Writing Formulas and Naming Ionic & Covalent Compounds Douglas Gilliland Honors Physical Sarasota High Sarasota, Florida

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1 Writing Formulas and Naming Ionic & Covalent Compounds 2005 Douglas Gilliland Honors Physical Sarasota High Sarasota, Florida

2 Chemical Compounds An atom consist of a positively charged nucleus (protons and neutrons) and orbiting electrons. Atoms of elements are not chemically stable until they have 8 electrons (octet rule). Atoms gain, lose or share electrons with other atoms to be come chemically stable ( have 8 valence electrons ). Six valence electrons. 8+ Not chemically stable. Oxygen Atom Eight valence electrons. Chemically stable Oxide Ion

3 Types of Compounds I o n i c - occurs when a metal loses all its valence electrons to a nonmetal. Metal becomes a cation, nonmetal an anion. C o v a l e n t - two nonmetals share electrons. Neither loses or gains electrons - they share electrons. Neither atom becomes and ion.

4 Ionic Compounds Crystalline Lattice

5 Burning Magnesium 2Mg + 2MgO O Magnesium Atom + Oxygen Atom Magnesium Ion + Oxide Ion

6 Sodium Atom + Chlorine Atom Sodium Ion + Chloride Ion Reaction between sodium + chlorine 2Na + Cl2 2NaCl

7 Ionic Compounds Includes a metal and a nonmetal. Metal loses e- and becomes a cation (+). Nonmetal gains e- and becomes an anion(-). Metal comes first followed by nonmetal. Change the name of the nonmetal to -ide. Examples: nitride, sulfide, fluoride, oxide, bromide, iodide, chloride, telluride, phosphide.

8 Valence electrons are electrons in the outer energy level of an atom. Metals have between 1-3 valence electrons. Nonmetals have between 5-7 valence electrons. Lose e- Gain e- Cations (+ ions) Anions (- ions)

9 The valence of an elements is the charge it takes when it loses or gains electrons. Metal atoms lose electrons and become + ions (cations) Nonmetals gain electrons and become - ions (anions) Transition Metals Multiple valences 0

10 The 5 Steps for writing an ionic compound formula: Write the symbols of the two elements. Write the valence of each as superscripts. Drop the positive and negative signs. Crisscross the superscripts so they become subscripts. Reduce when possible.

11 Formula for boron oxide 1. Write the symbols of the two elements. B O

12 Formula for boron oxide 2. Write the valence for each element B O

13 Formula for boron oxide 3. Drop the positive & negative sign. 3 2 B O

14 Formula for boron oxide 4. Crisscross the superscripts so they become subscripts. B 3 2 O

15 Formula for boron oxide 4. Crisscross the superscripts so they become subscripts. B O 2 3

16 Formula for boron oxide 5. Reduce subscripts when possible. (not possible here) B O 2 3

17 Examples of Reduction Ca S CaS 2 2 Ge O Ge O Be Te 2 3 can t reduce Al N 3 3 Sn O 2 4 AlN SnO 2

18 Most Transition elements have 2 valences. Roman numerals are used in the name to show the valence on the ion. Period 4 Transition Metals Examples: Mn Manganese(IV) Mn Manganese(VI) Fe Iron(II) Fe Iron(III) Cu Copper(I) Cu Copper(II) +2

19 Examples of Transition Metals Iron(II) Iron(III) Copper(I) Copper(II) Fe +2 Fe +3 Manganese(II) Cu +1 Cu +2 Mn +2 Manganese(IV)Mn +4

20 Naming compounds with a transition metal. formula Fe O 2 3 name Iron(III) oxide ZnCl AgCl 2 Zinc(II) chloride Silver(I) chloride Cu P 3 2 PbS 2 MnO 2 Copper(II) phosphide Lead(IV) sulfide Manganese(IV) oxide

21 Polyatomic Ions -1 Polyatomic (many atom) ions are covalent molecules with a charge. They behave as if they were a single atom ion.

