MATERIAL SAFETY DATA SHEET MSDS DATE: 8/2/11

Transcription

1 SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: DISTRIBUTOR: Alligare, LLC ADDRESS: 13 N 8 th Street, Opelika, AL CHEMTREC PHONE: US: International: CHEMICAL NAME: Proprietary mixture CHEMICAL FAMILY: Surfactant blend CHEMICAL FORMULA: Mixture PRODUCT USE: SECTION 1 NOTES: Agricultural adjuvant SECTION 2: HAZARDOUS INGREDIENTS SARA 313 OSHA ACGIH INGREDIENT CAS NO. % WT REPORTABLE TWA STEL Ceiling TWA STEL Ceiling Ethanol, 2, 2-oxybis < 10% No Not listed Not listed SECTION 2 NOTES: SECTION 3: HAZARDS IDENTIFICATION ROUTES OF ENTRY: Eyes, skin, ingestion, inhalation POTENTIAL HEALTH EFFECTS EYES: May cause eye irritation. SKIN: INGESTION: INHALATION: Short- and long-term exposure can irritate and cause local redness and swelling. Harmful if swallowed. May cause dizziness and drowsiness. This product is not to be used in food, cosmetic or potable water applications. Product contains diethylene glycol, which is toxic when swallowed. Inhalation hazards only exist if the product is misted or sprayed so that fine droplets enter the respiratory system. This may cause redness and irritation of the tissues, headache, nausea and drowsiness ACUTE HEALTH HAZARDS: beyond those above CHRONIC HEALTH HAZARDS: known MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: known CARCINOGENICITY OSHA: No ACGIH: No NTP: No IAR No OTHER: No SECTION 3 NOTES: PAGE 1 OF 5

2 SECTION 4: FIRST AID MEASURES If in Eyes: Hold eye open and rinse slowly and gently with water for minutes. Remove contact lenses if present, after the first 5 minutes, then continue rinsing eye. Have the product container with you when calling a poison control center or doctor, or going for treatment. If on Skin or Clothing: Take off contaminated clothing. Rinse skin immediately with plenty of water for minutes. If Swallowed: Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by a poison control center or doctor. Do not give anything by mouth to an unconscious person. If Inhaled: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth to mouth if possible. NOTES TO PHYSICIANS OR FIRST AID PROVIDERS: Does NOT contain pesticidal products. SECTION 4 NOTES: SECTION 5: FIRE-FIGHTING MEASURES FLAMMABLE LIMITS IN AIR, UPPER: (% BY VOLUME) LOWER: FLASH POINT: METHOD USED: AUTOIGNITION TEMPERATURE: >200 >93 PMCC NFPA HAZARD CLASSIFICATION HEALTH: 2 FLAMMABILITY: 1 REACTIVITY: 1 OTHER: - EXTINGUISHING MEDIA: SPECIAL FIRE FIGHTING PROCEDURES: UNUSUAL FIRE AND EXPLOSION HAZARDS: HAZARDOUS DECOMPOSITION PRODUCTS: SECTION 5 NOTES: CO2, dry chemical, chemical foam or water spray Mixture with water will cause foaming known Under fire conditions, oxides of carbon SECTION 6: ACCIDENTAL RELEASE MEASURES ACCIDENTAL RELEASE MEASURES: Collect using absorbent material. See section 13 for disposal. SECTION 6 NOTES: SECTION 7: HANDLING AND STORAGE HANDLING AND STORAGE: Store in a cool, dry place. Keep container tightly closed. For optimum storage stability, store at temperatures between 40 F (5 C) and 90 F (32 C). Keep away from heat, sparks, and flame. Do not use with aluminum equipment at temperatures above 120 F (49 C). Avoid contact with eyes and skin. Do not store near oxidizing agents SECTION 7 NOTES: KEEP OUT OF REACH OF CHILDREN PAGE 2 OF 5

