SAFETY DATA SHEET Monoethanolamine & Dilutions

Transcription

1 Safety Data Sheet MEA Revision 1 Revision Date 29/10/10 1 / 5 SAFETY DATA SHEET 1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING PRODUCT NAME CAS-No EU INDEX NO EC No SUPPLIER SYNONYMS, TRADE NAMES Emergency Contact Number (Office Hours) Emergency Contact Number (Outside Office Hours) Central Chemical Supplies Ltd 44 Hall Road Donaghcloney Co Armagh Northern Ireland BT66 7LJ info@ccsni.co.uk Ethanolamine,, MELA,, 2- Amino Ethanol,, MEA, HAZARDS IDENTIFICATION CLASSIFICATION (1999/45) Xn;R20/21/22. C;R34. CLASSIFICATION (EC 1272/200) Physical Health Environmental LABEL IN ACCORDANCE WITH (EC) NO. 1272/200 Not classified. Acute Tox. 4 - H302;Acute Tox. 4 - H312;Acute Tox. 4 - H332;Skin Corr. 1B - H314;STOT SE 3 - H335 Not classified. SIGNAL WORD CONTAINS HAZARD STATEMENTS Danger H302 Harmful if swallowed. H312 Harmful in contact with skin. H314 Causes severe skin burns and eye damage. H332 Harmful if inhaled. H335 May cause respiratory irritation.

2 PRECAUTIONARY STATEMENTS P271 P305/351/33 P310 Use only outdoors or in a well-ventilated area. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. P20 Wear protective gloves/protective clothing/eye protection/face protection. ENVIRONMENT Substantial amounts of the product may lead to a local change in acidity in small water systems which may have adverse effects on aquatic organisms. 3 COMPOSITION/INFORMATION ON INGREDIENTS 2 / 5 >45 CAS-No.: EC No.: CLASSIFICATION (EC 1272/200) Acute Tox. 4 - H302 Acute Tox. 4 - H312 Acute Tox. 4 - H332 Skin Corr. 1B - H314 STOT SE 3 - H335 CLASSIFICATION (67/54) C;R34 Xn;R20/21/22 The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16 EU INDEX NO EC No CAS-No FIRST-AID MEASURES INHALATION Remove victim immediately from source of exposure. Keep the affected person warm and at rest. Get prompt medical attention. INGESTION NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS! Rinse mouth thoroughly. Get medical attention immediately! SKIN CONTACT Remove affected person from source of contamination. Remove contaminated clothing. Wash the skin immediately with soap and water. Get medical attention promptly if symptoms occur after washing. EYE CONTACT Remove victim immediately from source of exposure. Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Get medical attention immediately. Continue to rinse. 5 FIRE-FIGHTING MEASURES EXTINGUISHING MEDIA This product is not flammable. Use fire-extinguishing media appropriate for surrounding materials. SPECIFIC HAZARDS Oxides of: Nitrogen. PROTECTIVE MEASURES IN FIRE Self contained breathing apparatus and full protective clothing must be worn in case of fire. 6 ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS Wear protective clothing as described in Section of this safety data sheet.

3 3 / 5 ENVIRONMENTAL PRECAUTIONS Do not allow ANY environmental contamination. SPILL CLEAN UP METHODS DO NOT TOUCH SPILLED MATERIAL! Stop leak if possible without risk. Absorb in vermiculite, dry sand or earth and place into containers. Flush with plenty of water to clean spillage area. 7 HANDLING AND STORAGE USAGE PRECAUTIONS Avoid spilling, skin and eye contact. STORAGE PRECAUTIONS Store in tightly closed original container in a dry and cool place. Keep in original container. STORAGE CLASS Corrosive storage. EXPOSURE CONTROLS/PERSONAL PROTECTION Name Std TWA - hrs STEL - 15 min Notes 1 ppm(sk) ppm(sk) 7.6 INGREDIENT COMMENTS WEL = Workplace Exposure Limits PROTECTIVE EQUIPMENT PROCESS CONDITIONS Provide eyewash, quick drench. ENGINEERING MEASURES Provide adequate ventilation. Observe occupational exposure limits and minimize the risk of inhalation of vapours. RESPIRATORY EQUIPMENT No specific recommendation made, but respiratory protection may still be required under exceptional circumstances when excessive air contamination exists. HAND PROTECTION Use suitable protective gloves if risk of skin contact. EYE PROTECTION Wear approved safety goggles. Use safety goggles and face shield in case of splash risk. OTHER PROTECTION Wear appropriate clothing to prevent any possibility of skin contact. HYGIENE MEASURES DO NOT SMOKE IN WORK AREA! Wash at the end of each work shift and before eating, smoking and using the toilet. Wash promptly if skin becomes wet or contaminated. Promptly remove any clothing that becomes contaminated. When using do not eat, drink or smoke. 9 PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE Colourless liquid ODOUR Mild Amine. SOLUBILITY Miscible with water BOILING POINT ( C) VAPOUR PRESSURE C RELATIVE DENSITY FLASH POINT ( C) 20 C 96.1 PM Closed cup.

