Chapter 25. Organic and Biological Chemistry. Organic and
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1 Chapter 25
2 Calculate grade: (Add exam1 exam 3 scores) (520 total 4) (Add 4 best quizzes) x 1.25 (50 total) (Add Total Mastering chemistry points x 0.70) (200 total) Gives you the # points you have so far. + recitation points (50 possible) + Final (worth 180 points) = total points Grades: etc.
3 Organic The chemistry of carbon compounds. What s special about carbon? tetravalent (sp 3 hybridization) wide choice in oxidation states CO 2 C, +4 CH 4 C, -4 bonds well to O, N,halides,itself,etc. Covalent bonds are very strong
4 Structure of Carbon Compounds There are three hybridization states and geometries found in organic compounds: sp 3 Tetrahedral sp 2 Trigonal planar sp Linear
5 Four types: Hydrocarbons (contain only H and C) Alkanes Alkenes Alkynes Aromatic hydrocarbons
6 Alkanes Only single bonds. Saturated hydrocarbons. Saturated with hydrogens.
7 Formulas Lewis structures of alkanes look like this. Also called structural formulas. Often not convenient, though
8 Formulas so more often condensed formulas are used.
9 Properties of Alkanes Only van der Waals force: London force. Boiling point increases with length of chain.
10 Structure of Alkanes Carbons in alkanes sp 3 hybrids. Tetrahedral geometry bond angles.
11 Structure of Alkanes Only σ-bonds in alkanes Free rotation about C C bonds.
12 Structural Isomers Have same molecular formulas, but atoms are bonded in different order.
13 Organic Nomenclature Three parts to a compound name: Base: Tells how many carbons are in the longest continuous chain.
14 Organic Nomenclature Three parts to a compound name: Base: Tells how many carbons are in the longest continuous chain. Suffix: Tells what type of compound it is.
15 Organic Nomenclature Three parts to a compound name: Base: Tells how many carbons are in the longest continuous chain. Suffix: Tells what type of compound it is. Prefix: Tells what groups are attached to chain.
16 To Name a Compound 1. Find the longest chain in the molecule. 2. Number the chain from the end nearest the first substituent encountered. 3. List the substituents as a prefix along with the number(s) of the carbon(s) to which they are attached.
17 To Name a Compound If there is more than one type of substituent in the molecule, list them alphabetically. If there is more than one way to make the longest chain, pick the one with the most substituents.
18 Cycloalkanes Carbon can also form ringed structures. Five- and six-membered rings are most stable. Can take on conformation in which angles are very close to tetrahedral angle. Smaller rings are quite strained.
19 Reactions of Alkanes Rather unreactive due to presence of only C C and C H σ-bonds. Therefore, great nonpolar solvents. General rule of organic chemistry; reactivity comes from the functional groups, ie. the part of the molecule that is not a straight alkane. different functional groups give rise to different kinds of activity.
20 Alkenes Contain at least one carbon carbon double bond. Unsaturated. Have fewer than maximum number of hydrogens.
21 Structure of Alkenes Unlike alkanes, alkenes cannot rotate freely about the double bond. Side-to-side overlap makes this impossible without breaking π-bond.
22 Structure of Alkenes This creates geometric isomers, which differ from each other in the spatial arrangement of groups about the double bond.
23 Properties of Alkenes Structure also affects physical properties of alkenes.
24 Nomenclature of Alkenes Chain numbered so double bond gets smallest possible number. cis- alkenes have carbons in chain on same side of molecule. trans- alkenes have carbons in chain on opposite side of molecule.
25 Reactions of Alkenes Addition Reactions Two atoms (e.g., bromine) add across the double bond. One π-bond and one σ-bond are replaced by two σ-bonds; therefore, ΔH is negative.
26 Mechanism of Addition Reactions H H The basics of arrow pushing: Arrow goes from where electrons come from to where they are going. Alkene addition two-step mechanism: First step is slow, rate-determining step. Second step is fast.
27 Mechanism of Addition Reactions In first step, π-bond breaks and new C H bond and cation form.
28 Mechanism of Addition Reactions In second step, new bond forms between negative bromide ion and positive carbon.
29 Alkynes Contain at least one carbon carbon triple bond. Carbons in triple bond sp-hybridized and have linear geometry. Also unsaturated.
30 Nomenclature of Alkynes 4-methyl-2-pentyne Analogous to naming of alkenes. Suffix is -yne rather than ene.
31 Reactions of Alkynes Undergo many of the same reactions alkenes do. As with alkenes, impetus for reaction is replacement of π-bonds with σ-bonds.
32 Aromatic Hydrocarbons Cyclic hydrocarbons. p-orbital on each atom. Molecule is planar. Odd number of electron pairs in π-system.
33 Aromatic Nomenclature Many aromatic hydrocarbons are known by their common names.
34 Reactions of Aromatic Compounds Unlike in alkenes and alkynes, π- electrons do not sit between two atoms. Electrons are delocalized; this stabilizes aromatic compounds.
