Stainless Steel - Grade 440 (UNS S44000)

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1 AISI 440C (1.4125, S44004) Stainless Steel Stainless Steel - Grade 440 (UNS S44000) Introduction What is 440C? A martensitic stainless steel. It's composed of these major alloy elements (I don't list the minor elements since they don't play a major role) : Carbon: % This increases hardenability and wear resistance, but decreases toughness in higher amounts. Manganese:.45% This is added to reduce brittleness and improve forgeability, hardenability, and reducing deformation. Silicon:.30% This is a deoxidizer and improves hot-forming properties. Chromium: % Added only to high alloy tool steels, this improves hardenability, high wear resistance, toughness, and corrosion resistance. Molybdenum:.50% Improves deep hardening and toughness. These basic elements (along with iron) are a simple combination that works well together, and has for many decades. This alloy is technically classified as UNS (Unified Numbering System) S It's also classified as SAE (Society for Automotive Engineers) as 51440C. The American Iron and Steel Institute classifies it as 440C martensitic standard stainless steel. Most modern knifemakers simply call it 440C. 440A: this is a hardenable stainless steel alloy, hardenable to a higher hardness than 420 series stainless steels (which are only hardenable to 52 HRC!). 440A has good corrosion resistance, and is used in less expensive bearings and in harder surgical tools (rare). It has 0.6 to 0.75 percent carbon, about the same carbon content as most steel springs. Its advantage is that is cheaper than 440B and slightly more corrosion resistant. 440B: this is a hardenable stainless steel alloy, hardenable to a higher hardness than 440A. It has good corrosion resistance and is used in cutlery (economy), valves, and instrument bearings, where high wear is less important than high corrosion resistance. It has 0.75 to 0.95 percent carbon. 440C: this is also a hardenable stainless steel alloy, hardenable to a higher hardness than 440B. It has good corrosion resistance, and is used in ball bearing balls and races, high pressure nozzles,

2 valve seats and high wear components. It has 0.95 to 1.20 percent carbon. As detailed in the Machinery's Handbook: "This steel has the greatest quenched hardness and wear resistance upon heat treatment of any corrosion-resistant or heat-resistant steel." All three of these steels have the same amount of chromium, from 16 to 18 percent. They are all high chromium martensitic standard stainless steels. All of their other alloy elements are about the same, including manganese, silicon, phosphorus, sulfur, and molybdenum. Truly, the difference in these three is the carbon content, which is substantial. The higher carbon content in 440C yields a much more wear resistant knife blade. It's important to understand the background of this special type of steel. Stainless steels were invented roughly around the beginning of the 20th century. Many different alloys were experimented with, and it didn't take long to discover that chromium, the hardest of all known metals on the Periodic Table of Elements, was highly beneficial as an alloy element to steel. It was discovered that the addition of this extremely corrosion resistant, hard, brittle, and lustrous metal would make steel (basically iron with a tiny amount of carbon) a lot harder, a lot more corrosion resistant, and stronger overall. Another curious fact surfaced too, that the higher the carbon content in the chromium steel, the less corrosion resistant the stainless steel becomes. More carbon makes the steels more hardenable, and thus more wear resistant, but decreases the corrosion resistance. The issue is one of balance, a term frequently referred to in machinists' and engineers' references. This balance depends on the use, exposure, strength, and corrosion resistance needed for particular applications. Grade 440C stainless steels are high carbon steels, which attain the highest hardness, wear resistance and strength of all stainless steel grades after heat treatment. These properties make this grade suitable for applications such as valve components and ball bearings. Grade 440A and 440B stainless steels, on the other hand, have similar properties - except for a slightly lower percentage of carbon in grade 440A. These grades have a corrosion resistance lower than that of other austenitic grades. The applications of martensitic steels are limited by the loss of strength caused by over-tempering at high temperatures, and loss of ductility at temperatures below zero. All three forms of grade 440 steels are commonly used. However, grade 440C is more readily available than the other standard grades. Grade 440F, a free-machining type of grade 440 series, is also available with a high carbon content similar to that of grade 440C. Martensitic steel grades are high-hardness steels, usually fabricated using techniques that require hardening and tempering treatments.

3 Specifications The following specifications cover Stainless Steel 440 C AISI 440C AMS 5618 AMS 5630 AMS 5880 ASTM A276 ASTM A314 ASTM A473 ASTM A493 ASTM A580 DIN QQ S763 UNS S44004 Key Properties The following section discusses the properties of grade 440 bar products covered under ASTM A276. These values may not be similar to that of other forms such as forgings and plates. Composition The chemical compositions of various elements of grade 440 stainless steels are tabulated below: Table 1. Chemical composition ranges of grade 440 stainless steels Grade C Mn Si P S Cr Mo Ni N min. 440A max min. 440B max min. 440C max Mechanical Properties Table 2. Mechanical properties of grade 440C stainless steels Tempering Tensile Yield Strength Elongation (% Hardness Impact

