitization: Practically Non-Irritating (Rabbit) A weak skin sensitizer in animal tests. Reproductive/Developmental Effects Lambda-Cyhalothrin : Not a developmental or reproductive toxicant. Chronic/Subchronic Toxicity Studies Lambda-Cyhalothrin : Reversible paresthesia (abnormal skin sensation). Reversible clinical signs of neurotoxicity in mammals. Carcinogenicity Page 5 of 9

74 Safety Data Sheet DEMAND CS Insecticide Date: Replaces: 6/12/2015 1/28/2015 Lambda-Cyhalothrin : No treatment-related tumors in rats or mice. Chemical Name Xylene IARC Group 3 1,2,4-Trimethylbenzene Cumene 1,2-Propanediol Petroleum Solvent Other ingredients [1a(S*),3a(Z)]-cyano(3-phenoxyphenyl)methyl- 3-(2-chloro-3,3,3-trifluoro-1-propenyl)-2,2- dimethylcyclopropanecarboxylate Other Toxicity Information In humans, contact with exposed skin may result in temporary itching, tingling, burning or numbness, called paresthesia. The effect may result from splash, aerosol, or hot vapor contact, or transfer to the face from contaminated gloves and hands. The symptoms normally disappear within 24 hours. Face and genital areas are especially susceptible to this effect. Paresthesia involving the face is also known as "subjective facial sensation" or SFS. Toxicity of Other Components 1,2,4-Trimethylbenzene Inhalation of 1,2,4-trimethylbenzene at high concentrations can cause central nervous system depression, respiratory tract irritation, asphyxiation, cardiac stress and coma. Effects of chronic exposure to this solvent can include blood disorders (anemia, leukopenia) and kidney or liver damage. Cumene Exposure to cumene vapors may cause irritation to eyes, skin, and respiratory tract. Cumene may also cause headaches, dizziness, anesthesia, drowsiness, unconsciousness and other central nervous system effects. Prolonged exposure to high concentrations (>100 PPM) may result in liver, kidney or lung damage. Other ingredients Not Applicable NTP/IARC/OSHA Carcinogen No No No No No No Petroleum Solvent The supplier reports that high vapor/aerosol concentrations (> 1000 ppm) are irritating to the eyes and the respiratory tract, may cause headaches, dizziness, anesthesia, drowsiness, unconsciousness and other central nervous system effects. Propylene Glycol Reported to cause central nervous system depression (anesthesia, dizziness, confusion), headache and nausea. Also, eye irritation may occur with lacrimation but no residual discomfort or injury. Prolonged contact to skin may cause mild to moderate irritation and possible allergic reactions. Chronic dietary exposure caused kidney and liver injury in experimental animals. Xylene Inhalation of xylene at high concentrations can cause central nervous system depression, respiratory tract irritation, asphyxiation, cardiac stress and coma. Target Organs Active Ingredients Lambda-Cyhalothrin : Inert Ingredients 1,2,4-Trimethylbenzene: Cumene: Other ingredients: Petroleum Solvent: Liver, nervous system CNS, liver, kidney, blood, respiratory tract, skin, eye Skin, eye, liver, respiratory tract, kidney, CNS Not Applicable Eye, respiratory tract, CNS Page 6 of 9

75 Safety Data Sheet DEMAND CS Insecticide Date: Replaces: 6/12/2015 1/28/2015 Propylene Glycol: Xylene: CNS, kidney, liver CNS, respiratory tract, skin 12. ECOLOGICAL INFORMATION Eco-Acute Toxicity Lambda-Cyhalothrin : Fish (Rainbow Trout) 96-hour LC ppb Bird (Mallard Duck) LD50 Oral > 3950 mg/kg Invertebrate (Water Flea) 48-hour EC ppb Environmental Fate Lambda-Cyhalothrin : The information presented here is for the active ingredient, lambda-cyhalothrin. Not persistent in soil or water. Immobile in soil. Sinks in water (after 24 h). 13. DISPOSAL CONSIDERATIONS Disposal: Do not reuse product containers. Dispose of product containers, waste containers, and residues according to local, state, and federal health and environmental regulations. Characteristic Waste: Not Applicable Listed Waste: 14. TRANSPORT INFORMATION Not Applicable DOT Classification Ground Transport - NAFTA Containers < 450 liters: Not regulated Containers > 450 liters: Proper Shipping Name: Environmentally Hazardous Substance, Liquid, N.O.S. (Lambda-Cyhalothrin) Hazard Class or Division: Class 9 Identification Number: UN 3082 Packing Group: PG III Comments Water Transport - International Proper Shipping Name: Environmentally Hazardous Substance, Liquid, N.O.S. (Lambda-Cyhalothrin), Marine Pollutant Hazard Class or Division: Class 9 Identification Number: UN 3082 Packing Group: PG III Air Transport Proper Shipping Name: Environmentally Hazardous Substance, Liquid, N.O.S. (Lambda-Cyhalothrin) Hazard Class or Division: Class 9 Identification Number: UN 3082 Packing Group: PG III Page 7 of 9

76 Safety Data Sheet DEMAND CS Insecticide Date: Replaces: 6/12/2015 1/28/ REGULATORY INFORMATION Pesticide Registration: This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: Caution: Harmful if absorbed through skin. Avoid breathing spray mist or vapor. Avoid contact with skin, eyes, or clothing. Wash thoroughly with soap and water after handling, and before eating, drinking, chewing gum, using tobacco, or using the toilet. Remove contaminated clothing and wash before reuse. Prolonged or frequently repeated skin contact may cause allergic skin reactions in some individuals. EPA Registration Number(s): EPCRA SARA Title III Classification: Section 311/312 Hazard Classes: Section 313 Toxic Chemicals: Acute Health Hazard Chronic Health Hazard Xylene <1% (CAS No ) 1,2,4-Trimethylbenzene <2.5% (CAS No ) Cumene <1% (CAS No ) CERCLA/SARA 304 Reportable Quantity (RQ): Report product spills > 520 gal. (based on xylene [RQ = 100 lbs.] content in the formulation) RCRA Hazardous Waste Classification (40 CFR 261): Not Applicable TSCA Status: Exempt from TSCA, subject to FIFRA 16. OTHER INFORMATION NFPA Hazard Ratings Health: Flammability: Instability: Syngenta Hazard Category: C,S HMIS Hazard Ratings Health: Flammability: Reactivity: Minimal 1 Slight 2 Moderate 3 Serious 4 Extreme * Chronic Original Issued Date: Revision Date: Section(s) Revised: 7/14/1999 6/12/2015 2, 4, 11 For non-emergency questions about this product call: Replaces: 1/28/2015 The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with respect to the information contained herein. Page 8 of 9

77 Safety Data Sheet DEMAND CS Insecticide Date: 6/12/2015 Replaces: 1/28/2015 Page 9 of 9

78 Return to Index... EcoPCO ACU Insecticide Safety Data Sheet Section 1: Identification Product identifier Product Name Synonyms Product Description EcoPCO ACU Insecticide EPA Reg. No.: Colorless aerosol spray. Relevant identified uses of the substance or mixture and uses advised against Recommended use Restrictions on use Insecticide. KEEP OUT OF THE REACH OF CHILDREN. Keep away from heat, sparks and flames. Do not take internally. Avoid contact with eyes and skin. Avoid inhalation of vapors or fumes. Details of the supplier of the safety data sheet Manufacturer Central Garden & Pet Company 1501 E. Woodfield Road, Suite 200W Schaumburg, IL United States Emergency telephone number Manufacturer Manufacturer CHEMTREC Outside North America Collect Calls Accepted CHEMTREC Manufacturer Section 2: Hazard Identification United States (US) According to: OSHA 29 CFR HCS Classification of the substance or mixture OSHA HCS 2012 Aspiration 1 Flammable Aerosols 2 Skin Irritation 2 Specific Target Organ Toxicity Single Exposure 3: Narcotic Effects Eye Irritation 2A Label elements OSHA HCS 2012 DANGER Preparation Date: 10/July/2015 Revision Date: 10/July/2015 Page 1 of 9 Format: GHS Language: English (US) OSHA HCS 2012

79 EcoPCO ACU Insecticide Hazard statements Flammable aerosol May be fatal if swallowed and enters airways Causes skin irritation May cause drowsiness or dizziness Causes serious eye irritation Precautionary statements Prevention Avoid breathing dust, fume, gas, mist, vapours and/or spray. Keep away from heat, sparks, open flames and/or hot surfaces. No smoking. Pressurized container: Do not pierce or burn, even after use. Wash thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection. Use only outdoors or in a well ventilated area. Do not spray on an open flame or other ignition source. Response IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Do NOT induce vomiting. IF INHALED: Remove person to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment, see supplemental first aid information in Section 4 First Aid Measures. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Storage/Disposal Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50ºC/122ºF. Store in a well ventilated place. Keep container tightly closed. Other hazards OSHA HCS 2012 Under United States Regulations (29 CFR Hazard Communication Standard), this product is considered hazardous. Section 3 Composition/Information on Ingredients Substances Mixtures Material does not meet the criteria of a substance. Composition Chemical Name Identifiers % 2 Phenethyl Propionate CAS: % Benzyl alcohol CAS: % Distillates (petroleum), hydrotreated light CAS: % Propane CAS: % Other ingredients NDA 6% Preparation Date: 10/July/2015 Revision Date: 10/July/2015 Page 2 of 9 Format: GHS Language: English (US) OSHA HCS 2012

80 EcoPCO ACU Insecticide Section 4: First Aid Measures Description of first aid measures Inhalation Skin Eye Ingestion IF INHALED: Remove person to fresh air and keep at rest in a position comfortable for breathing. Call a poison control center or doctor if you feel unwell. IF ON SKIN: Wash skin with soap and water. If skin irritation occurs: Get medical advice/attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF SWALLOWED: Immediately call a poison control center or doctor. Do NOT induce vomiting. Most important symptoms and effects, both acute and delayed Aspiration hazard, may cause dizziness or drowsiness if vapor is inhaled, causes skin irritation, causes serious eye irritation. Refer to Section 11 Toxicological Information. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically and supportively. May present an aspiration hazard. Section 5: Fire Fighting Measures Extinguishing media Suitable Extinguishing Media Use CO2, dry chemical, or foam. Unsuitable Extinguishing Media Firefighting Procedures Water is unsuitable for use on burning material but may be used to cool containers exposed to heat. Do not allow fire fighting water to escape into waterways or sewers. Flammable aerosols exposed to high temperatures may rupture, rocket and cause secondary hazards. Move containers from fire area if you can do it without risk. Ventilate closed spaces before entering. Do not breathe gas/fumes/vapor/spray. Special hazards arising from the substance or mixture Unusual Fire and Explosion Hazards Hazardous Combustion Products Advice for firefighters Containers may explode when heated. Flammable aerosols exposed to high temperatures may rupture, rocket and cause secondary hazards. Flammable; may be ignited by heat, sparks or flames. At temperatures above 130 F, container may rupture. Carbon monoxide and carbon dioxide. Wear positive pressure self contained breathing apparatus (SCBA). Section 6 Accidental Release Measures Personal precautions, protective equipment and emergency procedures Personal Precautions Emergency Procedures Environmental precautions Approach leaking or punctured pressurized containers cautiously. Isolate leaking container from all sources of ignition. Ventilate the area before entry. Avoid breathing fumes. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Ventilate closed spaces before entering. Avoid unnecessary personnel and equipment traffic in the spill area. Preparation Date: 10/July/2015 Revision Date: 10/July/2015 Page 3 of 9 Format: GHS Language: English (US) OSHA HCS 2012

81 EcoPCO ACU Insecticide Avoid run off to waterways and sewers. Methods and material for containment and cleaning up Containment/Clean up Measures Section 7 Handling and Storage Precautions for safe handling Handling SMALL SPILLS: Take up with sand or other non combustible absorbent material and place into containers for later disposal. Do not flush to sewer or allow to enter waterways. Keep away from fire No Smoking. Contents under pressure, do not crush, puncture or incinerate. Exposure to temperatures above 130ºF may cause bursting. Avoid contact with skin, eyes, and clothing. Wash thoroughly with soap and water after handling and before eating, drinking, or using tobacco. Conditions for safe storage, including any incompatibilities Storage Incompatible Materials or Ignition Sources Keep away from fire, sparks and heated surfaces. Store in cool, dry area, inaccessible to children. Store locked up. Keep container tightly closed and do not store above 130 F(55 C). Ventilate enclosed areas. NFPA Aerosol Classification: Level 1. Oxidizing agents. Heat, sparks, open flame. Section 8 Exposure Controls/Personal Protection Control parameters Exposure Limits/Guidelines Propane ( ) No data available. Exposure Limits/Guidelines Result ACGIH NIOSH OSHA TWAs 1000 ppm TWA (listed under Aliphatic hydrocarbon gases: Alkane C1 4) 1000 ppm TWA; 1800 mg/m3 TWA 1000 ppm TWA; 1800 mg/m3 TWA Exposure Limits Supplemental ACGIH Propane ( ): TLV Basis Critical Effects: (asphyxia (See Appendix F: Minimal Oxygen Content)) Exposure controls Engineering Measures/Controls Personal Protective Equipment Pictograms Use adequate ventilation to remove vapors (fumes, dust etc) Respiratory Eye/Face Hands Skin/Body Environmental Exposure Controls Follow the OSHA respirator regulations found in 29 CFR Use a NIOSH/MSHA approved respirator if exposure limits are exceeded or symptoms are experienced. Wear safety goggles. Impervious gloves. If prolonged exposure is anticipated, it is recommended for handlers to wear appropriate clothing to prevent skin contact. Refer to Section 13 Disposal Considerations. Preparation Date: 10/July/2015 Revision Date: 10/July/2015 Page 4 of 9 Format: GHS Language: English (US) OSHA HCS 2012

82 EcoPCO ACU Insecticide Section 9 Physical and Chemical Properties Information on Physical and Chemical Properties Material Description Physical Form Aerosol Appearance/Description Colorless aerosol spray. Color Colorless liquid in container / colorless aerosol when discharged. Odor Very faint, almost odorless. Aerosol Type Spray Odor Threshold No data available General Properties Boiling Point No data available Melting Point/Freezing Point 17ºF ( 8ºC) Decomposition Temperature No data available ph No data available Specific Gravity/Relative Density Bulk Density No data available Water Solubility No data available Viscosity No data available Explosive Properties No data available Volatility Vapor Pressure No data available Vapor Density 5.26 Air=1 Evaporation Rate Flammability Less than n butyl acetate Flash Point No data available UEL No data available LEL No data available Autoignition No data available Heat of Combustion (ΔHc) 11.3 kj/g Flammability (solid, gas) Flammable aerosol. Environmental Octanol/Water Partition coefficient No data available Flame Extension >43 cm (>17 in) Section 10: Stability and Reactivity Reactivity Chemical stability Non reactive Stable Possibility of hazardous reactions Conditions to avoid Incompatible materials Store away from oxidizers. Hazardous decomposition products Flammable, aerosols exposed to high temperatures may rupture, rocket and cause secondary hazards. Keep away from fire. Heat, sparks, open flame. Excessive heat. Strong oxidizers. None. However, as with any organic material, combustion will product carbon dioxide and possibly carbon monoxide. Preparation Date: 10/July/2015 Revision Date: 10/July/2015 Page 5 of 9 Format: GHS Language: English (US) OSHA HCS 2012

83 EcoPCO ACU Insecticide Section 11 Toxicological Information Information on toxicological effects GHS Properties Acute toxicity Classification Aspiration Hazard OSHA HCS 2012 Aspiration 1 Carcinogenicity Germ Cell Mutagenicity OSHA HCS 2012 Acute Toxicity Dermal Classification criteria not met; Acute Toxicity Inhalation Classification criteria not met; Acute Toxicity Oral Classification criteria not met OSHA HCS 2012 Classification criteria not met OSHA HCS 2012 Classification criteria not met Skin corrosion/irritation OSHA HCS 2012 Skin Irritation 2 Skin sensitization STOT RE STOT SE Toxicity for Reproduction Respiratory sensitization Serious eye damage/irritation OSHA HCS 2012 Classification criteria not met OSHA HCS 2012 Classification criteria not met OSHA HCS 2012 Specific Target Organ Toxicity Single Exposure 3: Narcotic Effects OSHA HCS 2012 Classification criteria not met OSHA HCS 2012 Classification criteria not met OSHA HCS 2012 Eye Irritation 2A Route(s) of entry/exposure Potential Health Effects Inhalation Acute (Immediate) Chronic (Delayed) Skin Acute (Immediate) Chronic (Delayed) Eye Acute (Immediate) Chronic (Delayed) Ingestion Acute (Immediate) Chronic (Delayed) Other Chronic (Delayed) Mutagenic Effects Carcinogenic Effects Reproductive Effects Inhalation, Skin, Eye, Ingestion. May affect the central nervous system. Symptoms may include dizziness or drowsiness. No data available. Causes skin irritation. No data available. Causes serious eye irritation. No data available. Aspiration Hazard may be fatal if swallowed and enters airways. No data available. None known. No data available. No data available. No data available. Section 12 Ecological Information Toxicity Preparation Date: 10/July/2015 Revision Date: 10/July/2015 Page 6 of 9 Format: GHS Language: English (US) OSHA HCS 2012

84 EcoPCO ACU Insecticide No data available Persistence and degradability No data available. Bioaccumulative potential No data available. Mobility in Soil No data available. Other adverse effects No data available. Ecological Fate No data available. Section 13 Disposal Considerations Waste treatment methods Product waste Do not puncture or incinerate. If partly filled: Call your local solid waste agency for disposal instructions. Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Packaging waste If empty: Place in trash or offer for recycling if available. Do not puncture or incinerate. Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Section 14 Transport Information UN number UN proper shipping name Transport hazard class (es) Packing group Environmental hazards DOT UN1950 Aerosols 2.1 Not Applicable Not Applicable IMO/IMDG UN1950 Aerosols 2.1 Not Applicable Not Applicable IATA/ICAO UN1950 Aerosols, flammable 2.1 Not Applicable Not Applicable Special precautions for user None specified. Transport in bulk according No data available to Annex II of MARPOL 73/78 and the IBC Code Other information No data available. IMO/IMDG No data available Key to abbreviations = N/A = Not applicable. IATA/ICAO No data available Section 15 Regulatory Information Safety, health and environmental regulations/legislation specific for the substance or mixture SARA Hazard Classifications Acute Preparation Date: 10/July/2015 Revision Date: 10/July/2015 Page 7 of 9 Format: GHS Language: English (US) OSHA HCS 2012

85 EcoPCO ACU Insecticide FIFRA Pesticide Labeling This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of nonpesticide chemicals. The hazard information required on the pesticide label is reproduced below. The pesticide label also includes other important information, including directions for use. CAUTION Hazard Statements Keep out of reach of children. Precautionary Statements Hazards to Humans and Domestic Animals PRECAUTIONARY STATEMENTS Hazards to Humans & Domestic Animals CAUTION Causes moderate eye irritation. Avoid contact with eyes or clothing. Wear safety glasses, safety goggles, or face shield. Wash Thoroughly with soap and water after handling and before eating, drinking, chewing gum or using tobacco. First Aid IF IN EYES: Hold eye open and rinse slowly and gently with water for minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. Note to Physician: Contains petroleum distillate vomiting may cause aspiration pneumonia. Environmental Hazards For terrestrial uses: Do not apply directly to water, or to areas where surface water is present or to intertidal areas below the mean high water mark. Do not contaminate water when disposing of equipment washwaters or rinsate. Physical or Chemical Hazards Flammable. Contents under pressure. Keep away from fire, sparks, and heated surfaces. Do not puncture or incinerate container. Exposure to temperatures above 130 F may cause bursting. Inventory Component CAS TSCA Benzyl alcohol Yes Distillates (petroleum), hydrotreated light Yes Propane Yes 2 Phenethyl Propionate Yes United States Environment U.S. RCRA (Resource Conservation & Recovery Act) List for Hazardous Constituents Propane Not Listed 2 Phenethyl Propionate Not Listed Distillates (petroleum), hydrotreated light Not Listed Benzyl alcohol U.S. RCRA (Resource Conservation & Recovery Act) TSD Facilities Ground Water Monitoring Propane Not Listed 2 Phenethyl Propionate Not Listed Distillates (petroleum), hydrotreated light Not Listed Benzyl alcohol Section 16 Other Information Preparation Date: 10/July/2015 Revision Date: 10/July/2015 Page 8 of 9 Format: GHS Language: English (US) OSHA HCS 2012

86 EcoPCO ACU Insecticide Last Revision Date Preparation Date Disclaimer/Statement of Liability 10/July/ /July/2015 The information and statements herein are believed to be reliable but are not to be construed as a warranty or representation for which we assume legal responsibility. Users should undertake sufficient verification and testing to determine the suitability for their own particular purpose of any information or products referred to herein. NO WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE IS MADE. Preparation Date: 10/July/2015 Revision Date: 10/July/2015 Page 9 of 9 Format: GHS Language: English (US) OSHA HCS 2012

87 Return to Index... SAFETY DATA SHEET EndZone Insecticide Sticker SDS # : A Revision date: Format: NA Version 1 1. PRODUCT AND COMPANY IDENTIFICATION Product Identifier Product Name EndZone Insecticide Sticker Other means of identification Product Code(s) Synonyms Active Ingredient(s) Chemical Family A ACETAMIPRID: (E)-1-(6-chloro-3-pyridylmethyl)-N-nitroimidazolidin-2-ylideneamine;(2E)-1-[(6-chloro-3-pyrid inyl)methyl]-n-nitro-2-imidazolidinimine Acetamiprid Neonicotinoid Recommended use of the chemical and restrictions on use Recommended Use: Restrictions on Use: Manufacturer Address Emergency telephone number Pesticide Use as recommended by the label FMC Corporation 1735 Market Street Philadelphia, PA (215) (General Information) msdsinfo@fmc.com ( General Information) For leak, fire, spill or accident emergencies, call: / (CHEMTREC - U.S.A.) / (CHEMTREC - Collect - All Other Countries) Medical Emergencies: / (PROSAR - U.S.A. & Canada) / (PROSAR - All Other Countries - Collect) 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR ) Acute toxicity - Oral Category 4 GHS Label elements, including precautionary statements Page 1 / 7

88 EndZone Insecticide Sticker Warning Hazard Statements H302 - Harmful if swallowed EMERGENCY OVERVIEW SDS # : A Revision date: Version 1 Precautionary Statements - Prevention P264 - Wash face, hands and any exposed skin thoroughly after handling P270 - Do not eat, drink or smoke when using this product P301 + P312 - IF SWALLOWED: Call a POISON CENTER or doctor if you feel unwell P330 - Rinse mouth Precautionary Statements - Disposal P501 - Dispose of contents/ container to an approved waste disposal plant Hazards not otherwise classified (HNOC) No hazards not otherwise classified were identified. Other Information No information available 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Family Neonicotinoid. Chemical name CAS-No Weight % Acetamiprid Synonyms are provided in Section FIRST AID MEASURES Eye Contact Hold eyes open and rinse slowly and gently with water for 15 to 20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for further treatment advice. Skin Contact Take off contaminated clothing. Rinse skin immediately with plenty of water for minutes. Call a poison control center or doctor for further treatment advice. Inhalation Ingestion Most important symptoms and effects, both acute and delayed Indication of immediate medical attention and special treatment needed, if necessary Not applicable. Call a poison control center or doctor immediately for treatment advice Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by a poison control center or doctor Never give anything by mouth to an unconscious person None known. Treat symptomatically. Page 2 / 7

89 EndZone Insecticide Sticker Suitable Extinguishing Media Specific Hazards Arising from the Chemical Explosion data Sensitivity to Mechanical Impact Sensitivity to Static Discharge Protective equipment and precautions for firefighters 5. FIRE-FIGHTING MEASURES Carbon dioxide (CO2). Foam. Water spray. Dry powder. Not flammable Not sensitive. Not sensitive. Wear self-contained breathing apparatus and protective suit. 6. ACCIDENTAL RELEASE MEASURES SDS # : A Revision date: Version 1 Personal Precautions Isolate and post spill area. Wear suitable protective clothing, gloves and eye/face protection. For personal protection see section 8. Other For further clean-up instructions, call FMC Emergency Hotline number listed in Section 1 "Product and Company Identification" above. Environmental Precautions Methods for Containment Methods for cleaning up See Section 12 for additional Ecological Information. Sweep up and shovel into suitable containers for disposal. Clean and neutralize spill area, tools and equipment by washing with bleach water and soap. Absorb rinsate and add to the collected waste. Waste must be classified and labeled prior to recycling or disposal. Dispose of waste as indicated in Section HANDLING AND STORAGE Handling Storage Incompatible products Do not contaminate other pesticides, fertilizers, water, food, or feed by storage or disposal. Keep in a dry, cool and well-ventilated place. Keep away from open flames, hot surfaces and sources of ignition. Keep out of reach of children and animals. Keep/store only in original container. None known 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies Appropriate engineering controls Engineering measures Apply technical measures to comply with the occupational exposure limits. When working in confined spaces (tanks, containers, etc.), ensure that there is a supply of air suitable for breathing and wear the recommended equipment. Individual protection measures, such as personal protective equipment Eye/Face Protection Skin and Body Protection Hand Protection If there is a potential for exposure to particles which could cause eye discomfort, wear chemical goggles. Wear suitable protective clothing. Protective shoes or boots. Protective gloves Page 3 / 7

90 EndZone Insecticide Sticker Respiratory Protection Hygiene measures General information SDS # : A Revision date: Version 1 If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Respiratory protection must be provided in accordance with current local regulations. Clean water should be available for washing in case of eye or skin contamination. Wash skin prior to eating, drinking, chewing gum or using tobacco. Shower or bathe at the end of working. Remove and wash contaminated clothing before re-use. Launder work clothing separately from regular household laundry. If the product is used in mixtures, it is recommended that you contact the appropriate protective equipment suppliers 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Appearance Clear, Rectangular strip Physical State Solid Color Clear Odor Neutral Odor threshold No information available ph 6.86 Melting point/freezing point Not applicable Boiling Point/Range No information available Flash point Not applicable Evaporation Rate No information available Flammability (solid, gas) No information available Flammability Limit in Air Upper flammability limit: No information available Lower flammability limit: No information available Vapor pressure No information available Vapor density No information available Density No information available Specific gravity No information available Water solubility No information available Solubility in other solvents No information available Partition coefficient No information available Autoignition temperature No information available Decomposition temperature No information available Viscosity, kinematic No information available Viscosity, dynamic No information available Explosive properties No information available Oxidizing properties No information available Molecular weight No information available Bulk density lb/cu ft 10. STABILITY AND REACTIVITY Reactivity Chemical Stability Not applicable Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous polymerization Conditions to avoid Incompatible materials Hazardous polymerization does not occur. Excessive heat None known. Hazardous Decomposition Products None known based on information supplied. 11. TOXICOLOGICAL INFORMATION Page 4 / 7

91 EndZone Insecticide Sticker SDS # : A Revision date: Version 1 Product Information LD50 Oral LD50 Dermal Sensitization Acetamiprid: mg/kg (rat) Acetamiprid: > 2000 mg/kg (rat) Non-sensitizer. Information on toxicological effects Symptoms None known. Delayed and immediate effects as well as chronic effects from short and long-term exposure Chronic toxicity Mutagenicity Carcinogenicity Neurological effects Reproductive toxicity Developmental toxicity STOT - single exposure STOT - repeated exposure Target organ effects Neurological effects Aspiration hazard Acetamiprid: Prolonged exposure in animal studies caused nonspecific toxicity observed as decreases in body weight and food consumption. Acetamiprid. Not genotoxic in animal studies Acetamiprid: No evidence of carcinogenicity from animal studies. Acetamiprid: Caused clinical signs of neurotoxicity (decreased locomotor activity, tremors) in animal studies. Acetamiprid: Reductions in pup weight, litter size, viability and weaning indices; delay in sexual maturity endpoints. Acetamiprid: Not teratogenic in animal studies. Not classified. Not classified. Acetamiprid: No specific target organ toxicity; the liver effects were considered an adaptive response to chemicals rather than frank toxicity. Acetamiprid: Caused clinical signs of neurotoxicity (decreased locomotor activity, tremors) in animal studies. No information available. 12. ECOLOGICAL INFORMATION Ecotoxicity Acetamiprid ( ) Active Ingredient(s) Duration Species Value Units Acetamiprid 72 h EC50 Algae >98.3 mg/l 96 h LC50 Fish >100 mg/l 48 h LC50 Crustacea 49.8 mg/l 21 d NOEC Fish 19.2 mg/l 21 d NOEC Crustacea 5 mg/l Persistence and degradability Bioaccumulation Mobility Acetamiprid: Non-persistent. Does not readily hydrolyze. Not readily biodegradable. Acetamiprid: The substance does not have a potential for bioconcentration. Acetamiprid: Moderately mobile. Has some potential to reach groundwater. 13. DISPOSAL CONSIDERATIONS Waste disposal methods Contaminated Packaging Improper disposal of excess pesticide, spray mixture, or rinsate is prohibited. If these wastes cannot be disposed of by use according to label instructions, contact appropriate disposal authorities for guidance. Containers must be disposed of in accordance with local, state and federal regulations. Refer to the product label for container disposal instructions. Page 5 / 7

92 EndZone Insecticide Sticker 14. TRANSPORT INFORMATION SDS # : A Revision date: Version 1 DOT TDG ICAO/IATA IMDG/IMO This material is not a hazardous material as defined by U.S. Department of Transportation at 49 CFR Parts 100 through 185. Not regulated Not regulated Not regulated U.S. Federal Regulations 15. REGULATORY INFORMATION SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 SARA 311/312 Hazard Categories Acute health hazard Chronic health hazard Fire hazard Sudden release of pressure hazard Reactive Hazard No No No No No Clean Water Act This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR and 40 CFR ) CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material FIFRA Information This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: CAUTION Harmful if swallowed or absorbed through the skin. Do not let children handle stickers. Do not handle stickers with wet hands. This product is toxic to wildlife. This product is very toxic to bees. US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations This product does not contain any substances regulated by state right-to-know regulations International Inventories Page 6 / 7

93 EndZone Insecticide Sticker Component Acetamiprid ( 4.4 ) TSCA (United States) DSL (Canada) EINECS/ELI NCS (Europe) ENCS (Japan) China (IECSC) X KECL (Korea) X SDS # : A Revision date: Version 1 PICCS (Philippines) AICS (Australia) Mexico - Grade Slight risk, Grade 1 WHMIS Hazard Class Non-controlled 16. OTHER INFORMATION NFPA Health Hazards 1 Flammability 0 Instability 0 Special Hazards - HMIS Health Hazards 1 Flammability 0 Physical hazard 0 Personal Protection X Revision date: Revision note Format Change Disclaimer FMC Corporation believes that the information and recommendations contained herein (including data and statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information provided herein relates only to the specified product designated and may not be applicable where such product is used in combination with any other materials or in any process. Use of this product is regulated by the U.S. Environmental Protection Agency (EPA). It is a violation of Federal law to use this product in a manner inconsistent with its labeling. Further, since the conditions and methods of use are beyond the control of FMC Corporation, FMC corporation expressly disclaims any and all liability as to any results obtained or arising from any use of the products or reliance on such information. Prepared By: FMC Corporation FMC Logo - Trademark of FMC Corporation 2015 FMC Corporation. All Rights Reserved. End of Safety Data Sheet Page 7 / 7

94 Return to Index Essentria IC3 Insect Concentrate Safety Data Sheet Section 1: Identification Product identifier Product Name l Essentria IC3 Insect Concentrate Synonyms l Product Description l Clear, light brown liquid. Relevant identified uses of the substance or mixture and uses advised against Recommended use l Restrictions on use l Insecticide. KEEP OUT OF THE REACH OF CHILDREN. Avoid contact with eyes, skin and clothing. Do not use or store near heat or open flame. Do not take internally. When used indoors, ensure adequate ventilation. Details of the supplier of the safety data sheet Manufacturer l Central Garden & Pet Company 1501 E. Woodfield Road, Suite 200W Schaumburg, IL United States Emergency telephone number Manufacturer (Transportation) l CHEMTREC Outside North America Collect Calls Accepted Manufacturer (Transportation) l CHEMTREC Manufacturer l Section 2: Hazard Identification United States (US) According to: OSHA 29 CFR HCS Classification of the substance or mixture OSHA HCS 2012 l Acute Toxicity Oral 4 Aspiration 1 Flammable Liquids 4 Reproductive Toxicity 1B Serious Eye Damage 1 Skin Irritation 2 Skin Sensitization 1 Specific Target Organ Toxicity Single Exposure 3: Narcotic Effects Label elements OSHA HCS 2012 DANGER Preparation Date: 26/January/2015 Revision Date: 26/January/2015 Page 1 of 7 Format: GHS Language: English (US) OSHA HCS 2012

95 Essentria IC3 Insect Concentrate Hazard statements Causes serious eye damage Causes skin irritation Harmful if swallowed May be fatal if swallowed and enters airways May cause an allergic skin reaction May cause drowsiness or dizziness Combustible liquid May damage fertility or the unborn child. Precautionary statements Prevention Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. Avoid breathing dust, fume, gas, mist, vapors and/or spray. Keep away from heat, sparks, open flames and/or hot surfaces. No smoking. Avoid contact during pregnancy/while nursing. Do not eat, drink or smoke when using this product. Use only outdoors or in a well ventilated area. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Response IF ON SKIN: Wash with plenty of soap and water. Specific treatment, see supplemental first aid information. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Do NOT induce vomiting. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a poison control center or doctor if you feel unwell. IF exposed or concerned: Get medical advice/attention. In case of fire: Use appropriate media CO2, Dry chemical, Foam for extinction. Storage/Disposal Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Store locked up. Store in a well ventilated place. Keep container tightly closed. Other hazards OSHA HCS 2012 Under United States Regulations (29 CFR Hazard Communication Standard), this product is considered hazardous. Section 3 Composition/Information on Ingredients Substances Mixtures Material does not meet the criteria of a substance. Composition Chemical Name Identifiers % Rosemary oil CAS: % Preparation Date: 26/January/2015 Revision Date: 26/January/2015 Page 2 of 7 Format: GHS Language: English (US) OSHA HCS 2012

96 Essentria IC3 Insect Concentrate Geraniol CAS: % Wintergreen Oil CAS: % White mineral oil CAS: % Vanillin CAS: % Other ingredients NDA 5% Section 4: First Aid Measures Description of first aid measures Inhalation IF INHALED: If breathing is difficult, remove person to fresh air and keep at rest in a position comfortable for breathing. Call a poison control center or doctor for further treatment advice. Skin IF ON SKIN: Wash with plenty of soap and water. If irritation or rash occurs, get medical advice/attention. Take off contaminated clothing and wash before reuse. Eye IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Ingestion IF SWALLOWED: Immediately call a poison control center or doctor. Aspiration hazard if swallowed, do NOT induce vomiting. Most important symptoms and effects, both acute and delayed Aspiration hazard; eye irritant, skin irritant, may cause an allergic skin reaction in individuals with a sensitivity to Wintergreen Oil or Geraniol, harmful if swallowed, may damage fertility or the unborn child. Refer to Section 11 Toxicological Information. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically and supportively. Section 5: Fire Fighting Measures Extinguishing media Suitable Extinguishing Media Use foam, carbon dioxide, or dry chemical. Unsuitable Extinguishing Do not use water. May spread fire. Media Firefighting Procedures Do not allow fire fighting water to escape into waterways or sewers. Ventilate closed spaces before entering. Do not breathe gas/fumes/vapor/spray. Do not use direct stream of water. A direct stream of water may spread fire. Eliminate ignition sources. Special hazards arising from the substance or mixture Unusual Fire and Explosion Hazards Hazardous Combustion Products Advice for firefighters Combustible liquid. Containers may explode when heated. Liquid will float and may reignite on surface of water. Carbon dioxide, carbon monoxide, smoke, fumes, and unburned hydrocarbons and terpenes. Wear positive pressure self contained breathing apparatus (SCBA). Section 6 Accidental Release Measures Personal precautions, protective equipment and emergency procedures Personal Precautions Ventilate enclosed areas. Wear appropriate personal protective equipment, avoid direct contact. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep all sources of ignition away. Preparation Date: 26/January/2015 Revision Date: 26/January/2015 Page 3 of 7 Format: GHS Language: English (US) OSHA HCS 2012

97 Essentria IC3 Insect Concentrate Emergency Procedures ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Ventilate closed spaces before entering. Environmental precautions No data available Methods and material for containment and cleaning up Containment/Clean up Measures Section 7 Handling and Storage Absorb spills with an inert material, clay granules or other inert absorbent material and put in container for disposal. Precautions for safe handling Handling Keep away from fire No Smoking. Avoid breathing fumes. Use only in well ventilated areas. Wear appropriate personal protective equipment, avoid direct contact. Conditions for safe storage, including any incompatibilities Storage Store locked up. Store in a cool/low temperature, well ventilated dry place away from heat and ignition sources. Keep from freezing. Protect from sunlight. Do not expose to temperatures exceeding 50 C/122 F Incompatible Materials or Ignition Sources Heat, sparks, open flame. Oxidizing agents. Section 8 Exposure Controls/Personal Protection Control parameters Exposure Limits/Guidelines No data available. Exposure controls Engineering Measures/Controls Personal Protective Equipment Pictograms Use adequate ventilation to remove vapors (fumes, dust, etc.) Respiratory In case of insufficient ventilation, wear suitable respiratory equipment. Eye/Face Wear chemical splash safety goggles. Hands Wear appropriate gloves. Skin/Body Wear full body suit. Environmental Exposure Controls While specific data regarding toxicity to fish or other aquatic organisms is not available for this product, care should always be taken to prevent pesticides from entering aquifers. Section 9 Physical and Chemical Properties Information on Physical and Chemical Properties Material Description Physical Form Liquid Appearance/Description Clear, light brown liquid. Color Light brown. Odor Faint minty. Odor Threshold No data available General Properties Boiling Point No data available Melting Point No data available Preparation Date: 26/January/2015 Revision Date: 26/January/2015 Page 4 of 7 Format: GHS Language: English (US) OSHA HCS 2012

98 Essentria IC3 Insect Concentrate Decomposition Temperature No data available ph No data available Specific Gravity/Relative Density 0.985g/ml Density No data available Water Solubility Not soluble Critical Temperature No data available Volatility Viscosity No data available Vapor Pressure No data available Vapor Density No data available Evaporation Rate No data available Flammability Flash Point 145 F( C) UEL No data available LEL No data available Autoignition No data available Flammability (solid, gas) No data available Environmental Octanol/Water Partition coefficient No data available Section 10: Stability and Reactivity Reactivity Chemical stability Non reactive under normal handling and storage conditions. Stable Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products Hazardous polymerization will not occur. Direct sunlight. Do not freeze. Excessive heat >110 F. Heat, sparks, open flame, other ignition sources, and oxidizing conditions. Heat, strong acids, strong bases and oxidizing agents. Carbon dioxide, carbon monoxide, smoke, fumes, and unburned hydrocarbons and terpenes. Section 11 Toxicological Information Information on toxicological effects GHS Properties Acute toxicity Classification OSHA HCS 2012 Acute Toxicity Dermal Classification criteria not met; Acute Toxicity Inhalation Classification criteria not met; Acute Toxicity Oral 4 Aspiration Hazard OSHA HCS 2012 Aspiration 1 Carcinogenicity Germ Cell Mutagenicity OSHA HCS 2012 Classification criteria not met OSHA HCS 2012 Not classified data lacking Skin corrosion/irritation OSHA HCS 2012 Skin Irritation 2 Skin sensitization OSHA HCS 2012 Skin Sensitizer 1 Preparation Date: 26/January/2015 Revision Date: 26/January/2015 Page 5 of 7 Format: GHS Language: English (US) OSHA HCS 2012

99 Essentria IC3 Insect Concentrate STOT RE STOT SE Toxicity for Reproduction Respiratory sensitization OSHA HCS 2012 Classification criteria not met OSHA HCS 2012 Specific Target Organ Toxicity Single Exposure 3: Narcotic Effects OSHA HCS 2012 Toxic to Reproduction 1B OSHA HCS 2012 Classification criteria not met Serious eye damage/irritation OSHA HCS 2012 Serious Eye Damage 1 Potential Health Effects Inhalation Acute (Immediate) May cause drowsiness and dizziness. Chronic (Delayed) No data available Skin Acute (Immediate) May cause an allergic reaction in individuals with a sensitivity to Wintergreen oil or Geraniol. Causes skin irritation. Chronic (Delayed) No data available Eye Acute (Immediate) Causes serious eye damage. Chronic (Delayed) No data available Ingestion Acute (Immediate) Aspiration hazard small amounts of liquid aspirated into the lungs during ingestion or from vomiting may cause chemical pneumonitis or pulmonary edema. Harmful if swallowed. Chronic (Delayed) No data available Reproductive Effects Laboratory experiments have shown teratogenic effects. Section 12 Ecological Information Toxicity Persistence and degradability Bioaccumulative potential Mobility in Soil Other adverse effects No data available No data available No data available. No data available Section 13 Disposal Considerations Waste treatment methods Product waste Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Wastes resulting from the use of this product may be disposed of on site or at an approved waste disposal facility. Do not contaminate water by disposal. Packaging waste Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. See product label for disposal instructions. Preparation Date: 26/January/2015 Revision Date: 26/January/2015 Page 6 of 7 Format: GHS Language: English (US) OSHA HCS 2012

100 Essentria IC3 Insect Concentrate Section 14 Transport Information UN number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards DOT None Not Regulated N/A N/A N/A IMO/IMDG None Not Regulated N/A N/A N/A IATA/ICAO UN3334 Aviation regulated liquid, n.o.s. (rosemary oil) Special precautions for user None specified. Transport in bulk according No data available to Annex II of MARPOL 73/78 and the IBC Code Other information IMO/IMDG No data available Key to abbreviations N/A = Not applicable. IATA/ICAO No data available 9 III N/A Section 15 Regulatory Information Safety, health and environmental regulations/legislation specific for the substance or mixture SARA Hazard Classifications Not regulated Inventory Component CAS TSCA Geraniol Yes Rosemary oil Yes Vanillin Yes White mineral oil Yes Wintergreen Oil Yes Section 16 Other Information Last Revision Date 26/January/2015 Preparation Date 26/January/2015 Disclaimer/Statement of Liability The information and statements herein are believed to be reliable but are not to be construed as a warranty or representation for which we assume legal responsibility. Users should undertake sufficient verification and testing to determine the suitability for their own particular purpose of any information or products referred to herein. NO WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE IS MADE. Preparation Date: 26/January/2015 Revision Date: 26/January/2015 Page 7 of 7 Format: GHS Language: English (US) OSHA HCS 2012