22 Polyatomic Ions NH +1 OH -1 NO -1 2 SO 2-2 Hydroxide Sulfate 4 Ammonium Nitrite SO -2 3 CO -2 3 Sulfite Carbonate NO -1 3 Nitrate PO -3 4 Phosphate Treat polyatomic ions as you would any ion - crisscross to determine the formula. The only difference is that when you have more than one of a specific polyatomic ion in a formula you must encase it in parenthesis.

23 Writing Formulas Cation Anion Compound Ca +2 NO -1 3 Mg +2 PO Na OH -1 Ba +2-2 SO 4 Ca(NO ) 3 2 Mg ( PO ) NaOH Ba SO 4 As in all ionic compounds you must reduce subscripts, but you cannot change the formula of the polyatomic ion. You can only reduce subscripts outside the parenthesis.

24 Compounds with Polyatomic ions Carbonate CO 3-2 Sodium carbonate Na CO 3 2 Calcium carbonate Ca CO 3 Aluminum carbonate Al ( ) 2 CO 3 3 Phosphate PO -3 4 Sodium phosphate Na PO 4 3 Calcium phosphate Ca ( PO ) Aluminum phosphate AlPO 3

25 Covalent Compounds Water Molecule Hydrogen Atom Oxygen Atom Hydrogen Atom

26 Covalent Compounds Two nonmetals share electrons so both have 8 valence electrons. Exception: H Neither takes on a charge - no valence. Must use prefixes in the name. Name tells you the formula. Example: N2O4 is dinitrogen tetraoxide. You cannot reduce the formulas!!!

27 Reaction between hydrogen + oxygen 2H2 + O2 2H2O Hydrogen Atoms Oxygen Atom Water Molecule 1+

28 The Space Shuttle Oxygen Hydrogen Water Vapor Exothermic Reaction 2H2 + O2 2H2O

29 Covalent Prefixes Mon - 1 Di - 2 Tri - 3 Tetra - 4 Pent - 5 Hex - 6 A prefix tells you the number of atoms of that element in the compound.

30 Examples of Covalent Compounds Dinitrogen trioxide Carbon tetrahydride N O 2 3 CH 4 Phosphorus pentoxide disulfur trifluoride PO 5 S F 2 3

31 Ionic and Covalent Structure Ionic compounds form a crystalline lattice - a repeating pattern of ions. Water H atoms O atom Covalent compounds -3 N ions Boron nitride +3 B ions form individual molecules that are not connected to each other.

32 Naming Binary Compounds Use Roman Numerals to tell the valence of the metal. Does the compound have a metal? Yes Ionic (Metal cation + Nonmetal anion) Place metal first followed by nonmetal ending in -ide Contain a Transition Metal? Yes Examples: iron(iii) oxide copper(ii) chloride manganese(iv) oxide silver(i) chloride No Do not use Roman Numerals Examples: sodium chloride magnesium nitride aluminum fluoride beryllium oxide No Covalent (Two Nonmetals) Place the nonmetal furthest to the left on the periodic table first, then the other nonmetal ending in -ide. Use prefixes to tell the number of atoms in the compound mon(o)-1, di-2, tri-3, tetr(a)-4, pent(a)-5, hex-6 Examples: dinitrogen trioxide, nitrogen trichloride, phosphorus pentoxide, sulfur dioxide carbon tetrachloride, dihydrogen oxide

33 Summing up: Ionic Ionic bonding occurs between a metal and a nonmetal. Metals lose all their valence e- and become cations. Nonmetals gain enough e- to fill their valence level and become anions. Always crisscross valences and reduce to determine the formulas of ionic compounds Do not use prefixes in the names. Ions form a crystalline lattice.

34 Summing up: Covalent Covalent bonding occurs when two nonmetals share electrons to fill their valence energy level. Never use valence to determine the formula - there isn t any valence. Since the two atoms share electrons, they do not take on a charge. Always use prefixes in the names. Atoms combine to form individual molecules.

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