4 Temperature ( C) Strength (MPa) 0.2% Proof (MPa) in 50mm) Rockwell (HR C) Charpy V (J) Annealed* HB max# * Annealed properties are typical for Condition A of ASTM A276# Brinell hardness is ASTM A276 specified maximum for annealed 440A, B and C. Mechanical Property Requirements For Material in the Annealed Condition to 1) AS C and 2) ASTM A276-98b 440C Specification Finish Brinell Hardness AS C 269 Max Capable of attaining Rc59 minimum in 10mm test bar oil quenched from 1010 o C o C. Specifrication ASTM A276-98b 440C Finish Hot Finished Cold Finished Brinell Hardness 269 Max 285 Max Capable of attaining Rc58 minimum in 9.50mm test bar air cooled 1020 o C. Typical Mechanical Properties At Room Temperature in the Annealed Condition (AS Supplied) Tensile Strength Mpa 785 Yield Strength Mpa 420 Elongation in 50mm % 15 Impact Charpy J 6 Hardness HB 240 Rc 24 Typical Mechanical Properties At Room Temperature - Hardened By Oil Quench at 1030 o C and Tempered as Indicated Tempering Temperature o C Tensile Strengt Mpa Yield Strength Mpa Elongation in 50mm % Impact Charpy J Hardness Rc Section Size 25mm High tensile strength, high yield strength and high hardness but low impact properties.

5 Elevated Temperature Properties 440C is not generally recommended for elevated temperature applications due to a reduction in corrosion resistance when tempered above 400 o C Low Temperature Properties 440C is also not recommended for use at sub-zero temperatures due to a further drop in impact properties. Cold Bending Moderate cold bending is possible when fully annealed to maximum softness. Hot Bending Not generally recommended due to the high hardenability - air hardening capabilities of this grade. If really necessary then work piece following operation should be cooled as slowly as possible either in a furnace or in warm dry lime or ashes to room temperature prior to annealing. Material Properties Base Metal Price: 3.5 % rel Density : 7.8 g/cm3 (490 lb/ft3) Elastic (Young's, Tensile) : Modulus210 GPa (30 x 106 psi) Elongation: at Break2 to 14 % Melting : Onset (Solidus)1370 C (2500 F) PREN (Pitting Resistance): 18 Specific Heat Capacity: 430 J/kg-K Strength to Weight Ratio : 97 to 253 kn-m/kg Ultimate (UTS)760 to 1970 MPa (110 to 286 x 103 Tensile Strength: psi) Tensile Strength: Yield (Proof)450 to 1900 MPa (65 to 280 x 103 psi) Thermal Conductivity: 24.2 W/m-K Thermal Diffusivity: 7 Thermal Expansion: 10.8 µm/m-k

6 Thermal Properties Metric English Comments CTE, linear 10.2 µm/m- C 5.67 µin/in F Specific Heat Capacity J/g- C BTU/lb- F from C ( F) Maximum Service Temperature, Air 760 C 1400 F Continuous Service 815 C 1500 F Intermittent Service Physical Properties The following table outlines the physical properties of grade 440 stainless steels:

7 Table 3. Typical physical properties of grade 440 stainless steels Mean Coefficient of Thermal Specific Elastic Thermal Expansion Conductivity Electrical Density Heat Grade (µm/m/ C) (W/m.K) (kg/m 3 Modulus ) Resistivity C (GPa) C C C at at (nω.m) (J/kg.K) 100 C 500 C 440A/B/C Grade Specification Comparison Grade specifications for 440 stainless steels are given in the following table: Table 4. Grade specifications of grade 440 stainless steels Grade UNS No Old British Euronorm BS En No Name 440A S B S X90CrMoV18 Swedish SS 440C S X105CrMo17 - Japanese JIS SUS 440A SUS 440B SUS 440C Possible Alternative Grades Suitable alternatives to grade 440 stainless steels are listed in the table below: Table 5. Possible alternative grades to 440 stainless steels Grade Reasons for choosing 440C 440A/B Slightly softer and more corrosion resistant grade needed 440F High machinability required, with same hardness and hardenability as 440C 420 Lower strength and hardness needed than any of the 440 grades 416 Higher machinability required, and the much lower hardness and strength is still adequate Corrosion Resistance