101 FINAL ALL-WEATHER BLOX SAFETY DATA SHEET ACCORDING TO REGULATION: OSHA Hazard Communication Standard 29 CFR DATE OF ISSUE: January PRODUCT AND COMPANY IDENTIFICATION Product Identifier: FINAL ALL-WEATHER BLOX EPA Registration Number: Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses: Anticoagulant Rodenticide - Ready to use Uses advised against: Use only for the purpose described above Return to Index... MANUFACTURER/SUPPLIER: Bell Laboratories, Inc Kinsman Blvd. Madison, WI 53704, USA sds@belllabs.com Phone: Medical or Vet Emergency: or Spill or Transportation Emergency: (CHEMTREC) 2. HAZARD IDENTIFICATION Classification according to Regulation OSHA (d): Not classified PREPARED BY: CAR See Section 15 for information on FIFRA applicable safety, health, and environmental classifications. 3. COMPOSITION/INFORMATION ON INGREDIENTS Component CAS No. % By weight Brodifacoum [3-[3-(4'-Bromo-[1,1'-biphenyl]-4-yl)-1,2,3,4-tetrahydro-1-naphthalenyl]- 4-hydroxy-2H-1-benzopyran-2-one] % Inert and Non-Hazardous Ingredients Proprietary % 4. FIRST AID MEASURES Description of first aid measures Ingestion: Call physician or emergency number immediately. Have person sip a glass of water if able to swallow. Do not induce vomiting unless instructed by physician. Inhalation: Not applicable. Eye contact: Hold eye open and rinse slowly with water for minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. If irritation develops, obtain medical assistance. Skin contact: Take off contaminated clothing. Rinse skin immediately with plenty of water for minutes. If irritation develops, obtain medical assistance. Most important symptoms and effects, both acute and delayed Ingestion of excessive quantities may cause nausea, vomiting, loss of appetite, extreme thirst, lethargy, diarrhea, bleeding. Advice to physician: If ingested, administer Vitamin K 1 intramuscularly or orally as indicated for bishydroxycoumarin overdoses. Repeat as necessary as based upon monitoring of prothrombin times. Advice to Veterinarian: For animals ingesting bait and/or showing poisoning signs (bleeding or elevated prothrombin times), give Vitamin K 1. If needed, check prothrombin times every 3 days until values return to normal (up to 30 days). In severe cases, blood transfusions may be needed. Trade Name: Final All-Weather Blox Date Created: January 2015 Supplier: Bell Laboratories, Inc. Page 1 of 4

102 5. FIRE-FIGHTING MEASURES Extinguishing media Suitable Extinguishing Media: water, foam or inert gas. Unsuitable Extinguishing Media: None known. Special hazards arising from the mixture: High temperature decomposition or burning in air can result in the formation of toxic gases, which may include carbon monoxide and traces of bromine and hydrogen bromide. Advice for firefighters: Wear protective clothing and self-contained breathing apparatus. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures: Gloves should be worn when handling the bait. Collect spillage without creating dust. Environmental precautions: Do not allow bait to enter drains or water courses. Where there is contamination of streams, rivers or lakes contact the appropriate environment agency. Methods and materials for containment and cleaning up For Containment: Sweep up spilled material immediately. Place in properly labeled container for disposal or re-use. For Cleaning Up: Wash contaminated surfaces with detergent. Dispose of all wastes in accordance with all local, regional and national regulations. Reference to other sections: Refer to Sections 7, 8 & 13 for further details of personal precautions, personal protective equipment and disposal considerations. 7. HANDLING AND STORAGE Precautions for safe handling: Do not handle the product near food, animal foodstuffs or drinking water. As soon as possible, wash hands thoroughly after applying bait and before eating, drinking, chewing gum, using tobacco, or using the toilet. Conditions for safe storage, including any incompatibilities: Store only in original container in a cool, dry place, inaccessible to pets and wildlife. Do not contaminate water, food or feed by storage or disposal. Keep containers closed and away from other chemicals. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Established Limits Component OSHA ACGIH Other Limits Brodifacoum Not Established Not Established Not Established Appropriate Engineering Controls: Not required Occupational exposure limits: Not established Personal Protective Equipment: Respiratory protection: Not required Eye protection: Not required Skin protection: Shoes plus socks, and waterproof gloves. Hygiene recommendations: Wash thoroughly with soap and water after handling. Trade Name: Final All-Weather Blox Date Created: January 2015 Supplier: Bell Laboratories, Inc. Page 2 of 4

103 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Appearance/Color: Red wax block Odor: Sweet grain-like Odor Threshold: Not applicable, odor not associated with a hazardous material. ph: Not applicable, Final All-Weather Blox is not dispersible with water. Melting point: Not applicable to rodenticide bait Boiling point: Not applicable to rodenticide bait Flash point: Not applicable, Final All-Weather Blox does not contain components classified as flammable. Evaporation rate: Not applicable, Final All-Weather Blox is a solid. Upper/lower flammability or explosive limits: Not applicable, Final All-Weather Blox does not contain components classified as flammable or explosive. Vapor Pressure: Vapor Density: Not applicable to rodenticide bait NA: Final All-Weather Blox is a solid Relative Density: C Solubility (water): Not water soluble Solubility (solvents): Not applicable to rodenticide bait Partition coefficient: n- Not applicable to rodenticide bait octanol/water: Auto-ignition temperature: Not applicable, Final All-Weather Blox does not contain components classified as flammable. Decomposition temperature: Not applicable to rodenticide bait Viscosity: Not applicable, Final All-Weather Blox is not a liquid. 10. STABILITY AND REACTIVITY Reactivity: Stable when stored in original container in a cool, dry location. Chemical stability: Stable when stored in original container in a cool, dry location. Possibility of hazardous reactions: Refer to Hazardous decomposition products Conditions to avoid: Avoid extreme temperatures (below 0 C or above 40 C). Incompatible materials: Avoid strongly alkaline materials. Hazardous decomposition products: High temperature decomposition or burning in air can result in the formation of toxic gases, which may include carbon monoxide and traces of bromine and hydrogen bromide. 11. TOXICOLOGICAL INFORMATION Information on toxicological effects Acute Toxicity LD50, oral (ingestion): >5001 mg/kg (rats) (Brodifacoum rat LD50 oral: mg/kg bw). LD50, dermal (skin contact): > 5001 mg/kg (rats) (Brodifacoum rabbit LD50 dermal: mg/kg bw). LC50, inhalation: Final All-Weather Blox is a wax block and therefore exposure by inhalation is not relevant. Skin corrosion/irritation: Not irritating to skin. Serious eye damage/irritation: Not irritating to eyes. Respiratory or skin sensitization: Dermal sensitization: Not a Sensitizer (Guinea pig maximization test). Germ cell mutagenicity: Final All-Weather Blox contains no components known to have a mutagenetic effect. Carcinogenicity: Final All-Weather Blox contains no components known to have a carcinogenetic effect. Components NTP IARC OSHA Brodifacoum Not listed Not listed Not listed Reproductive Toxicity: Final All-Weather Blox: No data Aspiration Hazard: Not applicable. Final All-Weather Blox is a wax block. Target Organ Effects: Reduced blood clotting ability. 12. ECOLOGICAL INFORMATION Ecotoxicity Effects: This product is extremely toxic to fish, birds and other wildlife. Dogs and predatory and scavenging mammals and birds might be poisoned if they feed upon animals that have eaten this bait. Do not apply this product directly to water or to areas where surface water is present or to intertidal areas below the mean high water mark. Runoff also may be hazardous to aquatic organisms in water adjacent to treated areas. Do not contaminate water when disposing of equipment wash water or rinsate. Persistence and degradability: Final All-Weather Blox is inherently biodegradable. Bioaccumulative potential: Not determined for Final All-Weather Blox. Brodifacoum water solubility is extremely low (< 0.1mg/l). Mobility in Soil: Not determined for Final All-Weather Blox. Mobility of brodifacoum in soil is considered to be limited. Other adverse effects: None. Trade Name: Final All-Weather Blox Date Created: January 2015 Supplier: Bell Laboratories, Inc. Page 3 of 4

104 13. DISPOSAL CONSIDERATIONS Do not contaminate water, food or feed by storage or disposal. Pesticide Storage: Store only in original container in a cool, dry place inaccessible to children and pets. Keep containers closed and away from other chemicals. Pesticide Disposal: Wastes resulting from the use of this product may be placed in trash or delivered to an approved waste disposal facility. Container Handling: Non-refillable container. Do not reuse or refill this container. [Plastic:] Offer for recycling or reconditioning; or puncture and dispose of in a sanitary landfill; or by incineration. In most states, burning is not allowed. [Paper:] Dispose of empty container by placing in trash, at an approved waste disposal facility or by incineration. In most states, burning is not allowed. 14. TRANSPORT INFORMATION UN number: Not regulated UN proper shipping name: Not regulated Transport hazard class(es): Not regulated Packing group : Not regulated Environmental Hazards DOT Road/Rail: Not considered hazardous for transportation via road/rail. DOT Maritime: Not considered hazardous for transportation by vessel. DOT Air: Not considered hazardous for transportation by air. Freight Classification: LTL Class 60 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC code: Not applicable Special precautions for user: None 15. REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture: FIFRA: This pesticide product is regulated by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non-pesticide chemicals. The safety, health, environmental, and hazard information required on the pesticide label is listed below and reflected throughout this SDS. The pesticide label also includes other important information, including directions for use. Signal Word: CAUTION Precautionary Statements: Contains the anticoagulant Brodifacoum which may cause bleeding if ingested. Harmful if swallowed or absorbed through the skin. Keep away from children, domestic animals and pets. Do not get in eyes, on skin or on clothing. Potential Health Effects: Eye Contact: May cause irritation Skin Contact: Non-irritating to the skin Ingestion: Harmful if swallowed TSCA: All components are listed on the TSCA Inventory or are not subject to TSCA requirements CERCLA/SARA 313: Not listed CERCLA/SARA 302: Not listed 16. OTHER INFORMATION For additional information, please contact the manufacturer noted in Section 1. NFPA Health: 1 (caution) Flammability: 0 (will not burn) Reactivity: 0 (stable) Specific Hazard: None HMIS Health: 2 (moderate) Flammability: 0 (minimal) Reactivity: 0 (minimal) Protective Equipment: B Disclaimer: The information provided in this Safety Data Sheet has been obtained from sources believed to be reliable. Bell Laboratories, Inc. provides no warranties; either expressed or implied, and assumes no responsibility for the accuracy or completeness of the data contained herein. This information is offered for your consideration and investigation. The user is responsible to ensure that they have all current data, including the approved product label, relevant to their particular use. Trade Name: Final All-Weather Blox Date Created: January 2015 Supplier: Bell Laboratories, Inc. Page 4 of 4

105 Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR (g) and GHS Rev 03. Page 1/15 Printing date 04/02/2015 Reviewed on 04/02/2015 * 1 Identification Product identifier Trade name: Fumitoxin Tablets - U.S. EPA Reg. No ; Fumitoxin Pellets - U.S. EPA Reg. No Relevant identified uses of the substance or mixture and uses advised against Product description Fumigant for Insect & Rodent Control Application of the substance / the mixture Fumigants used to treat raw agricultural commodities, processed foods, non-food commodities and rodent burrows. Details of the supplier of the safety data sheet Manufacturer/Supplier: DEGESCH America, Inc. 153 Triangle Dr. P.O. Box 116 Weyers Cave, VA USA Telephone: (540) / Telefax: (540) degesch@degeschamerica.com Emergency telephone number: For human or animal emergencies: (Rocky Mountain Poison and Drug Center) For all other chemical emergencies: (Chemtrec) Emergency and Information - DEGESCH America, Inc.: (540) / * 2 Hazard(s) identification Return to Index... Classification of the substance or mixture GHS02 Flame Water-react. 1 H260 In contact with water releases flammable gases which may ignite spontaneously. GHS06 Skull and crossbones Acute Tox. 2 Acute Tox. 2 H300 Fatal if swallowed. H330 Fatal if inhaled. GHS05 Corrosion Eye Dam. 1 H318 Causes serious eye damage. GHS09 Environment Aquatic Acute 1 H400 Very toxic to aquatic life. GHS07 (Contd. on page 2)

106 Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR (g) and GHS Rev 03. Page 2/15 Printing date 04/02/2015 Reviewed on 04/02/2015 Trade name: Fumitoxin Tablets - U.S. EPA Reg. No ; Fumitoxin Pellets - U.S. EPA Reg. No Skin Irrit. 2 H315 Causes skin irritation. Label elements GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). Hazard pictograms GHS02 GHS05 GHS06 GHS09 Signal word Danger Hazard-determining components of labeling: Aluminum Phosphide Ammonium Carbamate Hazard statements In contact with water releases flammable gases which may ignite spontaneously. Fatal if swallowed or if inhaled. Causes skin irritation. Causes serious eye damage. Very toxic to aquatic life. Precautionary statements Keep away from any possible contact with water, because of violent reaction and possible flash fire. Do not breathe dust/fume/gas/mist/vapors/spray. Wear respiratory protection. Wear protective gloves/protective clothing/eye protection/face protection. Avoid release to the environment. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. If swallowed: Immediately call a poison center/doctor. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment is urgent (see supplementary first aid instructions on this Safety Data Sheet). IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If skin irritation occurs: Get medical advice/attention. In case of fire: Use for extinction: CO2, sand, extinguishing powder. If on skin: Wash with plenty of water. Collect spillage. Take off contaminated clothing and wash it before reuse. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Store in a dry place. Store in a closed container. Dispose of contents/container in accordance with local/regional/national/international regulations. Unknown acute toxicity: 10.3 percent of the mixture consists of ingredient(s) of unknown toxicity. (Contd. on page 3)

107 Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR (g) and GHS Rev 03. Page 3/15 Printing date 04/02/2015 Reviewed on 04/02/2015 Trade name: Fumitoxin Tablets - U.S. EPA Reg. No ; Fumitoxin Pellets - U.S. EPA Reg. No Classification system: NFPA ratings (scale 0-4) W Health = 4 Fire = 4 Reactivity = 2 The substance demonstrates unusual reactivity with water. HMIS-ratings (scale 0-4) HEALTH *4 FIRE 4 REACTIVITY 2 Health = *4 Fire = 4 Reactivity = 2 Other hazards None known * 3 Composition/information on ingredients Chemical characterization: Mixtures Description: Mixture of substances listed below with nonhazardous additions. Dangerous Components: CAS: RTECS: BD Aluminum Phosphide 55% Water-react. 1, H260; Acute Tox. 2, H300; Aquatic Acute 1, H400 CAS: Ammonium Carbamate Proprietary% Eye Dam. 1, H318; Acute Tox. 4, H302; Skin Irrit. 2, H315; Aquatic Acute 3, H402 RTECS: BD Proprietary 5-10% STOT SE 3, H335 Proprietary 2-12% Skin Irrit. 2, H315; STOT SE 3, H335; Eye Irrit. 2B, H320 Additional information: Fumitoxin Tablets and Fumitoxin Pellets react with water to produce phosphine (hydrogen phosphide, PH3, CAS No ) as shown in Equation 1. Fumitoxin products are formulated with 55% aluminum phosphide and also contains ammonium carbamate (AC) and inert ingredients. Ammonium carbamate decomposes to liberate ammonia (CAS No ) and carbon dioxide (CAS No ) as shown in Equation 2. 1) AlP + 3H2O ---> Al(OH)3 + PH3 2) NH2COONH4 ---> 2NH3 + CO2 * 4 First-aid measures Description of first aid measures General information: Symptoms of overexposure are headache, dizziness, nausea, difficult breathing, vomiting, and diarrhea. In ALL cases of overexposure, get medical attention immediately. Take victim to a doctor or emergency treatment facility. Have product container label or applicator's manual with you when calling a poison control center, doctor, or when going for treatment. (Contd. on page 4)

108 Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR (g) and GHS Rev 03. Page 4/15 Printing date 04/02/2015 Reviewed on 04/02/2015 Trade name: Fumitoxin Tablets - U.S. EPA Reg. No ; Fumitoxin Pellets - U.S. EPA Reg. No After inhalation: Get exposed person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably by mouth to mouth, if possible. Contact a poison control center or doctor for treatment advice. After skin contact: Take off contaminated clothing immediately. Rinse skin immediately with plenty of water for minutes. Call a poison control center or doctor for treatment advice. After eye contact: Hold eye open and rinse slowly and gently with water for minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eyes. Call a poison control center or doctor for treatment advice. After swallowing: Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not give anything by mouth to an unconscious person. Do not induce vomiting unless told to by a poison control center or doctor. Information for doctor: Most important symptoms and effects, both acute and delayed Aluminum phosphide fumigant products react with moisture from the air, acids and many other liquids to release phosphine gas (hydrogen phosphide, PH3). Mild exposure by inhalation causes malaise (indefinite feeling of sickness), headache, ringing in the ears, fatigue, nausea and pressure in the chest which is relieved by removal to fresh aid. Moderate poisoning causes weakness, vomiting, pain just above the stomach, chest pain, diarrhea and dyspnea (difficulty breathing). Symptoms of severe poisoning may occur within a few hours to several days resulting in pulmonary edema and may lead to dizziness, cyanosis, unconsciousness, and death. Indication of any immediate medical attention and special treatment needed No further relevant information available. * 5 Fire-fighting measures Extinguishing media Suitable extinguishing agents: CO2, sand, extinguishing powder. Do not use water. For safety reasons unsuitable extinguishing agents: Water Special hazards arising from the substance or mixture Phosphine (hydrogen phosphide, PH3)-air mixtures at concentrations above the LEL of 1.8% v/v (18,000 ppm) may ignite spontaneously. Ignition of high concentrations of phosphine gas (hydrogen phosphide, PH3) can product a very energetic reaction. Explosions can occur under these conditions and may cause severe personal injury. Never allow the buildup of phosphine gas (hydrogen phosphide, PH3) to exceed explosive concentrations. Open containers of metal phosphides in open air only and never in a flammable atmosphere. Do not confine spent or partially spent dust from metal phosphide fumigants as the slow release of phosphine gas (hydrogen phosphide, PH3) from these materials may result in the formation of an explosive atmosphere. Spontaneous ignition may occur if large quantities of aluminum phosphide are piled in contact with liquid water. This is particularly true if quantities of these materials are placed in an environment which can provide partial confinement of the hydrogen phosphide gas liberated by hydrolysis. If incinerated, product will release the following toxic materials: Oxides of aluminum, magnesium, phosphorous, nitrogen (NOx), carbon, phosphine gas (hydrogen phosphide, PH3), ammonia and phosphoric acid. Advice for firefighters Aluminum phosphide is not flammable by itself. However, it reacts readily with water to produce phosphine gas (hydrogen phosphide, PH3) which may ignite spontaneously in air at concentrations above its LEL of 1.8% v/v (18,000 ppm). The UEL of phosphine gas (hydrogen phosphide, PH3) is unknown. (Contd. on page 5)

109 Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR (g) and GHS Rev 03. Page 5/15 Printing date 04/02/2015 Reviewed on 04/02/2015 Trade name: Fumitoxin Tablets - U.S. EPA Reg. No ; Fumitoxin Pellets - U.S. EPA Reg. No Protective equipment: As in any fire, wear self-contained breathing apparatus pressure-demand (NIOSH approved or equivalent), and full protective gear to prevent contact with skin and eyes. Wear a NOISH/MSHA approved full-face gas mask phosphine gas canister combination may be used at levels up to 15 ppm or following manufacturers use conditions instructions for escape. Above 15 ppm or in situations where the phosphine gas concentration is unknown, a NIOSH/MSHA approved SCBA must be worn. * 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Respiratory protection will most likely be required during cleanup of spilled aluminum phosphide fumigants. If the concentration of phosphine (hydrogen phosphide, PH3) is unknown, NIOSH/MSHA approved SCBA or its equivalent must be worn. Full-face gas mask canister combinations may only be worn at concentrations no higher than 15 ppm. Environmental precautions: Inform respective authorities in case of seepage into water course or sewage system. Methods and material for containment and cleaning up: If possible, dispose of spilled material by use according to label instructions. Freshly spilled material which has not been contaminated by water or foreign matter may be placed into original or other gas-tight containers. Punctured flasks, pouches or containers may be temporarily repaired using aluminum tape. If the age of the spill is unknown or if the product has been contaminated with soil, debris, water, etc., gather up the spillage in small open buckets having a capacity no larger than about 1 gallon. Do not add more than about 1 to 1.5 kg (2 to 3 lbs.) to a bucket. If on-site wet-deactivation is not feasible, transport the uncovered buckets in open vehicles to a suitable area. Small amounts of spillage, from about 4 to 8 kg (9 to 18 lbs.) may be spread out over the ground in an open area to be deactivated by atmospheric moisture. Alternatively, spilled aluminum phosphide fumigants may be deactivated by the wet method as described in the following: Wet Deactivation of Spilled Fumitoxin Products: 1. Deactivating solution is prepared by adding the appropriate amount of low sudsing detergent to water in a drum or other suitable container. A 2% solution or 4 cups of detergent in 30 gallons is suggested. The container should be filled with deactivating solution to within a few inches of the top. 2. The material is added slowly to the deactivating solution and stirred so as to thoroughly wet all of the product. This should be carried out in open air and respiratory protection may be required. At no time should the deactivation drum be covered. 3. No more than about 45 to 50 lbs. of Fumitoxin should be added to 15 gallons of water-detergent mixture. Products may ignite during wet deactivation if they are allowed to float to the surface. Add weights or otherwise ensure that products stay submerged until deactivation is completed. 4. Allow the mixture to stand, with occasional stirring, for about 36 hours. The resultant slurry of dust or packaged product will then be safe for disposal. 5. Dispose of the slurry of deactivated material, with or without preliminary decanting, at a sanitary landfill or other suitable site approved by local authorities. Where permissible, this slurry may be poured into a storm sewer or out onto the ground. Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. * 7 Handling and storage Handling: Precautions for safe handling Store in a cool, dry place in tightly closed containers. (Contd. on page 6)

110 Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR (g) and GHS Rev 03. Page 6/15 Printing date 04/02/2015 Reviewed on 04/02/2015 Trade name: Fumitoxin Tablets - U.S. EPA Reg. No ; Fumitoxin Pellets - U.S. EPA Reg. No Information about protection against explosions and fires: Keep ignition sources away - Do not smoke. Protect against electrostatic charges. Protect from heat. Keep protective respiratory device available. Conditions for safe storage, including any incompatibilities Store away from water, acids, bases, strong oxidizing agents and strong reducing agents. Storage: Requirements to be met by storerooms and receptacles: Store products in a locked, dry, well-ventilated area away from heat. Post as a pesticide storage area. Do not store in buildings inhabited by humans or domestic animals. Information about storage in one common storage facility: Not required. Further information about storage conditions: Keep container tightly sealed. Store in cool, dry conditions in well-sealed containers. Specific end use(s) No further relevant information available. * 8 Exposure controls/personal protection Additional information about design of technical systems: No further data; see section 7. Control parameters All ventilation should be designed in accordance with OSHA standard (29 CFR ). Use local exhaust at filling zones and where leakage and dust formation is probable. Use mechanical (general) ventilation for storage areas. Use appropriate ventilation as required to keep Exposure Limits in Air below TLV & PEL limits. Components with occupational exposure limits: Aluminum Phosphide REL Long-term value: 2 mg/m³ as Al TLV Long-term value: 1* mg/m³ as Al;*as respirable fraction Proprietary PEL Long-term value: 15*; 15** mg/m³ *Total dust; ** Respirable fraction REL Long-term value: 10* 5** mg/m³ as Al*Total dust**respirable/pyro powd./welding f. TLV Long-term value: 1* mg/m³ as Al; *as respirable fraction Proprietary TLV Long-term value: 10 mg/m³ phosphine PEL REL TLV Long-term value: 0.4 mg/m³, 0.3 ppm Short-term value: 1 mg/m³, 1 ppm Long-term value: 0.4 mg/m³, 0.3 ppm Short-term value: (1.4) mg/m³, (1) ppm Long-term value: (0.42) mg/m³, (0.3) NIC-0.1 ppm Ceiling limit value: NIC-0.5 ppm (Contd. on page 7)

111 Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR (g) and GHS Rev 03. Page 7/15 Printing date 04/02/2015 Reviewed on 04/02/2015 Trade name: Fumitoxin Tablets - U.S. EPA Reg. No ; Fumitoxin Pellets - U.S. EPA Reg. No ammonia, anhydrous PEL Long-term value: 35 mg/m³, 50 ppm REL Short-term value: 27 mg/m³, 35 ppm Long-term value: 18 mg/m³, 25 ppm TLV Short-term value: 24 mg/m³, 35 ppm Long-term value: 17 mg/m³, 25 ppm Additional information: The lists that were valid during the creation were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing and wash before reuse. Wash hands before breaks and at the end of work. Avoid contact with the skin. Avoid contact with the eyes and skin. Breathing equipment: Respiratory protection will most likely be required while using aluminum phosphide fumigants. If the concentration of phosphine (hydrogen phosphide, PH3) is unknown, NIOSH/MSHA approved SCBA or its equivalent must be worn. Full-face gas mask canister combinations may only be worn at concentrations no higher than 15 ppm. Protection of hands: Protective gloves Wear dry gloves of cotton or other material if contact with tablets, pellets, or dust is likely. Gloves should remain dry after use. Aerate gloves and other clothing that may be contaminated in a well-ventilated area prior to laundering. Material of gloves Dry gloves of cotton or other material. Penetration time of glove material The exact break-through time has to be determined and observed by the manufacturer of the protective gloves. Eye protection: Not required. * 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: Solid Color: Greenish-gray Odor: Garlic, carbide or decaying fish Odor threshold: Not determined. ph-value: Not applicable. Change in condition Melting point/melting range: Boiling point/boiling range: Flash point: Not determined AlP = > 1000 C (AlP = > 1832 F) (PH3 = C) AlP = > 1000 C (AlP = > 1832 F) (PH3 = C) (Contd. on page 8)

112 Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR (g) and GHS Rev 03. Page 8/15 Printing date 04/02/2015 Reviewed on 04/02/2015 Trade name: Fumitoxin Tablets - U.S. EPA Reg. No ; Fumitoxin Pellets - U.S. EPA Reg. No Flammability (solid, gaseous): Contact with water or acids liberates extremely flammable gases. Ignition temperature: Not determined Decomposition temperature: Decomposes at ambient conditions when moisture is present. Auto igniting: Spontaneously flammable in air. Danger of explosion: Not determined. Explosion limits: Lower: Upper: 1.8% Vol % (for PH3) Not established Vol % (for PH3) Vapor pressure: AlP = 0 mm Hg PH3 = 40 mm C AC = 100 mm 26.7 C 20 C (68 F): AlP = 2.85 g/cm³ (AlP = lbs/gal) (PH3 = 1.17 g/cm³) Relative density Not determined. Vapor density Not applicable. Evaporation rate Not applicable. Solubility in / Miscibility with Water: AlP = Insoluble, reacts PH3 = 26 cc in 100 ml at 17 C AC = Very soluble, reacts Partition coefficient (n-octanol/water): Not determined. Viscosity: Dynamic: Kinematic: Solvent content: Not applicable. Not applicable. Solids content: % Other information No further relevant information available. * 10 Stability and reactivity Reactivity No further relevant information available. Chemical stability Products are stable to most chemical reactions, except for hydrolysis. Products will react with moist air, liquid water, acids and some other liquids to produce toxic and flammable phosphine (hydrogen phosphide, PH3) gas. Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. Possibility of hazardous reactions Contact with water releases flammable gases. Contact with water releases toxic gases. Conditions to avoid: Avoid prolonged exposure to air. Incompatible materials: Water, acids, bases, strong oxidizing agents and strong reducing agents. Hazardous decomposition products: Oxides of aluminum, phosphorous, nitrogen (NOx), magnesium, carbon, phosphine gas (hydrogen phosphide, PH3), ammonia and phosphoric acid. Additional information: Phosphine (hydrogen phosphide, PH3) gas may react with certain metals and cause corrosion, especially at higher temperatures and relative humidity. Metals such as copper, brass and other copper alloys, and (Contd. on page 9)

113 Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR (g) and GHS Rev 03. Page 9/15 Printing date 04/02/2015 Reviewed on 04/02/2015 Trade name: Fumitoxin Tablets - U.S. EPA Reg. No ; Fumitoxin Pellets - U.S. EPA Reg. No precious metals such as gold and silver are susceptible to corrosion by phosphine. Small electric motors, smoke detectors, brass sprinkler heads, batteries and battery chargers, fork lifts, temperature monitoring systems, switching gears, communication devices, computers, calculators and other electrical equipment may be damaged by this gas. Phosphine (hydrogen phosphide, PH3) will also react with certain metallic salts and, therefore, sensitive items such as photographic film, some inorganic pigments, etc., should not be exposed. * 11 Toxicological information Information on toxicological effects Acute toxicity: LD/LC50 values that are relevant for classification: Aluminum Phosphide Oral LD mg/kg (rat) Ammonium Carbamate Oral Inhalative LD50 LC50/96 hours 1470 mg/kg (rat) 37 mg/l (Trout) phosphine Inhalative LC50/1 h 180 ppm (rat) ammonia, anhydrous Oral Inhalative LD50 LC50/4 h 350 mg/kg (rat) 2000 mg/l (rat) Primary irritant effect: on the skin: May be irritating. Irritant to skin and mucous membranes. on the eye: Direct contact may cause eye irritation. Strong irritant with the danger of severe eye injury. Causes serious eye irritation. Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Irritant Very toxic Carcinogenic categories IARC (International Agency for Research on Cancer) None of the ingredients are listed. Group 1 - Carcinogenic to humans Group 2A - Probably carcinogenic to humans Group 2B - Possibly carcinogenic to humans Group 3 - Not classifiable as to its carcinogenicity to humans Group 4 - Probably not carcinogenic to humans NTP (National Toxicology Program) None of the ingredients are listed. OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients are listed. (Contd. on page 10)

114 Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR (g) and GHS Rev 03. Page 10/15 Printing date 04/02/2015 Reviewed on 04/02/2015 Trade name: Fumitoxin Tablets - U.S. EPA Reg. No ; Fumitoxin Pellets - U.S. EPA Reg. No * 12 Ecological information Toxicity Aquatic toxicity: Avoid release into the environment. Runoff from fire control or dilution water may cause pollution Ammonium Carbamate EC mg/l (Green algae) 63 mg/l (Water flea) Persistence and degradability No further relevant information available. Behavior in environmental systems: Bioaccumulative potential No further relevant information available. Mobility in soil No further relevant information available. Ecotoxical effects: Remark: Very toxic for fish Additional ecological information: General notes: Do not allow product to reach ground water, water course or sewage system. Danger to drinking water if even small quantities leak into the ground. Also poisonous for fish and plankton in water bodies. Very toxic for aquatic organisms Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. Other adverse effects No further relevant information available. * 13 Disposal considerations Waste treatment methods Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. When being disposed of, spilled or partially reacted Fumitoxin products are considered hazardous wastes under existing Federal Regulations. If properly exposed, the grayish-white residual dust after a fumigation will not be a hazardous waste and normally contains only a very small amount of unreacted aluminum phosphide. This waste will be safe for disposal. However, the spent residual dust from incompletely exposed Fumitoxin products may require special care. Triple rinse tablet and pellet flasks and stoppers with water. Then offer for recycling or reconditioning, or puncture and dispose of in a sanitary landfill, or by other procedures approved by state and local authorities. Rinsate may be disposed of in a storm sewer, sanitary landfill or by other approved procedures. Or, it is permissible to remove lids and expose empty flasks to atmospheric conditions until the residue in the flasks is reacted. Then puncture and dispose of in a sanitary landfill or other approved site, or by other procedures approved by state and local authorities. Some local and state waste disposal regulations may vary from the following recommendations. Disposal procedures should be reviewed with appropriate authorities to ensure compliance with local regulations. Contact your State Pesticide or Environmental Control Agency or Hazardous Waste Specialist at the nearest EPA Regional Office for guidance. 1. Confinement of partially spent residual materials, as in a closed container, or collection and storage of large quantities of dust may result in a fire or explosion hazard. Small amounts of phosphine (hydrogen phosphide, PH3) may be given off from unreacted aluminum phosphide, and confinement of the gas may result in a flash. 2. In open areas, small amounts of spent residual dust or spent packaged products may be disposed of on site by burial or by spreading over the land surface away from inhabited buildings. 3. Residual dust from Fumitoxin products may also be collected and disposed of at a sanitary landfill, or other (Contd. on page 11)

115 Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR (g) and GHS Rev 03. Page 11/15 Printing date 04/02/2015 Reviewed on 04/02/2015 Trade name: Fumitoxin Tablets - U.S. EPA Reg. No ; Fumitoxin Pellets - U.S. EPA Reg. No approved sites or by other procedures approved by Federal, State or Local authorities. 4. From 3 to 5 kg (7 to 10 lbs.) of spent dust from 2 to 3 flasks of Fumitoxin may collected for disposal in a 1-gallon bucket. Larger amounts, up to about one-half case, may be collected in burlap, cotton or other types of porous cloth bags for transportation in an open vehicle to the disposal site. Do not collect dust from more than 7 flasks of tablets, 10 flasks of pellets (about 11 kg or 25 lbs.) in a single bag. Do not pile cloth bags together. Do not use this method for partially spent or "green" dust. Caution: Do not collect dust in large drums, dumpsters, plastic bags or other containers where confinement may occur. Uncleaned packagings: Recommendation: Triple rinse tablet and pellet flasks and stoppers with water and then offer for recycling or reconditioning; or puncture and dispose of in a sanitary landfill, or by other procedures approved by state and local authorities. * 14 Transport information UN-Number DOT, ADR, IMDG, IATA UN1397 UN proper shipping name DOT Aluminum phosphide ADR UN1397 Aluminum phosphide, ENVIRONMENTALLY HAZARDOUS IMDG ALUMINIUM PHOSPHIDE, MARINE POLLUTANT IATA ALUMINIUM PHOSPHIDE Transport hazard class(es) DOT Class 4.3 Substances which, in contact with water, emit flammable gases Label 4.3, 6.1 ADR Class 4.3 (WT2) Substances which, in contact with water, emit flammable gases Label 4.3, 6.1 IMDG Class 4.3 Substances which, in contact with water, emit flammable gases (Contd. on page 12)

116 Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR (g) and GHS Rev 03. Page 12/15 Printing date 04/02/2015 Reviewed on 04/02/2015 Trade name: Fumitoxin Tablets - U.S. EPA Reg. No ; Fumitoxin Pellets - U.S. EPA Reg. No Label 4.3/6.1 IATA Class 4.3 Substances which, in contact with water, emit flammable gases Label 4.3 (6.1) Packing group DOT, ADR, IMDG, IATA I Environmental hazards: Product contains environmentally hazardous substances: Aluminum Phosphide Special marking (ADR): Symbol (fish and tree) Special precautions for user Warning: Substances which, in contact with water, emit flammable gases Danger code (Kemler): 462 EMS Number: F-G,S-N Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. Transport/Additional information: DOT Quantity limitations On passenger aircraft/rail: Forbidden On cargo aircraft only: 15 kg ADR Excepted quantities (EQ) Code: E0 Not permitted as Excepted Quantity IMDG Limited quantities (LQ) 0 Excepted quantities (EQ) Code: E0 Not permitted as Excepted Quantity UN "Model Regulation": UN 1397, Aluminum phosphide, ENVIRONMENTALLY HAZARDOUS, 4.3, 6.1, I * 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Sara Section 355 (extremely hazardous substances): Aluminum Phosphide Section 313 (Specific toxic chemical listings): Aluminum Phosphide Proprietary Proprietary TSCA (Toxic Substances Control Act): Aluminum Phosphide (Contd. on page 13)

117 Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR (g) and GHS Rev 03. Page 13/15 Printing date 04/02/2015 Reviewed on 04/02/2015 Trade name: Fumitoxin Tablets - U.S. EPA Reg. No ; Fumitoxin Pellets - U.S. EPA Reg. No Proprietary Proprietary Proprietary Proposition 65 Chemicals known to cause cancer: None of the ingredients are listed. Chemicals known to cause reproductive toxicity for females: None of the ingredients are listed. Chemicals known to cause reproductive toxicity for males: None of the ingredients are listed. Chemicals known to cause developmental toxicity: None of the ingredients are listed. Carcinogenic categories EPA (Environmental Protection Agency) Proprietary TLV (Threshold Limit Value established by ACGIH) Proprietary NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients are listed. GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). Hazard pictograms D, I, II A4 GHS02 GHS05 GHS06 GHS09 Signal word Danger Hazard-determining components of labeling: Aluminum Phosphide Ammonium Carbamate Hazard statements In contact with water releases flammable gases which may ignite spontaneously. Fatal if swallowed or if inhaled. Causes skin irritation. Causes serious eye damage. Very toxic to aquatic life. Precautionary statements Keep away from any possible contact with water, because of violent reaction and possible flash fire. Do not breathe dust/fume/gas/mist/vapors/spray. Wear respiratory protection. Wear protective gloves/protective clothing/eye protection/face protection. Avoid release to the environment. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. (Contd. on page 14)

118 Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR (g) and GHS Rev 03. Page 14/15 Printing date 04/02/2015 Reviewed on 04/02/2015 Trade name: Fumitoxin Tablets - U.S. EPA Reg. No ; Fumitoxin Pellets - U.S. EPA Reg. No If swallowed: Immediately call a poison center/doctor. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment is urgent (see supplementary first aid instructions on this Safety Data Sheet). IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If skin irritation occurs: Get medical advice/attention. In case of fire: Use for extinction: CO2, sand, extinguishing powder. If on skin: Wash with plenty of water. Collect spillage. Take off contaminated clothing and wash it before reuse. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Store in a dry place. Store in a closed container. Dispose of contents/container in accordance with local/regional/national/international regulations. National regulations: The product is subject to be labeled according with the prevailing version of the regulations on hazardous substances. State Right to Know CAS: RTECS: BD Aluminum Phosphide 55% Water-react. 1, H260; Acute Tox. 2, H300; Aquatic Acute 1, H400 CAS: Ammonium Carbamate Proprietary% Eye Dam. 1, H318; Aquatic Acute 3, H402 Acute Tox. 4, H302; Skin Irrit. 2, H315; RTECS: BD Proprietary 5-10% STOT SE 3, H335 Proprietary 2-12% Proprietary 2-12% Skin Irrit. 2, H315; STOT SE 3, H335; Eye Irrit. 2B, H320 All ingredients are listed. Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 16 Other information The information and recommendations in this safety data sheet are, to the best of our knowledge, accurate as of the date of issue. Nothing herein shall be deemed to create warranty, expressed or implied and shall not establish a legally valid contractual relationship. It is the responsibility of the user to determine applicability of this information and the suitability of the material or product for any particular purpose. Date of preparation / last revision 04/02/2015 / - Abbreviations and acronyms: ADR: The European Agreement concerning the International Carriage of Dangerous Goods by Road ADN: The European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) LC50: Lethal concentration, 50 percent (Contd. on page 15)

119 Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR (g) and GHS Rev 03. Page 15/15 Printing date 04/02/2015 Reviewed on 04/02/2015 Trade name: Fumitoxin Tablets - U.S. EPA Reg. No ; Fumitoxin Pellets - U.S. EPA Reg. No LD50: Lethal dose, 50 percent Water-react. 1: Substances and Mixtures which, in contact with water, emit flammable gases, Hazard Category 1 Acute Tox. 2: Acute toxicity, Hazard Category 2 Acute Tox. 4: Acute toxicity, Hazard Category 4 Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2 Eye Dam. 1: Serious eye damage/eye irritation, Hazard Category 1 Eye Irrit. 2B: Serious eye damage/eye irritation, Hazard Category 2B STOT SE 3: Specific target organ toxicity - Single exposure, Hazard Category 3 Aquatic Acute 1: Hazardous to the aquatic environment - AcuteHazard, Category 1 Aquatic Acute 3: Hazardous to the aquatic environment - AcuteHazard, Category 3 * Data compared to the previous version altered. SDS created by MSDS Authoring Services (877)

120 Return to Index... Safety Data Sheet InVict Xpress Granular Bait Release Date: 5/15/2015 Print Date: 5/28/2015 Version PRODUCT IDENTIFICATION 1.1. Product Identifiers Product name : InVict Xpress Granular Bait 1.2. Other Means of Identification Product synonyms : InVict Blitz Ant Granules 1.3. Recommended Uses/Restrictions to Use Uses : 0.5% imidacloprid granular bait for control of various pest species per label Restrictions : See product label for details 1.4. Supplier Details Company : Rockwell Labs Ltd 1257 Bedford Avenue North Kansas City, MO USA Telephone : Emergency Contact Outside normal business hours Emergency Phone # : (USA & Canada) (Outside USA & Canada) 2. HAZARDS IDENTIFICATION 2.1. Classification of Substance or Mixture none 2.2. GHS label elements, including precautionary statements Pictogram(s) none Signal word Hazard statement(s) Precautionary statement(s) none none none 2.3. Other hazards which do not result in classification Imidacloprid is a neurotoxin that when consumed in sufficient quantities can have adverse effects up to and including death. This product contains a low Rockwell - RP0011 Page 1 of 8

121 Safety Data Sheet InVict Xpress Granular Bait Release Date: 5/15/2015 Print Date: 5/28/2015 Version 1.0 concentration of imidacloprid and normal use should not result in significant occupational hazard. 3. COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substances Not applicable 3.2. Mixtures Hazardous component(s) or components of note: Chemical Identity Contains (% w/w) CAS-No. Hazard Classification Imidacloprid none 4. FIRST AID MEASURES 4.1. Description of first aid measures General advice Consult a physician or poison control center. Provide this safety data sheet to medical personnel. Move out of hazardous areas. If inhaled Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth to mouth if possible. Call a poison control center or doctor for further treatment advice. In case of skin contact Take off contaminated clothing. Rinse skin immediately with plenty of water for minutes. Call a poison control center or doctor for treatment advice. In case of eye contact Hold eye open and rinse slowly and gently with water for minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. If swallowed Call a poison control center or doctor for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by a poison control center or doctor. Do not give anything by mouth to an unconscious person Most important symptoms and effects, both acute and delayed Imidacloprid may cause drowsiness, dizziness, vomiting, disorientation, and fever with ingestion of more than an incidental amount Indication of any immediate medical attention and special treatment needed, if necessary See section FIRE FIGHTING MEASURES 5.1. Extinguishing media Suitable extinguishing media: use water spray, alcohol-resistant foam, dry chemical or carbon dioxide Specific hazards arising from the chemical Rockwell - RP0011 Page 2 of 8

122 Safety Data Sheet InVict Xpress Granular Bait Release Date: 5/15/2015 Print Date: 5/28/2015 Version 1.0 Oxides of carbon, nitrogen, and sulfur Special protective equipment and precautions for fire fighters Wear self contained breathing apparatus for firefighting if deemed necessary. Additional information: none Further information No data available 6. ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Avoid contact with spilled product and contaminated surfaces. Evacuate personnel to safe areas during emergencies. For safe handling instructions see section 7. For proper PPE see section Environmental precautions Prevent further leakage or spillage if safe to do so. Do not allow release directly to water, to areas where surface water is present or to intertidal areas below the mean high-water mark Methods and materials for containment and cleaning up Sweep up any spilled material and dispose of according to instructions in section 13. Wash contaminated surfaces with soap and water. 7. HANDLING AND STORAGE 7.1. Precautions for safe handling Handle in accordance with good industrial hygiene practices. Wash hands thoroughly with soap and water after use and before eating, drinking, chewing gum, using tobacco, or using the toilet. For additional precautions see section Conditions for safe storage, including any incompatibilities Store in a dry place. Store in original container. Do not store where children or animals may gain access. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Components with workplace parameters Control Component CAS-No. Value Basis parameters none Appropriate engineering controls Ensure relevant engineering controls are employed to prevent exceeding threshold values for the listed control parameters in section Individual protection measures, such as personal protective equipment In normal use and handling conditions refer to the product label for required PPE. In all other cases the following recommendations would apply. Eye/face protection Rockwell - RP0011 Page 3 of 8