3 SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION VENTILATION : RESPIRATORY PROTECTION: EYE PROTECTION: SKIN PROTECTION: Normal room ventilation or outdoor handling should be satisfactory required during normal use. If exposure is expected, use an approved respirator with an organic vapor filter. Chemical goggles Chemically impervious gloves, long sleeves and long pants OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Eye wash station and safety shower WORK HYGIENIC PRACTICES: EXPOSURE GUIDELINES: SECTION 8 NOTES: Do not take by mouth. Wash hands before eating, drinking, smoking, chewing tobacco or doing anything by mouth SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: ODOR: PHYSICAL STATE: Amber Mild Liquid ph AS SUPPLIED: Not applicable ph (Other): % in water BOILING POINT: MELTING POINT: FREEZING POINT: VAPOR PRESSURE (mmhg): VAPOR DENSITY (AIR = 1): SPECIFIC GRAVITY (H2O = 1): ~ EVAPORATION RATE: BASIS (butyl acetate=1): SOLUBILITY IN WATER: Soluble VISCOSITY: SECTION 9 NOTES: SECTION 10: STABILITY AND REACTIVITY PAGE 3 OF 5

4 STABILITY: Stable Unstable CONDITIONS TO AVOID (STABILITY): INCOMPATIBILITY (MATERIAL TO AVOID): known Strong oxidizing agents HAZARDOUS DECOMPOSITION OR BY-PRODUCTS: known HAZARDOUS POLYMERIZATION: CONDITIONS TO AVOID (POLYMERIZATION): SECTION 10 NOTES: Will not occur known SECTION 11: TOXICOLOGICAL INFORMATION TOXICOLOGICAL INFORMATION: SECTION 11 NOTES: Not available SECTION 12: ECOLOGICAL INFORMATION ECOLOGICAL INFORMATION: SECTION 12 NOTES: Not available SECTION 13: DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD: RCRA HAZARD CLASS: SECTION 13 NOTES: Absorb into appropriate material then incinerate or landfill, if permitted. Dispose of according to all local, state and federal laws and regulations. Triple rinse container then incinerate or landfill, if permitted. Not listed SECTION 14: TRANSPORT INFORMATION U.S. DEPARTMENT OF TRANSPORTATION PROPER SHIPPING NAME: Not regulated HAZARD CLASS: ID NUMBER: PACKING GROUP: LABEL STATEMENT: OTHER AGENCIES: SECTION 14 NOTES: known SECTION 15: REGULATORY INFORMATION U.S. FEDERAL REGULATIONS TSCA (TOXIC SUBSTANCE CONTROL ACT): Not listed PAGE 4 OF 5

5 CERCLA (COMPREHENSIVE RESPONSE COMPENSATION, AND LIABILITY ACT): Not regulated SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT): 311/312 HAZARD CATEGORIES: 313 REPORTABLE INGREDIENTS: STATE REGULATIONS: WARNING! This product contains a detectable amount of ethylene oxide, which is known to the State of California to cause cancer and/or reproductive toxicity. Ethoxylated products may contain residual amounts of ethylene oxide (EO) which can accumulate in the container headspace and be released into the ambient environment. This process is enhanced when the product is agitated, as during tank car loading and unloading, and blending operations. Ethylene oxide causes tumors in laboratory animals. The Occupational Safety and Health Administration (OSHA) PermissibleExposure Level (PEL) for EO is 1 ppm for an eight-hour time weighted average exposure. The standard regulates occupational exposure to EO from all sources, including products containing residual EO. It is the responsibility of the employer to comply with OSHA ethylene oxide standard (29) CFR ). INTERNATIONAL REGULATIONS: SECTION 15 NOTES: SECTION 16: OTHER INFORMATION OTHER INFORMATION: PREPARATION INFORMATION: Prepared on 8/2/11 DISCLAIMER: The recommendation for safe handling and protection procedures is believed to be generally suitable for the standard uses of this compound. However, each user should identify his intended uses of this material and determine whether they are appropriate. All data included in this document is released as typical values and should not be utilized to determine the suitability of this material for a particular use or purpose. No warranty, either expressed or implied, is hereby made, nor do we give permission, inducement, or recommendations to practice any patented invention without a license. All data is offered for consideration, investigation and verification purposes only. Alligare, LLC 13 N 8th Street Opelika, AL PAGE 5 OF 5