Hourly I (March 17) E4 Acids, Bases, and Salts March Session two: Acid - Base Neutralization (Parts 3-5) Acid - Base Neutralization

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1 Review Notes Hourly I (March 17) Posted on CTools and course website Review Sessions Friday, March 13, 6-8 pm, 1210 chem. 6-6:40 am: Experiment 1 6:40-7:20 am: Experiment 2 7:20-8: Experiment 3 Monday, March 15, 5:30-7:30 pm, 1800 chem. Question and answers Session two: E4 Acids, Bases, and Salts March Complete E4, Parts 3-5. Complete the team report and discussion presentation. Acid - Base Neutralization (Parts 3-5) Acid - Base Neutralization Neutralization: HNO 3 + NaOH NaNO 3 + HOH acid + base salt + water The reaction of an acid with a base to produce salt and water HCl(g) + NH 3 (g) NH 4 Cl(s) acid base salt Neutralization Reaction Stoichiometry Carboxylic Acids (Parts 3-5) Neutralization reaction stoichiometry is dependant on the number of ionizable protons. HNO 3 + NaOH NaNO 3 + HOH 1 mol 1 mol Carboxylic acids C-based weak acids containing the group H 2 SO NaOH Na 2 SO HOH 1 mol 2 mol 1

2 Carboxylic Acids and Ionizable Protons Electronegativity of the elements* IA IIA IIIB IVB VB VIB VIIB VIIIB IB IIB IIIA IVA VA VIA VIIA H 2.1 O Li Be B C N O F R - C - O - H Na Mg Al Si P S Cl Carboxylic acid group K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At 0.7 The 0.9 electronegativity -Lu of 2.2 H and 2.2 O 2.2 differ and 1.8 therefore H 2.0 in2.2 the Fr Ra Ac group Th Pa is U ionizable. Np- N o The electronegativity of H and C are similar and therefore C- = Metalloids = Nonmetals = Metals H bonds are stable and H in the C-H bond is NOT ionizable Q. How many ionizable protons does benzene (C 6 H 6 ) contain? Answer No ionizable protons. Not an acid. Q. How many ionizable protons does adipic acid contain? O H H H H O Adipic acid HOOC(CH 2 ) 4 H - O C C C C C C O H H H H H Answer: Two ionizable protons. Acid-Base Neutralization CH 3 + NaOH CH 3COONa + HOH acid base salt water Adding base to the weak carboxylic acid drives the reaction (donation of proton/s) to completion Titration (Parts 3-5) Titration Stoichiometry Reaction stoichiometry is dependant on the number of ionizable protons in the carboxylic acid. Acetic acid (Part 3): CH 3 + NaOH CH 3 COONa 1 mol 1 mol + HOH Base delivered from buret Indicator color change signals the end-point or neutralization Oxalic acid (Part 4): HOOC- + 2 NaOH 2COONa + 2HOH 1 mol 2 mol 2

3 Q. How many ml of 0.10 M NaOH will be required to neutralize 10.0 ml of 0.10 M acetic acid? Acetic acid CH 3 + NaOH CH 3 OONa + HOH 1 mol of NaOH is required to neutralize one mol of acetic acid: 1 mmol acid = 1 mmol base 10.0 ml 0.10 M acid = x ml 0.10 M base = 10 ml of 0.10 M NaOH Watch the titration of 10.0 ml of 0.10 M acetic acid with 0.10 M NaOH Note: Look for an error! Titration (Parts 3-5) Part 3 Acid-Base Neutralizations and Indicators Compare the use of indicators for monitoring the neutralization of acetic acid with sodium hydroxide Experiment variable: Indicators Experiment constants Acid identity, concentration, and volume Base identity and concentration CH 3 + NaOH CH 3 COONa + HOH Reaction monitored with phenolphthalein indicator Indicator End Point ph The ph interval where the indicator changes color colorless pink Phenolphthalein: ph ph 10.1 ph 9.1 Titration and Indicator ph End Points yellow blue Bromocresol green: ph ph 5.4 ph 4.6 3