123 Safety Data Sheet InVict Xpress Granular Bait Release Date: 5/15/2015 Print Date: 5/28/2015 Version 1.0 Safety glasses or other similar eye protection conforming to ANSI Z87.1 standards recommended when handling product. Skin protection Chemical resistant nitrile rubber or similarly compatible gloves recommended when handling product. Dispose of contaminated gloves after use in accordance with applicable local and state regulations. Wash exposed skin with soap and water immediately. Wash all contaminated clothing prior to reuse. Respiratory protection Not required under normal use conditions. Particulate respirator recommended when risk assessment show need for air-purifying respirators. Thermal hazards None known 9. PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Appearance; Odor; Odor threshold; ph; Melting point/freezing point; Initial boiling point and boiling range; Flash point; Evaporation rate; Flammability (solid, gas); Upper/lower flammability or explosive limits; Vapor pressure; Vapor density; Relative density; Solubility; Partition coefficient: n- octanol/water; Auto-ignition temperature; Decomposition temperature; Opaque, yellow beige granule Oily/fishy No data available 1% in water (23.4 ºC) No data available No data available No data available No data available No data available No data available No data available No data available g/ml Partially soluble in water No data available No data available No data available Rockwell - RP0011 Page 4 of 8

124 Safety Data Sheet InVict Xpress Granular Bait Release Date: 5/15/2015 Print Date: 5/28/2015 Version 1.0 Viscosity; No data available 9.2. Additional Information No data available 10. STABILITY AND REACTIVITY Reactivity No data available Chemical stability Stable under recommended storage conditions Possibility of hazardous reactions No data available Conditions to avoid Exposure to excessive heat Incompatible materials Strong oxidizing agents. Strong reducing agents Hazardous decomposition products Other decomposition products no data available In the event of a fire: see Section TOXICOLOGICAL INFORMATION Information on toxicological effects Acute Toxicity LD50 Oral Rat > 5000 mg/kg LD50 Dermal Rat > 5000 mg/kg LD50 Inhalation no data available Skin corrosion/irritation Skin Rabbit Results: not irritating to skin (OECD Test Guideline 404) Serious eye damage/irritation Eye Rabbit Results: minimal eye irritation (OECD Test Guideline 405) Respiratory or skin sensitization Not a known sensitizer Germ cell mutagenicity Not a known mutagen Carcinogenicity IARC: No component of this product presents at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Rockwell - RP0011 Page 5 of 8

125 Safety Data Sheet InVict Xpress Granular Bait Release Date: 5/15/2015 Print Date: 5/28/2015 Version 1.0 ACGIH: No component of this product presents at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by ACGIH. NTP: No component of this product presents at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by NTP. OSHA: No component of this product presents at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by OSHA. Reproductive toxicity No data available Specific target organ toxicity single exposure Imidacloprid is a neurotoxin that when consumed in sufficient quantities can have adverse effects up to and including death. This product contains a low concentration of imidacloprid and normal use should not result in significant occupational hazard. Specific target organ toxicity repeated exposure No data available Aspiration hazard No data available Other information No data available 12. ECOLOGICAL INFORMATION Toxicity Toxicity to fish no data available Toxicity to daphnia no data available and other aquatic invertebrates Persistence and degradability No data available Bioaccumulative potential No data available Mobility in soil No data available Other adverse effects No data available 13. DISPOSAL CONSIDERATIONS Disposal Methods. The best disposal method is to use the entire product per label directions. If it is necessary to dispose of unused material then follow the label instructions and relevant local, state and federal waste disposal guidelines. Product Disposal: Do not contaminate water, food or feed by storage or disposal. Rockwell - RP0011 Page 6 of 8

126 Safety Data Sheet InVict Xpress Granular Bait Release Date: 5/15/2015 Print Date: 5/28/2015 Version 1.0 Packaging Disposal: If empty: Place in trash or offer for recycling if available. If partly filled: Call your local solid waste agency or CLEANUP which is managed as a public-private partnership. 14. TRANSPORT INFORMATION DOT Not dangerous goods IMDG Not dangerous goods IATA Not dangerous goods 15. REGULATORY INFORMATION This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: KEEP OUT OF THE REACH OF CHILDREN CAUTION Causes moderate eye irritation. Avoid contact with eyes or clothing. Wash hands thoroughly with soap and water after use and before eating, drinking, chewing gum, using tobacco, or using the toilet. This pesticide is highly toxic to birds and aquatic invertebrates. Do not apply directly to water, or to areas where surface water is present or to intertidal areas below the mean high water mark. To protect the environment, do not allow pesticide to enter or run off into storm drains, drainage ditches, gutters or surface waters. SARA 302 Components No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313 Components This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. SARA 311/312 Hazards Acute Health Hazard (Imidacloprid) California Proposition 65 Components This product does not contain any chemicals known to the state of California to cause cancer, birth defects, or reproductive harm. Rockwell - RP0011 Page 7 of 8

127 Safety Data Sheet InVict Xpress Granular Bait Release Date: 5/15/2015 Print Date: 5/28/2015 Version 1.0 TSCA All components of this product are listed, exempted, or excluded from listing on the U.S. Toxic Substances Control Act chemical substance inventory. 16. OTHER INFORMATION Acronyms and abbreviations used LD50 Lethal Dose, 50% OECD Organization for Economic Cooperation and Development IARC International Agency for Research on Cancer ACGIH American Conference of Industrial Hygienists NTP National Toxicology Program OSHA Occupational Safety and Health Administration DOT Department of Transportation IMDG International Maritime Dangerous Goods IATA International Air Transport Association SARA Superfund Amendments and Reauthorization Act TSCA Toxic Substances Control Act CAS-No. Chemical Abstract Services - Number PPE Personal Protective Equipment HMIS Hazardous Materials Identification System NFPA National Fire Protection Association PPM Parts Per Million Hazard Rating System Crossover HMIS Rating NFPA Rating Health Hazard: 1 Health Hazard: 1 Flammability: 0 Flammability: 0 Reactivity: 0 Reactivity: 0 Preparation information Prepared by: Rockwell Labs Ltd Version: 1.0 Revision Date: May 15, 2015 Reason for revision: none Notice to Reader: The information provided in this Safety Data Sheet has been obtained from sources believed to be reliable. Rockwell Labs Ltd provides no warranties, express or implied, and assumes no responsibility for the accuracy and completeness of the data contained herein. The customer assumes all responsibility for safety and use not in accordance with label instructions. The product names are trademarks of Rockwell Labs Ltd. Rockwell - RP0011 Page 8 of 8

128 Return to Index IDENTIFICATION SAFETY DATA SHEET Martin s Gopher Bait 50 Product name: Martin s Gopher Bait 50 Product type: Strychnine treated grain bait EPA Registration No.: Chemical name of active ingredient(s): Quinclorac: 3,7-dichloro-8-quinolinecarboxylic acid Manufacturer/Registrant: Control Solutions, Inc Genoa-Red Bluff Pasadena, TX For fire, spill, and/or leak emergencies, contact Chemtrec: Phone: For medical emergencies and health and safety inquiries, contact Safety Call: Phone: Poison Control Center Phone: HAZARDS IDENTIFICATIONS OSHA HCS CLASSIFICATION (29 CFR ) Acute Toxicity: Acute oral Acute dermal Acute inhalation Eye irritation Skin irritation Category 4 NC NC 2B 2 1B NC: Not classified SIGNAL WORD: WARNING HAZARD STATEMENTS: - Harmful is swallowed Cause eye irritation - Cause skin irritation - May cause skin reaction PICTOGRAM: Skin Sensitization PRECAUTIONARY STATEMENTS: - Wash hand thoroughly after handling. Do not eat, drink or smoke when using this product. If swallowed: Call a poison center or a doctor if you feel unwell. Rinse mouth. - Wash hands thoroughly after handling. If in eyes: rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: get medical advice. - Wash hand thoroughly after handling. Wear protective gloves. If on skin: wash with plenty of water. If skin/irritation occurs: Get medical advice. Take off contaminated clothing and wash it before reuse. - Avoid breathing dust, fume or gas. Contaminated work clothing must not be allowed out of the workplace. Wear protective gloves. If on skin: wash with plenty of water. If skin irritation or rash occurs: get medical advice. Wash contaminated clothing before reuse. Contact Safety Call International for emergency medical treatment at (866) Page 1 of 5

129 SAFETY DATA SHEET Martin s Gopher Bait COMPOSITION/INFORMATION ON INGREDIENTS COMMON NAME CAS NO. % ACGIH NTP/IARC/OSHA OSHA PEL TLV OTHER (Carcinogen) Strychnine mg/m 3 NE NE NA Calcium carbonate mg/m 3 NE NE NA (Limestone) Grain Dust None >1% 10 mg/m 3 NE NE NA NE=Not established; NA=Not applicable. 4. FIRST AID MEASURES FIRST AID IF SWALLOWED: Call a physician or poison control center immediately. If less than ten (10) minutes have passed since poison was taken, give1 or 2 glasses of water and induce vomiting by touching back of throat with finger. Repeat until vomit fluid is clear. Have patient lie down in quiet, darkened room and keep warm and quiet. If person is unconscious, do not give anything by mouth and do no induce vomiting. Do not give anything by mouth to an unconscious person. IF INHALED: Remove victim to fresh air. If not breathing, give artificial respiration. Get medical attention. IF IN EYES: Hold eyelids open and flush with steady, gentle stream of water for 15 minutes. Get medical attention. IF ON SKIN: Wash with plenty of soap and water. Get medical attention. NOTE TO PHYSICIAN: (A) Administer 100% oxygen by positive pressure to provide as much pulmonary gas exchange as possible despite seizures. (B) Administer ANTICONVULASANT DRUGS intravenously to control convulsions. NOTICE: It may be difficult of impossible to stop the seizure activity without stopping respiration. Be prepared to maintain pulmonary ventilation mechanically. Tracheotomy may be necessary if seizures are prolonged. Have the product container or label with you when calling a poison control center or doctor, or going for treatment. In case of a medical emergency call SafetyCall at (866) FIRE FIGHTING MEASURES FLASH POINT: Non-flammable FLAMMABLE LIMITS: Not available. EXTINGUISHING MEDIA: Water spray, CO 2, foam, dry chemical. UNUSUAL FIRE, EXPLOSION HAZARDS: Not known. FIRE-FIGHTING PROCEDURES: Wear full-faced self-contained breathing apparatus along with full protective gear. HAZARDOUS DECOMPOSITION PRODUCTS: Only when heated. 6. ACCIDENTAL RELEASE MEASURES ACTION TO TAKE FOR SPILLS/LEAKS: Do not allow bait to be exposed on soil surface. Do not contaminate water by cleaning of equipment or disposal of wastes. Sweep up all spilled bait carefully and bury. 7. HANDLING AND STORAGE PRECAUTIONS TO BE TAKEN IN HANDLING: Keep out of reach of children, pets and domestic animals. Convulsion poison. Poisonous if swallowed. This bait may cause an allergic reaction. Do not breathe dust. Do not get in eyes, on skin or on clothing. Do not contaminate feed and foodstuffs. Wash arms, hands and face with germicidal soap and Water after using and before eating or accepting anything by mouth or smoking. All spilled bait must be cleaned up immediately. Page 2 of 5

130 SAFETY DATA SHEET Martin s Gopher Bait 50 PRECAUTIONS TO BE TAKEN IN STORAGE: Store in original container in a dry place inaccessible to children and pets, under lock and key. Do not store near heat or flame. Do not store near food or feeds. Do not stack pallets more than two (2) high. STORAGE TEMPERATURE (MIN/MAX): 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Normal ambient temperatures. THE FOLLOWING RECOMMENDATIONS FOR EXPOSURE CONTROLS/PERSONAL PROTECTION ARE INTENDED FOR THE MANUFACTURE, FORMULATION, PACKAGING AND USE OF THIS PRODUCT. FOR COMMERCIAL APPLICATIONS AND/OR ON-FARM APPLICATIONS CONSULT THE PRODUCT LABEL. SKIN PROTECTION: Long-sleeve shirt, long pants, shoes plus socks and rubber or water gloves. EYE PROTECTION: Not required. RESPIRATOR REQUIREMENTS: For most conditions, no respiratory protection required. VENTILATION: Whenever possible, adequate ventilation should be used to minimize the need for personal protective equipment. Local exhaust required. Do not stand down wind. ADDITIONAL PROTECTIVE MEASURES: Follow manufacturer s instructions for cleaning/maintaining PPE. If no such instructions for washables, use detergent and hot water. Keep and wash PPE separately from other laundry. USER SAFETY RECOMMENDATIONS: Users Should: Wash hands before eating, drinking, chewing gum, using tobacco or using the toilet. Remove clothing immediately if pesticide gets inside. Then wash thoroughly and put on clean clothing. Remove PPE immediately after handling this product. Wash the outside of gloves before removing. As soon as possible, wash thoroughly and change into clean clothing. EXPOSURE GUIDELINES: Refer to Section 3. ENGINEERING CONTROLS: Local exhaust required. Do not stand down wind. 9. PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: Green colored, milo with crystalline-alkaloid coating ODOR: No odor ph: 6.95 (5% solution) FLASH POINT: Non-flammable SPECIFIC GRAVITY: 42 lbs./cu. ft. VISCOSITY: Not available 10. STABILITY AND REACTIVITY STABILITY: Stable under normal conditions. CONDITIONS TO AVOID: Spilling and heating. HAZARDOUS DECOMPOSITION PRODUCTS: Only when heated. HAZARDOUS POLYMERIZATION: May occur. 11. TOXICOLOGICAL INFORMATION ACUTE TOXICITY/IRRITATION STUDIES: Acute Oral LD 50 (Rat): 659 mg/kg (Highly toxic convulsive poison) Acute Dermal LD 50 (Rabbit): > 2,000 mg/kg Acute Inhalation LC 50 (Rat): None expected but dust may cause mild irritation of nasal mucous membranes. Eye Irritation: May cause irritation Skin Irritation: May cause irritation Page 3 of 5

131 SAFETY DATA SHEET Martin s Gopher Bait 50 Dermal Sensitization: May cause an allergic reaction REPRODUCTIVE/DEVELOPMENTAL EFFECTS: No information available CHRONIC/SUBCHRONIC TOXICITY STUDIES: No information available MUTAGENICITY: No information available 12. ECOLOGICAL INFORMATION ENVIRONMENTAL HAZARDS: This product is toxic to fish, birds, and other wildlife. Do not allow bait to be exposed on soil surface. Do not apply directly to water, or to areas where surface water is present or to intertidal areas below the mean high water mark. Do not contaminate water by cleaning of equipment disposal of wastes. ECOTOXICITY: (Strychnine technical): Northern bobwhite quail 8-d NOEC: 3,536 ppm Mallard duck 8-day NOEC : 212 ppm Rainbow trout 96-h LC 50 : 2.3 mg/l Bluegill sunfish 96-h LC 50 : 0.76 mg/l Daphnia magna 48-h EC 50 : 10 mg/l ENVIRONMENTAL FATE: (Strychnine technical) When released into the soil, this material has the potential to photolyze on soil surfaces. Volatilization and chemical hydrolysis are not expected to be important fate processes. When released into water, this material has the potential to photolyze. Volatilization, chemical hydrolysis and bioaccumulation in aquatic organisms are not expected. 13. DISPOSAL CONSIDERATIONS PESTICIDE DISPOSAL: Pesticide, spray mixture or rinse water that cannot be used according to label instructions must be disposed of at or by an approved waste disposal facility. CONTAINER DISPOSAL: Dispose of product containers, waste containers, and residues according to label instructions and local, state, and federal health and environmental regulations. 14. TRANSPORT INFORMATION DOT CLASSIFICATION: Not Regulated. INTERNATIONAL TRANSPORTATION: Not Regulated. 15. REGULATORY INFORMATION FIFRA INFORMATION: This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information for safety data sheet, and for workplace labels of nonpesticide chemicals. Following is the hazard information as required on the pesticide label. POISON DANGER Convulsive Poison. Fatal if swallowed if swallowed. SARA TITLE III CLASSIFICATION: Section 302: Strychnine (CAS# ) TPQ 100 lbs. (lower threshold); 10,000 lbs. TPQ (upper thresh old) Section 311/312: Acute health hazard (immediate) Chronic health hazard (delayed) Section 313: Strychnine (CAS# ) CA PROPOSITION 65: Not applicable Page 4 of 5

132 SAFETY DATA SHEET Martin s Gopher Bait 50 CERCLA RQ: Strychnine (CAS# ) RQ= 10 lbs. (4.54 kg) RCRA CLASSIFICATION: Under RCRA, it is the responsibility of the product user to determine at the time of disposal, whether a material containing the product or derived from the product should be classified as a hazardous waste. TSCA STATUS: The ingredients of this product are listed on the TSCA inventory or are exempt. 16. OTHER INFORMATION HAZARD RATINGS NFPA HMIS HEALTH: MINIMAL FLAMMABILITY: SLIGHT REACTIVITY: MODERATE 3 HIGH 4 SEVERE MSDS DATE: Supersedes version dated Changes made to all sections. The information and recommendations contained herein are based upon data believed to be correct. However, no warranty of any kind, expressed or implied, is made with respect to the information contained herein. Page 5 of 5

133 Bayer Environmental Science SAFETY DATA SHEET Return to Index... MAXFORCE FC MAGNUM ROACH KILLER BAIT GEL 1/9 Version 2.0 / USA Revision Date: 11/06/ Print Date: 11/06/2014 SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Product identifier Trade name Product code (UVP) SDS Number MAXFORCE FC MAGNUM ROACH KILLER BAIT GEL EPA Registration No Relevant identified uses of the substance or mixture and uses advised against Use Restrictions on use Information on manufacturer Emergency telephone no. Emergency Telephone Number (24hr/ 7 days) Product Information Telephone Number Insecticide See product label for restrictions. Bayer Environmental Science 2 T.W. Alexander Drive Research Triangle PK, NC United States (24 hours/day) SDS Information or Request SDSINFO.BCS-NA@bayer.com SECTION 2: HAZARDS IDENTIFICATION Classification in accordance with regulation HCS 29CFR This material is not hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29CFR Other hazards No particular hazards known. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Component Name CAS-No. Concentration % by weight Fipronil

134 Bayer Environmental Science SAFETY DATA SHEET MAXFORCE FC MAGNUM ROACH KILLER BAIT GEL 2/9 Version 2.0 / USA Revision Date: 11/06/ Print Date: 11/06/2014 SECTION 4: FIRST AID MEASURES Description of first aid measures General advice Inhalation Skin contact Eye contact When possible, have the product container or label with you when calling a poison control center or doctor or going for treatment. Move to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a physician or poison control center immediately. Take off contaminated clothing and shoes immediately. Wash off immediately with plenty of water for at least 15 minutes. Call a physician or poison control center immediately. Hold eye open and rinse slowly and gently with water for minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a physician or poison control center immediately. Ingestion Call a physician or poison control center immediately. Rinse out mouth and give water in small sips to drink. DO NOT induce vomiting unless directed to do so by a physician or poison control center. Never give anything by mouth to an unconscious person. Do not leave victim unattended. Most important symptoms and effects, both acute and delayed Symptoms The following symptoms may occur:, Restlessness, Anxiety, Tremors Indication of any immediate medical attention and special treatment needed Treatment Appropriate supportive and symptomatic treatment as indicated by the patient's condition is recommended. There is no specific antidote. SECTION 5: FIREFIGHTING MEASURES Extinguishing media Suitable Unsuitable Special hazards arising from the substance or mixture Advice for firefighters Special protective equipment for fire-fighters Further information Dry chemical, Foam, Water, Carbon dioxide (CO2) None known. Dangerous gases are evolved in the event of a fire. In the event of fire and/or explosion do not breathe fumes. Firefighters should wear NIOSH approved self-contained breathing apparatus and full protective clothing. Keep out of smoke. Fight fire from upwind position. Cool closed containers exposed to fire with water spray. Do not allow run-off from fire fighting to enter drains or water courses.

135 Bayer Environmental Science SAFETY DATA SHEET MAXFORCE FC MAGNUM ROACH KILLER BAIT GEL 3/9 Version 2.0 / USA Revision Date: 11/06/ Print Date: 11/06/2014 Flash point Autoignition temperature Lower explosion limit Upper explosion limit Explosivity no data available no data available no data available no data available not applicable SECTION 6: ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Precautions Keep unauthorized people away. Isolate hazard area. Avoid contact with spilled product or contaminated surfaces. Methods and materials for containment and cleaning up Methods for cleaning up Additional advice Collect and transfer the product into a properly labelled and tightly closed container. Clean contaminated floors and objects thoroughly, observing environmental regulations. Use personal protective equipment. Do not allow to enter soil, waterways or waste water canal. Reference to other sections Information regarding safe handling, see section 7. Information regarding personal protective equipment, see section 8. Information regarding waste disposal, see section 13. SECTION 7: HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Advice on protection against fire and explosion Product will stain porous surfaces. Use only in area provided with appropriate exhaust ventilation. Do not use this product in or on electrical equipment due to the possibility of shock hazard. Hygiene measures Remove Personal Protective Equipment (PPE) immediately after handling this product. Remove soiled clothing immediately and clean thoroughly before using again. Wash thoroughly and put on clean clothing. Wash hands thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco, using the toilet or applying cosmetics. Conditions for safe storage, including any incompatibilities

136 Bayer Environmental Science SAFETY DATA SHEET MAXFORCE FC MAGNUM ROACH KILLER BAIT GEL 4/9 Version 2.0 / USA Revision Date: 11/06/ Print Date: 11/06/2014 Requirements for storage areas and containers Keep out of reach of children and animals. Keep away from direct sunlight. Keep containers tightly closed in a dry, cool and well-ventilated place. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Components CAS-No. Control parameters Update Basis Fipronil ug/m TX ESL (Particulate.) (ST ESL) Fipronil ug/m TX ESL (Particulate.) (AN ESL) Fipronil mg/m3 OES BCS* (TWA) Sucrose mg/m ACGIH (TWA) Sucrose mg/m NIOSH (Respirable.) (REL) Sucrose mg/m NIOSH (Total) (REL) Sucrose mg/m OSHA Z1 (Total dust.) (PEL) Sucrose mg/m OSHA Z1 (Respirable fraction.) (PEL) Sucrose mg/m OSHA Z1A (Respirable fraction.) (TWA) Sucrose mg/m OSHA Z1A (Total dust.) (TWA) Sucrose mg/m TN OEL (Respirable fraction.) (TWA) Sucrose mg/m TN OEL (Total dust.) (TWA) Sucrose ug/m TX ESL (Particulate.) (ST ESL) Sucrose ug/m TX ESL (Particulate.) (AN ESL) No control parameters known. *OES BCS: Internal Bayer CropScience "Occupational Exposure Standard" Exposure controls Personal protective equipment In normal use and handling conditions please refer to the label and/or leaflet. In all other cases the following recommendations would apply. Respiratory protection Respiratory protection is not required under anticipated circumstances of exposure.

137 Bayer Environmental Science SAFETY DATA SHEET MAXFORCE FC MAGNUM ROACH KILLER BAIT GEL 5/9 Version 2.0 / USA Revision Date: 11/06/ Print Date: 11/06/2014 Hand protection Eye protection Skin and body protection General protective measures Chemical resistant nitrile rubber gloves Safety glasses with side-shields Wear long-sleeved shirt and long pants and shoes plus socks. Follow manufacturer's instructions for cleaning/maintaining PPE. If no such instructions for washables, use detergent and warm/tepid water. Keep and wash PPE separately from other laundry. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Physical State Odor Odour Threshold ph Vapor Pressure Vapor Density (Air = 1) Specific Gravity Evapouration rate Boiling Point Melting / Freezing Point Water solubility Minimum Ignition Energy Decomposition temperature Partition coefficient: n- octanol/water light brown gel characteristic no data available no data available no data available no data available no data available no data available no data available no data available soluble not applicable not applicable not applicable Viscosity 40, ,000 cps at 25 C Flash point no data available Autoignition temperature Lower explosion limit Upper explosion limit Explosivity no data available no data available no data available not applicable

138 Bayer Environmental Science SAFETY DATA SHEET MAXFORCE FC MAGNUM ROACH KILLER BAIT GEL 6/9 Version 2.0 / USA Revision Date: 11/06/ Print Date: 11/06/2014 SECTION 10: STABILITY AND REACTIVITY Reactivity Thermal decomposition Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products not applicable Stable under normal conditions. No dangerous reaction known under conditions of normal use. Extremes of temperature and direct sunlight. Exposure to moisture. Strong oxidizing agents, Strong bases, Strong acids No decomposition products expected under normal conditions of use. SECTION 11: TOXICOLOGICAL INFORMATION Exposure routes Immediate Effects Eye Skin Eye contact, Skin Absorption, Skin contact, Ingestion Moderate eye irritation. Harmful if absorbed through skin. Information on toxicological effects Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity Skin irritation Eye irritation Sensitisation Assessment repeated dose toxicity LD50 (rat) > 5,000 mg/kg no data available LD50 (rat) > 5,000 mg/kg Slight irritation (rabbit) Minimally irritating. (rabbit) Non-sensitizing. (guinea pig) Fipronil caused specific target organ toxicity in experimental animal studies in the following organ(s): liver. Fipronil caused neurobehavioral effects and/or neuropathological changes in animal studies. Assessment Mutagenicity Fipronil was not mutagenic or genotoxic in a battery of in vitro and in vivo tests. Assessment Carcinogenicity Fipronil caused an increased incidence of tumours in rats in the following organ(s): Thyroid. The mechanism that triggers tumours in rodents and the type of tumours observed are not relevant to humans.

139 Bayer Environmental Science SAFETY DATA SHEET MAXFORCE FC MAGNUM ROACH KILLER BAIT GEL 7/9 Version 2.0 / USA Revision Date: 11/06/ Print Date: 11/06/2014 ACGIH None. NTP None. IARC None. OSHA None. Assessment toxicity to reproduction Fipronil caused reproduction toxicity in a two-generation study in rats only at dose levels also toxic to the parent animals. The reproduction toxicity seen with Fipronil is related to parental toxicity. Assessment developmental toxicity Fipronil did not cause developmental toxicity in rats and rabbits. Further information Acute toxicity studies have been bridged from a similar formulation(s). Only acute toxicity studies have been performed on the formulated product. SECTION 12: ECOLOGICAL INFORMATION Toxicity to fish Toxicity to aquatic invertebrates LC50 (Oncorhynchus mykiss (rainbow trout)) 0.25 mg/l Exposure time: 96 h The value mentioned relates to the active ingredient fipronil. EC50 (Daphnia magna (Water flea)) 0.19 mg/l Exposure time: 48 h The value mentioned relates to the active ingredient fipronil. Toxicity to aquatic plants Biodegradability EC50 (Scenedesmus subspicatus) mg/l Exposure time: 96 h The value mentioned relates to the active ingredient fipronil. Fipronil: ; not rapidly biodegradable Koc Fipronil: Koc: Bioaccumulation Mobility in soil Environmental precautions Fipronil: Bioconcentration factor (BCF) 321; Does not bioaccumulate. Fipronil: Slightly mobile in soils Do not allow to get into surface water, drains and ground water. Do not contaminate surface or ground water by cleaning equipment or disposal of wastes, including equipment wash water. Apply this product as specified on the label.

140 Bayer Environmental Science SAFETY DATA SHEET MAXFORCE FC MAGNUM ROACH KILLER BAIT GEL 8/9 Version 2.0 / USA Revision Date: 11/06/ Print Date: 11/06/2014 SECTION 13: DISPOSAL CONSIDERATIONS Waste treatment methods Product Contaminated packaging RCRA Information It is best to use all of the product in accordance with label directions. If it is necessary to dispose of unused product, please follow container label instructions and applicable local guidelines. Never place unused product down any indoor or outdoor drain. Do not re-use empty containers. Place empty container in trash. Follow advice on product label and/or leaflet. Characterization and proper disposal of this material as a special or hazardous waste is dependent upon Federal, State and local laws and are the user's responsibility. RCRA classification may apply. SECTION 14: TRANSPORT INFORMATION According to national and international transport regulations this material is not classified as dangerous goods / hazardous material. SECTION 15: REGULATORY INFORMATION EPA Registration No US Federal Regulations TSCA list None. US. Toxic Substances Control Act (TSCA) Section 12(b) Export Notification (40 CFR 707, Subpt D) None. SARA Title III - Section Notification and Information None. SARA Title III - Section Toxic Chemical Release Reporting None. US States Regulatory Reporting CA Prop65 This product does not contain any substances known to the State of California to cause cancer. This product does not contain any substances known to the State of California to cause reproductive harm. US State Right-To-Know Ingredients None. Canadian Regulations Canadian Domestic Substance List None.

141 Bayer Environmental Science SAFETY DATA SHEET MAXFORCE FC MAGNUM ROACH KILLER BAIT GEL 9/9 Version 2.0 / USA Revision Date: 11/06/ Print Date: 11/06/2014 Environmental CERCLA None. Clean Water Section 307 Priority Pollutants None. Safe Drinking Water Act Maximum Contaminant Levels None. EPA/FIFRA Information: This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information required on the pesticide label: Signal word: Hazard statements: Caution! Harmful if absorbed through skin. Moderate eye irritation. Avoid contact with skin, eyes and clothing. Wash thoroughly with soap and water after handling. SECTION 16: OTHER INFORMATION NFPA 704 (National Fire Protection Association): Health - 1 Flammability - 1 Instability - 0 Others - none HMIS (Hazardous Materials Identification System, based on the Third Edition Ratings Guide) Health - 1 Flammability - 1 Physical Hazard - 0 PPE - 0 = minimal hazard, 1 = slight hazard, 2 = moderate hazard, 3 = severe hazard, 4 = extreme hazard Reason for Revision: Revised according to the current OSHA Hazard Communication Standard (29CFR ) Revision Date: 11/06/2014 This information is provided in good faith but without express or implied warranty. The customer assumes all responsibility for safety and use not in accordance with label instructions. The product names are registered trademarks of Bayer.

142 Bayer Environmental Science SAFETY DATA SHEET Return to Index MAXFORCE FLY SPOT BAIT 1/10 Version 1.0 / USA Revision Date: 08/15/ Print Date: 02/09/2015 SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Product identifier Trade name Product code (UVP) SDS Number MAXFORCE FLY SPOT BAIT EPA Registration No Relevant identified uses of the substance or mixture and uses advised against Use Restrictions on use Information on manufacturer Emergency telephone no. Emergency Telephone Number (24hr/ 7 days) Product Information Telephone Number Insecticide See product label for restrictions. Bayer Environmental Science 2 T.W. Alexander Drive Research Triangle PK, NC United States (24 hours/day) SDS Information or Request SDSINFO.BCS-NA@bayer.com SECTION 2: HAZARDS IDENTIFICATION Classification in accordance with regulation HCS 29CFR This material is not hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29CFR Other hazards No particular hazards known. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Component Name CAS-No. Concentration % by weight Imidacloprid

143 Bayer Environmental Science SAFETY DATA SHEET MAXFORCE FLY SPOT BAIT 2/10 Version 1.0 / USA Revision Date: 08/15/ Print Date: 02/09/2015 SECTION 4: FIRST AID MEASURES Description of first aid measures General advice Inhalation Skin contact Eye contact When possible, have the product container or label with you when calling a poison control center or doctor or going for treatment. Move to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a physician or poison control center immediately. Take off contaminated clothing and shoes immediately. Wash off immediately with plenty of water for at least 15 minutes. Call a physician or poison control center immediately. Hold eye open and rinse slowly and gently with water for minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a physician or poison control center immediately. Ingestion Call a physician or poison control center immediately. Rinse out mouth and give water in small sips to drink. DO NOT induce vomiting unless directed to do so by a physician or poison control center. Never give anything by mouth to an unconscious person. Do not leave victim unattended. Most important symptoms and effects, both acute and delayed Symptoms If large amounts are ingested, the following symptoms may occur: Dizziness, Abdominal pain, Nausea Indication of any immediate medical attention and special treatment needed Treatment There is no specific antidote. Appropriate supportive and symptomatic treatment as indicated by the patient's condition is recommended. SECTION 5: FIREFIGHTING MEASURES Extinguishing media Suitable Unsuitable Special hazards arising from the substance or mixture Advice for firefighters Special protective equipment for fire-fighters Further information Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. High volume water jet In the event of fire the following may be released:, Hydrogen chloride (HCl), Hydrogen cyanide (hydrocyanic acid), Carbon monoxide (CO), Nitrogen oxides (NOx) In the event of fire and/or explosion do not breathe fumes. In the event of fire, wear self-contained breathing apparatus. Keep out of smoke. Fight fire from upwind position. Cool closed containers exposed to fire with water spray. Do not allow run-off from fire fighting to enter drains or water courses.

144 Bayer Environmental Science SAFETY DATA SHEET MAXFORCE FLY SPOT BAIT 3/10 Version 1.0 / USA Revision Date: 08/15/ Print Date: 02/09/2015 Flash point not applicable Autoignition temperature 345 C / 653 F Lower explosion limit Upper explosion limit Explosivity not applicable not applicable Not explosive 92/69/EEC, A.14 / OECD 113 SECTION 6: ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Precautions Keep unauthorized people away. Isolate hazard area. Avoid contact with spilled product or contaminated surfaces. Methods and materials for containment and cleaning up Methods for cleaning up Additional advice Avoid dust formation. Sweep up or vacuum up spillage and collect in suitable container for disposal. Clean contaminated floors and objects thoroughly, observing environmental regulations. Use personal protective equipment. Do not allow to enter soil, waterways or waste water canal. Reference to other sections Information regarding safe handling, see section 7. Information regarding personal protective equipment, see section 8. Information regarding waste disposal, see section 13. SECTION 7: HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Use only in area provided with appropriate exhaust ventilation. Hygiene measures Wash hands thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco, using the toilet or applying cosmetics. Remove Personal Protective Equipment (PPE) immediately after handling this product. Before removing gloves clean them with soap and water. Remove soiled clothing immediately and clean thoroughly before using again. Wash thoroughly and put on clean clothing. Conditions for safe storage, including any incompatibilities Requirements for storage areas and containers Store in a cool, dry place and in such a manner as to prevent cross contamination with other crop protection products, fertilizers, food, and feed. Store in original container and out of the reach of children, preferably in a locked storage area.

145 Bayer Environmental Science SAFETY DATA SHEET MAXFORCE FLY SPOT BAIT 4/10 Version 1.0 / USA Revision Date: 08/15/ Print Date: 02/09/2015 Advice on common storage Keep away from food, drink and animal feedingstuffs. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Components CAS-No. Control parameters Update Basis Imidacloprid ug/m TX ESL (AN ESL) Imidacloprid ug/m TX ESL (ST ESL) Imidacloprid mg/m3 OES BCS* (TWA) Synthetic amorphous silica mg/m NIOSH (REL) Synthetic amorphous silica mg/m OSHA Z1A (TWA) Synthetic amorphous silica mg/m TN OEL (TWA) Synthetic amorphous silica ug/m TX ESL (Particulate.) (AN ESL) Synthetic amorphous silica ug/m TX ESL (Particulate.) (ST ESL) Synthetic amorphous silica millions of particles per 2000 Z3 cubic foot of air (TWA) Synthetic amorphous silica mg/m Z3 (TWA) Sucrose mg/m ACGIH (TWA) Sucrose mg/m NIOSH (Respirable.) (REL) Sucrose mg/m NIOSH (Total) (REL) Sucrose mg/m OSHA Z1 (Total dust.) (PEL) Sucrose mg/m OSHA Z1 (Respirable fraction.) (PEL) Sucrose mg/m OSHA Z1A (Respirable fraction.) (TWA) Sucrose mg/m OSHA Z1A (Total dust.) (TWA) Sucrose mg/m TN OEL (Respirable fraction.) (TWA) Sucrose mg/m TN OEL (Total dust.) (TWA) Sucrose ug/m TX ESL

146 Bayer Environmental Science SAFETY DATA SHEET MAXFORCE FLY SPOT BAIT 5/10 Version 1.0 / USA Revision Date: 08/15/ Print Date: 02/09/2015 (Particulate.) Sucrose (Particulate.) (ST ESL) ug/m3 (AN ESL) *OES BCS: Internal Bayer CropScience "Occupational Exposure Standard" Exposure controls TX ESL Personal protective equipment In normal use and handling conditions please refer to the label and/or leaflet. In all other cases the following recommendations would apply. Respiratory protection Hand protection Eye protection Skin and body protection General protective measures When respirators are required, select NIOSH approved equipment based on actual or potential airborne concentrations and in accordance with the appropriate regulatory standards and/or industry recommendations. Chemical resistant nitrile rubber gloves Safety glasses with side-shields Wear long-sleeved shirt and long pants and shoes plus socks. Follow manufacturer's instructions for cleaning/maintaining PPE. If no such instructions for washables, use detergent and warm/tepid water. Keep and wash PPE separately from other laundry. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Physical State Odor Odour Threshold ph Vapor Pressure Vapor Density (Air = 1) Specific Gravity Evapouration rate Boiling Point white to beige granular weak characteristic no data available at 1 % (23 C) (CIPAC D water (342ppm)) no data available no data available no data available not applicable not applicable Melting / Freezing Point 181 C / F Water solubility Minimum Ignition Energy Decomposition temperature dispersible no data available > 420 C, Heating rate: 0.5 K/min

147 Bayer Environmental Science SAFETY DATA SHEET MAXFORCE FLY SPOT BAIT 6/10 Version 1.0 / USA Revision Date: 08/15/ Print Date: 02/09/2015 Partition coefficient: n- octanol/water Viscosity Flash point no data available not applicable not applicable Autoignition temperature 345 C / 653 F Lower explosion limit Upper explosion limit Explosivity Other information not applicable not applicable Not explosive 92/69/EEC, A.14 / OECD 113 Further safety related physical-chemical data are not known. SECTION 10: STABILITY AND REACTIVITY Reactivity Thermal decomposition Self heating Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products > 420 C, Heating rate: 0.5 K/min not self-heating Stable under recommended storage conditions. No hazardous reactions when stored and handled according to prescribed instructions. Extremes of temperature and direct sunlight. no data available No decomposition products expected under normal conditions of use. SECTION 11: TOXICOLOGICAL INFORMATION Exposure routes Immediate Effects Eye Ingestion Ingestion, Skin contact, Eye contact May cause mild irritation to eyes. Harmful if swallowed. Information on toxicological effects Acute oral toxicity LD 50 cut-off (rat) > 5,000 mg/kg

148 Bayer Environmental Science SAFETY DATA SHEET MAXFORCE FLY SPOT BAIT 7/10 Version 1.0 / USA Revision Date: 08/15/ Print Date: 02/09/2015 Acute inhalation toxicity Acute dermal toxicity Skin irritation Eye irritation Sensitisation Assessment repeated dose toxicity ATE (rat) > 5 mg/l Exposure time: 4 h calculated ATE acute toxicity estimate ATE (rat) > 5,000 mg/kg Calculation method ATE acute toxicity estimate No skin irritation (rabbit) Minimally irritating. (rabbit) Non-sensitizing. (guinea pig) OECD Test Guideline 406, Magnusson & Kligman test Imidacloprid did not cause specific target organ toxicity in experimental animal studies. Assessment Mutagenicity Imidacloprid was not mutagenic or genotoxic based on the overall weight of evidence in a battery of in vitro and in vivo tests. Assessment Carcinogenicity Imidacloprid was not carcinogenic in lifetime feeding studies in rats and mice. ACGIH None. NTP None. IARC None. OSHA None. Assessment toxicity to reproduction Imidacloprid caused reproduction toxicity in a two-generation study in rats only at dose levels also toxic to the parent animals. The reproduction toxicity seen with Imidacloprid is related to parental toxicity. Assessment developmental toxicity Imidacloprid caused developmental toxicity only at dose levels toxic to the dams. The developmental effects seen with Imidacloprid are related to maternal toxicity. Further information Acute toxicity studies have been bridged from a similar formulation(s). The non-acute information pertains to the active ingredient(s).

149 Bayer Environmental Science SAFETY DATA SHEET MAXFORCE FLY SPOT BAIT 8/10 Version 1.0 / USA Revision Date: 08/15/ Print Date: 02/09/2015 SECTION 12: ECOLOGICAL INFORMATION Toxicity to fish Toxicity to aquatic invertebrates LC50 (Rainbow trout (Oncorhynchus mykiss)) 211 mg/l Exposure time: 96 h The value mentioned relates to the active ingredient imidacloprid. EC50 (Water flea (Daphnia magna)) 85 mg/l Exposure time: 48 h The value mentioned relates to the active ingredient imidacloprid. EC10 (Chironomus riparius (non-biting midge)) 2,09 µg/l Exposure time: 28 d The value mentioned relates to the active ingredient imidacloprid. Toxicity to aquatic plants Biodegradability Bioaccumulation Mobility in soil Additional ecological information Environmental precautions EC50 (Desmodesmus subspicatus) > 10 mg/l Growth rate; Exposure time: 72 h The value mentioned relates to the active ingredient imidacloprid. Not applicable for this mixture. Not applicable for this mixture. Not applicable for this mixture. No other effects to be mentioned. Do not apply directly to water, to areas where surface water is present or to intertidal areas below the mean high water mark. Do not contaminate surface or ground water by cleaning equipment or disposal of wastes, including equipment wash water. Do not apply this product or allow it to drift to blooming crops or weeds if bees are visiting the treatment area. Apply this product as specified on the label. SECTION 13: DISPOSAL CONSIDERATIONS Waste treatment methods Product Contaminated packaging Pesticide, spray mixture or rinse water that cannot be used according to label instructions may be disposed of on site or at an approved waste disposal facility. Do not re-use empty containers. Completely empty container into application equipment, then dispose of empty container in a sanitary landfill, by incineration or by other procedures approved by state/provincial and local authorities. If burned, stay out of smoke. Follow advice on product label and/or leaflet.

150 Bayer Environmental Science SAFETY DATA SHEET MAXFORCE FLY SPOT BAIT 9/10 Version 1.0 / USA Revision Date: 08/15/ Print Date: 02/09/2015 RCRA Information Characterization and proper disposal of this material as a special or hazardous waste is dependent upon Federal, State and local laws and are the user's responsibility. RCRA classification may apply. SECTION 14: TRANSPORT INFORMATION 49CFR Not dangerous goods / not hazardous material IMDG UN number 3077 Class 9 Packaging group III Marine pollutant Proper shipping name IATA UN number 3077 Class 9 Packaging group III Environm. Hazardous Mark Proper shipping name YES ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (IMIDACLOPRID MIXTURE) YES ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (IMIDACLOPRID MIXTURE ) This transportation information is not intended to convey all specific regulatory information relating to this product. It does not address regulatory variations due to package size or special transportation requirements. SECTION 15: REGULATORY INFORMATION EPA Registration No US Federal Regulations TSCA list None. US. Toxic Substances Control Act (TSCA) Section 12(b) Export Notification (40 CFR 707, Subpt D) None. SARA Title III - Section Notification and Information None. SARA Title III - Section Toxic Chemical Release Reporting None. US States Regulatory Reporting CA Prop65 This product does not contain any substances known to the State of California to cause cancer. This product does not contain any substances known to the State of California to cause

151 Bayer Environmental Science SAFETY DATA SHEET MAXFORCE FLY SPOT BAIT 10/10 Version 1.0 / USA Revision Date: 08/15/ Print Date: 02/09/2015 reproductive harm. US State Right-To-Know Ingredients None. Canadian Regulations Canadian Domestic Substance List None. Environmental CERCLA None. Clean Water Section 307 Priority Pollutants None. Safe Drinking Water Act Maximum Contaminant Levels None. EPA/FIFRA Information: This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information required on the pesticide label: Signal word: Hazard statements: Caution! Harmful if swallowed. Avoid contact with skin, eyes and clothing. Wash thoroughly with soap and water after handling. SECTION 16: OTHER INFORMATION NFPA 704 (National Fire Protection Association): Health - 1 Flammability - 1 Instability - 0 Others - none HMIS (Hazardous Materials Identification System, based on the Third Edition Ratings Guide) Health - 1 Flammability - 1 Physical Hazard - 0 PPE - 0 = minimal hazard, 1 = slight hazard, 2 = moderate hazard, 3 = severe hazard, 4 = extreme hazard Reason for Revision: New Safety Data Sheet. Revision Date: 08/15/2014 This information is provided in good faith but without express or implied warranty. The customer assumes all responsibility for safety and use not in accordance with label instructions. The product names are registered trademarks of Bayer.