35 Reactions of Aromatic Compounds Due to stabilization, aromatic compounds do not undergo addition reactions; they undergo substitution. Hydrogen is replaced by substituent.
36 Structure of Aromatic Compounds Two substituents on a benzene ring could have three possible relationships ortho-: On adjacent carbons. meta-: One carbon between them. para-: On opposite sides of ring.
37 Reactions of Aromatic Compounds Halogenation Friedel-Crafts Reaction Reactions of aromatic compounds often require a catalyst.
38 Functional Groups Term used to refer to parts of organic molecules where reactions tend to occur.
39 Alcohols Contain one or more hydroxyl groups, OH Named from parent hydrocarbon; suffix changed to -ol and number designates carbon to which hydroxyl is attached.
40 Alcohols a steroid
41 Ethers Tend to be quite unreactive. Therefore, they are good polar solvents.
42 Carbonyl Compounds Contain C O double bond. Include many classes of compounds.
43 Aldehydes At least one hydrogen attached to carbonyl carbon.
44 Ketones Two carbons bonded to carbonyl carbon.
45 Carboxylic Acids Have hydroxyl group bonded to carbonyl group. Tart tasting. Carboxylic acids are weak acids CH 3 COOH Acetic acid
46 Carboxylic Acids
47 Esters Products of reaction between carboxylic acids and alcohols. Found in many fruits and perfumes.
48 Amides Formed by reaction of carboxylic acids with amines.
49 Amines Organic bases. Generally have strong, unpleasant odors.
50 Chirality Carbons with four different groups attached to them are handed, or chiral. Optical isomers or stereoisomers If one stereoisomer is right-handed, its enantiomer is left-handed.
51 Chirality Many pharmaceuticals are chiral. Often only one enantiomer is clinically active. Why? S-ibuprofen
52 Chirality Protein S-ibuprofen Because they interact with a chiral protein binding site.
53 Amino Acids and Proteins Proteins are polymers of α-amino acids. A condensation reaction between the amine end of one amino acid and the acid end of another produces a peptide bond.
54 Amino Acids and Proteins Hydrogen bonding in peptide chains causes coils and helices in the chain. Kinking and folding of the coiled chain gives proteins a characteristic shape.
55 Amino Acids and Proteins pyrophosphorylase makes starch in plants The complete molecule is a tetramter. It s mass is 240,000 amu.
56 Carbohydrates Simple sugars are polyhydroxy aldehydes or ketones.
57 Carbohydrates In solution they form cyclic structures. These can form chains of sugars that form structural molecules such as starch and cellulose.
58 Nucleic Acids Two of the building blocks of RNA and DNA are sugars (ribose or deoxyribose) And cyclic bases (adenine, guanine, cytosine, and thymine or uracil).
59 Nucleic Acids These combine with a phosphate to form a nucleotide.
60 Nucleic Acids Nucleotides combine to form the familiar double-helix form of the nucleic acids.
61
62 The FINAL The best preparation: 1. The four exams and 9 quizzes. I ll bet, since I m, after all, a little lazy, that I ll use some of these questions Topics: Chapter 1. Dimensional analysis significant figures
63 The FINAL Chapter 2. History of atomic structure dalton cathode ray tubes rutherford gold foil experiment Miliken s oil drop experiment atomic numbers, mass, isotopes average at. weights The periodic table groups, periods, etc. molecular and empirical formulas ions, ionic compounds naming inorganic compounds naming binary molecular compounds (nitrogen triodide)
64 The FINAL Chapter 2. compounds naming binary molecular compounds (nitrogen triodide) atomic structure, protons, neutrons, electrons Chapter 3. stoichiometry calculations dealing with chemical reactions limiting reagent calculate empirical formula
65 The FINAL Chapter 4, aqueous reactions, solution stoichiometry strong and weak electrolytes the strong acids and the strong bases Know your anions and cations. precipitation reactions acid/base reactions Redox, oxidations numbers, redox reactions. the activity series solution stoichiometry titrations
66 The FINAL Chapter 5, thermochemistry Kinetic and potential energy what is work versus heat? ΔH and E what is a state function pv work calorimetry Hess s law enthalpies of formation
67 The FINAL Chapter 6, electronic structure of atoms wave and particle nature of light black body radiation, quantization of energy photons The photoelectric effect Line spectra & the bohr model Quantum mechanics atomic numbers atomic orbitals electron spin electron configuration The periodic table explained
68 The FINAL Chapter 7, Periodic properties of the elements effective nuclear charge sizes of atoms sizes of ions ionization energies electron affinities group trends for: alkali metals alkine earch metals oxygen group, halogens, noble gases
69 The FINAL Chapter 8, chemical bonding ionic bonding metal bonding covalent bonding bond polarity electronegativity lewis structures multiple bonds resonance structures octet rule and exceptions bond enthalpy and bond length
70 The FINAL Chapter 9, VSEPR, valence bond and molecular orbital theory self explanatory. Chapter 25, organic and biochemistry hydrocarbons functional groups naming organic compounds isomers what s an amino acid? What s a protein? What s a sugar? polysaccharide?
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