4 Indicator ph End Points Equivalence Point ph The ph of the salt and water products of the neutralization reaction = the equivalence point ph. The products may be acidic, or basic or neutral Example: CH 3 + NaOH CH 3COONa + HOH Equivalence point ph ph 8 Indicators have different end-point ph color changes For information on lab indicators, see the lab manual, p. 194 Acid-Base Neutralization Products Parts 4-5: Equivalent Weight (EW) of an Acid Mass (grams) of compound providing one mole of H + or = Molecular weight # ionizable protons Examples: H 2 SO 4 = molecular weight = 98 H 2 SO 4 = equivalent weight = 49 Acetic acid + NaOH sodium acetate + HOH The salt and water product is not neutral HCl = molecular weight = 36.5 HCl = equivalent weight = 36.5 Q. Themolecular weight of benzoic acid = 122. What is its equivalent weight? Benzoic acid Benzoic acid = C 6 H 5 Answer: EW = 122 Q. An acid has an equivalent weight (EW) of g/mole. List the number of any compound from the table that may be the acid. Compound Formula MW 1. Ethanoic acid CH Butanoic acid CH3CH2CH Oxalic acid HOOC methyl, 1,2 benzene dicarboxylic acid CH3C 6 H3()2 180 Answer. Compounds # 2 and # 4. 4

5 A teammate titrates a carboxylic acid and calculates the EW of the acid to be 72.50g/mol. The result is correct within 2%. The MW of the acid = 1.5 x 10 2 Circle each structure that is consistent with the data. Adipic Acid, MW = 146: HO 2 CCH 2 CH 2 CH 2 CH 2 CO 2 H Trans-cinnamic acid, MW=148 -CH=CH- Parts 4-5: EW from Experiment Data Experimentally determine the equivalent weight of a carboxylic acid by titration EW = Mass (g) of acid providing 1 mol H + or neutralizing 1 mol OH -. Citric Acid, MW = 192: Oxalic acid, MW = 90 HO 2 C-CH 2 -C(OH)-CH 2 -CO 2 H HO 2 C CO 2 H CO 2 H EW = mass acid (g) moles of OH - neutralized Part 4: Equivalent Weight Practice EW of Oxalic Acid (Part 4) Q ml of 0.10 M NaOH neutralizes 0.22 grams of acid. What is the equivalent weight of the acid? Mass of acid = ; mol of OH - neutralized = Answer g acid neutralized 3.49 mmol of NaOH. The mass of acid needed to neutralize 1 mol =? Sample = oxalic acid dihydrate, HOOC2H 2 O (MW = ; EW = 63.04g/mol) g/mol = EW Equivalent Weight Errors 1. Acid mass is incorrect 2. Sample is not all transferred to titration flask 3. Buret tip is not filled with titrant 4. Buret volume readings are incorrect 5. Titration flask and contents not mixed properly 6. Incorrect indicator used to monitor titration 7. Recorded volume of delivered base is incorrect EW = mass acid (g) moles of OH - neutralized Part 5. Identification of an Unknown Acid Identify a carboxylic acid from melting point and equivalent weight titration data Q. Error 2 will result in an EW that is greater than true. Why? 5

6 Determine the approximate volume of NaOH needed to neutralize a mass of unknown acid BEFORE conducting a quantitative determination of the equivalent weight by titration Practice melting point and equivalent weight skills with known compounds BEFORE testing the unknown See Table, p.118 Name 2-hydroxybenzoic acid acetate trans-cinnamic acid Formula OCOCH 3 MW EW CH CH MP 135 HOOC Determine the approximate melting point 2-chlorobenzoic acid Cl range (e.g., ºC) BEFORE quantitatively determining the actual melting point range cis-butenedioic (maleic) acid H H Q. You titrate g of an acid ml of 0.10 M NaOH neutralizes the sample. Identify the acid from the list below. Name Formula MW MP 2-hydroxybenzoic acid acetate OCOCH 3 trans-cinnamic acid chlorobenzoic acid CH cis-butenedioic (maleic) acid H H HOOC Cl CH Equivalent weight determination. 1) Determine mol of NaOH the acid has neutralized. Fact: The acid mass neutralized ml of 0.10 M NaOH mol OH - = V(L) x M NaOH = L x 0.10 mol L = 3.0 x 10-3 mol Equivalent Weight determination. 2) Determine the mass of acid that would neutralize one mol of hydroxide ions. Known: g = mol OH- X g acid 1 mol OH - X = 58 g Q. What is the identity of the acid if EW = 58? Name Formula MW MP 2-hydroxybenzoic acid acetate OCOCH 3 trans-cinnamic acid chlorobenzoic acid CH cis-butenedioic (maleic) acid H H HOOC Cl CH

7 Questions? Contact 7

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