152 Bayer Environmental Science SAFETY DATA SHEET Return to Index MAXFORCE GRANULAR FLY BAIT 1/10 Version 1.0 / USA Revision Date: 09/05/ Print Date: 02/09/2015 SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Product identifier Trade name Product code (UVP) SDS Number MAXFORCE GRANULAR FLY BAIT EPA Registration No Relevant identified uses of the substance or mixture and uses advised against Use Restrictions on use Information on manufacturer Emergency telephone no. Emergency Telephone Number (24hr/ 7 days) Product Information Telephone Number Insecticide See product label for restrictions. Bayer Environmental Science 2 T.W. Alexander Drive Research Triangle PK, NC United States (24 hours/day) SDS Information or Request SDSINFO.BCS-NA@bayer.com SECTION 2: HAZARDS IDENTIFICATION Classification in accordance with regulation HCS 29CFR This material is not hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29CFR Other hazards Dust may form explosive mixture in air. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Component Name CAS-No. Concentration % by weight Imidacloprid ,6-Di-tert-butyl-4-methylphenol >=0.10 <0.25

153 Bayer Environmental Science SAFETY DATA SHEET MAXFORCE GRANULAR FLY BAIT 2/10 Version 1.0 / USA Revision Date: 09/05/ Print Date: 02/09/2015 SECTION 4: FIRST AID MEASURES Description of first aid measures General advice Inhalation Skin contact Eye contact When possible, have the product container or label with you when calling a poison control center or doctor or going for treatment. Move to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a physician or poison control center immediately. Take off contaminated clothing and shoes immediately. Wash off immediately with plenty of water for at least 15 minutes. Call a physician or poison control center immediately. Hold eye open and rinse slowly and gently with water for minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a physician or poison control center immediately. Ingestion Call a physician or poison control center immediately. Rinse out mouth and give water in small sips to drink. DO NOT induce vomiting unless directed to do so by a physician or poison control center. Never give anything by mouth to an unconscious person. Do not leave victim unattended. Most important symptoms and effects, both acute and delayed Symptoms If large amounts are ingested, the following symptoms may occur: Dizziness, Abdominal pain, Nausea Symptoms and hazards refer to effects observed after intake of significant amounts of the active ingredient(s). Indication of any immediate medical attention and special treatment needed Treatment There is no specific antidote. Appropriate supportive and symptomatic treatment as indicated by the patient's condition is recommended. SECTION 5: FIREFIGHTING MEASURES Extinguishing media Suitable Unsuitable Special hazards arising from the substance or mixture Advice for firefighters Special protective equipment for fire-fighters Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. High volume water jet Dangerous gases are evolved in the event of a fire. Firefighters should wear NIOSH approved self-contained breathing apparatus and full protective clothing.

154 Bayer Environmental Science SAFETY DATA SHEET MAXFORCE GRANULAR FLY BAIT 3/10 Version 1.0 / USA Revision Date: 09/05/ Print Date: 02/09/2015 Further information Flash point Autoignition temperature Lower explosion limit Upper explosion limit Explosivity Keep out of smoke. Fight fire from upwind position. Do not allow run-off from fire fighting to enter drains or water courses. not applicable no data available not applicable not applicable no data available SECTION 6: ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Precautions Keep unauthorized people away. Isolate hazard area. Avoid dust formation. Avoid contact with spilled product or contaminated surfaces. Methods and materials for containment and cleaning up Methods for cleaning up Avoid dust formation. Use mechanical handling equipment. Clean contaminated floors and objects thoroughly, observing environmental regulations. Keep in suitable, closed containers for disposal. Reference to other sections Information regarding safe handling, see section 7. Information regarding personal protective equipment, see section 8. Information regarding waste disposal, see section 13. SECTION 7: HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Advice on protection against fire and explosion Avoid dust formation. Use only in area provided with appropriate exhaust ventilation. For personal protection see section 8. Dust may form explosive mixture in air. Take measures to prevent the build up of electrostatic charge. Keep away from heat and sources of ignition. Hygiene measures Avoid contact with skin, eyes and clothing. Wash hands thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco, using the toilet or applying cosmetics. Remove Personal Protective Equipment (PPE) immediately after handling this product. Before removing gloves clean them with soap and water. Remove soiled clothing immediately and clean thoroughly before using again. Wash thoroughly and put on clean clothing. Conditions for safe storage, including any incompatibilities

155 Bayer Environmental Science SAFETY DATA SHEET MAXFORCE GRANULAR FLY BAIT 4/10 Version 1.0 / USA Revision Date: 09/05/ Print Date: 02/09/2015 Requirements for storage areas and containers Store in original container. Keep containers tightly closed in a dry, cool and well-ventilated place. Store in a place accessible by authorized persons only. Keep away from direct sunlight. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Components CAS-No. Control parameters Update Basis Imidacloprid ug/m TX ESL (AN ESL) Imidacloprid ug/m TX ESL (ST ESL) Imidacloprid mg/m3 OES BCS* (TWA) 2,6-Di-tert-butyl mg/m ACGIH methylphenol (Inhalable fraction and vapor.) (TWA) 2,6-Di-tert-butyl mg/m NIOSH methylphenol (REL) 2,6-Di-tert-butyl mg/m OSHA Z1A methylphenol (TWA) 2,6-Di-tert-butyl-4- methylphenol mg/m3 (TWA) TN OEL 2,6-Di-tert-butyl-4- methylphenol (Particulate.) 2,6-Di-tert-butyl-4- methylphenol (Particulate.) 2,6-Di-tert-butyl-4- methylphenol ug/m3 (ST ESL) ug/m3 (AN ESL) mg/m3 (TWA PEL) *OES BCS: Internal Bayer CropScience "Occupational Exposure Standard" Exposure controls TX ESL TX ESL US CA OEL Personal protective equipment In normal use and handling conditions please refer to the label and/or leaflet. In all other cases the following recommendations would apply. Respiratory protection Hand protection Eye protection When respirators are required, select NIOSH approved equipment based on actual or potential airborne concentrations and in accordance with the appropriate regulatory standards and/or industry recommendations. Chemical resistant nitrile rubber gloves Safety glasses with side-shields

156 Bayer Environmental Science SAFETY DATA SHEET MAXFORCE GRANULAR FLY BAIT 5/10 Version 1.0 / USA Revision Date: 09/05/ Print Date: 02/09/2015 Skin and body protection General protective measures Wear long-sleeved shirt and long pants and shoes plus socks. Follow manufacturer's instructions for cleaning/maintaining PPE. If no such instructions for washables, use detergent and warm/tepid water. Keep and wash PPE separately from other laundry. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Physical State Odor Odour Threshold ph Vapor Pressure Vapor Density (Air = 1) Evapouration rate light red granular weak characteristic no data available at 1 % (23 C) (deionized water) no data available no data available not applicable Boiling Point not applicable Melting / Freezing Point C / F Minimum Ignition Energy Decomposition temperature Partition coefficient: n- octanol/water Viscosity Flash point no data available no data available not applicable not applicable not applicable Autoignition temperature Lower explosion limit Upper explosion limit Explosivity Other information no data available not applicable not applicable no data available Further safety related physical-chemical data are not known. SECTION 10: STABILITY AND REACTIVITY Reactivity Thermal decomposition Chemical stability no data available Stable under recommended storage conditions.

157 Bayer Environmental Science SAFETY DATA SHEET MAXFORCE GRANULAR FLY BAIT 6/10 Version 1.0 / USA Revision Date: 09/05/ Print Date: 02/09/2015 Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products No hazardous reactions when stored and handled according to prescribed instructions. Extremes of temperature and direct sunlight. Store only in the original container. No decomposition products expected under normal conditions of use. SECTION 11: TOXICOLOGICAL INFORMATION Exposure routes Immediate Effects Eye Skin Ingestion Eye contact, Skin contact, Inhalation, Ingestion Causes eye irritation. May cause slight irritation. Harmful if absorbed through skin. Harmful if swallowed. Inhalation Harmful if inhaled. Information on toxicological effects Acute oral toxicity Acute inhalation toxicity LD50 (rat) > 2,500 mg/kg no data available Acute dermal toxicity Skin irritation Eye irritation Sensitisation Assessment repeated dose toxicity During intended and foreseen applications, no respirable aerosol is formed. LD50 (rat) > 2,000 mg/kg No skin irritation (rabbit) No eye irritation (rabbit) Non-sensitizing. (guinea pig) OECD Test Guideline 406, Magnusson & Kligman test Imidacloprid did not cause specific target organ toxicity in experimental animal studies. Assessment Mutagenicity Imidacloprid was not mutagenic or genotoxic based on the overall weight of evidence in a battery of in vitro and in vivo tests. Assessment Carcinogenicity Imidacloprid was not carcinogenic in lifetime feeding studies in rats and mice. ACGIH 2,6-Di-tert-butyl-4-methylphenol Group A4

158 Bayer Environmental Science SAFETY DATA SHEET MAXFORCE GRANULAR FLY BAIT 7/10 Version 1.0 / USA Revision Date: 09/05/ Print Date: 02/09/2015 NTP None. IARC 2,6-Di-tert-butyl-4-methylphenol Overall evaluation: 3 OSHA None. Assessment toxicity to reproduction Imidacloprid caused reproduction toxicity in a two-generation study in rats only at dose levels also toxic to the parent animals. The reproduction toxicity seen with Imidacloprid is related to parental toxicity. Assessment developmental toxicity Imidacloprid caused developmental toxicity only at dose levels toxic to the dams. The developmental effects seen with Imidacloprid are related to maternal toxicity. Further information Only acute toxicity studies have been performed on the formulated product. The non-acute information pertains to the active ingredient(s). SECTION 12: ECOLOGICAL INFORMATION Toxicity to fish Toxicity to aquatic invertebrates LC50 (Rainbow trout (Oncorhynchus mykiss)) 211 mg/l Exposure time: 96 h The value mentioned relates to the active ingredient imidacloprid. EC50 (Water flea (Daphnia magna)) 85 mg/l Exposure time: 48 h The value mentioned relates to the active ingredient imidacloprid. EC10 (Chironomus riparius (non-biting midge)) 2,09 µg/l Exposure time: 28 d The value mentioned relates to the active ingredient imidacloprid. Toxicity to aquatic plants Biodegradability EC50 (Desmodesmus subspicatus) > 10 mg/l Growth rate; Exposure time: 72 h The value mentioned relates to the active ingredient imidacloprid. Imidacloprid: ; not rapidly biodegradable Koc Imidacloprid: Koc: 225 Bioaccumulation Mobility in soil Additional ecological information Imidacloprid: ; Does not bioaccumulate. Imidacloprid: Moderately mobile in soils No other effects to be mentioned.

159 Bayer Environmental Science SAFETY DATA SHEET MAXFORCE GRANULAR FLY BAIT 8/10 Version 1.0 / USA Revision Date: 09/05/ Print Date: 02/09/2015 Environmental precautions Do not allow to get into surface water, drains and ground water. SECTION 13: DISPOSAL CONSIDERATIONS Waste treatment methods Product Contaminated packaging RCRA Information Dispose in accordance with all local, state/provincial and federal regulations. Do not re-use empty packagings. Completely empty container into application equipment, then dispose of empty container in a sanitary landfill, by incineration or by other procedures approved by state/provincial and local authorities. If burned, stay out of smoke. Follow advice on product label and/or leaflet. Characterization and proper disposal of this material as a special or hazardous waste is dependent upon Federal, State and local laws and are the user's responsibility. RCRA classification may apply. SECTION 14: TRANSPORT INFORMATION 49CFR Not dangerous goods / not hazardous material IMDG UN number 3077 Class 9 Packaging group III Marine pollutant Proper shipping name IATA UN number 3077 Class 9 Packaging group III Environm. Hazardous Mark Proper shipping name YES ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (IMIDACLOPRID MIXTURE) YES ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (IMIDACLOPRID MIXTURE ) This transportation information is not intended to convey all specific regulatory information relating to this product. It does not address regulatory variations due to package size or special transportation requirements. Freight Classification: INSECTICIDES OR FUNGICIDES, N.O.I., OTHER THAN POISON

160 Bayer Environmental Science SAFETY DATA SHEET MAXFORCE GRANULAR FLY BAIT 9/10 Version 1.0 / USA Revision Date: 09/05/ Print Date: 02/09/2015 SECTION 15: REGULATORY INFORMATION EPA Registration No US Federal Regulations TSCA list 2,6-Di-tert-butyl-4-methylphenol US. Toxic Substances Control Act (TSCA) Section 12(b) Export Notification (40 CFR 707, Subpt D) None. SARA Title III - Section Notification and Information None. SARA Title III - Section Toxic Chemical Release Reporting None. US States Regulatory Reporting CA Prop65 This product does not contain any substances known to the State of California to cause cancer. This product does not contain any substances known to the State of California to cause reproductive harm. US State Right-To-Know Ingredients 2,6-Di-tert-butyl-4-methylphenol CA, MN Canadian Regulations Canadian Domestic Substance List None. Environmental CERCLA None. Clean Water Section 307 Priority Pollutants None. Safe Drinking Water Act Maximum Contaminant Levels None. EPA/FIFRA Information: This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information required on the pesticide label: Signal word: Hazard statements: Caution! Harmful if swallowed, inhaled or absorbed through the skin. Avoid contact with skin, eyes and clothing. Wash thoroughly with soap and water after handling.

161 Bayer Environmental Science SAFETY DATA SHEET MAXFORCE GRANULAR FLY BAIT 10/10 Version 1.0 / USA Revision Date: 09/05/ Print Date: 02/09/2015 SECTION 16: OTHER INFORMATION NFPA 704 (National Fire Protection Association): Health - 1 Flammability - 1 Instability - 1 Others - none HMIS (Hazardous Materials Identification System, based on the Third Edition Ratings Guide) Health - 1 Flammability - 1 Physical Hazard - 1 PPE - 0 = minimal hazard, 1 = slight hazard, 2 = moderate hazard, 3 = severe hazard, 4 = extreme hazard Reason for Revision: New Safety Data Sheet. Revision Date: 09/05/2014 This information is provided in good faith but without express or implied warranty. The customer assumes all responsibility for safety and use not in accordance with label instructions. The product names are registered trademarks of Bayer.

162 Return to Index

163 For the control of crickets, cockroaches, silverfish, ants (except fire ants) and earwigs. FOR BOTH INTERIOR AND EXTERIOR USE ACTIVE INGREDIENT: Orthoboric Acid % OTHER INGREDIENTS % TOTAL % EPA Reg. No EPA Est TN-1 KEEP OUT OF REACH OF CHILDREN CAUTION If in Eyes If on Skin First Aid Hold eye open and rinse slowly and gently with water for minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eyes. Call a poison control center or doctor for treatment advice. Take off contaminated clothing. Immediately rinse with plenty of water for minutes. Call a poison control center or doctor for treatment advice. Have the product container or label with you when calling a poison control center or doctor or going for treatment. You may also contact for emergency medical treatment information. PRECAUTIONARY STATEMENTS Hazards to Humans & Domestic Animals CAUTION: Harmful if absorbed through skin. Causes moderate eye irritation. Avoid contact with skin, eyes or clothing. Personal Protective EquipmenT (PPE) Applicators and handlers must wear: Long-sleeved shirt and long pants; waterproof gloves; and shoes plus socks. Follow manufacturer s instructions for cleaning/ maintaining PPE. If no such instructions for washables are given, use detergent and hot water. User Safety Recommendations Users should: Wash hands before eating, drinking, chewing gum, using tobacco or using the toilet. Remove clothing immediately if pesticide gets inside; then thoroughly wash and put on clean clothing. Immediately remove PPE after handling this product. Wash the outside of gloves before removing. As soon as possible, thoroughly wash and change into clean clothing. Environmental Hazards Do not apply directly to water, to areas where surface water is present or to intertidal areas below the mean high water mark. Do not contaminate water when disposing of equipment washwaters or rinsate. DIRECTIONS FOR USE It is a violation of Federal law to use this product in a manner inconsistent with its labeling. General Information This product is a ready-to-use, weather/moisture resistant bait that controls and kills ants (except fire ants), cockroaches, crickets, earwigs and silverfish specifically: Ants: Argentine, carpenter, thief, pharaoh, little black, pavement, odorous house and crazy ants. Cockroaches: Asian, American, brown, brown-banded, smokybrown, German and oriental cockroaches. Crickets: Camel, house, field and mole crickets. European Earwigs. Do not contaminate this product with other pesticides. If this product becomes contaminated with another pesticide it will lose its effectiveness. Do not apply directly to food and avoid contamination of feed and foodstuff. In commercial food handling facilities, cover or remove any food during application. In food handling and other areas, bait may be placed in removable bait stations. Always record the number and location of bait stations. This product is designed to be used as a residual treatment in an Integrated Pest Management program incorporating good sanitation practices. This product may be applied in appropriate areas with a power duster (except in California). Consult equipment manufacturer for recommended settings. Keep children and pets out of treatment area until application has been completed. Do not treat pets with this product. Avoid over-application around ornamental plants and fish ponds. Do not apply this product in combination with fertilizers, other pesticides or other biologically-active materials. Application Instructions Exterior Baiting to Control and Kill Ants (Except Fire Ants), Including Carpenter Ants, Around Apartment Buildings, Food Processing Plants, Garages, Homes, Hospitals, Hotels, Kennels, Motels, Pet Stores, Public

164 & Private Institutions, Recreational Vehicles, Restaurants, Schools, Supermarkets and Warehouses: Treat exterior perimeter areas of structure in a band 2 to 4 feet wide at a rate of 6 ounces per 100 square feet. Also apply product in a 2- to 4-foot band around all trees, stumps, firewood piles and other locations where carpenter ants may nest. If the nest is located in a hollow tree or stump, apply 1/2 to 1 ounce of product directly into the cavity. Apply along ant trails and in areas where ant activity has been noted. To Control and Kill Ants (Except Fire Ants), Cockroaches, Crickets, Earwigs and Silverfish Within and Around the Exterior of Structures Such as Apartment Buildings, Food Processing Plants (Non-Food Areas), Garages, Homes, Hospitals, Hotels, Kennels, Motels, Pet Stores, Public & Private Institutions, Recreational Vehicles, Restaurants (Non-Food Areas), Schools, Sewers, Stores, Supermarkets and Warehouses: Apply at a rate of 6 ounces or 1 1/4 cups per 100 square feet of surface area. Spread evenly in crawl spaces, attics, drop ceilings and cellars with dirt or gravel floors. Concentrate application in areas where insect activity is most prevalent. In attics, be sure to apply in eaves and access drains. In warehouses, garages and basements, concentrate application along walls and baseboards. This product may also be applied in inaccessible areas such as cracks and crevices where insects may hide. Any bait visible after application must be brushed into cracks and crevices or removed. Apply in pits of elevator, dumbwaiter and trash chute shafts. Apply under and behind pallets and boxes in storerooms. Bait may also be placed in removable bait stations in areas accessible to insects but inaccessible to children and pets. Always record the location and number of bait stations. Regularly inspect bait stations and replace bait as needed. In sewers, apply along ledges and around manhole entrances. Treat exterior perimeter building walls in a band approximately 2 feet wide and scatter bait in flower beds, leaf litter, wood piles, trash cans and refuse areas. Reapply as necessary. To Control and Kill Ants (Except Fire Ants), Cockroaches, Crickets, Earwigs and Silverfish in Aircraft, Apartment Buildings, Boats, Buses, Factories, Food Handling Establishments, Food Processing Plants, Garages, Grocery Stores, Homes, Hospitals, Hotels, Industrial Plants, Kennels, Libraries, Markets, Military Bases, Mobile Homes, Motels, New Construction, Nursing Homes, Offices, Pet Stores, Private & Public Institutions, Recreational Vehicles, Restaurants, Schools, Sewers, Ships, Supermarkets, Theaters, Trains, Trucks, Utilities, Warehouses, Yachts, and Zoos: Food area application limited to only crack and crevice treatment. Apply only in areas inaccessible to children and pets. Avoid contamination of feed and foodstuffs. Apply by scattering/dusting under and behind refrigerator, cooler, stove, sink, dishwasher, washing machine and dryer tubs; counters; into openings around drains, water pipes and electrical conduits; and in cracks and crevices along baseboards and corners of cabinets, counter tops, cupboards, and closets. Remove all lower drawers in kitchen and bathroom cabinets, bedroom dressers and chests of drawers, then scatter/dust in drawer wells. Bait may also be applied into and around areas of insect infestation of above-ground transformers, in-ground utility boxes, pedestal boxes and vending machines. Any bait visible after application must be brushed into cracks and crevices or removed. Reapply as necessary. Bait may also be placed in removable bait stations in areas accessible to insects but inaccessible to children and pets. Always record the location and number of bait stations. Regularly inspect bait stations and replace bait as needed. Crack and Crevice Applications in Aircraft, Apartment Buildings, Boats, Buses, Factories, Food Handling Establishments, Food Processing Plants, Garages, Grocery Stores, Homes, Hospitals, Hotels, Industrial Plants, Kennels, Libraries, Markets, Military Bases, Mobile Homes, Motels, New Construction, Nursing Homes, Offices, Pet Stores, Private & Public Institutions, Recreational Vehicles, Restaurants, Schools, Sewers, Ships, Supermarkets, Thea-ters, Trains, Trucks, Utilities, Warehouses, Yachts and Zoos: Crack and crevice applications may be made using most types of dust applicators. A bellows type duster works best. Insert stem into gaps, cracks and crevices and apply 2 to 6 puffs per lineal foot, depending upon the severity of the infestation. Any bait visible after application must be brushed into cracks and crevices or removed. Drill small holes to gain access into wall voids and under cabinets. This product may also be applied in appropriate areas with a power duster (except in California). Consult equipment manufacturer for recommended settings. Application Sites and Directions: 1. Apply under and behind appliances in kitchens, bathrooms and utility rooms (remove kick plates if possible). 2. Kitchen and bathroom cabinets and vanities often have a space between the floor and the bottom drawer or cabinet. If a gap exists along the top of the kickplate, dust this product into the void area. If no gaps are present, drill a small hole every two feet along the kickplate, drilling at least one hole under each cabinet, and apply this product through the holes. 3. Apply in voids around plumbing pipes behind water heaters and under sinks in kitchens, bath-rooms, showers and utility rooms. Pull back escutcheon plates around pipes to allow access to the void. 4. Remove electrical wall socket and switch covers and dust product around boxes and into voids. Do not apply product directly into electrical switch and outlet boxes. 5. Cracks or spaces between the wall and doorframes, cabinets, counter tops, molding or baseboards provide excellent hiding places for roaches and ants. Dust a small amount of this product into these areas wherever possible. 6. Apply under and behind vending machines. If access can be gained to the interior of the machine, apply around the interior base, being careful not to contaminate any foodstuffs. To Control and Kill Cockroaches, Crickets, Ants, Earwigs and Silverfish in Federally-Inspected (USDA)

165 Meat and Poultry Plants: For application only in inedible product areas and non-processing areas as a crack and crevice treatment. Apply to cracks and crevices in areas such as around base-boards and in closets; beneath cabinets and appliances, in and around waste containers and into openings around drains, water pipes and electrical conduits. Any bait visible after application must be brushed into cracks and crevices or removed. Avoid contamination of feed and food stuffs. Bait stations may be used. Always record the number and location of bait stations. Regularly inspect bait stations and replace bait as needed. This product is best used as a supplemental residual treatment preceded by approved spray and good sanitation practices. STORAGE AND DISPOSAL Do not contaminate water, food or feed by storage or disposal. Pesticide Storage: Store in a dry place. Do not store where children or animals may gain access. Pesticide Disposal: Wastes resulting from the use of this product may be disposed of on site or at an approved waste disposal facility. Container Disposal: Non-refillable container; do not reuse or refill this container. Completely empty container then offer for recycling, if available; otherwise dispose of empty container in a sanitary landfill or by incineration. WARRANTY DISCLAIMER To the extent not prohibited by applicable law, Manufacturer warrants that this product conforms to the chemical description on the label and is reasonably fit for the purposes stated on the label when used in strict accordance with the directions, subject to the inherent risks set forth below. To the extent not prohibited by applicable law, MANUFACTURER MAKES NO OTHER EXPRESS OR IMPLIED WARRANTY OF MERCHANT- ABILITY, FITNESS FOR A PARTICULAR PURPOSE OR ANY OTHER EXPRESS OR IMPLIED WARRANTY. Inherent Risks of Use The directions for use are believed to be adequate and must be carefully followed. It is impossible to eliminate all risks associated with use of this product. Lack of performance or other unintended consequences may result because of such factors as use of the product contrary to label instructions, abnormal conditions, the presence of other materials, climatic conditions or the manner of application, all of which are beyond the control of the Manufacturer. To the extent not prohibited by applicable law, the buyer/user assumes all such risks. Limitation of Remedies To the extent not prohibited by applicable law the exclusive remedy for losses or damages resulting from this product (including claims based on contract, negligence, strict liability or other legal theories) shall be limited to, at Manufacturer s election, one of the following: 1. Refund of purchase price paid by buyer or user for product bought, or 2. Replacement of amount of product used. To the extent not prohibited by applicable law: a) Manufacturer shall not be liable for losses or damages resulting from handling or use of this product unless Manufacturer is promptly notified of such loss or damage in writing; and b) TO THE EXTENT NOT PROHIBITED BY APPLICABLE LAW, IN NO CASE SHALL MANUFAC- TURER BE LIABLE FOR CONSEQUENTIAL OR INCI- DENTAL DAMAGES OR LOSSES, INCLUDING WITHOUT LIMIT, HEALTH RELATED DAMAGES OR INJURIES. The terms of this Warranty Disclaimer and Limitation of Remedies cannot be varied by any written or verbal statements or agreements. No employee or sales agent of Manufacturer or the seller is authorized to vary or exceed the terms of this Warranty Disclaimer or Limitation of Remedies in any manner. It is not intended that this product be used to practice any applicable patent, whether mentioned or not, without procurement of a license, if necessary, from the owner, following investigation by the user. 100 Nisus Drive Rockford, TN (800) Niban-FG and Nisus Corporation are trademarks or registered trademarks of Nisus Corporation Nisus Corporation #NFG- SL-0315a-SAL020515

166 SAFETY DATA SHEET Health Emergencies: INFOTRAC (800) PRODUCT AND COMPANY INFORMATION Product Identity: Niban-FG Fine Granular Bait Recommended use of the chemical and restrictions on use: A weather/moisture resistant bait to kill and control ants (except fire ants), carpenter ants, cockroaches, crickets, mole crickets, earwigs, silverfish, snails, and slugs. Read and understand the entire label before using. Use only according to label directions. It is a violation of Federal law to use this product in a manner inconsistent to label directions. Manufacturer: Nisus Corporation 100 Nisus Drive Rockford, TN Telephone: Phone: (800) Fax: (865) Emergency Phone: (INFOTRAC) SDS Date of Preparation: 01/12/16 2. HAZARDS IDENTIFICATION GHS Classification: Physical Health Environment Not Hazardous Acute Toxicity Oral Category 4 Specific Target Organ Toxicity Repeat Exposure Category 2 Aquatic Acute Toxicity Category 3 GHS Label Elements: None Required Statements of Hazard Precautionary Statements None Required None Required 3. COMPOSITION/INFORMATION ON INGREDIENTS Component CAS No. Amount Boric Acid % Non-Hazardous Ingredient Proprietary 95% The exact formulation is being withheld as a trade secret. 4. FIRST AID MEASURES Eye: Flush victim's eyes with large quantities of water, while holding the eyelids apart. Get medical attention if irritation develops or persists. Skin: Wash skin thoroughly with soap and water. Get medical attention if irritation develops. Remove and launder clothing before re-use. Ingestion: Do not induce vomiting unless directed to do so by a medical professional. Get medical attention for large ingestions or if symptoms develop or if you feel unwell. Inhalation: Remove victim to fresh air. If breathing is difficult or irritation persists, get medical attention. Most important Symptoms: May cause eye and skin irritation. Inhalation of dust may cause mild mucous membrane and respiratory irritation. Harmful if swallowed. Repeated ingestion may cause kidney damage. Indication of immediate medical attention/special treatment: Immediate medical attention is required for large ingestions. 5. FIRE FIGHTING MEASURES Suitable (and Unsuitable) Extinguishing Media: Use media appropriate for surrounding fire. Specific hazards arising from the chemical: Fine particles may present an explosion hazard if suspended in air. Burning may produce carbon monoxide and carbon dioxide. Special Protective Equipment and Precautions for Fire-Fighting Instructions: Firefighters should wear positive pressure self-contained breathing apparatus and full protective clothing. Contain runoff. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions, Protective Equipment, and Emergency Procedures: Wear appropriate protective clothing as described in Section 8. Do not apply directly to water or contaminate water. Methods and Materials for Containment and Cleaning Up: Collect and place in appropriate containers for disposal. Avoid generating dust. Clean spill area thoroughly. Prevent spill from entering sewers and watercourses. Report releases as required by local, state and federal authorities. 7. HANDLING AND STORAGE Precautions for Safe Handling: Avoid contact with the eyes, skin and clothing. Avoid breathing dusts. Wear protective clothing and equipment as described in Section 8. Wash thoroughly with soap and water after handling. Remove contaminated clothing immediately and wash before reuse. Remove PPE immediately after handling. Wash thoroughly after using and change into clean clothing. Do not apply this product in a way that will contact workers or other persons, either directly or through drift. Only protected handlers may be in the area during application. Keep containers closed when not in use. Refer product label for additional information on use and handling. Nonrefillable container. Do not reuse containers. Product residues in empty containers can be hazardous. Follow all SDS precautions when handling empty containers. Conditions for Safe Storage, Including Any Incompatibilities: Store in a dry area away from incompatible materials. Do not store where children or animals may gain access. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines: 2 mg/m 3 TWA ACGIH TLV (inhalable) Boric Acid 6 mg/m 3 STEL ACGIH TLV (inhalable) Engineering Controls: Use with adequate ventilation to maintain exposure levels below the occupational exposure limits. Refer product label for additional information. Respiratory Protection: In operations where exposure levels are exceeded, a NIOSH approved respirator with dust/mist cartridges appropriate for the form and concentration of the contaminants should be used. Selection and use of respiratory equipment must be in accordance with OSHA and good industrial hygiene practice. Refer to the product label for additional information. Skin Protection: Use gloves for normal application of this product. Eye Protection: Wear safety glasses to prevent eye contact. Other: Wear long-sleeve shirts, long pants, socks and shoes when using this product. Suitable washing facilities should be available in the work area. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance And Odor: Brown, granular particles with no odor. Physical State: Granular particles Odor Threshold: Not established Vapor Density: Not determined Initial Boiling Point/Range: Not determined Solubility In Water: Not soluble Vapor Pressure: Negligible Relative Density: 0.62 of water Evaporation Rate: N/A Melting/Freezing Point: N/A ph: N/A Percent Volatile: Minimal Octanol/Water Coefficient: N/A Solubility: Not soluble Decomposition Temperature: N/A Viscosity: N/A Flammability (solid, gas): Fine dust may form explosive mixtures in air Flashpoint: >451 F (233 C) TOC Autoignition Temperature: None Flammable Limits: LEL: Not determined UEL: N/A

167 10. STABILITY AND REACTIVITY Reactivity: Not normally reactive Chemical Stability: Stable under normal storage and handling conditions. Possibility of Hazardous Reactions: None known. Conditions to Avoid: Avoid generating fine dust. Incompatible Materials: None known Hazardous Decomposition Products: When heated to decomposition emits carbon monoxide and carbon dioxide. 11. TOXICOLOGICAL INFORMATION HEALTH HAZARDS: Ingestion: May be harmful if large quantities are ingested. Inhalation: Inhalation of dust may cause irritation of the nose, throat and upper respiratory tract. Eye: May cause slight irritation. Skin: Not expected to cause irritation. Chronic: Borates have been shown to have some chronic toxicity in animals fed high doses, but this has not been found in humans. Sensitization: This material is not expected to cause sensitization. Carcinogenicity: None of the components is listed as a carcinogen or suspected carcinogen by IARC, NTP or OSHA. Germ Cell Mutagenicity: No data available Reproductive Toxicity: Borates have been found to have some reproductive toxicity in animals, but this has not been found in humans. Numerical Measures of Toxicity: Product Toxicity Data: Oral rat LD 50: >5000 mg/kg; Dermal rabbit LC 50: >5050 mg/kg 12. ECOLOGICAL INFORMATION This product breaks down naturally in the environment to provide organic matter and boron micro nutrients. Boron occurs naturally in sea water at an average concentration of 5 mg B/l and fresh water at 1 mg B/l or less. In dilute aqueous solutions the predominant boron species present is undissociated boric acid. Ecotoxicity: EC 10 Green Algae: 24 mg B/l; LC 50 Daphnia magna: 530 mg B/l/96 hr; LC 50 Dab: 74 mg B/l/48hr; LC 50 Rainbow Trout: 88 mg B/l/24hr; LC 50 Goldfish: 71 mg B/l/72hr Persistence and Degradability: Boron is naturally occurring and ubiquitous in the environment. Niban-FG decomposes in the environment to natural borate. Bioaccumulative Potential: Not determined. Mobility in Soil: Boric acid is soluble in water and is leachable through normal soil. Other Adverse Effects: Some plants are sensitive to boron. This product is designed to be used for certain types of insects. Use product only as directed on the label. See product label for full instructions and restrictions on use. 13. DISPOSAL CONSIDERATION Dispose in accordance with local, state and federal environmental regulations. Do not apply directly to water, to areas where surface water is present or to intertidal areas below the mean high-water mark. Do not contaminate water when disposing of equipment washwaters or rinsate. Wastes resulting from the use of this product may be disposed of on site or at an approved waste disposal facility. Non-refillable container: do not reuse or refill this container. Completely empty container into application equipment, then offer for recycling, if available; otherwise dispose of empty container in a sanitary landfill or by incineration. For guidance contact your state water board or regional office of the EPA. 14. TRANSPORTATION INFORMATION DOT Hazardous Materials Description: Not Regulated Sea Transport IMDG, not classified as dangerous Air Trasnport IATA/ICAO, not classified as dangerous 15. REGULATORY INFORMATION This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non-pesticide chemicals. The hazard information required on the pesticide label is reproduced below. The pesticide label also includes other important information, including directions for use. FIFRA Labeling: Niban-FG Fine Granular Bait EPA Reg. No Keep Out of Reach of Children CAUTION PRECAUTIONARY STATEMENTS Hazards to Humans & Domestic Animals Caution: Harmful if absorbed through skin. Causes moderate eye irritation. Avoid contact with skin, eyes or clothing. CERCLA: This product is not subject to reporting under CERCLA. Some states have more stringent reporting requirements. Report all spills in accordance with local, state, and federal regulations. SARA Hazard Category (311/312): Not hazardous SARA 313: This product contains the following chemicals subject to Annual Release Reporting Requirements Under SARA Title III, Section 313 (40 CFR 372): None EPA TSCA Inventory: This product is regulated under FIFRA, thus exempt. 16. OTHER INFORMATION NFPA Rating: Health = 0 Flammability = 0 Instability = 0 HMIS Rating: Health = 1 Flammability = 0 Physical Hazard = 0 SDS Revision History: 01/07/14: New SDS 01/12/16: Revised WARRANTY DISCLAIMER The information, data and recommendations contained herein are believed to be accurate but may not be all inclusive and should only be used as a guide. The information is furnished upon the condition that the person receiving it shall make his own determination of the suitability of the product for his particular use and on condition that they assume the risk of the use thereof. With respect to this publication and the product related thereto, unless otherwise expressly provided by Manufacturer in writing, MANUFACTURER MAKES NO EXPRESS OR IMPLIED WARRANTY OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR ANY OTHER EXPRESS OR IMPLIED WARRANTY. Remedy/Liability Limits The exclusive remedy for losses or damages resulting from this publication or the related product (including claims based on contract, negligence, strict liability or other legal theories) shall be limited to, at Manufacturer s sole election, one of the following: 1. Refund of purchase price paid by buyer or user for product bought, or 2. Replacement of amount of product used. Manufacturer shall not be liable for losses or damages resulting from use of this publication or handling or use of this product, IN NO CASE SHALL MANUFACTURER BE LIABLE FOR CONSEQUENTIAL OR INCIDENTAL DAMAGES OR LOSSES, INCLUDING WITHOUT LIMIT, HEALTH RELATED DAMAGES OR INJURIES. The terms of this Warranty Disclaimer and Remedy/Liability Limits cannot be varied by any written or verbal statements or agreements. No employee or sales agent of Manufacturer or the seller is authorized to vary or exceed the terms of this Warranty Disclaimer or Limitation of Remedies in any manner. 100 Nisus Drive Rockford, TN USA (800) Niban-FG and Nisus Corporation are registered trademarks of Nisus Corporation Nisus Corporation #NB-SDS a

168 Return to Index... SAFETY DATA SHEET Issue Date: 22-Sep-2015 Revision Date: 22-Sep-2015 Version: 1 1. PRODUCT AND COMPANY IDENTIFICATION Product identifier Product Name: Onslaught FastCap Spider & Scorpion Insecticide EPA Registration Number: Other means of identification Part Code: 2964 Recommended use of the chemical and restrictions on use: Recommended Use: Insecticide. Details of the supplier of the safety data sheet Manufacturer Address: McLaughlin Gormley King Company th Avenue North FAX #: (763) Minneapolis, MN Telephone Number: (800) , or (763) Address: mgk-sds@mgk.com Emergency telephone numbers: 24 Hour TRANSPORTATION Emergency: CHEMTREC : (800) International: (703) Hour MEDICAL Emergency: SafetyCall : (888) , or (952) Comments: MGK Hours of operation are 8:00 am to 4:30 pm CST, 14:00 to 22:30 GMT. For MEDICAL EMERGENCIES or PESTICIDE INCIDENTS, call 24 hours a day to (888) , or (952) HAZARDS IDENTIFICATION Classification OSHA Regulatory Status: This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR ). Acute toxicity - Oral Category 4 Acute toxicity - Inhalation (Dusts/Mists) Category 4 Skin corrosion/irritation Category 2 Label elements WARNING Emergency Overview Hazard statements Page 1 / 9

169 Onslaught FastCap Spider & Scorpion Insecticide Revision Date: 22-Sep-2015 Appearance: cream, light yellow / brown Physical state: Liquid Odor Slight - Sweet Precautionary Statements - Prevention: P261 - Avoid breathing dust/fume/gas/mist/vapors/spray P270 - Do not eat, drink or smoke when using this product P271 - Use only outdoors or in a well-ventilated area P264 - Wash hands thoroughly after handling P280 - Wear protective gloves Precautionary Statements - Response: P321 - Specific treatment (see Section 4/ First Aid). P302 + P352 - IF ON SKIN: Wash with plenty of soap and water P333 + P313 - If skin irritation or rash occurs: Get medical advice/attention P362 - Take off contaminated clothing and wash before reuse P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing P312 - Call a POISON CENTER or doctor/physician if you feel unwell P301 + P312 - IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell Precautionary Statements - Storage: P405 - Store locked up P403 + P233 - Store in a well-ventilated place. Keep container tightly closed Precautionary Statements - Disposal: P501 - Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC): Do not use this product in or on electrical equipment due to the possibility of shock hazard. 3. COMPOSITION/ INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% Esfenvalerate Prallethrin (ETOC ) Piperonyl Butoxide (PBO) Petroleum distillates, hydrotreated light < 10 * *The exact percentage (concentration) of composition has been withheld as a trade secret. Comments: Ingredients not identified are proprietary or non-hazardous. Values are not product specifications. 4. FIRST AID MEASURES Page 2 / 9

170 Onslaught FastCap Spider & Scorpion Insecticide Revision Date: 22-Sep-2015 Aspiration pneumonia hazard: Description of first aid measures: Eye contact: Skin Contact: Ingestion: Inhalation: Self-protection of the First Responder: Note to physicians: Hold eye open and rinse slowly and gently with water for minutes. Remove contact lenses, if present, after the first 5minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. Take off contaminated clothing. Rinse skin immediately with plenty of water for minutes. Call a poison control centeror doctor for treatment advice. If swallowed, IMMEDIATELY call a poison control center or doctor for treatment advice. DO NOT give any liquid to the person. Do not induce vomiting unless told to do so by a poison contol center or a doctor. Never give anything by mouth to an unconscious person. Remove affected person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificialrespiration, preferably mouth-to-mouth if possible. Call a poison control center or doctor for further treatment advice. Use personal protective equipment as required. For skin effects, a highly efficient therapeutic agent for Pyrethrin/ Pyrethroid exposure is topical application of tocopherol acetate (Vitamin E). 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media: Caution: Use of water spray when fighting fire may be inefficient. Hazardous combustion products: Carbon monoxide, Carbon dioxide (CO2), Hydrogen cyanide. Specific hazards arising from the chemical In the event of fire and/or explosion do not breathe fumes. May cause sensitization by inhalation and skin contact. Thermal decomposition can lead to release of irritating and toxic gases and vapors. Explosion data Sensitivity to Mechanical Impact: None. Sensitivity to Static Discharge: None. Protective equipment and precautions for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. NFPA Health hazards 1 Flammability 1 Instability 0 HMIS Health hazards 1 Flammability 1 Physical hazards 0 Chronic Hazard Star Legend * = Chronic Health Hazard Physical and Chemical Properties - Personal protection X 6. ACCIDENTAL RELEASE MEASURES Page 3 / 9

171 Onslaught FastCap Spider & Scorpion Insecticide Revision Date: 22-Sep-2015 Personal precautions, protective equipment and emergency procedures Personal precautions: Environmental precautions: Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Prevent entry into waterways, sewers, basements or confined areas. Do not flush into surface water or sanitary sewer system. Prevent further leakage or spillage if safe to do so. Prevent product from entering drains. See Section 12 for additional ecological information. Methods and material for containment and cleaning up Methods for containment: Methods for cleaning up: Prevent further leakage or spillage if safe to do so. Cover liquid spill with sand, earth or other non-combustible absorbent material. Cover powder spill with plastic sheet or tarp to minimize spreading. Pick up and transfer to properly labeled containers. Soak up with inert absorbent material. Dam up. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling: Avoid contact with skin, eyes or clothing. Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Use personal protective equipment as required. Do not breathe dust/fume/gas/mist/vapors/spray. Use with local exhaust ventilation. For more information, see product label. Conditions for safe storage, including any incompatibilities Storage Conditions: Keep container tightly closed in a dry and well-ventilated place. Keep out of the reach of children. Keep containers tightly closed in a cool, well-ventilated place. Keep in properly labeled containers. For more information, see product label. 8. EXPOSURE CONTROLS/ PERSONAL PROTECTION Control parameters Exposure Guidelines: This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies. Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Supplier OEL Petroleum distillates, hydrotreated light TWA: 100 ppm TWA: 525 mg/m 3 Appropriate engineering controls Engineering Controls: Safety showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection: Tight sealing safety goggles. Face protection shield. Page 4 / 9