8 Grade 440 stainless steels exhibit excellent resistance to mild acids, alkalis, foods, fresh water and air. A smooth polished surface also helps grade 440 steels resist corrosion in tempered, passivated and hardened conditions. For optimum corrosion resistance surfaces must be free of scale and foreign particles. Finished parts should be passivated. Grade 440C steels exhibit corrosion resistance similar to that of grade 304 steels. 440C has a corrosion resistance somewhat similar to 410 grade, but lower than 431 grade, also lower than most of the 400 series ferritic stainless steels and all of the 300 series austenitic stainless steels.nb. It has optimum corrosion resistance in the hardened and tempered condition when tempered below 400 o C. Hardening from 1090 o C will ensure better carbide solution, and therefore better corrosion resistance, but minimum soaking time should be allowed at this temperature otherwise excessive grain growth can occur. Polishing will further develop its corrosion resistance. It is not recommended for use in the annealed condition.it is most important that oxygen is always allowed to circulate freely on all stainless steel surfaces to ensure that a chrome oxide film is always present to protect it. If this is not the case, rusting will occur as with other types of non stainless steels. Principal Design Features : This is a high carbon martensitic stainless with moderate corrosion resistance good strength and the ability to obtain and keep excellent hardness (Rc 60) and wear resistance Heat Resistance Grade 440 stainless steels should not be used at temperatures below the relevant tempering temperature, due to loss of mechanical properties caused by over-tempering. Heat Treatment Annealing Grade 440 stainless steels are full annealed at 850 to 900 C, followed by slow furnace-cooling at about 600 C and air-cooling. Sub-critical annealing is carried out at 735 to 785 C, followed by slow furnace-cooling. Sub-Critical Annealing Heat uniformerly to 730 o C o C hold until temperature is uniform throughout the section. *Soak as required. Cool in air. Hardening Grade 440 stainless steels are heated at 1010 to 1065 C, then quenched in air or oil. Oil quenching is usually carried out for heavy sections. Following this process, these steels are

9 tempered at temperatures from 150 to 370 C, to achieve a high hardness and improved mechanical properties. Tempering at temperatures between 425 and 565 C should be avoided as the corrosion and impact resistance properties of grade 440 tend to reduce in this range. Also, tempering of these grades at 590 to 675 C will result in high impact resistance and loss of hardness. Tempering : For maximum properties, soak at 300 F (148 C). Maximum obtainable hardness is RC 60. Welding During welding, grade 440 stainless steels are pre-heated at 250 C, followed by full annealing. Grade 420 filler rods can be used to achieve a high hardness weld. Grade 309 or 310 filler rods will, however, provide soft welds, having high ductility. Grinding and Polishing 440C in the hardened and tempered condition requires care with finish grinding and polishing to avoid overheating as this can lower the hardness and corrosion resistance. Welding Welding 440C in the annealed as supplied condition is not recommended due to its high air hardening capability which can lead to the formation of brittle martensite, resulting in cold cracking due to contraction stresses within the weld and heat affected zone. Welding 440C in the hardened and tempered condition should not be attempted. If welding is really necessary in the annealed condition the following welding procedure and post-weld heat treatment may be taken as a guide only. Welding Procedure Welding electrodes or rods should be low hydrogen types and as *similar to the base metal as possible when high strength is required, otherwise an austenitic stainless *electrode or rod may be used, resulting in a more ductile weld if strength is not so critical.pre-heat at 260 o C and maintain interpass temperature at 260 o C minimum. On completion of welding cool slowly as possible to 260 o C minimum, followed immediately by: Post-weld sub-critical anneal at 730 o C o C or full anneal at 840 o C o C and harden and temper as required.*please consult your welding consumables supplier.

10 Forging Preheat to 760 o C o C, then heat slowly and uniformly to 1050 o C o C, hold until temperature is uniform throughout the section and commence forging immediately.do not overheat as this can cause a loss of toughness and ductility. Do not forge below 900 o CFinished forgings should be cooled slowly in a furnace, warm dry lime or ashes to room temperature and annealed immediately. NB. Air cooling after forging may cause cracking. Machining Grade 440 stainless steels can be easily machined in their annealed state. Machining these grades after hardening is extremely difficult, or impossible in some cases. Best machined in the annealed condition. Tough, stringy chips can be best handled by the use of chip breakers. Carbide or ceramic tooling is recommended. Applications Grade 440 stainless steels find applications in the following: Chisels Surgical equipment High quality knife blades Valve seats Rolling element bearings Ball beatings Gage blocks Moulds Dies Cutlery Valve components Measuring instruments KNIFE STEEL 440C Collectors, investors, professional knife users, active duty military, and others will continue to specifically order fine custom handmade knives made of 440C (and other steels) based on their needs, desires, and intelligent research. 440C is a fine steel for hand knives, it's bright, beautiful, durable, and proven, when properly processed and finished. It excels in corrosion resistance, and

11 is many times stronger than carbon steels, while being reasonably priced. It has high wear resistance, high toughness, and extremely high finish value, which is seldom mentioned, yet extremely important. It won't soon be replaced in the industrial and military complex as a fine, high grade martensitic stainless steel, and the machine tool industry will continue to rely upon it. There is no current replacement for 440C that has the same characteristics as this steel; if there were, and it was less expensive, it would disappear. This is how all products and their production works. In knives, there are only a couple steels that can compare with its beauty while exhibiting the toughness and wear resistance that 440C has. A polished 440C blade will hold its finish for many decades with a minimum of care. It's reasonable to sharpen, it's affordably priced and machined. This is why it simply is a popular knife steel and will remain so. Feel free to enjoy the many 440C blade projects I've made in my three decades of knifemaking on this website, as well as the projects made with other steels! Thanks for being here.