4 PARTITION COEFFICIENT (N-Octanol/Water) STABILITY AND REACTIVITY 4 / 5 STABILITY Stable under normal temperature conditions. CONDITIONS TO AVOID Avoid excessive heat for prolonged periods of time. Avoid contact with acids. MATERIALS TO AVOID Strong acids. Strong oxidising substances. Strong oxides. Chemically active metals. HAZARDOUS DECOMPOSITION PRODUCTS When heated, toxic and corrosive vapours/gases may be formed. 11 TOXICOLOGICAL INFORMATION TOXIC DOSE 1 - LD mg/kg (oral rat) INHALATION May cause damage to mucous membranes in nose, throat, lungs and bronchial system. INGESTION May cause burns in mucous membranes, throat, oesophagus and stomach. SKIN CONTACT May cause serious chemical burns to the skin. EYE CONTACT Causes burns. Name 12 ECOLOGICAL INFORMATION ECOTOXICITY The product may affect the acidity (ph-factor) in water with risk of harmful effects to aquatic organisms. LC 50, 96 Hrs, FISH mg/l 125 EC 50, 4 Hrs, DAPHNIA, mg/l 33 MOBILITY The product is soluble in water. COD 1.54 Name 13 DISPOSAL CONSIDERATIONS GENERAL INFORMATION Do not puncture or incinerate even when empty. DISPOSAL METHODS Dispose of waste and residues in accordance with local authority requirements. 14 TRANSPORT INFORMATION UK ROAD CLASS PROPER SHIPPING NAME UN NO. ROAD ADR CLASS NO. ETHANOLAMINE or ETHANOLAMINE SOLUTION UK ROAD PACK GR.

5 ADR CLASS TUNNEL RESTRICTION CODE ADR LABEL NO. CEFIC TEC(R) NO. RID PACK GROUP IMDG CLASS IMDG PACK GR. MARINE POLLUTANT AIR CLASS Class : Corrosive substances. (E) 0GC7-II+ No. 15 REGULATORY INFORMATION ADR PACK GROUP HAZARD No. (ADR) HAZCHEM CODE RID CLASS NO. UN NO. SEA IMDG PAGE NO. EMS UN NO. AIR AIR PACK GR. 0 2X 147 F-A, S-B 5 / 5 EU DIRECTIVES Dangerous Preparations Directive 1999/45/EC. STATUTORY INSTRUMENTS Chemicals (Hazard Information and Packaging) Regulations. APPROVED CODE OF PRACTICE Safety Data Sheets for Substances and Preparations. Classification and Labelling of Substances and Preparations Dangerous for Supply. GUIDANCE NOTES Workplace Exposure Limits EH40. CHIP for everyone HSG(10). 16 OTHER INFORMATION REVISION COMMENTS NOTE: Lines within the margin indicate significant changes from the previous revision. REVISION DATE SAFETY DATA SHEET STATUS Approved. DATE RISK PHRASES IN FULL R34 R20/21/22 R37 HAZARD STATEMENTS IN FULL H314 H332 H302 H312 H335 Causes burns. Harmful by inhalation, in contact with skin and if swallowed. Irritating to respiratory system. Causes severe skin burns and eye damage. Harmful if inhaled. Harmful if swallowed. Harmful in contact with skin. May cause respiratory irritation.