172 Onslaught FastCap Spider & Scorpion Insecticide Revision Date: 22-Sep-2015 Skin and body protection: Respiratory protection: General Hygiene Considerations: Wear protective gloves and protective clothing. If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. When using do not eat, drink or smoke. Wash contaminated clothing before reuse. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties: Physical state: Appearance: Odor Odor threshold: Color (Gardner Scale): Liquid cream, light yellow / brown Slight - Sweet No information available No information available Property: Values: ph: 5% in H2O.. Melting point / freezing point: No information available Boiling point / boiling range: No information available Flash point: > 93.3 C / > F Tag Closed Cup; Evaporation rate: No information available Flammability (solid, gas): No information available Upper flammability limit (UEL): No information available Lower flammability limit (LEL): No information available Vapor pressure: No information available Vapor density: No information available Specific Gravity: No information available Water solubility: No information available Partition coefficient; n-octanol/ No information available Water: Autoignition temperature: No information available Decomposition temperature: No information available Kinematic viscosity: No information available Dynamic viscosity: 1, C.. Refractive Index: No information available Other Information: Density: g/cm C VOC Content (%): 2.5 Miscibility/ Solubility: Water: Alcohol Aromatic solvents: Petroleum distillates: Immiscible Immiscible Immiscible Immiscible 10. STABILITY AND REACTIVITY Page 5 / 9

173 Onslaught FastCap Spider & Scorpion Insecticide Revision Date: 22-Sep-2015 Reactivity No data available Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous polymerization: Hazardous polymerization does not occur. Conditions to avoid Extremes of temperature and direct sunlight. Incompatible materials: Incompatible with strong acids and bases. Incompatible with oxidizing agents. Hazardous Decomposition Products Carbon monoxide, Carbon dioxide (CO2), Hydrogen cyanide. Numerical measures of toxicity - Product Information 11. TOXICOLOGICAL INFORMATION Oral LD50 1,750 mg/kg (rat) Dermal LD50 >5,000 mg/kg (rabbit) Inhalation LC50 >2.04 mg/l (rat; 4 hours) Eye contact: Slightly irritating. Irritation clearing in 72 hours. (rabbit). Skin Contact: Moderate irritation at 72 hours. (rabbit). Skin Irritation Index: 2.4 Sensitization: Piperonyl Butoxide: Carcinogenicity/ Oncogenicity: Carcinogenicity Reproductive toxicity: Developmental Toxicity Teratogenicity: STOT - single exposure: STOT - repeated exposure: Chronic toxicity: Negative. (guinea pig). Marginally higher incidences of benign liver tumors in mice were observed following lifetime high dose exposures to PBO. The significance of these observations is questionable and under review. The doses at which tumors were observed for PBO greatly exceeded potential human exposure from labeled uses. Doses at which these effects were observed greatly exceeded anticipated human dietary intake. At anticipated dietary exposure levels, it is highly unlikely that this product will result in carcinogenic effects. This product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARC or NTP. No information available. No information available. No information available. No information available. No information available. Repeated contact may cause allergic reactions in very susceptible persons. Avoid repeated exposure. 12. ECOLOGICAL INFORMATION Ecotoxicity: Page 6 / 9

174 Onslaught FastCap Spider & Scorpion Insecticide Revision Date: 22-Sep-2015 Persistence and degradability No information available. Bioaccumulation No information available. Chemical Name Prallethrin (ETOC ) Partition coefficient; n-octanol/ Water: 4.49 Other adverse effects: No information available Environmental hazards (EPA): Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance contact your State Water Board or Regional Office of the EPA. Waste treatment methods 13. DISPOSAL CONSIDERATIONS Disposal of wastes: Contaminated packaging: Disposal should be in accordance with applicable regional, national and local laws and regulations. For more information, see product label. For more information, see product label. DOT (Department of Transportation) 14. TRANSPORT INFORMATION Proper Shipping Name: Hazard Class: Air (IATA/ ICAO) Proper Shipping Name: Hazard Class: Insecticides, Insect or Animal Repellent, Liquid Non-Hazardous Insecticides, Insect or Animal Repellent, Liquid Non-Hazardous Vessel (IMO/ IMDG) Not available 15. REGULATORY INFORMATION US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name SARA Threshold Values % Piperonyl Butoxide (PBO) Page 7 / 9

175 Onslaught FastCap Spider & Scorpion Insecticide Revision Date: 22-Sep-2015 SARA 311/312 Hazard Categories Acute health hazard Chronic Health Hazard Fire hazard Sudden release of pressure hazard Reactive Hazard Yes No No No No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR and 40 CFR ) CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material US State Regulations: California Proposition 65: This product does not contain any Proposition 65 chemicals U.S. EPA Label Information: EPA Registration Number: Difference between SDS and EPA (FIFRA) Pesticide label: This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for Safety Data Sheets (SDS), and for workplace labels of non-pesticide chemicals. The pesticide label also includes other important information, including directions for use. The hazard information required on the pesticide label is reproduced below: Signal word: CAUTION Precautionary Statements: International: TSCA DSL/NDSL EINECS/ELINCS ENCS IECSC KECL PICCS AICS Does not comply Does not comply Does not comply Does not comply Does not comply Does not comply Does not comply Does not comply Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List Page 8 / 9

176 Onslaught FastCap Spider & Scorpion Insecticide Revision Date: 22-Sep-2015 EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION. Issue Date: 22-Sep-2015 Revision Date: 22-Sep-2015 Revision Note: - New SDS. - GHS - Classification. SDS Prepared By: Address: Disclaimer: Troy Azzivitto, MGK Chemistry Department. mgk-sds@mgk.com The data contained herein are based on information currently available to McLaughlin Gormley King Company and,to the best of our knowledge, are accurate and based on sound expert opinion. Our statements herein, however, are not to betaken as a warranty or representation for which McLaughlin Gormley King Company assumes legal responsibility. End of Safety Data Sheet. Page 9 / 9

177 Return to Index... Safety Data Sheet PHANTOM TERMITICIDE/INSECTICIDE Revision date : 2014/09/29 Page: 1/11 Version: 7.0 ( /SDS_CPA_US/EN) 1. Identification Product identifier used on the label PHANTOM TERMITICIDE/INSECTICIDE Recommended use of the chemical and restriction on use Recommended use*: insecticide * The Recommended use identified for this product is provided solely to comply with a US Federal requirement and is not part of the seller's published specification. The terms of this Safety Data Sheet (SDS) do not create or infer any warranty, express or implied, including by incorporation into or reference in the seller's sales agreement. Details of the supplier of the safety data sheet Company: BASF CORPORATION 100 Park Avenue Florham Park, NJ 07932, USA Telephone: Emergency telephone number CHEMTREC: BASF HOTLINE: HELP (4357) Other means of identification Substance number: EPA Register number: Molecular formula: C(15) H(11 ) Br Cl F(3) N(2) O Chemical family: pyrrole derivative Synonyms: chlorfenapyr 2. Hazards Identification According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part Classification of the product Acute Tox. 3 (Inhalation - vapour) Acute toxicity Acute Tox. 4 (oral) Acute toxicity Label elements

178 Safety Data Sheet PHANTOM TERMITICIDE/INSECTICIDE Revision date : 2014/09/29 Page: 2/11 Version: 7.0 ( /SDS_CPA_US/EN) Pictogram: Signal Word: Danger Hazard Statement: H331 H302 Toxic if inhaled. Harmful if swallowed. Precautionary Statements (Prevention): P271 Use only outdoors or in a well-ventilated area. P260 Do not breathe mist or vapour. P270 Do not eat, drink or smoke when using this product. P264 Wash with plenty of water and soap thoroughly after handling. Precautionary Statements (Response): P311 Call a POISON CENTER or doctor/physician. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P301 + P330 IF SWALLOWED: rinse mouth. Precautionary Statements (Storage): P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. Precautionary Statements (Disposal): P501 Dispose of contents/container to hazardous or special waste collection point. Hazards not otherwise classified Labeling of special preparations (GHS): The following percentage of the mixture consists of components(s) with unknown hazards regarding the acute toxicity: 1-3 % dermal The following percentage of the mixture consists of components(s) with unknown hazards regarding the acute toxicity: 0-2 % oral The following percentage of the mixture consists of components(s) with unknown hazards regarding the acute toxicity: % Inhalation - vapour The following percentage of the mixture consists of components(s) with unknown hazards regarding the acute toxicity: % Inhalation - mist According to Regulation 1994 OSHA Hazard Communication Standard; 29 CFR Part Emergency overview CAUTION: HARMFUL IF SWALLOWED. HARMFUL IF INHALED. HARMFUL IF ABSORBED THROUGH SKIN. MAY CAUSE EYE IRRITATION. KEEP OUT OF REACH OF CHILDREN. KEEP OUT OF REACH OF DOMESTIC ANIMALS. Do not get in eyes, on skin, or on clothing. Avoid inhalation of mists/vapours.

179 Safety Data Sheet PHANTOM TERMITICIDE/INSECTICIDE Revision date : 2014/09/29 Page: 3/11 Version: 7.0 ( /SDS_CPA_US/EN) 3. Composition / Information on Ingredients According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part CAS Number Content (W/W) Chemical name % Chlorfenapyr According to Regulation 1994 OSHA Hazard Communication Standard; 29 CFR Part CAS Number Content (W/W) Chemical name % Chlorfenapyr % Propylene glycol % Proprietary ingredients 4. First-Aid Measures Description of first aid measures General advice: First aid providers should wear personal protective equipment to prevent exposure. Remove contaminated clothing. Move person to fresh air. If person is not breathing, call 911 or ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or physician for treatment advice. Have the product container or label with you when calling a poison control center or doctor or going for treatment. If inhaled: Remove the affected individual into fresh air and keep the person calm. Assist in breathing if necessary. If on skin: Rinse skin immediately with plenty of water for minutes. If in eyes: Hold eyes open and rinse slowly and gently with water for 15 to 20 minutes. Remove contact lenses, if present, after first 5 minutes, then continue rinsing. If swallowed: Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to by a poison control center or doctor. Never induce vomiting or give anything by mouth if the victim is unconscious or having convulsions. Most important symptoms and effects, both acute and delayed Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further important symptoms and effects are so far not known. Indication of any immediate medical attention and special treatment needed Note to physician Antidote: Treatment: No known specific antidote. Treat symptomatically.

180 Safety Data Sheet PHANTOM TERMITICIDE/INSECTICIDE Revision date : 2014/09/29 Page: 4/11 Version: 7.0 ( /SDS_CPA_US/EN) 5. Fire-Fighting Measures Extinguishing media Suitable extinguishing media: foam, dry powder, carbon dioxide, water spray Special hazards arising from the substance or mixture Hazards during fire-fighting: carbon monoxide, carbon dioxide, hydrogen bromide, hydrochloric acid, Hydrofluoric acid, hydrogen fluoride, halogenated hydrocarbons, nitrogen dioxide, Hydrocarbons, If product is heated above decomposition temperature, toxic vapours will be released. The substances/groups of substances mentioned can be released if the product is involved in a fire. Advice for fire-fighters Protective equipment for fire-fighting: Firefighters should be equipped with self-contained breathing apparatus and turn-out gear. Further information: Evacuate area of all unnecessary personnel. Contain contaminated water/firefighting water. Do not allow to enter drains or waterways. Do not decontaminate personnel or equipment, or handle broken packages or containers without appropriate personal protective equipment. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Take appropriate protective measures. Clear area. Shut off source of leak only under safe conditions. Extinguish sources of ignition nearby and downwind. Ensure adequate ventilation. Wear suitable personal protective clothing and equipment. Environmental precautions Do not discharge into the subsoil/soil. Do not discharge into drains/surface waters/groundwater. Contain contaminated water/firefighting water. Methods and material for containment and cleaning up Dike spillage. Pick up with suitable absorbent material. Place into suitable containers for reuse or disposal in a licensed facility. Spilled substance/product should be recovered and applied according to label rates whenever possible. If application of spilled substance/product is not possible, then spills should be contained, solidified, and placed in suitable containers for disposal. After decontamination, spill area can be washed with water. Collect wash water for approved disposal. 7. Handling and Storage Precautions for safe handling RECOMMENDATIONS ARE FOR MANUFACTURING, COMMERCIAL BLENDING, AND PACKAGING WORKERS. PESTICIDE APPLICATORS & WORKERS must refer to the Product Label and Directions for Use attached to the product for Agricultural Use Requirements in accordance with the EPA Worker Protection Standard 40 CFR part 170. Ensure adequate ventilation. Provide good ventilation of working area (local exhaust ventilation if necessary). Keep away from sources of ignition - No smoking. Keep container tightly sealed. Protect contents from the effects of light. Protect against heat. Protect from air. Handle and open container with care. Do not open until ready to use. Once container is opened, content should be used as soon as possible. Avoid aerosol formation. Avoid dust formation. Provide means for controlling leaks and spills. Do not return residues to the storage containers. Follow label warnings even after container is emptied. The

181 Safety Data Sheet PHANTOM TERMITICIDE/INSECTICIDE Revision date : 2014/09/29 Page: 5/11 Version: 7.0 ( /SDS_CPA_US/EN) substance/ product may be handled only by appropriately trained personnel. Avoid all direct contact with the substance/product. Avoid contact with the skin, eyes and clothing. Avoid inhalation of dusts/mists/vapours. Wear suitable personal protective clothing and equipment. Protection against fire and explosion: The relevant fire protection measures should be noted. Fire extinguishers should be kept handy. Avoid all sources of ignition: heat, sparks, open flame. Sources of ignition should be kept well clear. Avoid extreme heat. Keep away from oxidizable substances. Electrical equipment should conform to national electric code. Ground all transfer equipment properly to prevent electrostatic discharge. Electrostatic discharge may cause ignition. Conditions for safe storage, including any incompatibilities Segregate from incompatible substances. Segregate from foods and animal feeds. Segregate from textiles and similar materials. Further information on storage conditions: Keep only in the original container in a cool, dry, wellventilated place away from ignition sources, heat or flame. Protect containers from physical damage. Protect against contamination. The authority permits and storage regulations must be observed. Protect from temperatures below: 0 C The product can crystallize below the limit temperature. Protect from temperatures above: 40 C Changes in the properties of the product may occur if substance/product is stored above indicated temperature for extended periods of time. 8. Exposure Controls/Personal Protection Users of a pesticidal product should refer to the product label for personal protective equipment requirements. Advice on system design: Whenever possible, engineering controls should be used to minimize the need for personal protective equipment. Personal protective equipment RECOMMENDATIONS FOR MANUFACTURING, COMMERCIAL BLENDING, AND PACKAGING WORKERS: Respiratory protection: Wear respiratory protection if ventilation is inadequate. Wear a NIOSH-certified (or equivalent) TC23C Chemical/Mechanical type filter system to remove a combination of particles, gas and vapours. For situations where the airborne concentrations may exceed the level for which an air purifying respirator is effective, or where the levels are unknown or Immediately Dangerous to Life or Health (IDLH), use NIOSH-certified full facepiece pressure demand self-contained breathing apparatus (SCBA) or a full facepiece pressure demand supplied-air respirator (SAR) with escape provisions. Hand protection: Chemical resistant protective gloves, Protective glove selection must be based on the user's assessment of the workplace hazards. Eye protection: Safety glasses with side-shields. Tightly fitting safety goggles (chemical goggles). Wear face shield if splashing hazard exists.

182 Safety Data Sheet PHANTOM TERMITICIDE/INSECTICIDE Revision date : 2014/09/29 Page: 6/11 Version: 7.0 ( /SDS_CPA_US/EN) Body protection: Body protection must be chosen depending on activity and possible exposure, e.g. head protection, apron, protective boots, chemical-protection suit. General safety and hygiene measures: Wear long sleeved work shirt and long work pants in addition to other stated personal protective equipment. Work place should be equipped with a shower and an eye wash. Handle in accordance with good industrial hygiene and safety practice. Personal protective equipment should be decontaminated prior to reuse. Gloves must be inspected regularly and prior to each use. Replace if necessary (e.g. pinhole leaks). Take off immediately all contaminated clothing. Store work clothing separately. Hands and/or face should be washed before breaks and at the end of the shift. No eating, drinking, smoking or tobacco use at the place of work. Keep away from food, drink and animal feeding stuffs. 9. Physical and Chemical Properties Form: suspension Odour: sweetish Odour threshold: Not determined since toxic by inhalation. Colour: white to light brown ph value: approx. 6.9 ( 2 %(m), 20 C) Freezing point: approx. 0 C ( 1,013.3 hpa) Information applies to the solvent. Boiling point: approx. 100 C ( 1,013 mbar) Information applies to the solvent. Flash point: (ASTM D93) No flash point - Measurement made up to the boiling point. Flammability: not flammable Autoignition: not applicable Vapour pressure: approx hpa ( 20 C) Information applies to the solvent. Density: approx g/cm3 ( 20 C) Vapour density: not applicable Partitioning coefficient n- not applicable octanol/water (log Pow): Thermal decomposition: carbon monoxide, carbon dioxide, hydrogen bromide, hydrochloric acid, Hydrofluoric acid, hydrogen fluoride, halogenated hydrocarbons, nitrogen dioxide, Hydrocarbons Stable at ambient temperature. If product is heated above decomposition temperature toxic vapours may be released. Viscosity, dynamic: approx. > 1 ( 20 C) mpa.s Solubility in water: dispersible Molar mass: g/mol Evaporation rate: not determined Other Information: If necessary, information on other physical and chemical parameters is indicated in this section. 10. Stability and Reactivity Reactivity No hazardous reactions if stored and handled as prescribed/indicated. Corrosion to metals:

183 Safety Data Sheet PHANTOM TERMITICIDE/INSECTICIDE Revision date : 2014/09/29 Page: 7/11 Version: 7.0 ( /SDS_CPA_US/EN) Corrosive effects to metal are not anticipated. Oxidizing properties: not fire-propagating Not an oxidizer. Chemical stability The product is stable if stored and handled as prescribed/indicated. Possibility of hazardous reactions The product is chemically stable. No hazardous reactions if stored and handled as prescribed/indicated. Conditions to avoid 183 degrees Celsius Disregard of the conditions mentioned may result in undesirable decomposition reactions. Incompatible materials strong oxidizing agents Hazardous decomposition products Decomposition products: Hazardous decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated., Prolonged thermal loading can result in products of degradation being given off. Thermal decomposition: Possible thermal decomposition products: carbon monoxide, carbon dioxide, hydrogen bromide, hydrochloric acid, Hydrofluoric acid, hydrogen fluoride, halogenated hydrocarbons, nitrogen dioxide, Hydrocarbons Stable at ambient temperature. If product is heated above decomposition temperature toxic vapours may be released. 11. Toxicological information Primary routes of exposure Routes of entry for solids and liquids are ingestion and inhalation, but may include eye or skin contact. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route of entry for liquefied gases. Acute Toxicity/Effects Acute toxicity Assessment of acute toxicity: Slightly toxic after single ingestion. Slightly toxic after short-term inhalation. Slightly toxic after short-term skin contact. Oral Type of value: LD50 Species: rat (male/female) Value: mg/kg Inhalation Type of value: LC50 Species: rat (male) Value: mg/l (calculated)

184 Safety Data Sheet PHANTOM TERMITICIDE/INSECTICIDE Revision date : 2014/09/29 Page: 8/11 Version: 7.0 ( /SDS_CPA_US/EN) Exposure time: 1 h Type of value: LC50 Species: rat (female) Value: > 6.4 mg/l (calculated) Exposure time: 1 h Dermal Type of value: LD50 Species: rabbit Value: > 2,000 mg/kg Irritation / corrosion Assessment of irritating effects: May cause slight irritation to the skin. May cause slight but temporary irritation to the eyes. Skin Species: rabbit Result: non-irritant Eye Species: rabbit Result: non-irritant Sensitization Assessment of sensitization: Skin sensitizing effects were not observed in animal studies. modified Buehler test Species: guinea pig Result: Skin sensitizing effects were not observed in animal studies. Method: OECD Guideline 406 Chronic Toxicity/Effects Repeated dose toxicity Assessment of repeated dose toxicity: The product has not been tested. The statement has been derived from the properties of the individual components. No substance-specific organtoxicity was observed after repeated administration to animals. Genetic toxicity Information on: Chlorfenapyr Assessment of mutagenicity: No mutagenic effect was found in various tests with microorganisms and mammalian cell culture. The substance was not mutagenic in a test with mammals Carcinogenicity Assessment of carcinogenicity: The product has not been tested. The statement has been derived from the properties of the individual components. The results of various animal studies gave no indication of a carcinogenic effect. Reproductive toxicity Assessment of reproduction toxicity: The product has not been tested. The statement has been derived from the properties of the individual components. The results of animal studies gave no indication of a fertility impairing effect. Teratogenicity

185 Safety Data Sheet PHANTOM TERMITICIDE/INSECTICIDE Revision date : 2014/09/29 Page: 9/11 Version: 7.0 ( /SDS_CPA_US/EN) Assessment of teratogenicity: The product has not been tested. The statement has been derived from the properties of the individual components. Animal studies gave no indication of a developmental toxic effect at doses that were not toxic to the parental animals. Symptoms of Exposure The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further important symptoms and effects are so far not known. Medical conditions aggravated by overexposure Individuals with pre-existing diseases of the respiratory system, skin or eyes may have increased susceptibility to excessive exposures. 12. Ecological Information Toxicity Aquatic toxicity Assessment of aquatic toxicity: Very toxic (acute effect) to fish. Very toxic (acute effect) to aquatic invertebrates. Acutely toxic for aquatic plants. Toxicity to fish LC50 (96 h) mg/l, Oncorhynchus mykiss (Flow through.) Aquatic invertebrates EC50 (48 h) mg/l, Daphnia magna (static) Aquatic plants EC50 (72 h) 4.09 mg/l, Selenastrum capricornutum (OECD Guideline 201) Assessment of terrestrial toxicity Acutely very toxic to terrestrial organisms. Bioaccumulative potential Assessment bioaccumulation potential The product has not been tested. The statement has been derived from the properties of the individual components. Additional information Other ecotoxicological advice: The ecological data given are those of the active ingredient. 13. Disposal considerations Waste disposal of substance: Pesticide wastes are regulated. Improper disposal of excess pesticide, spray mix or rinsate is a violation of federal law. If pesticide wastes cannot be disposed of according to label instructions, contact the State Pesticide or Environmental Control Agency or the Hazardous Waste representative at the nearest EPA Regional Office for guidance.

186 Safety Data Sheet PHANTOM TERMITICIDE/INSECTICIDE Revision date : 2014/09/29 Page: 10/11 Version: 7.0 ( /SDS_CPA_US/EN) Container disposal: Rinse thoroughly at least three times (triple rinse) in accordance with EPA recommendations. Consult state or local disposal authorities for approved alternative procedures such as container recycling. Recommend crushing, puncturing or other means to prevent unauthorized use of used containers. RCRA: This product is not regulated by RCRA. 14. Transport Information Land transport USDOT Not classified as a dangerous good under transport regulations Sea transport IMDG Hazard class: 9 Packing group: III ID number: UN 3082 Hazard label: 9, EHSM Marine pollutant: YES Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains CHLORFENAPYR 24%) Air transport IATA/ICAO Hazard class: 9 Packing group: III ID number: UN 3082 Hazard label: 9, EHSM Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains CHLORFENAPYR 24%) 15. Regulatory Information Federal Regulations Registration status: Chemical TSCA, US blocked / not listed Crop Protection TSCA, US released / exempt EPCRA 311/312 (Hazard categories): Acute; State regulations State RTK CAS Number Chemical name PA Propylene glycol

187 Safety Data Sheet PHANTOM TERMITICIDE/INSECTICIDE Revision date : 2014/09/29 Page: 11/11 Version: 7.0 ( /SDS_CPA_US/EN) NFPA Hazard codes: Health : 2 Fire: 1 Reactivity: 1 Special: Labeling requirements under FIFRA This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label. CAUTION: HARMFUL IF SWALLOWED. HARMFUL IF INHALED. HARMFUL IF ABSORBED THROUGH SKIN. May cause moderate but temporary irritation to the eyes. KEEP OUT OF REACH OF CHILDREN. KEEP OUT OF REACH OF DOMESTIC ANIMALS. Do not get in eyes, on skin, or on clothing. Avoid inhalation of mists/vapours. 16. Other Information SDS Prepared by: BASF NA Product Regulations SDS Prepared on: 2014/09/29 We support worldwide Responsible Care initiatives. We value the health and safety of our employees, customers, suppliers and neighbors, and the protection of the environment. Our commitment to Responsible Care is integral to conducting our business and operating our facilities in a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring the safe and environmentally sound handling of our products, and minimizing the impact of our operations on society and the environment during production, storage, transport, use and disposal of our products. IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU MAKE TESTS TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR INFORMATION SET FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE USED WITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESSLY UNDERSTAND AND AGREE THAT THE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION FURNISHED BY OUR COMPANY HEREUNDER ARE GIVEN GRATIS AND WE ASSUME NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DESIGNS, DATA AND INFORMATION GIVEN OR RESULTS OBTAINED, ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK. END OF DATA SHEET

188 Precor 2000 Plus Premise Spray Return to Index... Safety Data Sheet Section 1: Identification Product identifier Product Name Synonyms Product Description Precor 2000 Plus Premise Spray ; ; ; ; EPA Reg. No.: ; RF9910 Aerosol Clear to white aerosol spray. Relevant identified uses of the substance or mixture and uses advised against Recommended use Insecticide. Restrictions on use Details of the supplier of the safety data sheet Manufacturer Wellmark International Emergency telephone number Manufacturer Keep out of the reach of children. Avoid contact with skin, eyes and clothing. Keep away from heat, sparks and flame. Do not allow product to enter drain or any body of water E. Woodfield Road, Suite 200W Schaumburg, IL United States Manufacturer (Transportation) CHEMTREC Manufacturer (Transportation) CHEMTREC Outside North America Collect Calls Accepted Section 2: Hazard Identification United States (US) According to: OSHA 29 CFR HCS Classification of the substance or mixture OSHA HCS 2012 Aspiration 1 Specific Target Organ Toxicity Single Exposure 3: Narcotic Effects Flammable Aerosols 2 Skin Irritation 2 Skin Sensitization 1 Label elements OSHA HCS 2012 DANGER Preparation Date: 20/July/2015 Revision Date: 20/July/2015 Format: GHS Language: English (US) OSHA HCS 2012

189 Precor 2000 Plus Premise Spray Hazard statements May cause drowsiness or dizziness May be fatal if swallowed and enters airways Flammable aerosol Causes skin irritation May cause an allergic skin reaction Precautionary statements Prevention Use only outdoors or in a well ventilated area. Avoid breathing dust, fume, gas, mist, vapors and/or spray. Keep away from heat, sparks, open flames and/or hot surfaces. No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Wash thoroughly after handling. Wear protective gloves. Contaminated work clothing should not be allowed out of the workplace. Response IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Do NOT induce vomiting. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a poison control center or doctor if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Storage/Disposal Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Store locked up. Store in a well ventilated place. Keep container tightly closed. Protect from sunlight. Do not expose to temperatures exceeding 50ºC/122ºF. Other hazards OSHA HCS 2012 Under United States Regulations (29 CFR Hazard Communication Standard), this product is considered hazardous. Section 3 Composition/Information on Ingredients Substances Mixtures Material does not meet the criteria of a substance according to United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Composition Chemical Name Identifiers % (s) Methoprene CAS: % Permethrin CAS: % Piperonyl butoxide CAS: % Phenothrin CAS: % N Octyl Bicyloheptene Dicarboximide CAS: % Distillates (petroleum), hydrotreated light CAS: % Ethoxylated nonylphenol, branched CAS: % 2 Pyrrolidinone, 1 octyl CAS: % Preparation Date: 20/July/2015 Revision Date: 20/July/2015 Format: GHS Language: English (US) OSHA HCS 2012

190 Precor 2000 Plus Premise Spray Propane CAS: % Butane CAS: % Other ingredients NDA % Section 4: First Aid Measures Description of first aid measures Inhalation Skin Eye Ingestion IF INHALED: Remove person to fresh air and keep at rest in a position comfortable for breathing. Call a poison control center or doctor if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. If irritation or rash occurs, get medical advice/attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if symptoms occur. IF SWALLOWED: Aspiration hazard do NOT induce vomiting. Call a poison control center or doctor immediately for treatment advice. Most important symptoms and effects, both acute and delayed Aspiration hazard, may cause dizziness or drowsiness if inhaled, causes skin irritation, may cause an allergic reaction in individuals with a sensitivity to piperonyl butoxide and/or n octyl bicycloheptene dicarboximide. Refer to Section 11 Toxicological Information. Indication of any immediate medical attention and special treatment needed Notes to Physician Contains petroleum distillate vomiting may cause aspiration pneumonia. Treat symptomatically and supportively. Section 5: Fire Fighting Measures Extinguishing media Suitable Extinguishing Media LARGE FIRE: Water spray, fog or regular foam. SMALL FIRES: Dry chemical, CO2, water spray or regular foam. Unsuitable Extinguishing Media Firefighting Procedures Avoid heavy hose streams. Flammable aerosols exposed to high temperatures may rupture, rocket and cause secondary hazards. As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in all directions. Special hazards arising from the substance or mixture Unusual Fire and Explosion Hazards Hazardous Combustion Products Advice for firefighters At temperatures above 130 F, container may rupture. Flammable aerosols exposed to high temperatures may rupture, rocket and cause secondary hazards. Thermal degradation may produce oxides of carbon, oxides of nitrogen and/or volatile hydrocarbon vapors. Wear positive pressure self contained breathing apparatus (SCBA). Section 6 Accidental Release Measures Personal precautions, protective equipment and emergency procedures Personal Precautions Emergency Procedures Approach leaking or punctured pressurized containers cautiously. Isolate leaking container from all sources of ignition. Avoid breathing fumes. Ventilate enclosed areas. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate Preparation Date: 20/July/2015 Revision Date: 20/July/2015 Format: GHS Language: English (US) OSHA HCS 2012

191 Precor 2000 Plus Premise Spray area). Avoid unnecessary personnel and equipment traffic in the spill area. Turn off electric power to area. Stay upwind. Ventilate closed spaces before entering. Do not allow runoff into water, storm drains or drainage ditches. Environmental precautions Avoid run off to waterways and sewers. Methods and material for containment and cleaning up Containment/Clean up Measures Section 7 Handling and Storage Precautions for safe handling Handling Keep away from fire, sparks and heated surfaces. SMALL SPILLS: Take up with sand or other non combustible absorbent material and place into containers for later disposal. Do not use or store near heat or open flame. Do not smoke while using this product. Contents under pressure, do not crush, puncture or incinerate. Avoid breathing fumes. Conditions for safe storage, including any incompatibilities Storage Incompatible Materials or Ignition Sources Store in a cool, dry place. Keep out of reach of children. Keep away from sources of ignition No Smoking. Store locked up. Store in a well ventilated place. Keep container tightly closed. Keep at a temperature not exceeding 122 F (50 C). Keep from freezing. Heat, sparks, open flame. Section 8 Exposure Controls/Personal Protection Control parameters Butane ( ) Propane ( ) Exposure Limits/Guidelines Result ACGIH NIOSH OSHA STELs 1000 ppm STEL Not established Not established TWAs Not established 800 ppm TWA; 1900 mg/m3 TWA Not established TWAs 1000 ppm TWA (listed under Aliphatic hydrocarbon gases: Alkane C1 4) 1000 ppm TWA; 1800 mg/m3 TWA 1000 ppm TWA; 1800 mg/m3 TWA Exposure controls Engineering Measures/Controls Personal Protective Equipment Pictograms Use adequate ventilation to remove vapors (fumes, dust etc) Respiratory Eye/Face Hands Skin/Body Environmental Controls Exposure In case of insufficient ventilation, wear suitable NIOSH approved respiratory protection. Wear safety glasses. Impervious gloves. Some materials that are chemical resistant to this product are Barrier Laminate, Nitrile Rubber, Neoprene Rubber or Viton. It is recommended for handlers to wear appropriate clothing to prevent skin contact including long sleeves, long pants, socks and shoes. Controls should be engineered to prevent release to the environment, including procedures to prevent spills, atmospheric release and release to waterways. Preparation Date: 20/July/2015 Revision Date: 20/July/2015 Format: GHS Language: English (US) OSHA HCS 2012

192 Precor 2000 Plus Premise Spray Section 9 Physical and Chemical Properties Information on Physical and Chemical Properties Material Description Physical Form Aerosol Appearance/Description White to clear aerosol spray. Color White to clear. Odor No data available. Aerosol Type Spray Odor Threshold No data available General Properties Boiling Point No data available Melting Point/Freezing Point No data available Decomposition Temperature No data available Heat of Decomposition No data available ph No data available Specific Gravity/Relative Density No data available Water Solubility No data available Viscosity No data available Volatility Vapor Pressure No data available Vapor Density No data available Evaporation Rate No data available VOC (Wt.) No data available VOC (Vol.) No data available Flammability Flash Point Not relevant UEL No data available LEL No data available Heat of Combustion (ΔHc) 6.98 kj/g Flame Extension 1 in Flammability (solid, gas) Flammable aerosol. Environmental Octanol/Water Partition coefficient No data available Section 10: Stability and Reactivity Reactivity Chemical stability Non reactive under normal handling and storage conditions. Stable under normal temperatures and pressures. Possibility of hazardous reactions Conditions to avoid Incompatible materials Flammable, aerosols exposed to high temperatures may rupture, rocket and cause secondary hazards. Heat, sparks, open flame. Excess heat. Heat, strong acids, strong bases and oxidizing agents. Hazardous decomposition products Hazardous decomposition may occur when heated producing oxides of carbon and nitrogen, volatile hydrocarbon vapors. Section 11 Toxicological Information Information on toxicological effects CAS Preparation Date: 20/July/2015 Revision Date: 20/July/2015 Format: GHS Language: English (US) OSHA HCS 2012

193 Precor 2000 Plus Premise Spray Precor 2000 Plus Premise Spray NDA Acute Toxicity: Ingestion/Oral Rat LD50 >5000 mg/kg 14 Day(s); Inhalation Rat LC50 >2.12 mg/l 4 Hour(s); Skin Rabbit LD50 >5050 mg/kg 24 Hour(s); Irritation: Eye Rabbit Mild irritation; Skin Rabbit Moderate irritation GHS Properties Acute toxicity Classification Aspiration Hazard OSHA HCS 2012 Aspiration 1 Carcinogenicity Germ Cell Mutagenicity OSHA HCS 2012 Acute Toxicity Dermal Classification criteria not met; Acute Toxicity Inhalation Classification criteria not met; Acute Toxicity Oral Classification criteria not met OSHA HCS 2012 Classification criteria not met OSHA HCS 2012 Classification criteria not met Skin corrosion/irritation OSHA HCS 2012 Skin Irritation 2 Skin sensitization OSHA HCS 2012 Skin Sensitizer 1 STOT RE STOT SE Toxicity for Reproduction Respiratory sensitization Serious eye damage/irritation Potential Health Effects Inhalation Acute (Immediate) Chronic (Delayed) Skin Acute (Immediate) Chronic (Delayed) Eye Acute (Immediate) Chronic (Delayed) Ingestion Acute (Immediate) Chronic (Delayed) OSHA HCS 2012 Classification criteria not met OSHA HCS 2012 Specific Target Organ Toxicity Single Exposure 3: Narcotic Effects OSHA HCS 2012 Classification criteria not met OSHA HCS 2012 Classification criteria not met OSHA HCS 2012 Classification criteria not met May cause drowsiness and dizziness. No data available Causes skin irritation. May cause an allergic reaction in individuals with a sensitivity to piperonyl butoxide and/or n octyl bicycloheptene dicarboximide. No data available. Under normal conditions of use, no health effects are expected. No data available Aspiration Hazard may be fatal if swallowed and enters airways. No data available Section 12 Ecological Information Toxicity Component CAS Data (s) Methoprene (0.085%) Crustacea: NOEC Crustacea Mysid shrimp mg/l [Chronic]; 96 Hour(s) LC50 Crustacea Mysid shrimp 0.11 mg/l [Acute]; 48 Hour(s) LC50 Crustacea Daphnia magna 0.36 mg/l [Acute]; Fish: 96 Hour(s) LC50 Fish Rainbow Trout 0.76 mg/l [Acute]; 96 Hour(s) LC50 Fish Blue Gill >0.37 mg/l [Acute]; NOEC Fish Fathead minnow mg/l [Chronic] Crustacea: NOEC Crustacea Daphnia magna mg/l [Chronic]; NOEC Crustacea Mysid shrimp mg/l [Chronic]; LC50 Crustacea Hexagenia bilineuta mg/l [Acute]; 96 Hour Preparation Date: 20/July/2015 Revision Date: 20/July/2015 Format: GHS Language: English (US) OSHA HCS 2012

194 Precor 2000 Plus Premise Spray Permethrin (0.35%) Piperonyl butoxide (1.75%) Phenothrin (0.3%) N Octyl Bicyloheptene Dicarboximide (1.75%) Persistence and degradability No data available Bioaccumulative potential No data available Mobility in Soil No data available Other adverse effects Potential Environmental No data available. Effects Section 13 Disposal Considerations (s) LC50 Crustacea Mysid shrimp mg/l [Acute]; Fish: 96 Hour(s) LC50 Fish Blue gill mg/l [Acute]; 96 Hour(s) LC50 Fish Atlantic silverside mg/l [Acute]; NOEC Fish Fathead minnow mg/l [Chronic]; NOEC Fish Sheepshead minnow mg/l [Chronic] Crustacea: LC50 Crustacea Gammarus fasciatus (amphipod) 0.51 mg/l [Acute]; LC50 Crustacea Mysid shrimp 0.49 mg/l [Acute]; NOEC Crustacea Daphnia magna 0.03 mg/l [Chronic]; Fish: LC50 Fish Rainbow Trout 1.9 mg/l [Acute]; LC50 Fish Sheephead minnow 3.94 mg/l [Acute]; NOEC Fish Fathead minnow 0.04 mg/l [Chronic] Crustacea: NOEC Crustacea Daphnia magna mg/l [chronic]; 48 Hour(s) LC50 Crustacea Daphnia magna mg/l [acute]; 96 Hour(s) LC50 Crustacea Mysid shrimp mg/l [acute]; Fish: 96 Hour(s) LC50 Fish Rainbow trout mg/l [acute]; 96 Hour(s) LC50 Fish Blue gill mg/l [acute]; NOEC Fish Rainbow trout mg/l [chronic] Crustacea: 48 Hour(s) LC50 Crustacea Daphnia magna 2.3 mg/l [Acute]; Fish: LC50 Fish mg/l [Acute] Waste treatment methods Product waste Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Do not allow entry into storm drains, drainage ditches, gutters or surface waters. Packaging waste Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Do not puncture or incinerate. Section 14 Transport Information UN number UN proper shipping name Transport hazard class (es) Packing group Environmental hazards DOT UN1950 Aerosols (contains Phenothrin) 2.1 Not Applicable Marine Pollutant IMO/IMDG UN1950 Aerosols (contains Phenothrin) 2.1 Not Applicable Marine Pollutant IATA/ICAO UN1950 Aerosols, flammable 2.1 Not Applicable Not Applicable Special precautions for user None specified. Transport in bulk according No data available to Annex II of MARPOL 73/78 and the IBC Code Other information IMO/IMDG No data available IATA/ICAO No data available Preparation Date: 20/July/2015 Revision Date: 20/July/2015 Format: GHS Language: English (US) OSHA HCS 2012

195 Precor 2000 Plus Premise Spray Key to abbreviations = N/A = Not applicable. Section 15 Regulatory Information Safety, health and environmental regulations/legislation specific for the substance or mixture SARA Hazard Classifications Acute, SARA Title III Section 313 FIFRA Pesticide Labeling This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of nonpesticide chemicals. The hazard information required on the pesticide label is reproduced below. The pesticide label also includes other important information, including directions for use. CAUTION Precautionary Statements KEEP OUT OF THE REACH OF CHILDREN. Hazards to Humans and Domestic Animals HAZARDS TO HUMANS AND DOMESTIC ANIMALS CAUTION: Avoid contact with skin or clothing. Wash hands thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco, or using the toilet. Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals. First Aid IF ON SKIN OR CLOTHING: Take off contaminated clothing. Rinse skin immediately with plenty of water for minutes. Call a poison control center or doctor for treatment advice. IF SWALLOWED: Immediately call a poison control center or doctor for treatment advice. Do not induce vomiting unless told to do so by a poison control center or doctor. Do not give ANY liquid to the person. Do not give anything by mouth to an unconscious person. Note to Physician: Contains petroleum distillate vomiting may cause aspiration pneumonia. Physical or Chemical Hazards Contents under pressure. Do not use or store near open flame. Do not puncture or incinerate container. Exposure to temperatures above 130 F may cause bursting. Inventory Component CAS TSCA (s) Methoprene No 2 Pyrrolidinone, 1 octyl Yes Butane Yes Distillates (petroleum), hydrotreated light N Octyl Bicyloheptene Dicarboximide Yes No Permethrin No Phenothrin No Ethoxylated nonylphenol, branched Yes Piperonyl butoxide Yes Propane Yes Preparation Date: 20/July/2015 Revision Date: 20/July/2015 Format: GHS Language: English (US) OSHA HCS 2012

196 Precor 2000 Plus Premise Spray United States Environment U.S. CERCLA/SARA Section 313 Emission Reporting Ethoxylated nonylphenol, branched Not Listed Propane Not Listed Butane Not Listed (s) Methoprene Not Listed Permethrin 1.0 % de minimis concentration Distillates (petroleum), hydrotreated light Not Listed 2 Pyrrolidinone, 1 octyl Not Listed Piperonyl butoxide 1.0 % de minimis concentration N Octyl Bicyloheptene Dicarboximide Not Listed Phenothrin 1.0 % de minimis concentration Section 16 Other Information Last Revision Date Preparation Date Disclaimer/Statement of Liability 20/July/ /July/2015 The information and statements herein are believed to be reliable but are not to be construed as a warranty or representation for which we assume legal responsibility. Users should undertake sufficient verification and testing to determine the suitability for their own particular purpose of any information or products referred to herein. NO WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE IS MADE. Preparation Date: 20/July/2015 Revision Date: 20/July/2015 Format: GHS Language: English (US) OSHA HCS 2012

197 Zoecon Precor IGR Concentrate Safety Data Sheet Return to Index... Section 1: Identification Product identifier Product Name Synonyms Product Description Zoecon Precor IGR Concentrate 10290A 37190B 37740C EPA Reg. No.: Zoecon RF 291 Emulsifiable Concentrate Very light straw colored, transparent liquid. Relevant identified uses of the substance or mixture and uses advised against Recommended use Restrictions on use Insect growth regulator. KEEP OUT OF THE REACH OF CHILDREN. Avoid contact with eyes, skin and clothing. Do not use or store near heat or open flame. Do not take internally. Avoid inhalation of vapors or fumes. Details of the supplier of the safety data sheet Manufacturer Wellmark International 1501 E. Woodfield Road, Suite 200W Schaumburg, IL United States Emergency telephone number Manufacturer Manufacturer (Transportation) CHEMTREC Manufacturer (Transportation) CHEMTREC Outside North America Collect Calls Accepted Section 2: Hazard Identification United States (US) According to: OSHA 29 CFR HCS Classification of the substance or mixture OSHA HCS 2012 Aspiration 1 Flammable Liquids 4 Eye Mild Irritation 2B Skin Irritation 2 Specific Target Organ Toxicity Single Exposure 3: Narcotic Effects Label elements OSHA HCS 2012 DANGER Preparation Date: 20/July/2015 Revision Date: 20/July/2015 Page 1 of 8 Format: GHS Language: English (US) OSHA HCS 2012

198 Zoecon Precor IGR Concentrate Hazard statements Causes skin irritation May be fatal if swallowed and enters airways Combustible liquid Causes eye irritation May cause drowsiness or dizziness Precautionary statements Prevention Wash thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection. Avoid breathing dust, fume, gas, mist, vapors and/or spray. Use only outdoors or in a well ventilated area. Keep away from flames and hot surfaces. No smoking. Response IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Do NOT induce vomiting. In case of fire: Use appropriate media Foam, water, dry chemical or C02. for extinction. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a poison control center or doctor if you feel unwell. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Storage/Disposal Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Store in a well ventilated place. Keep cool. Store locked up. Keep container tightly closed. Other hazards OSHA HCS 2012 Under United States Regulations (29 CFR Hazard Communication Standard), this product is considered hazardous. Section 3 Composition/Information on Ingredients Substances Mixtures Material does not meet the criteria of a substance. Composition Chemical Name Identifiers % (s) Methoprene CAS: % Distillates (petroleum), hydrotreated light CAS: % Poly(oxy 1,2 ethanediyl), alpha (dodecylphenyl) omega hydroxy CAS: <= 16.6% Other ingredients NDA > 3% Preparation Date: 20/July/2015 Revision Date: 20/July/2015 Page 2 of 8 Format: GHS Language: English (US) OSHA HCS 2012

199 Zoecon Precor IGR Concentrate Section 4: First Aid Measures Description of first aid measures Inhalation Skin Eye Ingestion IF INHALED: If breathing is difficult, remove person to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF SWALLOWED: Immediately call a poison control center or doctor. Aspiration hazard if swallowed, do NOT induce vomiting. Most important symptoms and effects, both acute and delayed Aspiration hazard, causes skin irritation, causes eye irritation, may cause dizziness or drowsiness if inhaled. Refer to Section 11 Toxicological Information. Indication of any immediate medical attention and special treatment needed Notes to Physician Contains petroleum distillate vomiting may cause aspiration pneumonia. Treat symptomatically and supportively. Section 5: Fire Fighting Measures Extinguishing media Suitable Extinguishing Media LARGE FIRE: Water spray, fog or regular foam. SMALL FIRES: Dry chemical, CO2, water spray or regular foam. Unsuitable Extinguishing Media Firefighting Procedures Avoid heavy hose streams. LARGE FIRES: Move containers from fire area if you can do it without risk. Stay upwind. Ventilate closed spaces before entering. Do not breathe gas/fumes/vapor/spray. Special hazards arising from the substance or mixture Unusual Fire and Explosion Hazards Hazardous Combustion Products Advice for firefighters Combustible liquid. Containers may explode when heated. Liquid will float and may re ignite on surface of water. Combustible liquid may produce carbon dioxide and/or carbon monoxide. Wear positive pressure self contained breathing apparatus (SCBA). Section 6 Accidental Release Measures Personal precautions, protective equipment and emergency procedures Personal Precautions Emergency Procedures Environmental precautions Do not walk through spilled material. Ventilate enclosed areas. Wear appropriate personal protective equipment, avoid direct contact. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Ventilate closed spaces before entering. Avoid release into the environment. LARGE SPILLS: Prevent entry into waterways, sewers, basements or confined areas. Methods and material for containment and cleaning up Preparation Date: 20/July/2015 Revision Date: 20/July/2015 Page 3 of 8 Format: GHS Language: English (US) OSHA HCS 2012

200 Zoecon Precor IGR Concentrate Containment/Clean up Measures Section 7 Handling and Storage Precautions for safe handling Handling All equipment used when handling the product must be grounded. Stop leak if you can do it without risk. SMALL SPILLS: Take up with sand or other non combustible absorbent material and place into containers for later disposal. Use appropriate Personal Protective Equipment (PPE) Keep away from fire No Smoking. Avoid breathing fumes. Use only in well ventilated areas. Wear appropriate personal protective equipment, avoid direct contact. Conditions for safe storage, including any incompatibilities Storage Incompatible Materials or Ignition Sources Other Information Store locked up. Store in a cool/low temperature, well ventilated dry place away from heat and ignition sources. Keep from freezing. Do not store at temperatures exceeding 130 F. Keep container tightly closed. Heat, sparks, open flame. See product label for additional information. Section 8 Exposure Controls/Personal Protection Control parameters Exposure Limits/Guidelines Exposure controls Engineering Measures/Controls Personal Protective Equipment Pictograms No data available. Use adequate ventilation to remove vapors (fumes, dust, etc.) Respiratory Eye/Face Hands Skin/Body Environmental Exposure Controls Other Information In case of inadequate ventilation, avoid breathing vapors or mist, wear a NIOSH approved chemical cartridge respirator with organic vapor cartridges and a pesticide pre filter. Wear chemical splash safety goggles. Wear appropriate gloves. If prolonged exposure is anticipated, it is recommended for handlers to wear appropriate clothing to prevent skin contact. Refer to Section 13 Disposal Considerations. See product label for additional information. Section 9 Physical and Chemical Properties Information on Physical and Chemical Properties Material Description Physical Form Liquid Appearance/Description Very light straw, transparent liquid. Color Very light straw, transparent. Odor Faint aliphatic. Preparation Date: 20/July/2015 Revision Date: 20/July/2015 Page 4 of 8 Format: GHS Language: English (US) OSHA HCS 2012

201 Zoecon Precor IGR Concentrate Odor Threshold No data available General Properties Boiling Point No data available Melting Point/Freezing Point No data available Decomposition Temperature No data available ph 4.92 (10% in Type 1 Water) Specific Gravity/Relative Density 0.82 (6.8 lb/gal) Viscosity < 100 Centipoise (cps, cp) or mpas Volatility Water Solubility Insoluble Vapor Pressure No data available Vapor Density No data available Evaporation Rate No data available Flammability Flash Point 196 F (91 C) UEL No data available LEL No data available Autoignition No data available Flammability (solid, gas) No data available Environmental Octanol/Water Partition coefficient No data available Section 10: Stability and Reactivity Reactivity Chemical stability Stable Possibility of hazardous reactions Conditions to avoid Incompatible materials Non reactive under normal handling and storage conditions. Hazardous polymerization will not occur. Store away from oxidizers. Hazardous decomposition products Direct sunlight. Do not freeze. Excessive heat >130 F. Heat, sparks, open flame, other ignition sources, and oxidizing conditions. Strong oxidizers. Carbon dioxide and possibly carbon monoxide. Section 11 Toxicological Information Information on toxicological effects CAS Zoecon Precor IGR Concentrate NDA Acute Toxicity: Ingestion/Oral Rat LD50 >5100 mg/kg; Inhalation Rat LC mg/l 4 Hour (s); Skin Rabbit LD50 >2100 mg/kg; Irritation: Eye Rabbit Mild irritation; Skin Rabbit Moderate irritation GHS Properties Acute toxicity Classification OSHA HCS 2012 Acute Toxicity Dermal Classification criteria not met; Acute Toxicity Inhalation Classification criteria not met; Acute Toxicity Oral Preparation Date: 20/July/2015 Revision Date: 20/July/2015 Page 5 of 8 Format: GHS Language: English (US) OSHA HCS 2012

202 Zoecon Precor IGR Concentrate Classification criteria not met Aspiration Hazard OSHA HCS 2012 Aspiration 1 Carcinogenicity Germ Cell Mutagenicity OSHA HCS 2012 Classification criteria not met OSHA HCS 2012 Classification criteria not met Skin corrosion/irritation OSHA HCS 2012 Skin Irritation 2 Skin sensitization STOT RE STOT SE Toxicity for Reproduction Respiratory sensitization Serious eye damage/irritation Potential Health Effects Inhalation Acute (Immediate) Chronic (Delayed) Skin Acute (Immediate) Chronic (Delayed) Eye Acute (Immediate) Chronic (Delayed) Ingestion Acute (Immediate) Chronic (Delayed) OSHA HCS 2012 Classification criteria not met OSHA HCS 2012 Classification criteria not met OSHA HCS 2012 Specific Target Organ Toxicity Single Exposure 3: Narcotic Effects OSHA HCS 2012 Classification criteria not met OSHA HCS 2012 Classification criteria not met OSHA HCS 2012 Eye Mild Irritation 2B May cause drowsiness and dizziness. No data available Causes skin irritation. No data available Causes eye irritation. No data available Aspiration hazard small amounts of liquid aspirated into the lungs during ingestion or from vomiting may cause chemical pneumonitis or pulmonary edema. No data available Section 12 Ecological Information Toxicity Component CAS Data (s) Methoprene (1.2%) Persistence and degradability No data available. Bioaccumulative potential No data available. Mobility in Soil No data available Other adverse effects Potential Environmental No data available. Effects Crustacea: NOEC Crustacea Mysid shrimp mg/l [Chronic]; 96 Hour(s) LC50 Crustacea Mysid shrimp 0.11 mg/l [Acute]; 48 Hour(s) LC50 Crustacea Daphnia magna 0.36 mg/l [Acute]; Fish: 96 Hour(s) LC50 Fish Rainbow Trout 0.76 mg/l [Acute]; 96 Hour(s) LC50 Fish Blue Gill >0.37 mg/l [Acute]; NOEC Fish Fathead minnow mg/l [Chronic] Preparation Date: 20/July/2015 Revision Date: 20/July/2015 Page 6 of 8 Format: GHS Language: English (US) OSHA HCS 2012

203 Zoecon Precor IGR Concentrate Section 13 Disposal Considerations Waste treatment methods Product waste Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Wastes resulting from the use of this product may be disposed of on site or at an approved waste disposal facility. Never place unused product down any indoor or outdoor drain. Packaging waste Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. See product label for disposal instructions. Section 14 Transport Information UN number UN proper shipping name Transport hazard class (es) Packing group Environmental hazards DOT 1268 Petroleum distillates, n.o.s. 3 III Not Applicable IMO/IMDG 1268 Petroleum distillates, n.o.s. 3 III Not Applicable IATA/ICAO 1268 Petroleum distillates, n.o.s. 3 III Not Applicable Special precautions for user None specified. Transport in bulk according No data available to Annex II of MARPOL 73/78 and the IBC Code Other information IMO/IMDG No data available Key to abbreviations = N/A = Not applicable. IATA/ICAO No data available Section 15 Regulatory Information Safety, health and environmental regulations/legislation specific for the substance or mixture SARA Hazard Classifications Acute FIFRA Pesticide Labeling This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of nonpesticide chemicals. The hazard information required on the pesticide label is reproduced below. The pesticide label also includes other important information, including directions for use. CAUTION Precautionary Statements KEEP OUT OF THE REACH OF CHILDREN. Hazards to Humans and Domestic Animals HAZARDS TO HUMANS AND DOMESTIC ANIMALS CAUTION: Harmful if absorbed through the skin. Causes moderate eye irritation. Avoid contact with skin, eyes, or clothing. Wash thoroughly with soap and water after handling. First Aid Call a poison control center or doctor immediately for treatment advice. If in eyes Hold eye open and rinse slowly and gently with water for minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. If on Preparation Date: 20/July/2015 Revision Date: 20/July/2015 Page 7 of 8 Format: GHS Language: English (US) OSHA HCS 2012

204 Zoecon Precor IGR Concentrate skin or clothing Take off contaminated clothing. Rinse skin immediately with plenty of water for minutes. NOTE TO PHYSICIAN: This product contains petroleum distillates. If swallowed: Immediately call a poison control center or doctor. Do not induce vomiting unless told to do so by the poison control center or doctor. Do not give any liquid to the person. Do not give anything by mouth to an unconscious person. Physical or Chemical Hazards Combustible. Do not use or store near heat or open flame Inventory Component CAS TSCA (s) Methoprene No Distillates (petroleum), hydrotreated light Poly(oxy 1,2 ethanediyl), alpha (dodecylphenyl) omega hydroxy Yes Yes Section 16 Other Information Last Revision Date Preparation Date Disclaimer/Statement of Liability 20/July/ /July/2015 The information and statements herein are believed to be reliable but are not to be construed as a warranty or representation for which we assume legal responsibility. Users should undertake sufficient verification and testing to determine the suitability for their own particular purpose of any information or products referred to herein. NO WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE IS MADE. Preparation Date: 20/July/2015 Revision Date: 20/July/2015 Page 8 of 8 Format: GHS Language: English (US) OSHA HCS 2012

205 Safety Data Sheet PTB PHANTOM PRESSURIZED Return to Index... Revision date : 2015/12/04 Page: 1/12 Version: 5.0 ( /SDS_CPA_US/EN) 1. Identification Product identifier used on the label PTB PHANTOM PRESSURIZED Recommended use of the chemical and restriction on use Recommended use*: insecticide * The Recommended use identified for this product is provided solely to comply with a Federal requirement and is not part of the seller's published specification. The terms of this Safety Data Sheet (SDS) do not create or infer any warranty, express or implied, including by incorporation into or reference in the seller's sales agreement. Details of the supplier of the safety data sheet Company: BASF CORPORATION 100 Park Avenue Florham Park, NJ 07932, USA Telephone: Emergency telephone number CHEMTREC: BASF HOTLINE: HELP (4357) Other means of identification Substance number: EPA Registration number: Molecular formula: C15 H11 Br Cl F3 N2 O Chemical family: pyrrole derivative Synonyms: chlorfenapyr 2. Hazards Identification According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part Classification of the product Flam. Liq. 1 Flammable liquids Aquatic Acute 1 Hazardous to the aquatic environment - acute Aquatic Chronic 1 Hazardous to the aquatic environment - chronic Label elements

206 Safety Data Sheet PTB PHANTOM PRESSURIZED Revision date : 2015/12/04 Page: 2/12 Version: 5.0 ( /SDS_CPA_US/EN) Pictogram: Signal Word: Danger Hazard Statement: H224 H400 H410 Extremely flammable liquid and vapour. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. Precautionary Statements (Prevention): P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P280 Wear protective gloves and eye/face protection. P273 Avoid release to the environment. P243 Take precautionary measures against static discharge. P241 Use explosion-proof electrical/ventilating/lighting/equipment. P233 Keep container tightly closed. P240 Ground/bond container and receiving equipment. P242 Use only non-sparking tools. Precautionary Statements (Response): P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P391 Collect spillage. P370 + P378 In case of fire: Use water spray, dry powder, foam or carbon dioxide for extinction. Precautionary Statements (Storage): P403 + P235 Store in a well-ventilated place. Keep cool. Precautionary Statements (Disposal): P501 Dispose of contents/container to hazardous or special waste collection point. Hazards not otherwise classified Labeling of special preparations (GHS): The product contains fluorinated greenhouse gases according to regulation (EC) No 517/2014. The following percentage of the mixture consists of components(s) with unknown hazards regarding the acute toxicity: 12 % Inhalation - vapour The following percentage of the mixture consists of components(s) with unknown hazards regarding the acute toxicity: 12 % Inhalation - mist According to Regulation 1994 OSHA Hazard Communication Standard; 29 CFR Part Emergency overview CAUTION: KEEP OUT OF REACH OF CHILDREN. KEEP OUT OF REACH OF DOMESTIC ANIMALS. Avoid contact with the skin, eyes and clothing. Avoid inhalation of mists/vapours.

207 Safety Data Sheet PTB PHANTOM PRESSURIZED Revision date : 2015/12/04 Page: 3/12 Version: 5.0 ( /SDS_CPA_US/EN) Wash thoroughly after handling. 3. Composition / Information on Ingredients According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part CAS Number Weight % Chemical name % Chlorfenapyr < 10.0% Distillates (petroleum), hydrotreated light < 15.0% Acetone < 15.0% Hydrocarbons, C < 75.0% HFC-134A According to Regulation 1994 OSHA Hazard Communication Standard; 29 CFR Part CAS Number Weight % Chemical name % Chlorfenapyr < 10.0% Distillates (petroleum), hydrotreated light < 15.0% Acetone Hydrocarbons, C HFC-134A >= 75.0% Proprietary ingredients 4. First-Aid Measures Description of first aid measures General advice: First aid providers should wear personal protective equipment to prevent exposure. Remove contaminated clothing. Move person to fresh air. If person is not breathing, call 911 or ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or physician for treatment advice. Have the product container or label with you when calling a poison control center or doctor or going for treatment. If inhaled: Remove the affected individual into fresh air and keep the person calm. If on skin: Wash thoroughly with soap and water. If in eyes: Hold eyes open and rinse slowly and gently with water for 15 to 20 minutes. Remove contact lenses, if present, after first 5 minutes, then continue rinsing. If swallowed: Never induce vomiting or give anything by mouth if the victim is unconscious or having convulsions. Do not induce vomiting. Have person sip a glass of water if able to swallow. Most important symptoms and effects, both acute and delayed Symptoms: No significant reaction of the human body to the product known. Indication of any immediate medical attention and special treatment needed

208 Safety Data Sheet PTB PHANTOM PRESSURIZED Revision date : 2015/12/04 Page: 4/12 Version: 5.0 ( /SDS_CPA_US/EN) Note to physician Antidote: Treatment: No known specific antidote. Treat symptomatically. 5. Fire-Fighting Measures Extinguishing media Suitable extinguishing media: foam, dry powder, carbon dioxide, water spray Special hazards arising from the substance or mixture Hazards during fire-fighting: carbon monoxide, carbon dioxide, nitrogen dioxide, nitrogen oxide, Hydrogen chloride, hydrogen fluoride, hydrogen bromide, halogenated hydrocarbons, Hydrocarbons, If product is heated above decomposition temperature, toxic vapours will be released. The substances/groups of substances mentioned can be released in case of fire. Advice for fire-fighters Protective equipment for fire-fighting: Firefighters should be equipped with self-contained breathing apparatus and turn-out gear. Further information: Evacuate area of all unnecessary personnel. Contain contaminated water/firefighting water. Do not allow to enter drains or waterways. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Take appropriate protective measures. Clear area. Shut off source of leak only under safe conditions. Extinguish sources of ignition nearby and downwind. Ensure adequate ventilation. Wear suitable personal protective clothing and equipment. Environmental precautions Do not discharge into the subsoil/soil. Contain contaminated water/firefighting water. Methods and material for containment and cleaning up Dike spillage. Pick up with suitable absorbent material. Place into suitable containers for reuse or disposal in a licensed facility. Spilled substance/product should be recovered and applied according to label rates whenever possible. If application of spilled substance/product is not possible, then spills should be contained, solidified, and placed in suitable containers for disposal. After decontamination, spill area can be washed with water. Collect wash water for approved disposal. 7. Handling and Storage Precautions for safe handling RECOMMENDATIONS ARE FOR MANUFACTURING, COMMERCIAL BLENDING, AND PACKAGING WORKERS. PESTICIDE APPLICATORS & WORKERS must refer to the Product Label and Directions for Use attached to the product for Agricultural Use Requirements in accordance with the EPA Worker Protection Standard 40 CFR part 170. Ensure adequate ventilation. Provide good ventilation of working area (local exhaust ventilation if necessary). Keep away from sources of ignition - No smoking. Keep container tightly sealed. Protect contents from the

209 Safety Data Sheet PTB PHANTOM PRESSURIZED Revision date : 2015/12/04 Page: 5/12 Version: 5.0 ( /SDS_CPA_US/EN) effects of light. Protect against heat. Protect from air. Handle and open container with care. Do not open until ready to use. Once container is opened, content should be used as soon as possible. Provide means for controlling leaks and spills. Do not return residues to the storage containers. Follow label warnings even after container is emptied. The substance/ product may be handled only by appropriately trained personnel. Avoid all direct contact with the substance/product. Avoid contact with the skin, eyes and clothing. Avoid inhalation of dusts/mists/vapours. Wear suitable personal protective clothing and equipment. Protection against fire and explosion: The relevant fire protection measures should be noted. Fire extinguishers should be kept handy. Avoid all sources of ignition: heat, sparks, open flame. Sources of ignition should be kept well clear. Avoid extreme heat. Keep away from oxidizable substances. Electrical equipment should conform to national electric code. Ground all transfer equipment properly to prevent electrostatic discharge. Electrostatic discharge may cause ignition. Conditions for safe storage, including any incompatibilities Segregate from incompatible substances. Segregate from foods and animal feeds. Segregate from textiles and similar materials. Further information on storage conditions: Keep only in the original container in a cool, dry, wellventilated place away from ignition sources, heat or flame. Protect containers from physical damage. Protect against contamination. The authority permits and storage regulations must be observed. Protect from temperatures above: 40 C Changes in the properties of the product may occur if substance/product is stored above indicated temperature for extended periods of time. 8. Exposure Controls/Personal Protection Users of a pesticidal product should refer to the product label for personal protective equipment requirements. Components with occupational exposure limits Acetone OSHA PEL PEL 1,000 ppm 2,400 mg/m3 ; STEL value 1,000 ppm 2,400 mg/m3 ; TWA value 750 ppm 1,800 mg/m3 ; ACGIH TLV TWA value 250 ppm ; STEL value 500 ppm ; Distillates (petroleum), hydrotreated light ACGIH TLV TWA value 200 mg/m3 Non-aerosol (total hydrocarbon vapor); Application restricted to conditions in which there are negligible aerosol exposures. Skin Designation Non-aerosol (total hydrocarbon vapor); The substance can be absorbed through the skin. Advice on system design: Whenever possible, engineering controls should be used to minimize the need for personal protective equipment. Personal protective equipment RECOMMENDATIONS FOR MANUFACTURING, COMMERCIAL BLENDING, AND PACKAGING WORKERS:

210 Safety Data Sheet PTB PHANTOM PRESSURIZED Revision date : 2015/12/04 Page: 6/12 Version: 5.0 ( /SDS_CPA_US/EN) Respiratory protection: Wear respiratory protection if ventilation is inadequate. Wear a NIOSH-certified (or equivalent) organic vapour/particulate respirator. For situations where the airborne concentrations may exceed the level for which an air purifying respirator is effective, or where the levels are unknown or Immediately Dangerous to Life or Health (IDLH), use NIOSH-certified full facepiece pressure demand self-contained breathing apparatus (SCBA) or a full facepiece pressure demand supplied-air respirator (SAR) with escape provisions. Hand protection: Chemical resistant protective gloves, Protective glove selection must be based on the user's assessment of the workplace hazards. Eye protection: Safety glasses with side-shields. Tightly fitting safety goggles (chemical goggles). Wear face shield if splashing hazard exists. Body protection: Body protection must be chosen depending on activity and possible exposure, e.g. head protection, apron, protective boots, chemical-protection suit. General safety and hygiene measures: Wear long sleeved work shirt and long work pants in addition to other stated personal protective equipment. Work place should be equipped with a shower and an eye wash. Handle in accordance with good industrial hygiene and safety practice. Personal protective equipment should be decontaminated prior to reuse. Gloves must be inspected regularly and prior to each use. Replace if necessary (e.g. pinhole leaks). Take off immediately all contaminated clothing. Store work clothing separately. Hands and/or face should be washed before breaks and at the end of the shift. No eating, drinking, smoking or tobacco use at the place of work. Keep away from food, drink and animal feeding stuffs. 9. Physical and Chemical Properties Form: liquid, under pressure Odour: strong, of acetone Odour threshold: Not determined due to potential health hazard by inhalation. Colour: amber, cloudy ph value: approx. 7-9 ( 5 %(m), approx. 25 C) Melting point: The product has not been tested. Boiling point: approx. -12 C Information applies to the solvent. Flash point: approx C Information applies to the propellant. Flammability: Extremely flammable. Flammability of Aerosol 0 cm (ASTM D 3065) Products: no flashback Lower explosion limit: 1.9 %(V) Information applies to the solvent. Upper explosion limit: 13.3 %(V) Information applies to the solvent. Vapour pressure: approx hpa ( 21 C) Information applies to the solvent. Density: approx. 0.8 g/cm3 ( 20 C) Vapour density: not applicable

211 Safety Data Sheet PTB PHANTOM PRESSURIZED Revision date : 2015/12/04 Page: 7/12 Version: 5.0 ( /SDS_CPA_US/EN) Thermal decomposition: Viscosity, dynamic: Solubility in water: Evaporation rate: Other Information: 10. Stability and Reactivity carbon monoxide, carbon dioxide, nitrogen dioxide, nitrogen oxide, Hydrogen chloride, hydrogen fluoride, hydrogen bromide, halogenated hydrocarbons, Hydrocarbons Stable at ambient temperature. If product is heated above decomposition temperature toxic vapours may be released. 2.5 mpa.s ( 26 C) miscible not applicable If necessary, information on other physical and chemical parameters is indicated in this section. Reactivity No hazardous reactions if stored and handled as prescribed/indicated. Corrosion to metals: Corrosive effects to metal are not anticipated. Oxidizing properties: Not an oxidizer. Based on its structural properties the product is not classified as oxidizing. Chemical stability The product is stable if stored and handled as prescribed/indicated. Possibility of hazardous reactions The product is chemically stable. Hazardous polymerization will not occur. No hazardous reactions if stored and handled as prescribed/indicated. Conditions to avoid Avoid all sources of ignition: heat, sparks, open flame. Avoid prolonged storage. Avoid electro-static discharge. Avoid contamination. Avoid prolonged exposure to extreme heat. Avoid extreme temperatures. Incompatible materials strong oxidizing agents Hazardous decomposition products Decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated., Prolonged thermal loading can result in products of degradation being given off. Thermal decomposition: Possible thermal decomposition products: carbon monoxide, carbon dioxide, nitrogen dioxide, nitrogen oxide, Hydrogen chloride, hydrogen fluoride, hydrogen bromide, halogenated hydrocarbons, Hydrocarbons Stable at ambient temperature. If product is heated above decomposition temperature toxic vapours may be released. 11. Toxicological information Primary routes of exposure

212 Safety Data Sheet PTB PHANTOM PRESSURIZED Revision date : 2015/12/04 Page: 8/12 Version: 5.0 ( /SDS_CPA_US/EN) Routes of entry for solids and liquids are ingestion and inhalation, but may include eye or skin contact. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route of entry for liquefied gases. Acute Toxicity/Effects Acute toxicity Assessment of acute toxicity: Virtually nontoxic after a single ingestion. Virtually nontoxic by inhalation. Virtually nontoxic after a single skin contact. Oral Type of value: LD50 Species: rat (female) Value: > 5,000 mg/kg Inhalation Type of value: LC50 Species: rat (male/female) Value: > 5.2 mg/l Exposure time: 4 h Dermal Type of value: LD50 Species: rat (male/female) Value: > 5,000 mg/kg Irritation / corrosion Assessment of irritating effects: May cause slight irritation to the skin. May cause slight but temporary irritation to the eyes. Skin Species: rabbit Result: non-irritant Eye Species: rabbit Result: non-irritant Sensitization Assessment of sensitization: There is no evidence of a skin-sensitizing potential. Buehler test Species: guinea pig Result: Non-sensitizing. Chronic Toxicity/Effects Repeated dose toxicity Assessment of repeated dose toxicity: The product has not been tested. The statement has been derived from the properties of the individual components. Information on: Acetone Assessment of repeated dose toxicity: The substance may cause damage to the testes after repeated ingestion of high doses, as shown in animal studies. The substance may cause damage to the hematological system after repeated ingestion of high doses. The substance may cause damage to the kidney after repeated ingestion of high doses, as shown in animal studies

213 Safety Data Sheet PTB PHANTOM PRESSURIZED Revision date : 2015/12/04 Page: 9/12 Version: 5.0 ( /SDS_CPA_US/EN) Genetic toxicity Assessment of mutagenicity: The product has not been tested. The statement has been derived from the properties of the individual components. Mutagenicity tests revealed no genotoxic potential. Carcinogenicity Assessment of carcinogenicity: The product has not been tested. The statement has been derived from the properties of the individual components. The results of various animal studies gave no indication of a carcinogenic effect. Reproductive toxicity Assessment of reproduction toxicity: The product has not been tested. The statement has been derived from the properties of the individual components. Information on: chlorfenapyr Assessment of reproduction toxicity: The results of animal studies gave no indication of a fertility impairing effect. Information on: Acetone Assessment of reproduction toxicity: As shown in animal studies, the product may cause damage to the testes after repeated high exposures that cause other toxic effects Teratogenicity Assessment of teratogenicity: The product has not been tested. The statement has been derived from the properties of the individual components. Animal studies gave no indication of a developmental toxic effect at doses that were not toxic to the parental animals. Other Information Misuse can be harmful to health. Symptoms of Exposure No significant reaction of the human body to the product known. Medical conditions aggravated by overexposure Individuals with pre-existing diseases of the respiratory system, skin or eyes may have increased susceptibility to excessive exposures. 12. Ecological Information Toxicity Aquatic toxicity Assessment of aquatic toxicity: Very toxic (acute effect) to aquatic organisms. Toxicity to fish Information on: chlorfenapyr LC50 (96 h) mg/l, Oncorhynchus mykiss Aquatic invertebrates

214 Safety Data Sheet PTB PHANTOM PRESSURIZED Revision date : 2015/12/04 Page: 10/12 Version: 5.0 ( /SDS_CPA_US/EN) Information on: chlorfenapyr EC50 (96 h) mg/l, Mysidopsis bahia (Directive 84/449/EEC, C.2) Aquatic plants Information on: chlorfenapyr EC50 (72 h) mg/l, Desmodesmus subspicatus Assessment of terrestrial toxicity Acutely very toxic to terrestrial organisms. Additional information Other ecotoxicological advice: The ecological data given are those of the active ingredient. Do not release untreated into natural waters. 13. Disposal considerations Waste disposal of substance: Pesticide wastes are regulated. Improper disposal of excess pesticide, spray mix or rinsate is a violation of federal law. If pesticide wastes cannot be disposed of according to label instructions, contact the State Pesticide or Environmental Control Agency or the Hazardous Waste representative at the nearest EPA Regional Office for guidance. Container disposal: Consult state or local disposal authorities for approved alternative procedures such as container recycling. Do not reuse empty containers. RCRA: This product is not regulated by RCRA. 14. Transport Information Land transport USDOT Hazard class: 2.2 ID number: UN 1950 Hazard label: 2.2, EHSM Proper shipping name: AEROSOLS Sea transport IMDG Hazard class: 2.2 ID number: UN 1950 Hazard label: 2.2, EHSM Marine pollutant: YES Proper shipping name: AEROSOLS Air transport IATA/ICAO

215 Safety Data Sheet PTB PHANTOM PRESSURIZED Revision date : 2015/12/04 Page: 11/12 Version: 5.0 ( /SDS_CPA_US/EN) Hazard class: 2.2 ID number: UN 1950 Hazard label: 2.2 Proper shipping name: AEROSOLS, NON-FLAMMABLE Further information DOT: This product may be classified as ORM-D (Consumer Commodity) or Limited Quantity. After 12/31/2020, ORM-D will not apply. 15. Regulatory Information Federal Regulations Registration status: Crop Protection TSCA, US released / exempt Chemical TSCA, US blocked / not listed EPCRA 311/312 (Hazard categories): Acute; Chronic CERCLA RQ CAS Number Chemical name 5000 LBS Acetone State regulations State RTK CAS Number Chemical name PA Acetone Distillates (petroleum), hydrotreated light MA Acetone Distillates (petroleum), hydrotreated light NJ Acetone Distillates (petroleum), hydrotreated light CA Prop. 65: There are no listed chemicals in this product. NFPA Hazard codes: Health : 1 Fire: 1 Reactivity: 1 Special: Labeling requirements under FIFRA This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label. CAUTION: KEEP OUT OF REACH OF CHILDREN. KEEP OUT OF REACH OF DOMESTIC ANIMALS. Avoid contact with the skin, eyes and clothing.

216 Safety Data Sheet PTB PHANTOM PRESSURIZED Revision date : 2015/12/04 Page: 12/12 Version: 5.0 ( /SDS_CPA_US/EN) Avoid inhalation of mists/vapours. Wash thoroughly after handling. 16. Other Information SDS Prepared by: BASF NA Product Regulations SDS Prepared on: 2015/12/04 We support worldwide Responsible Care initiatives. We value the health and safety of our employees, customers, suppliers and neighbors, and the protection of the environment. Our commitment to Responsible Care is integral to conducting our business and operating our facilities in a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring the safe and environmentally sound handling of our products, and minimizing the impact of our operations on society and the environment during production, storage, transport, use and disposal of our products. IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU MAKE TESTS TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR INFORMATION SET FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE USED WITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESSLY UNDERSTAND AND AGREE THAT THE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION FURNISHED BY OUR COMPANY HEREUNDER ARE GIVEN GRATIS AND WE ASSUME NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DESIGNS, DATA AND INFORMATION GIVEN OR RESULTS OBTAINED, ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK. END OF DATA SHEET

217 Return to Index... SAFETY DATA SHEET PURGEÒ III INSECTICIDE SDS # : 6586-A Revision date: Format: NA Version 1 1. PRODUCT AND COMPANY IDENTIFICATION Product Identifier Product Name PURGEÒ III INSECTICIDE Other means of identification Product Code(s) 6586-A Synonyms Active Ingredient(s) PIPERONYL BUTOXIDE: Butylcarbityl(6-propylpiperonyl) ether, 1,3-Benzodioxole, 5-[[2-(2-butoxyethoxy)ethoxy]methyl]-6-propyl-; N-OCTYL BICYCLOHEPTENE DICARBOXIMIDE: N-(2-ethylhexyl)-5-norbornene-2,3-dicarboximide; N-(2-ethylhexyl)-8,9,10-trinorborn-5-ene-2,3-dicarboximide; Pyrethrins Piperonyl Butoxide, n-octyl bicycloheptene dicarboximide, Pyrethrins Recommended use of the chemical and restrictions on use Recommended Use: Restrictions on Use: Manufacturer Address Emergency telephone number Insecticide Use as recommended by the label FMC Corporation 1735 Market Street Philadelphia, PA (215) (General Information) msdsinfo@fmc.com ( General Information) For leak, fire, spill or accident emergencies, call: / (CHEMTREC - U.S.A.) / (CHEMTREC - Collect - All Other Countries) Medical Emergencies: / (PROSAR - U.S.A. & Canada) / (PROSAR - All Other Countries - Collect) 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR ) Acute toxicity - Inhalation (Dusts/Mists) Category 4 Aspiration toxicity Category 1 Flammable Aerosols Category 2 Gases Under Pressure Compressed Gas GHS Label elements, including precautionary statements Page 1 / 9

218 PURGEÒ III INSECTICIDE SDS # : 6586-A Revision date: Version 1 Danger EMERGENCY OVERVIEW Hazard Statements H304 - May be fatal if swallowed and enters airways H332 - Harmful if inhaled Physical Hazards H223 - Flammable aerosol H280 - Contains gas under pressure; may explode if heated Precautionary Statements - Prevention P261 - Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking P211 - Do not spray on an open flame or other ignition source P251 - Do not pierce or burn, even after use P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P312 - Call a POISON CENTER or doctor if you feel unwell P301 + P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor P331 - Do NOT induce vomiting Precautionary Statements - Storage P405 - Store locked up P410 + P403 - Protect from sunlight. Store in a well-ventilated place P412 - Do not expose to temperatures exceeding 50 C/ 122 F Precautionary Statements - Disposal P501 - Dispose of contents/ container to an approved waste disposal plant Hazards not otherwise classified (HNOC) No hazards not otherwise classified were identified. Other Information No information available. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical name CAS-No Weight % Piperonyl butoxide n-octyl bicycloheptene dicarboximide Pyrethrins ,1-Difluoroethane Petroleum distillates, hydrotreated light Petroleum gases, liquified, sweetened Synonyms are provided in Section FIRST AID MEASURES Page 2 / 9

219 PURGEÒ III INSECTICIDE Eye Contact SDS # : 6586-A Revision date: Version 1 Hold eyes open and rinse slowly and gently with water for 15 to 20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for further treatment advice. Skin Contact Take off contaminated clothing. Rinse skin immediately with plenty of water for minutes. Call a poison control center or doctor for further treatment advice. Inhalation Ingestion Most important symptoms and effects, both acute and delayed Indication of immediate medical attention and special treatment needed, if necessary Move to fresh air. If person is not breathing, call 911 (within the U.S. and Canada) or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or doctor for further treatment advice. Immediately call a poison control center or doctor. Do not induce vomiting unless told to do so by a poison control center or doctor. Do not give any liquid to the person. Do not induce vomiting or give anything by mouth to an unconscious person. Central nervous system effects. Contains petroleum distillate. Vomiting may cause aspiration pneumonia. Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Specific Hazards Arising from the Chemical Explosion data Sensitivity to Mechanical Impact Sensitivity to Static Discharge Protective equipment and precautions for firefighters Foam. Carbon dioxide (CO2). Dry chemical. Water spray. Contents under pressure. Not sensitive. Not sensitive. Isolate fire area. Evaluate downwind. In the event of fire, wear self contained breathing apparatus. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Isolate and post spill area. Remove all sources of ignition. Ventilate the area. Wear suitable protective clothing, gloves and eye/face protection. For personal protection see section 8. If ventilation is not possible wear full protection suit and chemical protective equipment. Other For further clean-up instructions, call FMC Emergency Hotline number listed in Section 1 "Product and Company Identification" above. Environmental Precautions Methods for Containment Methods for cleaning up Keep people and animals away from and upwind of spill/leak. Keep material out of lakes, streams, ponds, and sewer drains. Prevent further leakage or spillage if safe to do so. Transfer damaged cartridges or cans to containers for later disposal. Clean and neutralize spill area, tools and equipment by washing with bleach water and soap. Waste must be classified and labeled prior to recycling or disposal. Dispose of waste as indicated in Section 13. Rinsate may be disposed at a waste water treatment plant. 7. HANDLING AND STORAGE Handling Do not contaminate other pesticides, fertilizers, water, food, or feed by storage or disposal. BEWARE: Aerosol is pressurized. Keep away from direct sun exposure and temperatures over 130 F. Do not open by force or throw into fire even after use. Do not spray on flames or red-hot objects. Page 3 / 9

220 PURGEÒ III INSECTICIDE Storage Incompatible products SDS # : 6586-A Revision date: Version 1 Keep in a dry, cool and well-ventilated place. Keep away from open flames, hot surfaces and sources of ignition. Keep out of reach of children and animals. Keep/store only in original container. Strong oxidizing agents. Bases. Powdered earth metals. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Chemical name ACGIH TLV OSHA PEL NIOSH Mexico Pyrethrins TWA: 5 mg/m 3 TWA: 5 mg/m 3 IDLH: 5000 mg/m 3 TWA: 5 mg/m 3 Mexico: TWA 5 mg/m 3 Mexico: STEL 10 mg/m 3 Chemical name British Columbia Quebec Ontario TWAEV Alberta Pyrethrins TWA: 5 mg/m 3 TWA: 5 mg/m 3 TWA: 5 mg/m 3 TWA: 5 mg/m Petroleum distillates, hydrotreated light TWA: 200 mg/m 3 Skin Appropriate engineering controls Engineering measures Apply technical measures to comply with the occupational exposure limits. When working in confined spaces (tanks, containers, etc.), ensure that there is a supply of air suitable for breathing and wear the recommended equipment. Individual protection measures, such as personal protective equipment Eye/Face Protection Skin and Body Protection Hand Protection Respiratory Protection Hygiene measures General information If there is a potential for exposure to particles which could cause eye discomfort, wear chemical goggles. Wear long-sleeved shirt, long pants, socks, and shoes. Rubber/latex/neoprene or other suitable chemical resistant gloves. If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Respiratory protection must be provided in accordance with current local regulations. Clean water should be available for washing in case of eye or skin contamination. Wash skin prior to eating, drinking, chewing gum or using tobacco. Shower or bathe at the end of working. Remove and wash contaminated clothing before re-use. Launder work clothing separately from regular household laundry. If the product is used in mixtures, it is recommended that you contact the appropriate protective equipment suppliers These recommendations apply to the product as supplied Information on basic physical and chemical properties 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Physical State Color Odor Odor threshold ph Melting point/freezing point Boiling Point/Range Flash point Evaporation Rate Flammability (solid, gas) Clear, Aerosolized liquid Liquid Aerosol Clear No information available No information available No information available Not applicable No information available > 85 C / > 185 F (8-inch Flame Extension) No information available No information available Page 4 / 9

221 PURGEÒ III INSECTICIDE Flammability Limit in Air Upper flammability limit: Lower flammability limit: Vapor pressure Vapor density Density Specific gravity Water solubility Solubility in other solvents Partition coefficient Autoignition temperature Decomposition temperature Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidizing properties Molecular weight Bulk density Reactivity Chemical Stability No information available No information available No information available No information available 6.9 lb/gal No information available No information available No information available No information available No information available No information available No information available No information available No information available No information available No information available No information available 10. STABILITY AND REACTIVITY None under normal use conditions. Stable under recommended storage conditions. SDS # : 6586-A Revision date: Version 1 Possibility of Hazardous Reactions None under normal processing. Hazardous polymerization Conditions to avoid Incompatible materials Hazardous polymerization does not occur. Keep away from open flames, hot surfaces and sources of ignition. Strong oxidizing agents. Bases. Powdered earth metals. Hazardous Decomposition Products Carbon oxides (COx), Hydrogen fluoride, Carbonyl fluoride. Product Information LD50 Oral 2140 mg/kg (rat) LD50 Dermal > 2000 mg/kg (rabbit) LC50 Inhalation 2.5 mg/l (rat) 11. TOXICOLOGICAL INFORMATION Eye Contact Skin Contact Sensitization Slightly or non-irritating (rabbit) Slightly or non-irritating (rabbit) Non-sensitizing Information on toxicological effects Symptoms Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal. Delayed and immediate effects as well as chronic effects from short and long-term exposure Mutagenicity Carcinogenicity Reproductive toxicity STOT - single exposure STOT - repeated exposure Piperonyl butoxide ether may affect mammalian liver microsomal detoxification enzymes. n-octyl bicycloheptene dicarboximide was negative in a chromosome aberration assay, Not recognized as carcinogenic by Research Agencies (IARC, NTP, OSHA, ACGIH). No information available. Not classified. Not classified. Page 5 / 9

222 PURGEÒ III INSECTICIDE SDS # : 6586-A Revision date: Version 1 Target organ effects Mice fed 0.3 or 0.9% piperonyl butoxide in the diet for 20 days had increased liver weight and other signs of liver toxicity. Male rats given up to 2.4% of piperonyl butoxide in the diet for up to 12 weeks had clinical and histologic signs of liver damage; the highest dose group showed preneoplastic changes, including enlargement of hepatocyte nuclei and multinucleated cells. Kidney damage was also seen. Aspiration hazard Potential for aspiration if swallowed. May be fatal if swallowed and enters airways. Chemical name ACGIH IARC NTP OSHA Piperonyl butoxide Group 3 Ecotoxicity 12. ECOLOGICAL INFORMATION Piperonyl butoxide ( ) Active Ingredient(s) Duration Species Value Units Piperonyl Butoxide LC50 Fish 3.94 ppm LD50 Bee 25 µg/bee LD50 Bobwhite quail >2250 mg/kg LD50 Mallard duck >5620 ppm Persistence and degradability Bioaccumulation No information available. No information available. 13. DISPOSAL CONSIDERATIONS Waste disposal methods Contaminated Packaging Improper disposal of excess pesticide, spray mixture, or rinsate is prohibited. If these wastes cannot be disposed of by use according to label instructions, contact appropriate disposal authorities for guidance. Containers must be disposed of in accordance with local, state and federal regulations. Refer to the product label for container disposal instructions. 14. TRANSPORT INFORMATION DOT Packaging Type Proper Shipping Name Hazard class USDOT is requiring that products formerly classified as "Consumer Commodity, ORM-D" transition to "Limited Quantity" by 12/31/2020. During the transition period the 49CFR carton shipping marks may be Consumer Commodity (old) or Limited Quantity Diamond (new). Please prepare shipping documents to match the carton mark. 7.3 oz Containers Consumer commodity ORM-D TDG UN/ID no UN1950 Proper Shipping Name Aerosols Hazard class 2.1 Description UN1950, Aerosols (1-1-Difluroethane, Isopropyl alcohol), 2.1 ICAO/IATA UN/ID no ID8000 Proper Shipping Name Consumer commodity Hazard class 9 IMDG/IMO UN/ID no UN1950 Page 6 / 9

223 PURGEÒ III INSECTICIDE Proper Shipping Name Aerosols Hazard class 2.1 EmS No. F-D, S-U Description UN1950, Aerosols (1-1-Difluoroethane, Isopropyl alcohol), 2.1 SDS # : 6586-A Revision date: Version 1 U.S. Federal Regulations 15. REGULATORY INFORMATION SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372: Chemical name CAS-No Weight % SARA Threshold Values % Piperonyl butoxide SARA 311/312 Hazard Categories Acute health hazard Chronic health hazard Fire hazard Sudden release of pressure hazard Reactive Hazard Yes Yes Yes No No Clean Water Act This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR and 40 CFR ): Chemical name Pyrethrins CWA - Reportable Quantities 1 lb CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302): Chemical name Hazardous Substances RQs Extremely Hazardous RQ Substances RQs Pyrethrins lb RQ 1 lb final RQ RQ kg final RQ FIFRA Information This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: CAUTION Contains petroleum distilliate. Harmful if absorbed through the skin. US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Page 7 / 9

224 PURGEÒ III INSECTICIDE SDS # : 6586-A Revision date: Version 1 Chemical name New Jersey Massachusetts Pennsylvania Piperonyl butoxide X Pyrethrins X X X ,1-Difluoroethane X X International Inventories Component Piperonyl butoxide ( 1.95 ) n-octyl bicycloheptene dicarboximide ( 3.05 ) Pyrethrins ( ) 1,1-Difluoroethane ( ) Petroleum distillates, hydrotreated light ( ) Petroleum gases, liquified, sweetened ( ) TSCA (United States) DSL (Canada) EINECS/ELI NCS (Europe) ENCS (Japan) China (IECSC) KECL (Korea) PICCS (Philippines) AICS (Australia) X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X Mexico - Grade Moderate risk, Grade 2 CANADA WHMIS Hazard Class A - Compressed gases B5 - Flammable aerosol D2B - Toxic materials 16. OTHER INFORMATION NFPA Health Hazards 2 Flammability 3 Instability 0 Special Hazards - HMIS Health Hazards 2 Flammability 3 Physical hazard 0 Personal Protection X Revision date: Revision note Format Change Page 8 / 9

225 PURGEÒ III INSECTICIDE SDS # : 6586-A Revision date: Version 1 Disclaimer FMC Corporation believes that the information and recommendations contained herein (including data and statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information provided herein relates only to the specified product designated and may not be applicable where such product is used in combination with any other materials or in any process. Use of this product is regulated by the U.S. Environmental Protection Agency (EPA). It is a violation of Federal law to use this product in a manner inconsistent with its labeling. Further, since the conditions and methods of use are beyond the control of FMC Corporation, FMC corporation expressly disclaims any and all liability as to any results obtained or arising from any use of the products or reliance on such information. Prepared By: FMC Corporation FMC Logo - Trademark of FMC Corporation 2015 FMC Corporation. All Rights Reserved. End of Safety Data Sheet Page 9 / 9

226 Return to Index... SAFETY DATA SHEET Pyrethrin Fogger SDS # : 6597-A Revision date: Format: NA Version PRODUCT AND COMPANY IDENTIFICATION Product Identifier Product Name Pyrethrin Fogger Other means of identification Product Code(s) 6597-A Synonyms Active Ingredient(s) Chemical Family (Z)-(S)-2-methyl-4-oxo-3-(penta-2,4-dienyl)cyclopent-2-enyl (1R,3R)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropanecarboxylate 5-[2-(2-butoxyethoxy)ethoxymethyl]-6-propyl-1,3-benzodioxole; 5-[[2-(2-butoxyethoxy)ethoxy]methyl]-6-propyl-1,3-benzodioxole N-(2-ethylhexyl)-8,9,10-trinorborn-5-ene-2,3-dicarboximide; 2-(2-ethylhexyl)-3a,4,7,7a-tetrahydro-4,7-methano-1H-isoindole-1,3(2H)-dione Pyrethrins, Piperonyl Butoxide, n-octyl bicycloheptene dicarboximide (MGK264) Pyrethrins Recommended use of the chemical and restrictions on use Recommended Use: Restrictions on Use: Manufacturer Address Emergency telephone number Insecticide Use as recommended by the label FMC Corporation 1735 Market Street Philadelphia, PA (215) (General Information) msdsinfo@fmc.com ( General Information) For leak, fire, spill or accident emergencies, call: / (CHEMTREC - U.S.A.) / (CHEMTREC - Collect - All Other Countries) Medical Emergencies: / (PROSAR - U.S.A. & Canada) / (PROSAR - All Other Countries - Collect) 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR ) Acute toxicity - Inhalation (Dusts/Mists) Category 4 Page 1 / 9

227 Pyrethrin Fogger SDS # : 6597-A Revision date: Version 1.01 Skin sensitization Category 1 Flammable Aerosols Category 1 GHS Label elements, including precautionary statements Danger EMERGENCY OVERVIEW Hazard Statements H317 - May cause an allergic skin reaction H332 - Harmful if inhaled Physical Hazards H222 - Extremely flammable aerosol H229 - Pressurized container: May burst if heated Precautionary Statements - Prevention P261 - Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray P272 - Contaminated work clothing should not be allowed out of the workplace P280 - Wear protective gloves P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking P211 - Do not spray on an open flame or other ignition source P251 - Do not pierce or burn, even after use P302 + P352 - IF ON SKIN: Wash with plenty of water and soap P333 + P313 - If skin irritation or rash occurs: Get medical advice/ attention P363 - Wash contaminated clothing before reuse P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P312 - Call a POISON CENTER or doctor if you feel unwell Precautionary Statements - Storage P410 + P412 - Protect from sunlight. Do not expose to temperatures exceeding 50 C/ 122 F Precautionary Statements - Disposal P501 - Dispose of contents/ container to an approved waste disposal plant Hazards not otherwise classified (HNOC) No hazards not otherwise classified were identified. Other Information No information available 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Family Pyrethrins. Chemical name CAS-No Weight % n-octyl bicycloheptene dicarboximide Piperonyl butoxide Pyrethrins Propane Butane Petroleum distillates, hydrotreated light Isobutane Page 2 / 9

228 Pyrethrin Fogger SDS # : 6597-A Revision date: Version 1.01 Synonyms are provided in Section FIRST AID MEASURES Eye Contact Hold eyes open and rinse slowly and gently with water for 15 to 20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for further treatment advice. Skin Contact Take off contaminated clothing. Rinse skin immediately with plenty of water for minutes. Call a poison control center or doctor for further treatment advice. Inhalation Ingestion Most important symptoms and effects, both acute and delayed Indication of immediate medical attention and special treatment needed, if necessary Move to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or doctor for further treatment advice. Immediately call a poison control center or doctor. Do not induce vomiting unless told to do so by a poison control center or doctor. Do not give any liquid to the person. Do not induce vomiting or give anything by mouth to an unconscious person. None known. Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Specific Hazards Arising from the Chemical Explosion data Sensitivity to Mechanical Impact Sensitivity to Static Discharge Protective equipment and precautions for firefighters Foam. Carbon dioxide (CO2). Dry chemical. Water spray. Contents under pressure. Not sensitive. Not sensitive. Isolate fire area. Evaluate downwind. In the event of fire, wear self contained breathing apparatus. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Isolate and post spill area. Remove all sources of ignition. Ventilate the area. Wear suitable protective clothing, gloves and eye/face protection. For personal protection see section 8. If ventilation is not possible wear full protection suit and chemical protective equipment. Other For further clean-up instructions, call FMC Emergency Hotline number listed in Section 1 "Product and Company Identification" above. Environmental Precautions Methods for Containment Methods for cleaning up See Section 12 for additional Ecological Information. Prevent further leakage or spillage if safe to do so. Transfer damaged cartridges or cans to containers for later disposal. Clean and neutralize spill area, tools and equipment by washing with bleach water and soap. Waste must be classified and labeled prior to recycling or disposal. Dispose of waste as indicated in Section 13. Rinsate may be disposed at a waste water treatment plant. 7. HANDLING AND STORAGE Page 3 / 9

229 Pyrethrin Fogger Handling Storage Incompatible products SDS # : 6597-A Revision date: Version 1.01 Do not contaminate other pesticides, fertilizers, water, food, or feed by storage or disposal. BEWARE: Aerosol is pressurized. Keep away from direct sun exposure and temperatures over 130 F. Do not open by force or throw into fire even after use. Do not spray on flames or red-hot objects. Keep in a dry, cool and well-ventilated place. Keep away from open flames, hot surfaces and sources of ignition. Keep out of reach of children and animals. Keep/store only in original container. Strong oxidizing agents. Bases. Powdered earth metals. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Chemical name ACGIH TLV OSHA PEL NIOSH Mexico Pyrethrins TWA: 5 mg/m 3 TWA: 5 mg/m 3 IDLH: 5000 mg/m 3 TWA: 5 mg/m 3 Mexico: TWA 5 mg/m 3 Mexico: STEL 10 mg/m 3 Propane TWA: 1000 ppm TWA: 1000 ppm IDLH: 2100 ppm TWA: 1800 mg/m 3 TWA: 1000 ppm TWA: 1800 mg/m 3 Isobutane STEL 1000 ppm - TWA: 800 ppm TWA: 1900 mg/m 3 Chemical name British Columbia Quebec Ontario TWAEV Alberta Pyrethrins TWA: 5 mg/m 3 TWA: 5 mg/m 3 TWA: 5 mg/m 3 TWA: 5 mg/m 3 Propane Petroleum distillates, hydrotreated light Isobutane TWA: 1000 ppm TWA: 200 mg/m 3 Skin TWA: 1000 ppm TWA: 1000 ppm TWA: 1000 ppm TWA: 1800 mg/m TWA: 1000 ppm - TWA: 800 ppm TWA: 1000 ppm Appropriate engineering controls - Engineering measures Apply technical measures to comply with the occupational exposure limits. When working in confined spaces (tanks, containers, etc.), ensure that there is a supply of air suitable for breathing and wear the recommended equipment. Individual protection measures, such as personal protective equipment Eye/Face Protection Skin and Body Protection Hand Protection Respiratory Protection Hygiene measures General information If there is a potential for exposure to particles which could cause eye discomfort, wear chemical goggles. Wear long-sleeved shirt, long pants, socks, and shoes. Protective gloves If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Respiratory protection must be provided in accordance with current local regulations. Clean water should be available for washing in case of eye or skin contamination. Wash skin prior to eating, drinking, chewing gum or using tobacco. Shower or bathe at the end of working. Remove and wash contaminated clothing before re-use. Launder work clothing separately from regular household laundry. If the product is used in mixtures, it is recommended that you contact the appropriate protective equipment suppliers These recommendations apply to the product as supplied Page 4 / 9

230 Pyrethrin Fogger 9. PHYSICAL AND CHEMICAL PROPERTIES SDS # : 6597-A Revision date: Version 1.01 Information on basic physical and chemical properties Appearance No information available Physical State Aerosol Color No information available Odor Slight Pyrethrins Odor threshold No information available ph 7.0 Melting point/freezing point Not applicable Boiling Point/Range No information available Flash point C / F Evaporation Rate No information available Flammability (solid, gas) No information available Flammability Limit in Air Upper flammability limit: No information available Lower flammability limit: No information available Vapor pressure No information available Vapor density No information available Density 8 lb/gal Specific gravity No information available Water solubility Soluble in water Solubility in other solvents No information available Partition coefficient No information available Autoignition temperature No information available Decomposition temperature No information available Viscosity, kinematic No information available Viscosity, dynamic No information available Explosive properties No information available Oxidizing properties No information available Molecular weight No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity Chemical Stability Not applicable Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous polymerization Conditions to avoid Incompatible materials Hazardous polymerization does not occur. Keep away from open flames, hot surfaces and sources of ignition Strong oxidizing agents. Bases. Powdered earth metals. Hazardous Decomposition Products Carbon dioxide (CO2). Carbon monoxide (CO). Product Information LD50 Oral > 5000 mg/kg LD50 Dermal > 5000 mg/kg LC50 Inhalation > 2.11 mg/l 4 hr 11. TOXICOLOGICAL INFORMATION Serious eye damage/eye irritation Skin corrosion/irritation Sensitization Slightly or non-irritating (rabbit). Slightly or non-irritating (rabbit). Sensitizer. Page 5 / 9

231 Pyrethrin Fogger Information on toxicological effects Symptoms SDS # : 6597-A Revision date: Version 1.01 Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal. Delayed and immediate effects as well as chronic effects from short and long-term exposure Mutagenicity Piperonyl butoxide ether may affect mammalian liver microsomal detoxification enzymes. n-octyl bicycloheptene dicarboximide was negative in a chromosome aberration assay,. Carcinogenicity Not recognized as carcinogenic by Research Agencies (IARC, NTP, OSHA, ACGIH). Reproductive toxicity No information available. STOT - single exposure Not classified. STOT - repeated exposure Not classified. Target organ effects Mice fed 0.3 or 0.9% piperonyl butoxide in the diet for 20 days had increased liver weight and other signs of liver toxicity. Male rats given up to 2.4% of piperonyl butoxide in the diet for up to 12 weeks had clinical and histologic signs of liver damage; the highest dose group showed preneoplastic changes, including enlargement of hepatocyte nuclei and multinucleated cells. Kidney damage was also seen. Aspiration hazard No information available. Chemical name ACGIH IARC NTP OSHA Piperonyl butoxide Group 3 Ecotoxicity 12. ECOLOGICAL INFORMATION Piperonyl butoxide ( ) Active Ingredient(s) Duration Species Value Units Piperonyl Butoxide LC50 Fish 3.94 ppm LD50 Bee 25 µg/bee LD50 Bobwhite quail >2250 mg/kg LD50 Mallard duck >5620 ppm Persistence and degradability Bioaccumulation No information available. No information available. 13. DISPOSAL CONSIDERATIONS Waste disposal methods Contaminated Packaging Improper disposal of excess pesticide, spray mixture, or rinsate is prohibited. If these wastes cannot be disposed of by use according to label instructions, contact appropriate disposal authorities for guidance. Containers must be disposed of in accordance with local, state and federal regulations. Refer to the product label for container disposal instructions. 14. TRANSPORT INFORMATION DOT Proper Shipping Name Hazard class TDG USDOT is requiring that products formerly classified as "Consumer Commodity, ORM-D" transition to "Limited Quantity" by 12/31/2020. During the transition period the 49CFR carton shipping marks may be Consumer Commodity (old) or Limited Quantity Diamond (new). Please prepare shipping documents to match the carton mark. Consumer commodity ORM-D Page 6 / 9

232 Pyrethrin Fogger UN/ID no UN1950 Proper Shipping Name Aerosols Hazard class 2.1 Description UN1950, Aerosols, 2.1 SDS # : 6597-A Revision date: Version 1.01 ICAO/IATA UN/ID no ID8000 Proper Shipping Name Consumer commodity Hazard class 9 IMDG/IMO UN/ID no UN1950 Proper Shipping Name Aerosols Hazard class 2 EmS No. F-D, S-U Description UN1950, Aerosols, 2.1 U.S. Federal Regulations 15. REGULATORY INFORMATION SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372: Chemical name CAS-No Weight % SARA Threshold Values % Piperonyl butoxide SARA 311/312 Hazard Categories Acute health hazard Chronic health hazard Fire hazard Sudden release of pressure hazard Reactive Hazard Yes Yes No No No Clean Water Act This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR and 40 CFR ): Chemical name Pyrethrins CWA - Reportable Quantities 1 lb CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302): Chemical name Hazardous Substances RQs Extremely Hazardous RQ Substances RQs Pyrethrins lb RQ 1 lb final RQ RQ kg final RQ FIFRA Information This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: CAUTION Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals. Page 7 / 9

233 Pyrethrin Fogger US State Regulations SDS # : 6597-A Revision date: Version 1.01 California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical name New Jersey Massachusetts Pennsylvania Piperonyl butoxide X Pyrethrins X X X Propane X X X Isobutane X X X International Inventories Component n-octyl bicycloheptene dicarboximide ( 1.0 ) Piperonyl butoxide ( 1.0 ) Pyrethrins ( 0.5 ) Propane ( ) Petroleum distillates, hydrotreated light ( 5-10 ) Isobutane ( 5-10 ) TSCA (United States) DSL (Canada) EINECS/ELI NCS (Europe) ENCS (Japan) China (IECSC) KECL (Korea) PICCS (Philippines) AICS (Australia) X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X WHMIS Hazard Class A - Compressed gases B5 - Flammable aerosol 16. OTHER INFORMATION NFPA Health Hazards 1 Flammability 4 Instability 0 Special Hazards - HMIS Health Hazards 1* Flammability 4 Physical hazard 0 Personal Protection X NFPA/HMIS Ratings Legend * - Chronic hazard Revision date: Revision note Format Change Page 8 / 9

234 Pyrethrin Fogger SDS # : 6597-A Revision date: Version 1.01 Disclaimer FMC Corporation believes that the information and recommendations contained herein (including data and statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information provided herein relates only to the specified product designated and may not be applicable where such product is used in combination with any other materials or in any process. Use of this product is regulated by the U.S. Environmental Protection Agency (EPA). It is a violation of Federal law to use this product in a manner inconsistent with its labeling. Further, since the conditions and methods of use are beyond the control of FMC Corporation, FMC corporation expressly disclaims any and all liability as to any results obtained or arising from any use of the products or reliance on such information. Prepared By: FMC Corporation FMC Logo - Trademark of FMC Corporation 2015 FMC Corporation. All Rights Reserved. End of Safety Data Sheet Page 9 / 9

235 Page 1 of 8 SAFETY DATA SHEET (GHS) Return to Index... Date Issued : 10/6/2015 MSDS No : PYROCIDE300 Date-Revised : 10/6/2015 Revision No : 1 PYROCIDE PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: PYROCIDE 300 PRODUCT DESCRIPTION: An Insecticide for Indoor Use as a ULV, Space, Area, Contact Spray, or Thermal Fog. PRODUCT CODE: 5628, EPA REG. NO. : ACTIVE INGREDIENT(S): Pyrethrins; Piperonyl Butoxide; MGK -264 (N-Octyl Bicycloheptene Dicarboximide) MANUFACTURER McLaughlin Gormley King Company th Avenue North Minneapolis, MN Emergency Phone: 1(888) Alternate Emergency Phone: 1(952) Product Stewardship: 1(800) mgk-sds@mgk.com COMMENTS: MGK Hours of operation are 8:00 am to 4:30 pm CST, 14:00 to 22:30 GMT. 24 HR. EMERGENCY TELEPHONE NUMBERS FOR TRANSPORTATION: CHEMTREC U.S. and CANADA:1(800) CHEMTREC All Other Areas:1(703) For MEDICAL EMERGENCIES or PESTICIDE INCIDENTS, call 24 hours a day to or outside of the U.S.A. 2. HAZARDS IDENTIFICATION GHS CLASSIFICATIONS Health: Skin Sensitization, Category 1 Aspiration Hazard, Category 1 Environmental: Acute Hazards to the Aquatic Environment, Category 1 Chronic Hazards to the Aquatic Environment, Category 1 Physical: Flammable Liquids, Category 4 GHS LABEL Exclamation mark (GHS 07) Health hazard (GHS 08) SIGNAL WORD: DANGER HAZARD STATEMENTS Environment (GHS 09) H304: May be fatal if swallowed and enters airways. H317: May cause an allergic skin reaction. H400: Very toxic to aquatic life.

236 Page 2 of 8 SAFETY DATA SHEET (GHS) Date Issued : 10/6/2015 MSDS No : PYROCIDE300 Date-Revised : 10/6/2015 Revision No : 1 H410: Very toxic to aquatic life with long lasting effects. H227: Combustible liquid. PRECAUTIONARY STATEMENT(S) Prevention: PYROCIDE 300 P202: Do not handle until all safety precautions have been read and understood. P210: Keep away from heat/sparks/open flames/hot surfaces. No smoking. P240: Ground/bond container and receiving equipment. P241: Use explosion-proof electrical/ventilating/lighting equipment. P243: Take precautionary measures against static discharge. P264: Wash hands, face, and any exposed skin thoroughly after handling. P272: Contaminated work clothing should not be allowed out of the workplace. P280: Wear protective gloves/protective clothing/eye protection/face protection. Response: P321: Specific treatment (see Section 4/ First Aid). P302+P352: IF ON SKIN: Wash with plenty of soap and water. P333+P313: If skin irritation or rash occurs: Get medical advice/attention. P362: Take off contaminated clothing and wash before reuse. P301+P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P331: Do NOT induce vomiting. P370+P378: In case of fire: Use CO2, dry chemical, or foam for extinction. Storage: P405: Store locked up. P404: Store in a closed container. P403+P235: Store in a well-ventilated place. Keep cool. Disposal: P501: Dispose of contents/container to an approved waste disposal plant. COMMENTS: This material is considered hazardous by the 2012 OSHA Hazard Communication Standard [29 CFR ], and the G.H.S. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name Wt.% CAS Pyrethrins Piperonyl Butoxide MGK -264 (N-Octyl Bicycloheptene Dicarboximide) Petroleum Distillates COMMENTS: Ingredients not identified are proprietary or non-hazardous. Values are not product specifications. 4. FIRST AID MEASURES EYES: Hold eye open and rinse slowly and gently with water for minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. SKIN: Take off contaminated clothing. Rinse skin immediately with plenty of water for minutes. Call a poison control center

237 Page 3 of 8 SAFETY DATA SHEET (GHS) Date Issued : 10/6/2015 MSDS No : PYROCIDE300 Date-Revised : 10/6/2015 Revision No : 1 or doctor for treatment advice. PYROCIDE 300 INGESTION: If swallowed, IMMEDIATELY call a poison control center or doctor for treatment advice. DO NOT give any liquid to the person. Do not induce vomiting unless told to do so by a poison contol center or a doctor. Never give anything by mouth to an unconscious person. INHALATION: Remove affected person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or doctor for further treatment advice. NOTES TO PHYSICIAN: Contains Pyrethrins and Petroleum Distillates-vomiting may pose an aspiration pneumonia hazard. For skin effects, a highly efficient therapeutic agent for Pyrethrin exposure is topical application of Tocopherol Acetate (Vitamin E). 5. FIRE FIGHTING MEASURES FLAMMABLE CLASS: OSHA-COMBUSTIBLE LIQUID EXTINGUISHING MEDIA: Foam, carbon dioxide or dry chemical. HAZARDOUS COMBUSTION PRODUCTS: Under fire conditions this product will support combustion and may decompose to give off toxic gases such as carbon monoxide, carbon dioxide, and nitrogen oxides. FIRE FIGHTING PROCEDURES: Treat as an oil fire. Use a full-faced self-contained breathing apparatus along with full protective gear. Keep nearby containers and equipment cool with a water stream. SENSITIVE TO STATIC DISCHARGE: Yes, use proper bonding and/or grounding procedures. 6. ACCIDENTAL RELEASE MEASURES SMALL SPILL: Shut off ignition sources. Stop release, if possible without risk. Dike or contain release, if possible, and if immediate response can prevent further damage or danger. Isolate and control access to the release area. Take actions to reduce vapors. Absorb with appropriate absorbent. Clean spill area of residues and absorbent. LARGE SPILL: Shut off ignition sources. Stop release, if possible without risk. Dike or contain release, if possible, and if immediate response can prevent further damage or danger. Isolate and control access to the release area. Take actions to reduce vapors. Collect product into drums, etc. via drains, pumps, etc. Absorb with appropriate absorbent. Clean spill area of residues and absorbent. ENVIRONMENTAL PRECAUTIONS WATER SPILL: Contains Pyrethrins, which are toxic to fish and other aquatic invertebrates. Contaminated absorbent and wash water should be disposed of according to local, state, and federal regulations. 7. HANDLING AND STORAGE GENERAL PROCEDURES: Do not use or store near heat, sparks, open flame, or any other ignition sources. HANDLING: Mixers, loaders, and other handlers: Wear a long-sleeved shirt and long pants, shoes and socks. Wear chemical-resistant gloves such as Barrier Laminate, Neoprene Rubber, Nitrile Rubber, or Viton. Applicators using a high-pressure hand-wand in an enclosed-area must also wear the following additional PPE: A MSHA/ NIOSH-approved respirator with a dust/ mist filter with MSHA/ NIOSH approval number prefix TC-21C, or any R, P or HE filter.

238 Page 4 of 8 SAFETY DATA SHEET (GHS) Date Issued : 10/6/2015 MSDS No : PYROCIDE300 Date-Revised : 10/6/2015 Revision No : 1 PYROCIDE 300 Applicators using hand-held foggers in an enclosed-area must also wear the following additional PPE: Wear a MSHA/ NIOSH-approved respirator, such as a half-face, full-face, or hood-style NIOSH-approved respirator with a dust/ mist filtering cartridge (MSHA/ NIOSH approval number prefix TC-21C), or a canister approved for pesticides (MSHA/ NIOSH approval number prefix TC-14G), or a cartridge or canister with any N, R, P or HE filter. Do not contaminate water, food or feedstuffs by storage, handling, or disposal. READ AND OBSERVE ALL PRECAUTIONS AND INSTRUCTIONS ON THE PRODUCT LABEL. STORAGE: Store in a cool, dry, well-ventilated place. Keep container closed. Do not use or store near heat, sparks, open flame, any ignition sources, or near strong acids, bases, and oxidizers. Always store pesticides in the original container. Store away from food and pet-food. KEEP OUT OF REACH OF CHILDREN. ELECTROSTATIC ACCUMULATION HAZARD: This product contains petroleum distillates for which there is potential for the accumulation of static electricity. Consideration should be given to bonding and grounding of equipment during loading, unloading, and transfer of this product. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE GUIDELINES OSHA HAZARDOUS COMPONENTS (29 CFR ) EXPOSURE LIMITS OSHA PEL ACGIH TLV SupplierOEL Chemical Name ppm mg/m 3 ppm mg/m 3 ppm mg/m 3 Pyrethrins TWA 5 5 Piperonyl Butoxide TWA None None None MGK -264 (N-Octyl Bicycloheptene Dicarboximide) TWA None None None Petroleum Distillates TWA None None 152 [1] 1200 [1] OSHA TABLE COMMENTS: 1. Based on total hydrocarbon composition. ENGINEERING CONTROLS: Ventilate treatment area thoroughly before re-entry. PERSONAL PROTECTIVE EQUIPMENT EYES AND FACE: Take prudent precautions to avoid contact with eyes. SKIN: Wear chemical-resistant gloves such as Barrier Laminate, Neoprene Rubber, Nitrile Rubber, or Viton, and wear protective clothing. RESPIRATORY: Applicators using a high-pressure hand-wand in an enclosed-area must also wear the following additional PPE: A MSHA/ NIOSH-approved respirator with a dust/ mist filter with MSHA/ NIOSH approval number prefix TC-21C, or any N, R, P or HE filter. Applicators using hand-held foggers in an enclosed-area must also wear the following additional PPE: Wear a MSHA/ NIOSH-approved respirator, such as a half-face, full-face, or hood-style NIOSH-approved respirator with a

239 Page 5 of 8 SAFETY DATA SHEET (GHS) Date Issued : 10/6/2015 MSDS No : PYROCIDE300 Date-Revised : 10/6/2015 Revision No : 1 PYROCIDE 300 dust/ mist filtering cartridge (MSHA/ NIOSH approval number prefix TC-21C), or a canister approved for pesticides (MSHA/ NIOSH approval number prefix TC-14G), or a cartridge or canister with any N, R, P or HE filter. PROTECTIVE CLOTHING: Wear a long-sleeved shirt and long pants, shoes and socks. WORK HYGIENIC PRACTICES: DO NOT SMOKE, EAT, OR DRINK, OR APPLY COSMETICS IN WORK AREA! Wash promptly if skin becomes contaminated. Wash at the end of each work shift and before eating, smoking, or using the toilet. 9. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE: Liquid ODOR: Strong solvent-odor. APPEARANCE: Dark, amber-colored liquid. COLOR: 8.5 on Gardner Scale ph: Not Applicable; Product not intended to be diluted in water. FLASHPOINT AND METHOD: 83.3 C (182 F) TAG Closed Cup VAPOR DENSITY: Heavier than air. FREEZING POINT: Not Determined SOLUBILITY IN WATER: Immiscible in water. SPECIFIC GRAVITY: (Water = 1) at 20 C (68 F) VISCOSITY #1: 10.5 cps at 24.5 C (76.1 F) (VOC): < % 10. STABILITY AND REACTIVITY STABLE: Yes HAZARDOUS POLYMERIZATION: No CONDITIONS TO AVOID: Not compatible with strong acids or bases. Not compatible with strong oxidizers. 11. TOXICOLOGICAL INFORMATION ACUTE DERMAL LD 50 : > 2.0 gm/kg Notes: Albino rabbit. ORAL LD 50 : > 5.0 gm/kg Notes: Albino rat. INHALATION LC 50 : > 8.40 mg/l Notes: Rats exposed for 4 hours to test atmosphere. The Acute Inhalation LC 50 of this material places it in EPA Toxic Category IV. EYE EFFECTS: Irritation clearing in 24 hours. SKIN EFFECTS: Slight irritation at 72 hours. Irritation Index = 0.96 SENSITIZATION: When applied dermally to albino guinea pigs, this product appears to be a dermal sensitizer. COMMENTS: None of the components present in this material at concentrations equal to or greater than 0.1% are listed by IARC,

240 Page 6 of 8 SAFETY DATA SHEET (GHS) Date Issued : 10/6/2015 MSDS No : PYROCIDE300 Date-Revised : 10/6/2015 Revision No : 1 PYROCIDE 300 NTP, OSHA or ACGIH as being carcinogens. Marginally higher incidences of benign liver tumors in mice were observed following lifetime high dose exposures to PBO. The significance of these observations is questionable and under review. The doses at which tumors were observed for PBO greatly exceeded potential human exposure from labeled uses. Doses at which these effects were observed greatly exceeded anticipated human dietary intake. At anticipated dietary exposure levels, it is highly unlikely that this product will result in carcinogenic effects. 12. ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION: Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans or other waters, unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product into sewer systems without previously notifying the local sewage treatment plant authority. For guidance, contact your State Water Board or Regional Office of the EPA. 13. DISPOSAL CONSIDERATIONS DISPOSAL METHOD: To avoid wastes, use all materials in the containers by application according to label directions. If wastes cannot be avoided, offer remaining product to a waste disposal facility or pesticide disposal program (NOTE: such programs are often run by state or local governments, or by industry). EMPTY CONTAINER: Non-refillable container. DO NOT reuse or refill this container. Triple-rinse container (or equivalent) promptly after emptying. Then, offer for recycling if available, or puncture and dispose of container in a sanitary landfill. Triple-rinse as follows for containers less than < 5 gallons (< 18.9 L) or less: Empty the remaining contents into application equipment or a mix-tank and drain for 10 seconds after the flow begins to drip. Fill the container 1 / 4 full with water and re-cap. Shake for 10 seconds. Pour rinsate into application equipment or a mix-tank or store rinsate for later use or disposal. Drain for 10 seconds after the flow begins to drip. Repeat this procedure two more times. Triple-rinse as follows for containers greater than > 5 gallons (> 18.9 L): Empty the remaining contents into application equipment or a mix-tank. Fill the container 1 / 4 full with water. Replace and tighten closures. Tip container on its side and roll back and forth, ensuring at least one complete revolution, for 30 seconds. Stand the container on its end and tip it back and forth several times. Turn the container over onto its other end and tip it back and forth several times. Empty the rinsate into application equipment or a mix-tank or store rinsate for later use or disposal. Repeat this procedure two more times. RCRA/EPA WASTE INFORMATION: This product contains the following RCRA/CERCLA Hazardous wastes/substances: Component, RCRA ID#, CERCLA RQ: Pyrethrins, N/A, 1 Lb. 14. TRANSPORT INFORMATION DOT (DEPARTMENT OF TRANSPORTATION) PROPER SHIPPING NAME: UN3082, Environmentally Hazardous Substance, Liquid, N.O.S., RQ (Pyrethrins) PRIMARY HAZARD CLASS/DIVISION: 9 PACKING GROUP: III REPORTABLE QUANTITY (RQ) UNDER CERCLA: 1 Lb. (Pyrethrins/ Pyrethrum)

241 Page 7 of 8 SAFETY DATA SHEET (GHS) Date Issued : 10/6/2015 MSDS No : PYROCIDE300 Date-Revised : 10/6/2015 Revision No : 1 PYROCIDE 300 OTHER SHIPPING INFORMATION: This product is not regulated as a hazardous material by the DOT in quantities less than < 33.3 Lbs. Shipping name for quantities less than < 33.3 Lbs. : Insecticides, Insect or Animal Repellents, Liquid, N.O.S. AIR (ICAO/IATA) SHIPPING NAME: UN3082, Environmentally Hazardous Substance, Liquid, N.O.S., RQ (Pyrethrins) PRIMARY HAZARD CLASS/DIVISION: 9 PACKING GROUP: III VESSEL (IMO/IMDG) SHIPPING NAME: Not Available 15. REGULATORY INFORMATION UNITED STATES SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT) FIRE: Yes PRESSURE GENERATING: No REACTIVITY: No ACUTE: Yes 313 REPORTABLE INGREDIENTS: COMPONENT, CAS#, Max % Piperonyl Butoxide, , > 1.0% 302/304 EMERGENCY PLANNING EMERGENCY PLAN: There are no SARA Title III Section 302 extremely hazardous substances present in this formulation (40 CFR 355). See Section 13 of this MSDS for the components that are subject to emergency requirements under CERCLA Section 103(a)(40 CFR 302.4). TSCA (TOXIC SUBSTANCE CONTROL ACT) TSCA STATUS: All chemical substances found in this product comply with the Toxic Substances Control Act's inventory reporting requirements. REGULATIONS STATE REGULATIONS: VOLATILE ORGANIC COMPOUNDS (VOC): This product contains less than 6% VOC s. CALIFORNIA PROPOSITION 65: This product DOES NOT contain any known ingredients for which the State of California has found to cause cancer, birth defects, or other reporoductive harm, which requires a warning under the statute. FIFRA (FEDERAL INSECTICIDE, FUNGICIDE, AND RODENTICIDE ACT): NOTE: This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for Safety Data Sheets, and for workplace labels of non-pesticide chemicals. The following is the hazard information as required on the pesticide label: CAUTION. Harmful if swallowed or absorbed through the skin. Contains petroleum distillates - Vomiting may cause aspiration pneumonia. Avoid contact with skin, eyes, and clothing. Prolonged or frequently repeated skin contact may cause allergic reactions in

242 Page 8 of 8 SAFETY DATA SHEET (GHS) Date Issued : 10/6/2015 MSDS No : PYROCIDE300 Date-Revised : 10/6/2015 Revision No : 1 PYROCIDE 300 some individuals. 16. OTHER INFORMATION REVISION SUMMARY: This MSDS replaces the 10/6/2015 MSDS. Revised: Section 9: COLOR. HMIS RATING HEALTH 2 FLAMMABILITY 2 PHYSICAL HAZARD 1 PERSONAL PROTECTION HMIS RATINGS NOTES: We assign HMIS ratings to this product based on the hazards of its ingredients(s). Since the customer is most aware of the applications and conditions of use, he or she must ensure that the proper Personal Protective Equipment is provided, consistent with the information contained in Section's 2, 7, and 8 of this MSDS. COMMENTS: The data contained herein are based on information currently available to McLaughlin Gormley King Company and, to the best of our knowledge, are accurate and based on sound expert opinion. Our statements herein, however, are not to be taken as a warranty or representation for which McLaughlin Gormley King Company assumes legal responsibility. MSDS Prepared by T. Azzivitto

243 Return to Index... Safety Data Sheet RCO Omega Gopher Bait SDS Revision Date: 04/28/ Identification 1.1. Product identifier Product Identity RCO Omega Gopher Bait Alternate Names USEPA Reg # Relevant identified uses of the substance or mixture and uses advised against Intended use Application Method See Technical Data Sheet. See Technical Data Sheet Details of the supplier of the safety data sheet Company Name RCO International, Inc. P.O. Box 191 Harrisburg, OR Emergency CHEMTREC (USA) (800) Customer Service: RCO International, Inc. (541) Hazard(s) identification 2.1. Classification of the substance or mixture Acute Tox. 4;H302 Acute Tox. 3;H311 Harmful if swallowed. Toxic in contact with skin Label elements Using the Toxicity Data listed in section 11 and 12 the product is labeled as follows. H302 Harmful if swallowed. H311 Toxic in contact with skin. Danger [Prevention]: P264 Wash thoroughly after handling. P270 Do not eat, drink or smoke when using this product. Page 1 of 8

244 Safety Data Sheet RCO Omega Gopher Bait SDS Revision Date: 04/28/2015 P280 Wear protective gloves / eye protection / face protection. [Response]: P IF SWALLOWED: Call a POISON CENTER or doctor / physician immediately. P IF ON SKIN: Wash with plenty of soap and water. P322 Specific measures (see information on this label). P330 Rinse mouth. P361 Remove / Take off immediately all contaminated clothing. P363 Wash contaminated clothing before reuse. [Storage]: P405 Store locked up. [Disposal]: P501 Dispose of contents / container in accordance with local / national regulations. 3. Composition/information on ingredients There are no ingredients in this product which are in a concentration above the GHS cutoff. Contains active ingredient Strychnine (CAS Number ) at 0.5% 4. First aid measures 4.1. Description of first aid measures General Inhalation Eyes Skin Ingestion In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. Remove to fresh air, keep patient warm and at rest. If breathing is irregular or stopped, give artificial respiration. If unconscious place in the recovery position and obtain immediate medical attention. Give nothing by mouth. Irrigate copiously with clean water for at least 15 minutes, holding the eyelids apart and seek medical attention. Remove contaminated clothing. Wash skin thoroughly with soap and water or use a recognized skin cleanser. If less than ten (10) minutes have passed since the poison was taken, give or 2 glasses of water and induce vomiting by touching back of the throat with finger. Repeat until vomit fluid is clear. Have patient lie down in a quiet, darkened room and keep him warm and quiet. If person is unconscious, do not give anything by mouth and do not induce vomiting Most important symptoms and effects, both acute and delayed Overview DANGER: Convulsive Poison! Fatal if swallowed or inhaled. Harmful if absorbed through skin. Do not get in eyes or on clothing. Avoid contact with skin. Do not breathe dust. Do not apply this product in a way that will contact any person or pet. Wash hands before eating, drinking, chewing gum, using tobacco, or using the toilet. Remove contaminated clothing and wash clothing before reuse. Page 2 of 8

245 Safety Data Sheet RCO Omega Gopher Bait SDS Revision Date: 04/28/2015 Note to Physician: A. Administer 100% OXYGEN by positive pressure to provide as much pulmonary gas exchange as possible, despite seizures. B. Administer ANTICONVULSANT DRUGS intravenously to control convulsions. NOTICE: It may be difficult or impossible to stop the seizure activity without stopping respiration. Be prepared to maintain pulmonary ventilation mechanically. Tracheotomy may be necessary if seizures are prolonged. See section 2 for further details. Skin Ingestion Toxic in contact with skin. Harmful if swallowed. 5. Fire-fighting measures 5.1. Extinguishing media Recommended extinguishing media; alcohol resistant foam, CO2, powder, water spray. Do not use; water jet Special hazards arising from the substance or mixture Hazardous decomposition: No hazardous decomposition data available Advice for fire-fighters When heated, strychnine emits highly toxic fumes, thus firefighters must wear self-contained breathing apparatus. ERG Guide No Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Put on appropriate personal protective equipment (see section 8) Environmental precautions This product is toxic to fish, birds and other wildlife. Do not allow bait to be exposed on soil surface. Do not apply directly to water, or to areas where surface water is present or to intertidal areas below the mean high water mark. Do not contaminate water by cleaning or equipment, or disposal of wastes. Use good personal hygiene practices. Wash hands before eating, drinking, smoking or using toilet. Promptly remove soiled clothing and wash thoroughly before reuse Methods and material for containment and cleaning up Sweep up spilled materials completely and either use according to label directions or take to an approved pesticide disposal site in a sealed container. Pesticide wastes are acutely hazardous. Improper disposal of excess pesticide, spilled bait, or reinstate is a violation of Federal law. If these wastes cannot be disposed of by label instructions, contact your State Pesticide or Environment Control Agency, or the Hazardous Waste representative at the nearest EPA Regional Office for guidance. Page 3 of 8

246 Safety Data Sheet RCO Omega Gopher Bait SDS Revision Date: 04/28/ Handling and storage 7.1. Precautions for safe handling Non-refillable container. Do not reuse or refill this container. Offer to recycling, if available. Completely empty bag by shaking and tapping sides and bottom to loosen clinging particles. Empty residue into application equipment. Then dispose of bags in a sanitary landfill or by incineration if allowed by state and local authorities. See section 2 for further details. - [Prevention]: 7.2. Conditions for safe storage, including any incompatibilities Handle containers carefully to prevent damage and spillage. Incompatible materials: No data available. Store only in original container, in a dry place inaccessible to children, pets and domestic animals. See section 2 for further details. - [Storage]: 7.3. Specific end use(s) Keep away from children and pets. 8. Exposure controls and personal protection 8.1. Control parameters There are no ingredients in this product which are in a concentration above the GHS cutoff. Contains active ingredient Strychnine (CAS Number ) at 0.5% Strychnine has an OSHA PEL of 0.15 mg/m3 (TWA) and ACGIH TLV of 0.15 mg/m3 (TWA) 8.2. Exposure controls Respiratory Eyes Skin Engineering Controls If workers are exposed to concentrations above the exposure limit they must use the appropriate, certified respirators. MSHA/NIOSH approval # prefix TC-21C or NIOSH w/ N,P,R,HE filter. Safety Goggles Wear love sleeved shirts, pants, shoes with socks, and rubber gloves. Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates and any vapor below occupational exposure limits suitable respiratory protection must be worn. Other Work Practices Follow manufacturer s instructions for cleaning and maintaining PPE. If there are no such instructions, use detergent and hot water. Keep and wash PPE separately from other laundry Use good personal hygiene practices. Wash hands before eating, drinking, smoking or using toilet. Promptly remove soiled clothing and wash thoroughly before reuse. See section 2 for further details. - [Prevention]: Page 4 of 8

247 Safety Data Sheet RCO Omega Gopher Bait SDS Revision Date: 04/28/ Physical and chemical properties Appearance Odor Odor threshold ph Melting point / freezing point Initial boiling point and boiling range Flash Point Evaporation rate (Ether = 1) Flammability (solid, gas) Upper/lower flammability or explosive limits Vapor pressure (Pa) Vapor Density Specific Gravity Solubility in Water Partition coefficient n-octanol/water (Log Kow) Auto-ignition temperature Decomposition temperature Viscosity (cst) Bulk Density 9.2. Other information No other relevant information. Green Solid Slight smell of anise oil Not Measured Not Measured Not Measured 518F Not Measured Not Measured Not Applicable Lower Explosive Limit: Not Measured Upper Explosive Limit: Not Measured Not Measured Not Measured Not Measured Insoluble Not Measured Not Measured Not Measured Not Measured 5.5 lbs/gal 10. Stability and reactivity Reactivity Hazardous Polymerization will not occur Chemical stability Stable under normal circumstances Possibility of hazardous reactions No data available Conditions to avoid Excessive heat and open flame Incompatible materials Compatible with most materials Hazardous decomposition products May occur when bait is heated or burned. Page 5 of 8

248 Safety Data Sheet RCO Omega Gopher Bait SDS Revision Date: 04/28/ Toxicological information Acute toxicity There are no ingredients in this product which are in a concentration above the GHS cutoff. Contains active ingredient Strychnine (CAS Number ) at 0.5% Strychnine has an oral LD50 of 16 mg/kg (rat) The lethal dose to man is mg/kg of strychnine, equivalent to one gram of bait per kilogram of body weight. Note: When no route specific LD50 data is available for an acute toxin, the converted acute toxicity point estimate was used in the calculation of the product's ATE (Acute Toxicity Estimate). Classification Category Hazard Description Acute toxicity (oral) 4 Harmful if swallowed. Acute toxicity (dermal) 3 Toxic in contact with skin. Acute toxicity (inhalation) --- Not Applicable Skin corrosion/irritation --- Not Applicable Serious eye damage/irritation --- Not Applicable Respiratory sensitization --- Not Applicable Skin sensitization --- Not Applicable Germ cell mutagenicity --- Not Applicable Carcinogenicity --- Not Applicable Reproductive toxicity --- Not Applicable STOT-single exposure --- Not Applicable STOT-repeated exposure --- Not Applicable Aspiration hazard --- Not Applicable 12. Ecological information Toxicity The preparation has been assessed following the conventional method of the Dangerous Preparations Directive 1999/45/EC and GHS and is not classified as dangerous for the environment, but contains substance(s) dangerous for the environment. See section 3 for details Aquatic Ecotoxicity There are no ingredients in this product which are in a concentration above the GHS cutoff. Contains active ingredient Strychnine (CAS Number ) at 0.5% Strychnine is expected to be very toxic to aquatic and terrestrial life. The LC50/96 hour values for fish are less than 1 mg/l Page 6 of 8

249 Safety Data Sheet RCO Omega Gopher Bait SDS Revision Date: 04/28/ Persistence and degradability There is no data available on the preparation itself Bioaccumulative potential Not Measured Mobility in soil No data available Results of PBT and vpvb assessment This product contains no PBT/vPvB chemicals Other adverse effects No data available. 13. Disposal considerations Waste treatment methods Observe all federal, state and local regulations when disposing of this substance. 14. Transport information This product is not regulated by DOT; Freight Class Number is Regulatory information Regulatory Overview Toxic Substance Control Act ( TSCA) WHMIS Classification The regulatory data in Section 15 is not intended to be all-inclusive, only selected regulations are represented. All components of this material are either listed or exempt from listing on the TSCA Inventory. D1B US EPA Tier II Hazards Fire: No Sudden Release of Pressure: No Reactive: No Immediate (Acute): Yes Delayed (Chronic): No EPCRA 311/312 Chemicals and RQs: To the best of our knowledge, there are no chemicals at levels which require reporting under this statute. EPCRA 302 Extremely Hazardous: Strychnidin-10-one Page 7 of 8

250 Safety Data Sheet RCO Omega Gopher Bait SDS Revision Date: 04/28/2015 EPCRA 313 Toxic Chemicals: Strychnidin-10-one Proposition 65 - Carcinogens (>0.0%): To the best of our knowledge, there are no chemicals at levels which require reporting under this statute. Proposition 65 - Developmental Toxins (>0.0%): To the best of our knowledge, there are no chemicals at levels which require reporting under this statute. Proposition 65 - Female Repro Toxins (>0.0%): To the best of our knowledge, there are no chemicals at levels which require reporting under this statute. Proposition 65 - Male Repro Toxins (>0.0%): To the best of our knowledge, there are no chemicals at levels which require reporting under this statute. N.J. RTK Substances (>1%) : To the best of our knowledge, there are no chemicals at levels which require reporting under this statute. Penn RTK Substances (>1%): Soybean oil 16. Other information The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with respect to the information contained herein. We accept no responsibility and disclaim all liability for any harmful effects which may be caused by exposure to our products. Customers/users of this product must comply with all applicable health and safety laws, regulations, and orders. The full text of the phrases appearing in section 3 is: Not Applicable This is the first version in the GHS SDS format. Listings of changes from previous versions in other formats are not applicable. End of Document Page 8 of 8

251 Return to Index... SAFETY DATA SHEET TALSTAR PL GRANULAR INSECTICIDE SDS # : 1686-A Revision date: Format: NA Version 2 1. PRODUCT AND COMPANY IDENTIFICATION Product Identifier Product Name TALSTAR PL GRANULAR INSECTICIDE Other means of identification Product Code(s) 1686-A Synonyms Active Ingredient(s) Chemical Family BIFENTHRIN: (2-methyl[1,1'-biphenyl]-3-yl)methyl 3-(2-chloro-3,3,3-trifluoro-1-propenyl)-2,2-dimethylcyclopropanecarboxylate (CAS name); 2-methylbiphenyl-3-ylmethyl (Z)-(1RS)-cis-3-(2-chloro-3,3,3-trifluoroprop-1-enyl)-2,2-dimethylcyclopropanecarboxylate (IUPAC name) Bifenthrin Pyrethroid Pesticide Recommended use of the chemical and restrictions on use Recommended Use: Restrictions on Use: Manufacturer Address Emergency telephone number Insecticide, Miticide Use as recommended by the label FMC Corporation 1735 Market Street Philadelphia, PA (215) (General Information) msdsinfo@fmc.com ( General Information) For leak, fire, spill or accident emergencies, call: / (CHEMTREC - U.S.A.) / (CHEMTREC - Collect - All Other Countries) Medical Emergencies: / (PROSAR - U.S.A. & Canada) / (PROSAR - All Other Countries - Collect) 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR ) Carcinogenicity Category 1A Specific target organ toxicity (single exposure) Category 1 Specific target organ toxicity (repeated exposure) Category 1 Page 1 / 8

252 TALSTAR PL GRANULAR INSECTICIDE SDS # : 1686-A Revision date: Version 2 GHS Label elements, including precautionary statements Danger EMERGENCY OVERVIEW Hazard Statements H350 - May cause cancer H370 - Causes damage to organs H372 - Causes damage to organs through prolonged or repeated exposure Precautionary Statements - Prevention P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P281 - Use personal protective equipment as required P260 - Do not breathe dust/fume/gas/mist/vapors/spray P264 - Wash face, hands and any exposed skin thoroughly after handling P270 - Do not eat, drink or smoke when using this product Precautionary Statements - Response P321 - Specific treatment (see.? on this label) P308 + P311 - IF exposed or concerned: Call a POISON CENTER or doctor Precautionary Statements - Storage P405 - Store locked up Precautionary Statements - Disposal P501 - Dispose of contents/ container to an approved waste disposal plant Hazards not otherwise classified (HNOC) No hazards not otherwise classified were identified. Other Information Very toxic to aquatic life with long lasting effects 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Family Pyrethroid Pesticide. Chemical name CAS-No Weight % Bifenthrin crystalline silica, quartz >80 Synonyms are provided in Section FIRST AID MEASURES Eye Contact Hold eyes open and rinse slowly and gently with water for 15 to 20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for further treatment advice. Skin Contact Take off contaminated clothing. Rinse skin immediately with plenty of water for minutes. Call a poison control center or doctor for further treatment advice. Page 2 / 8

253 TALSTAR PL GRANULAR INSECTICIDE SDS # : 1686-A Revision date: Version 2 Inhalation Ingestion Most important symptoms and effects, both acute and delayed Indication of immediate medical attention and special treatment needed, if necessary Move to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or doctor for further treatment advice. Call a poison control center or doctor immediately for treatment advice Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by a poison control center or doctor. Do not give anything by mouth to an unconscious person. Central nervous system effects. Treat symptomatically. This product is a pyrethroid. If large amounts have been ingested, milk, cream, and other digestible fats and oils may increase absorption and so should be avoided. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Specific Hazards Arising from the Chemical Explosion data Sensitivity to Mechanical Impact Sensitivity to Static Discharge Protective equipment and precautions for firefighters Use CO2, dry chemical, or foam. Powdered material may form explosive dust-air mixtures Not sensitive. Not sensitive. As in any fire, wear self-contained breathing apparatus and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Isolate and post spill area. Remove all sources of ignition. Ventilate the area. Wear suitable protective clothing, gloves and eye/face protection. For personal protection see section 8. Other For further clean-up instructions, call FMC Emergency Hotline number listed in Section 1 "Product and Company Identification" above. Environmental Precautions Methods for Containment Methods for cleaning up See Section 12 for additional Ecological Information. Use a wet sweeping compound or water to prevent dust formation. Sweep up and shovel into suitable containers for disposal. Clean and neutralize spill area, tools and equipment by washing with bleach water and soap. Absorb rinsate and add to the collected waste. Waste must be classified and labeled prior to recycling or disposal. Dispose of waste as indicated in Section HANDLING AND STORAGE Handling Storage Incompatible products Do not contaminate other pesticides, fertilizers, water, food, or feed by storage or disposal. Keep in a dry, cool and well-ventilated place. Keep away from open flames, hot surfaces and sources of ignition. Keep out of reach of children and animals. Store in original container. None known 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Page 3 / 8

254 TALSTAR PL GRANULAR INSECTICIDE SDS # : 1686-A Revision date: Version 2 Chemical name ACGIH TLV OSHA PEL NIOSH Mexico crystalline silica, quartz TWA: mg/m 3 See note IDLH: 50 mg/m 3 Mexico: TWA 0.1 mg/m TWA: 0.05 mg/m 3 Chemical name British Columbia Quebec Ontario TWAEV Alberta crystalline silica, quartz TWA: mg/m 3 TWA: 0.1 mg/m 3 TWA: 0.10 mg/m 3 TWA: mg/m 3 Appropriate engineering controls Engineering measures Apply technical measures to comply with the occupational exposure limits. When working in confined spaces (tanks, containers, etc.), ensure that there is a supply of air suitable for breathing and wear the recommended equipment. Individual protection measures, such as personal protective equipment Eye/Face Protection Skin and Body Protection Hand Protection Respiratory Protection Hygiene measures General information If there is a potential for exposure to particles which could cause eye discomfort, wear chemical goggles. Wear long-sleeved shirt, long pants, socks, and shoes. Protective gloves If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Respiratory protection must be provided in accordance with current local regulations. Clean water should be available for washing in case of eye or skin contamination. Wash skin prior to eating, drinking, chewing gum or using tobacco. Shower or bathe at the end of working. Remove and wash contaminated clothing before re-use. Launder work clothing separately from regular household laundry. If the product is used in mixtures, it is recommended that you contact the appropriate protective equipment suppliers These recommendations apply to the product as supplied 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Appearance Light tan to tan, Granules Physical State Solid Color cream to tan Odor Slight Musty Odor threshold No information available ph Melting point/freezing point Not applicable Boiling Point/Range No information available Flash point Not applicable Evaporation Rate No information available Flammability (solid, gas) No information available Flammability Limit in Air Upper flammability limit: No information available Lower flammability limit: No information available Vapor pressure No information available Vapor density No information available Density 1.39 lb/ft 3 Specific gravity No information available Water solubility No information available Solubility in other solvents No information available Partition coefficient No information available Autoignition temperature No information available Decomposition temperature No information available Viscosity, kinematic No information available Viscosity, dynamic No information available Explosive properties No information available Page 4 / 8

255 TALSTAR PL GRANULAR INSECTICIDE Oxidizing properties No information available Molecular weight No information available Bulk density lb/ft 3 SDS # : 1686-A Revision date: Version STABILITY AND REACTIVITY Reactivity Chemical Stability None under normal use conditions Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous polymerization Conditions to avoid Incompatible materials Hazardous polymerization does not occur. Excessive heat. Keep away from open flames, hot surfaces and sources of ignition. None known. Hazardous Decomposition Products Carbon oxides (COx), Hydrogen chloride, Hydrogen fluoride. Product Information LD50 Oral > 5000 mg/kg (rat) LD50 Dermal > 2000 mg/kg (rabbit) LC50 Inhalation No information available 11. TOXICOLOGICAL INFORMATION Serious eye damage/eye irritation Skin corrosion/irritation Sensitization Non-irritating. Product dust may cause mechanical eye irritation. Non-irritating. Non-sensitizer. Information on toxicological effects Symptoms Large doses of bifenthrin ingested by laboratory animals produced signs of toxicity including convulsions, tremors and bloody nasal discharge. Delayed and immediate effects as well as chronic effects from short and long-term exposure Chronic toxicity Bifenthrin: Long-term exposure caused neurotoxicity (tremors and impaired gait) in the early exposure in animal studies, but tremors disappeared with continued exposure. Mutagenicity Bifenthrin: Not genotoxic in laboratory studies. Carcinogenicity Bifenthrin: Weak treatment-related response for liver adenocarcinomas and benign bladder tumors (lesion) in male mice. This product contains crystalline silica (quartz) in a non-respirable form. Inhalation of crystalline silica is unlikely to occur from exposure to this product. However, if granules are pulverized or crushed into a fine, respirable powder, silica exposure via inhalation is probable. Neurological effects Bifenthrin: Causes clinical signs of neurotoxicity (tremors, impaired gait, excessive salivation) following acute or subchronic exposure. Tremors disappeared with continued exposure. Reproductive toxicity Bifenthrin: No toxicity to reproduction in animal studies. Developmental toxicity Bifenthrin: Not teratogenic in animal studies. STOT - single exposure Not classified. STOT - repeated exposure Not classified. Target organ effects Bifenthrin: Central Nervous System. Neurological effects Bifenthrin: Causes clinical signs of neurotoxicity (tremors, impaired gait, excessive salivation) following acute or subchronic exposure. Tremors disappeared with continued exposure. Aspiration hazard No information available. Chemical name ACGIH IARC NTP OSHA crystalline silica, quartz A2 Group 1 Known X Page 5 / 8

256 TALSTAR PL GRANULAR INSECTICIDE SDS # : 1686-A Revision date: Version ECOLOGICAL INFORMATION Ecotoxicity Bifenthrin ( ) Active Ingredient(s) Duration Species Value Units Bifenthrin 96 h LC50 Fish 0.1 µg/l 72 h EC50 Algae mg/l 48 h EC50 Crustacea 0.11 µg/l 21 d NOEC Fish µg/l 21 d NOEC Crustacea µg/l Persistence and degradability Bioaccumulation Mobility Bifenthrin: Moderately persistent. Does not readily hydrolyze. Not readily biodegradable. Bifenthrin: The substance has a potential for bioconcentration. Bifenthrin: Immobile. Not expected to reach groundwater. 13. DISPOSAL CONSIDERATIONS Waste disposal methods Contaminated Packaging Improper disposal of excess pesticide, spray mixture, or rinsate is prohibited. If these wastes cannot be disposed of by use according to label instructions, contact appropriate disposal authorities for guidance. Containers must be disposed of in accordance with local, state and federal regulations. Refer to the product label for container disposal instructions. 14. TRANSPORT INFORMATION DOT This material is not a hazardous material as defined by U.S. Department of Transportation at 49 CFR Parts 100 through 185. TDG UN/ID no UN3077 Proper Shipping Name Environmentally hazardous substance, solid, n.o.s. Hazard class 9 Packing Group III Marine Pollutant Bifenthrin. Description UN3077, Environmentally hazardous substance, solid, n.o.s. (bifenthrin), 9, PGIII, Marine Pollutant ICAO/IATA UN/ID no UN3077 Proper Shipping Name Environmentally hazardous substance, solid, n.o.s. Hazard class 9 Packing Group III Description UN3077, Environmentally hazardous substance, solid, n.o.s. (bifenthrin), 9, PGIII, Marine Pollutant IMDG/IMO UN/ID no UN3077 Proper Shipping Name Environmentally hazardous substance, solid, n.o.s. Hazard class 9 Packing Group III EmS No. F-A, S-F Marine Pollutant Bifenthrin Description UN3077, Environmentally hazardous substance, solid, n.o.s. (bifenthrin), 9, PGIII, Marine Pollutant Page 6 / 8

257 TALSTAR PL GRANULAR INSECTICIDE SDS # : 1686-A Revision date: Version 2 U.S. Federal Regulations 15. REGULATORY INFORMATION SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372: Chemical name CAS-No Weight % SARA Threshold Values % Bifenthrin SARA 311/312 Hazard Categories Acute health hazard Chronic health hazard Fire hazard Sudden release of pressure hazard Reactive Hazard Yes Yes No No No Clean Water Act This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR and 40 CFR ) CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material FIFRA Information This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: CAUTION Harmful if absorbed through skin. This pesticide is extremely toxic to fish and aquatic invertebrates. US State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals:. Chemical name California Prop. 65 crystalline silica, quartz Carcinogen U.S. State Right-to-Know Regulations Chemical name New Jersey Massachusetts Pennsylvania Bifenthrin X crystalline silica, quartz X X X International Inventories Page 7 / 8

258 TALSTAR PL GRANULAR INSECTICIDE Component Bifenthrin ( 0.2 ) crystalline silica, quartz ( >80 ) TSCA (United States) DSL (Canada) EINECS/ELI NCS (Europe) ENCS (Japan) China (IECSC) KECL (Korea) X X X SDS # : 1686-A Revision date: Version 2 PICCS (Philippines) AICS (Australia) X X X X X X X X Mexico - Grade Moderate risk, Grade 2 WHMIS Hazard Class D2A - Very toxic materials 16. OTHER INFORMATION NFPA Health Hazards 2 Flammability 0 Instability 0 Special Hazards - HMIS Health Hazards 2* Flammability 0 Physical hazard 0 Personal Protection X *Indicates a chronic health hazard. Revision date: Revision note Format Change Disclaimer FMC Corporation believes that the information and recommendations contained herein (including data and statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information provided herein relates only to the specified product designated and may not be applicable where such product is used in combination with any other materials or in any process. Use of this product is regulated by the U.S. Environmental Protection Agency (EPA). It is a violation of Federal law to use this product in a manner inconsistent with its labeling. Further, since the conditions and methods of use are beyond the control of FMC Corporation, FMC corporation expressly disclaims any and all liability as to any results obtained or arising from any use of the products or reliance on such information. Prepared By: FMC Corporation FMC Logo - Trademark of FMC Corporation 2015 FMC Corporation. All Rights Reserved. End of Safety Data Sheet Page 8 / 8

259 Return to Index... Safety Data Sheet TERMIDOR 9.1% SC. Revision date : 2013/10/31 Page: 1/9 Version: 4.1 ( /SDS_CPA_US/EN) 1. Product and Company Identification Company BASF CORPORATION 100 Park Avenue Florham Park, NJ 07932, USA 24 Hour Emergency Response Information CHEMTREC: BASF HOTLINE: HELP (4357) Substance number: Molecular formula: C12 H4 Cl2 F6 N4 O S Chemical family: phenyl pyrazole Synonyms: fipronil 2. Hazards Identification Emergency overview CAUTION: HARMFUL IF SWALLOWED. HARMFUL IF ABSORBED THROUGH SKIN. HARMFUL IF INHALED. Causes eye irritation. Do not get in eyes, on skin, or on clothing. Do not breathe vapours/mists. Wash thoroughly after handling. See Product Label for additional precautionary statements. State of matter: liquid Colour: beige Odour: characteristic Potential health effects Primary routes of exposure: Routes of entry for solids and liquids include eye and skin contact, ingestion and inhalation. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route of entry for liquified gases. Acute toxicity: Slightly toxic after single ingestion. Slightly toxic after short-term skin contact. Slightly toxic after short-term inhalation. Irritation / corrosion: May cause slight irritation to the skin. May cause moderate but temporary irritation to the eyes. Sensitization:

260 Safety Data Sheet TERMIDOR 9.1% SC. Revision date : 2013/10/31 Page: 2/9 Version: 4.1 ( /SDS_CPA_US/EN) Skin sensitizing effects were not observed in animal studies. Medical conditions aggravated by overexposure: Individuals with pre-existing diseases of the respiratory system, skin or eyes may have increased susceptibility to excessive exposures. Signs and symptoms of overexposure: CNS stimulation, tremors, convulsions All injection injuries must be treated as potential threats to the future viability of the hand, foot, or limb. Injection wounds containing dirt, leather, product or other infectious detritus should be considered dangerous to the viability of the hand, foot or limb. Surgical exploration and debridement may be required. Potential environmental effects Aquatic toxicity: Very toxic (acute effect) to aquatic organisms. Terrestrial toxicity: With high probability not acutely harmful to terrestrial organisms. 3. Composition / Information on Ingredients CAS Number Content (W/W) Chemical name % fipronil % Propylene glycol 87.9 % Proprietary ingredients 4. First-Aid Measures General advice: First aid providers should wear personal protective equipment to prevent exposure. Remove contaminated clothing. Move person to fresh air. If person is not breathing, call 911 or ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or physician for treatment advice. Have the product container or label with you when calling a poison control center or doctor or going for treatment. If inhaled: Remove the affected individual into fresh air and keep the person calm. If on skin: Rinse skin immediately with plenty of water for minutes. If in eyes: Hold eyes open and rinse slowly and gently with water for 15 to 20 minutes. Remove contact lenses, if present, after first 5 minutes, then continue rinsing. If swallowed: Never induce vomiting or give anything by mouth if the victim is unconscious or having convulsions. Do not induce vomiting. Have person sip a glass of water if able to swallow. Note to physician Antidote: Treatment: No known specific antidote. Treat symptomatically. Anticonvulsant therapy as routinely administered to humans. Based on animal studies diazepam and phenobarbital prevented convulsions. Due to the slow elimination of the active compound and its metabolites, the treatment must be continued for several days, gradually decreasing the dose of anticonvulsant based on the clinical response.

261 Safety Data Sheet TERMIDOR 9.1% SC. Revision date : 2013/10/31 Page: 3/9 Version: 4.1 ( /SDS_CPA_US/EN) 5. Fire-Fighting Measures Flash point: > F Autoignition: Lower explosion limit: Upper explosion limit: Self-ignition temperature: Information applies to the solvent. not applicable As a result of our experience with this product and our knowledge of its composition we do not expect any hazard as long as the product is used appropriately and in accordance with the intended use. As a result of our experience with this product and our knowledge of its composition we do not expect any hazard as long as the product is used appropriately and in accordance with the intended use. not self-igniting Suitable extinguishing media: foam, dry powder, carbon dioxide, water spray Hazards during fire-fighting: carbon monoxide, carbon dioxide, hydrogen fluoride, Hydrogen chloride, nitrogen oxides, sulfur oxides, acid halides If product is heated above decomposition temperature, toxic vapours will be released. The substances/groups of substances mentioned can be released if the product is involved in a fire. Protective equipment for fire-fighting: Wear self-contained breathing apparatus and chemical-protective clothing. Further information: In case of fire and/or explosion do not breathe fumes. Keep containers cool by spraying with water if exposed to fire. Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems. Dispose of fire debris and contaminated extinguishing water in accordance with official regulations. 6. Accidental release measures Personal precautions: Take appropriate protective measures. Clear area. Shut off source of leak only under safe conditions. Extinguish sources of ignition nearby and downwind. Ensure adequate ventilation. Wear suitable personal protective clothing and equipment. Environmental precautions: Do not discharge into the subsoil/soil. Do not discharge into drains/surface waters/groundwater. Contain contaminated water/firefighting water. Cleanup: Dike spillage. Pick up with suitable absorbent material. Place into suitable containers for reuse or disposal in a licensed facility. Spilled substance/product should be recovered and applied according to label rates whenever possible. If application of spilled substance/product is not possible, then spills should be contained, solidified, and placed in suitable containers for disposal. After decontamination, spill area can be washed with water. Collect wash water for approved disposal. 7. Handling and Storage Handling General advice: RECOMMENDATIONS ARE FOR MANUFACTURING, COMMERCIAL BLENDING, AND PACKAGING WORKERS. PESTICIDE APPLICATORS & WORKERS must refer to the Product Label and Directions for Use attached to the product for Agricultural Use Requirements in accordance with the EPA Worker Protection

262 Safety Data Sheet TERMIDOR 9.1% SC. Revision date : 2013/10/31 Page: 4/9 Version: 4.1 ( /SDS_CPA_US/EN) Standard 40 CFR part 170. Ensure adequate ventilation. Provide good ventilation of working area (local exhaust ventilation if necessary). Keep away from sources of ignition - No smoking. Keep container tightly sealed. Protect contents from the effects of light. Protect against heat. Protect from air. Handle and open container with care. Do not open until ready to use. Once container is opened, content should be used as soon as possible. Avoid aerosol formation. Avoid dust formation. Provide means for controlling leaks and spills. Do not return residues to the storage containers. Follow label warnings even after container is emptied. The substance/ product may be handled only by appropriately trained personnel. Avoid all direct contact with the substance/product. Avoid contact with the skin, eyes and clothing. Avoid inhalation of dusts/mists/vapours. Wear suitable personal protective clothing and equipment. Protection against fire and explosion: The relevant fire protection measures should be noted. Fire extinguishers should be kept handy. Avoid all sources of ignition: heat, sparks, open flame. Sources of ignition should be kept well clear. Avoid extreme heat. Keep away from oxidizable substances. Electrical equipment should conform to national electric code. Ground all transfer equipment properly to prevent electrostatic discharge. Electrostatic discharge may cause ignition. Storage General advice: Keep only in the original container in a cool, dry, well-ventilated place away from ignition sources, heat or flame. Protect containers from physical damage. Protect against contamination. The authority permits and storage regulations must be observed. Storage incompatibility: General advice: Segregate from incompatible substances. Segregate from foods and animal feeds. Segregate from textiles and similar materials. Temperature tolerance Protect from temperatures below: 0 C Changes in the properties of the product may occur if substance/product is stored below indicated temperature for extended periods of time. Protect from temperatures above: 40 C Changes in the properties of the product may occur if substance/product is stored above indicated temperature for extended periods of time. 8. Exposure Controls and Personal Protection Users of a pesticidal product should refer to the product label for personal protective equipment requirements. Advice on system design: Whenever possible, engineering controls should be used to minimize the need for personal protective equipment. Personal protective equipment RECOMMENDATIONS FOR MANUFACTURING, COMMERCIAL BLENDING, AND PACKAGING WORKERS: Respiratory protection: Wear respiratory protection if ventilation is inadequate. Wear a NIOSH-certified (or equivalent) organic vapour/particulate respirator. For situations where the airborne concentrations may exceed the level for which an air purifying respirator is effective, or where the levels are unknown or Immediately Dangerous to Life or Health (IDLH), use NIOSH-certified full facepiece pressure demand self-contained breathing apparatus (SCBA) or a full facepiece pressure demand supplied-air respirator (SAR) with escape provisions. Hand protection: Chemical resistant protective gloves, Protective glove selection must be based on the user's assessment of the workplace hazards.

263 Safety Data Sheet TERMIDOR 9.1% SC. Revision date : 2013/10/31 Page: 5/9 Version: 4.1 ( /SDS_CPA_US/EN) Eye protection: Safety glasses with side-shields. Tightly fitting safety goggles (chemical goggles). Wear face shield if splashing hazard exists. Body protection: Body protection must be chosen depending on activity and possible exposure, e.g. head protection, apron, protective boots, chemical-protection suit. General safety and hygiene measures: Wear long sleeved work shirt and long work pants in addition to other stated personal protective equipment. Work place should be equipped with a shower and an eye wash. Handle in accordance with good industrial hygiene and safety practice. Personal protective equipment should be decontaminated prior to reuse. Gloves must be inspected regularly and prior to each use. Replace if necessary (e.g. pinhole leaks). Take off immediately all contaminated clothing. Store work clothing separately. Hands and/or face should be washed before breaks and at the end of the shift. No eating, drinking, smoking or tobacco use at the place of work. Keep away from food, drink and animal feeding stuffs. 9. Physical and Chemical Properties Form: suspension Odour: characteristic Colour: beige ph value: 7.2 ( 10 g/l) onset of boiling: approx. 100 C ( 1,013 hpa) Information applies to the solvent. Vapour pressure: approx hpa ( 20 C) Information applies to the solvent. Density: 1.06 g/cm3 ( 20 C) Vapour density: not determined Partitioning coefficient n- not applicable octanol/water (log Pow): Viscosity, dynamic: approx. 1,600 - ( 21.6 C) 1,850 mpa.s Solubility in water: dispersible Molar mass: g/mol 10. Stability and Reactivity Conditions to avoid: Avoid all sources of ignition: heat, sparks, open flame. Avoid prolonged storage. Avoid electro-static discharge. Avoid contamination. Avoid prolonged exposure to extreme heat. Avoid extreme temperatures. Substances to avoid: strong oxidizing agents Hazardous reactions: The product is chemically stable. Hazardous polymerization will not occur. No hazardous reactions if stored and handled as prescribed/indicated. Decomposition products: Hazardous decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated., Prolonged thermal loading can result in products of degradation being given off. Thermal decomposition: Possible thermal decomposition products: carbon monoxide, carbon dioxide, nitrogen oxide, Hydrogen chloride, hydrogen fluoride, Sulphur dioxide Stable at ambient temperature. If product is heated above decomposition temperature toxic vapours may be released. If product is heated above decomposition temperature hazardous fumes may be released. Corrosion to metals: Corrosive effects to metal are not anticipated.

264 Safety Data Sheet TERMIDOR 9.1% SC. Revision date : 2013/10/31 Page: 6/9 Version: 4.1 ( /SDS_CPA_US/EN) Oxidizing properties: Not an oxidizer. not fire-propagating 11. Toxicological information Acute toxicity Oral: Type of value: LD50 Species: rat Value: 1,999 mg/kg Inhalation: Type of value: LC50 Species: rat Value: > 1.7 mg/l Exposure time: 4 h Type of value: LC50 Species: rat Value: 6.8 mg/l (calculated) Exposure time: 1 h Dermal: Type of value: LD50 Species: rat Value: > 2,000 mg/kg Irritation / corrosion Skin: Species: rabbit Result: Slightly irritating. Eye: Species: rabbit Result: Slightly irritating. Sensitization: Species: guinea pig Skin sensitizing effects were not observed in animal studies. Genetic toxicity Information on: fipronil Results from a number of mutagenicity studies with microorganisms, mammalian cell culture and mammals are available. Taking into account all of the information, there is no indication that the substance is mutagenic Carcinogenicity Information on: fipronil In long-term studies in rats the substance induced thyroid tumors. In long-term studies in rodents exposed to high doses, a tumorigenic effect was found; however, these results are thought to be due to a rodent-specific liver effect that is not relevant to humans Reproductive toxicity Information on: fipronil

265 Safety Data Sheet TERMIDOR 9.1% SC. Revision date : 2013/10/31 Page: 7/9 Version: 4.1 ( /SDS_CPA_US/EN) Animal studies gave no indication of a developmental toxic effect at doses that were not toxic to the parental animals Ecological Information Fish Acute: Brachydanio rerio/lc50 (96 h): 3.89 mg/l Aquatic invertebrates Acute: Daphnia pulex/ec50 (48 h): 0.2 mg/l Aquatic plants Information on: fipronil Toxicity to aquatic plants: green algae/ec50 (96 h): mg/l Common duckweed/ec50 (336 h): > mg/l green algae/ec50 (120 h): > mg/l Algae/EC50 (120 h): > mg/l Algae/EC50 (120 h): > mg/l Non-Mammals Information on: fipronil Other terrestrial non-mammals: Honey bee/ld50 (48 d): 0,00593 ug/bee (contact) Honey bee/ld50 (48 d): 0,00417 ug/bee (oral) Degradability / Persistence Biological / Abiological Degradation Evaluation: Not readily biodegradable (by OECD criteria). Other adverse effects: The ecological data given are those of the active ingredient. Do not release untreated into natural waters. 13. Disposal considerations Waste disposal of substance: Pesticide wastes are regulated. Improper disposal of excess pesticide, spray mix or rinsate is a violation of federal law. If pesticide wastes cannot be disposed of according to label instructions, contact the State Pesticide or Environmental Control Agency or the Hazardous Waste representative at the nearest EPA Regional Office for guidance. Container disposal: Contaminated packaging should be emptied as far as possible and disposed of in the same manner as the substance/product. Rinse thoroughly at least three times (triple rinse) in accordance with EPA recommendations. Consult state or local disposal authorities for approved alternative procedures such as container recycling. Recommend crushing, puncturing or other means to prevent unauthorized use of used containers. RCRA:

266 Safety Data Sheet TERMIDOR 9.1% SC. Revision date : 2013/10/31 Page: 8/9 Version: 4.1 ( /SDS_CPA_US/EN) This product is not regulated by RCRA. 14. Transport Information Land transport USDOT Not classified as a dangerous good under transport regulations Sea transport IMDG Hazard class: 9 Packing group: III ID number: UN 3082 Hazard label: 9, EHSM Marine pollutant: YES Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains FIPRONIL 9%) Air transport IATA/ICAO Hazard class: 9 Packing group: III ID number: UN 3082 Hazard label: 9, EHSM Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains FIPRONIL 9%) 15. Regulatory Information Federal Regulations Registration status: Chemical TSCA, US blocked / not listed Crop Protection TSCA, US released / exempt OSHA hazard category: Acute target organ effects reported; Chronic target organ effects reported EPCRA 311/312 (Hazard categories): Acute; Chronic State regulations State RTK CAS Number Chemical name PA Propylene glycol 16. Other Information Refer to product label for EPA registration number.

267 Safety Data Sheet TERMIDOR 9.1% SC. Revision date : 2013/10/31 Page: 9/9 Version: 4.1 ( /SDS_CPA_US/EN) Recommended use: insecticide NFPA Hazard codes: Health : 2 Fire: 1 Reactivity: 1 Special: We support worldwide Responsible Care initiatives. We value the health and safety of our employees, customers, suppliers and neighbors, and the protection of the environment. Our commitment to Responsible Care is integral to conducting our business and operating our facilities in a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring the safe and environmentally sound handling of our products, and minimizing the impact of our operations on society and the environment during production, storage, transport, use and disposal of our products. SDS Prepared by: BASF NA Product Regulations SDS Prepared on: 2013/10/31 IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU MAKE TESTS TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR INFORMATION SET FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE USED WITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESSLY UNDERSTAND AND AGREE THAT THE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION FURNISHED BY OUR COMPANY HEREUNDER ARE GIVEN GRATIS AND WE ASSUME NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DESIGNS, DATA AND INFORMATION GIVEN OR RESULTS OBTAINED, ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK. END OF DATA SHEET

268 Return to Index...

269 TERRO -PCO Liquid Ant Bait For Control of Sweet Eating Ants Contains Borax No Unpleasant Odors Use Indoors Use Outdoors Attracts Ants Fast Active Ingredient: Sodium Tertaborate Decahydrate (Borax) % Other Ingredients % Total % EPA Reg. No EPA Est. 149-MO-1 Keep Out of Reach of Children CAUTION DIRECTIONS FOR USE It is a violation of Federal law to use this product in a manner inconsistent with its labeling. FOR USE IN AND AROUND: Homes, Hospitals, Restaurants, Apartments, Grocery Stores, Institutional Buildings, Schools, Cafeterias, Warehouses, Storage Areas, Food Processing Plants, Mobile Homes, Boats, Military Bases, Theaters, Nursing Homes and on Military, Commercial and Cruise Ships. ATTRACTS AND KILLS ALL COMMON HOUSEHOLD ANTS INCLUDING: Argentine ants, Ghost ants, Cornfield ants, Pavement ants, Acrobat ants, White-footed ants, Little black ants, Odorous house ants, Crazy ants, Big-headed ants and other sweet-eating ants. DO NOT USE in edible product areas of food handling establishments, restaurants or other areas where food is commercially prepared or processed. Do not use in serving areas while food is exposed. Avoid contamination of feed and foodstuffs. Place bait in areas inaccessible to children and pets. TERRO -PCO Liquid Ant Bait can be diluted with water to obtain a 1% or 2% solution of Borax. Such a dilution is helpful when you plan on using a substantial volume of TERRO -PCO Liquid Ant Bait in a baiting program designed to control very large multiqueen and multi-colony ant infestations. 1% Dilution: 1 part TERRO -PCO Liquid Ant Bait to 5 parts water. Mix thoroughly. 2% Dilution: 1 part TERRO -PCO Liquid Ant Bait to 2 parts water. Mix thoroughly. COMMON DILUTlONS 1% Dilution TERRO + WATER = FINISHED PRODUCT 5 fl. oz fl. oz. = 1 Quart (approximately) 20 fl. oz fl. oz. = 1 Gallon (approximately) 1 gallon + 5 gallons = 6 gallons 2% Dilution TERRO + WATER = FINISHED PRODUCT 10 fl. oz fl. oz. = 1 Quart (approximately) 42 fl. oz fl. oz. = 1 Gallon (approximately) 1 gallon + 2 gallons = 3 gallons USING TERRO -PCO LIQUID ANT BAIT IN BAIT STATIONS: Apply the 1% or 2% TERRO -PCO Liquid Ant Bait solution using bait stations designed to hold liquid bait. This product will work well in most bait stations such as those made by B&G, Kness, and Whitmire Micro-Gen. Follow directions included with the bait stations to obtain best results. Storage and Disposal STORAGE: Store in a cool dry place. Do not store where children or animals may gain access. DISPOSAL: If empty: Do not reuse this container. Place in trash or offer for recycling if available. If partly filled: Call your local solid waste agency for disposal instructions. Never place unused product down any indoor or outdoor drain. Distributed by: 100 Nisus Drive, Rockford, TN (800) Made in the U.S.A. Terro is registered trademark of Senoret Chemical Company, Nisus is a registered trademark of Nisus Corporation Nisus Corporation. #TGAL-SL-0710

270 TERROP P-PCO Liquid Ant Bait Stations Pre-Filled Ready-to-Use No Drips, Spill or Mess For Control of Sweet Eating Ants Active Ingredient: Sodium Tetraborate Decahydrate (Borax) % Other Ingredients % Total % EPA Reg. No EPA Est TN-1 KEEP OUT OF REACH OF CHILDREN CAUTION DIRECTIONS FOR USE It is a violation of Federal law to use this product in a manner inconsistent with its labeling. FOR USE IN AND AROUND: Homes, Hospitals, Restaurants, Apartments, Grocery Stores, Institutional Buildings, Schools, Cafeterias, Warehouses, Storage Areas, Food Processing Plants, Mobile Homes, Boats, Military Bases, Theaters, Nursing Homes and on Military, Commercial and Cruise Ships. ATTRACTS AND KILLS ALL COMMON HOUSEHOLD ANTS INCLUDING: Argentine ants, Ghost ants, Cornfield ants, Pavement ants, Acrobat ants, White-footed ants, Little black ants, Odorous house ants, Crazy ants, Big-headed ants and other sweeteating ants. TerroP P-PCO Liquid Ant Bait now comes as an easy-touse, pre-filled liquid ant bait. Ants will enter, feed and return to the nest where they will pass on the TerroP P-PCO Liquid Ant Bait to the rest of the colony. 1. Break pre-filled baits apart from the plastic frame. 2. Hold bait upright and cut off colored section. 3. Place baits, label side up, near ant trails or close to where ants are numerous. Place additional baits anywhere ants may enter the home. For best results, use seven baits to ensure sufficient supply for the ants. 4. Monitor regularly for activity but do not interfere with the ants or baits. Replace with additional baits when first set is depleted. 5. Once ants are controlled, replace baits every three months to keep ants from returning. DO NOT USE in edible product areas of food handling establishments, restaurants or other areas where food is commercially prepared or processed. Do not use in serving areas while food is exposed. Avoid contamination of feed and foodstuffs. Place bait in areas inaccessible to children and pets. STORAGE AND DISPOSAL STORAGE: Store in a cool dry place. Do not store where children or animals may gain access. DISPOSAL: If empty: Do not reuse this container. Place in trash or offer for recycling if available. If partly filled: Call your local solid waste agency for disposal instructions. Never place unused product down any indoor or outdoor drain. Distributed by: 100 Nisus Drive Rockford, TN Terro is a registered trademark of Senoret Chemical Company, Inc. Nisus is a registered trademark of Nisus Corporation Nisus Corporation #TBS-SL-1006a

271 SAFETY DATA SHEET Health Emergencies: INFOTRAC (800) PRODUCT AND COMPANY INFORMATION Product Identity: Terro PCO Recommended use of the chemical and restrictions on use: Insecticide - Crawling Bug - Non-Aerosol Distributed by: Nisus Corporation 100 Nisus Drive Rockford, TN Telephone: Phone: (800) Fax: (865) Emergency Phone: SDS Date of Preparation: 01/12/16 2. HAZARDS IDENTIFICATION GHS Classification: Health Reproductive Toxicity Category 1B GHS Label Elements: Signal Word: Danger! (INFOTRAC) Statements of Hazard May damage fertility or the unborn child Precautionary Statements Obtain special instructions before use Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required. Precautionary Statements - Response IF exposed or concerned: Get medical advice/attention Precautionary Statements - Storage Store locked up Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant 3. COMPOSITION/INFORMATION ON INGREDIENTS Component CAS No. Amount Sucrose % Sodium borate % The exact formulation is being withheld as a trade secret. 4. FIRST AID MEASURES General Advice : Show this safety data sheet to the doctor in attendance. Eye Contact: Rinse thoroughly with plenty of water, also under the eyelids. If symptoms persist, call a physician. Skin Contact: Wash skin with soap and water. In the case of skin irritation or allergic reactions see a physician. Inhalation: Remove to fresh air. If symptoms persist, call a physician. Ingestion : Do NOT induce vomiting. Drink plenty of water. If symptoms persist, call a physician. Most important Symptoms: No information available Notes to Physician Treat symptomatically. 5. FIRE FIGHTING MEASURES Suitable Extinguishing Media: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media: CAUTION: Use of water spray when fighting fire may be inefficient. Specific Hazards Arising from the Chemical No information available. Hazardous Combustion Products Carbon oxides. Explosion Data Sensitivity to Mechanical Impact: No. Sensitivity to Static Discharge: No. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressuredemand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Avoid contact with eyes. Environmental Precautions: Refer to protective measures listed in Sections 7 and 8. Methods and Materials for Containment and Cleaning Up: Prevent further leakage or spillage if safe to do so. Pick up and transfer to properly labeled containers. 7. HANDLING AND STORAGE STORAGE AND DISPOSAL: Do not contaminate water, food, or feed by storage and disposal. STORAGE: Store in a cool dry place. Do not store where children or animals may gain access. PESTICIDE DISPOSAL AND CONTAINER HANDLING: Non-refillable Container: Do not reuse or refill this container. If empty: Place in trash or offer for recycling if available. If partly filled: Call your local solid waste agency for disposal instructions. Never place unused product down any indoor or outdoor drain. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines: Chemical Name Sucrose ACGIH TLV TWA: 10 mg/m3 OSHA PEL TWA: 15 mg/m3 total dust TWA: 5 mg/m3 respirable fraction (vacated) TWA: 15 mg/m3 total dust NIOSH IDLH TWA: 10 mg/m3 total dust TWA: 5 mg/m3 respirable dust