Unit4Day5-LaBrake. Important Information. Vanden Bout/LaBrake/Crawford CH301. The 2 nd Law of Thermodynamics Entropy, continued.
|
|
|
- Marvin Long
- 7 years ago
- Views:
Transcription
1 Unit4Day5-LaBrake Monday, November 18, :25 PM Vanden Bout/LaBrake/Crawford CH301 The 2 nd Law of Thermodynamics Entropy, continued UNIT 4 Day 5 Important Information LM33 Due Th November 29 th 9AM HW11 Due T DECEMBER 4 th 9AM End of semester attitude survey opens today End of semester Course Evaluations open 2 weeks!! Unit4Day5-LaBrake Page 1
2 What are we going to learn today? Second & Third Law of Thermodynamics Quantify change in Entropy QUIZ: iclicker Question 1 Which of the following has the highest positional probability? a) 1 mole N 2 gas at 1 atm b) 1 mole N 2 gas at.001 atm c) No difference QUIZ: iclicker Question 2 Which of the following has the higher entropy? a) 1 mole N 2 gas at 1 atm b) 1 mole N 2 gas at.001 atm c) No difference Unit4Day5-LaBrake Page 2
3 QUIZ: iclicker Question 3 Predict sign for the for S sys for sugar dissolving in water. a) - b) + c) No difference QUIZ: iclicker Question 4 Predict the sign for the for S sys for iodine vapor condensing on a cold surface. a) - b) + c) No difference Entropy What affects the entropy of the system? Volume Change Mixing Phase Change Temperature Change Chemistry Unit4Day5-LaBrake Page 3
4 Entropy of the Surroundings We typically define heat from the perspective of the system. Therefore, when we look at changes for the surroundings, we see the relationship is Exothermic S surroundings > 0 Endothermic S surroundings < 0 Entropy and Temperature Entropy and Temperature Unit4Day5-LaBrake Page 4
5 Entropy for a Phase Change During a phase change, the heat is the reversible heat and the temperature is constant trans a phase transition (i.e. vaporization, melting) Entropy for a Chemical Change During a chemical change, the heat is NOT the reversible heat and the temperature is constant Reactants Products We need to be able to find the entropy of a substance The Third Law of Thermodynamics The entropies of all perfect crystals approach zero when the absolute temperature approaches zero. We can then use entropy change from temperature change and phase change to find the entropy of any substance at any temperature Unit4Day5-LaBrake Page 5
6 Absolute Entropies NOTE: This is not the same as enthalpy of formation. All elements in their standard states have values 2H 2 (g) + O 2 (g) 2H 2 O(l) Entropy What affects the entropy of the system? Volume Change - only qualitative Mixing - only qualitative Phase Change Temperature Change Chemistry Activity Please open your course pack to page 109 Thermo Unit- Entropy of Physical and Chemical Changes Unit4Day5-LaBrake Page 6
7 Given that H fus = 6.02 kj mol -1 and that the heat capacity for water is J g -1 C -1. How much heat flows into the system for this process? a. 12 kj b. 16 kj c kj d kj QUIZ: iclicker Question 5 QUIZ: iclicker Question 6 Which is the larger entropy change? a. ΔS melting b. ΔS warming c. They are the same QUIZ: iclicker Question 7 Did heat flow into or out of the surroundings during this change? a. into b. out c. No heat flow Unit4Day5-LaBrake Page 7
8 What is the entropy change for the surroundings? a. 42 J/K b. -42 J/K c. 53 J/K d. -53 J/K QUIZ: iclicker Question 8 QUIZ: iclicker Question 9 What is the total change in entropy per mole of solid ice that melts under these conditions? a. -55 J/K mol b. 55 J/K mol c J/K mol d. 2.1 J/K mol e. 0 J/K mol Learning Outcomes Calculate change in entropy of a system for physical change at constant temperature and with a change in temperature, and for a chemical change using tabulated standard molar entropy data. Calculate change in entropy for the surroundings for a physical change and a chemical change. Unit4Day5-LaBrake Page 8
The first law: transformation of energy into heat and work. Chemical reactions can be used to provide heat and for doing work.
The first law: transformation of energy into heat and work Chemical reactions can be used to provide heat and for doing work. Compare fuel value of different compounds. What drives these reactions to proceed
Bomb Calorimetry. Example 4. Energy and Enthalpy
Bomb Calorimetry constant volume often used for combustion reactions heat released by reaction is absorbed by calorimeter contents need heat capacity of calorimeter q cal = q rxn = q bomb + q water Example
Mr. Bracken. Multiple Choice Review: Thermochemistry
Mr. Bracken AP Chemistry Name Period Multiple Choice Review: Thermochemistry 1. If this has a negative value for a process, then the process occurs spontaneously. 2. This is a measure of how the disorder
Thermochemistry. r2 d:\files\courses\1110-20\99heat&thermorans.doc. Ron Robertson
Thermochemistry r2 d:\files\courses\1110-20\99heat&thermorans.doc Ron Robertson I. What is Energy? A. Energy is a property of matter that allows work to be done B. Potential and Kinetic Potential energy
Thermodynamics. Thermodynamics 1
Thermodynamics 1 Thermodynamics Some Important Topics First Law of Thermodynamics Internal Energy U ( or E) Enthalpy H Second Law of Thermodynamics Entropy S Third law of Thermodynamics Absolute Entropy
Chapter 18 Homework Answers
Chapter 18 Homework Answers 18.22. 18.24. 18.26. a. Since G RT lnk, as long as the temperature remains constant, the value of G also remains constant. b. In this case, G G + RT lnq. Since the reaction
1. Thermite reaction 2. Enthalpy of reaction, H 3. Heating/cooling curves and changes in state 4. More thermite thermodynamics
Chem 105 Fri 10-23-09 1. Thermite reaction 2. Enthalpy of reaction, H 3. Heating/cooling curves and changes in state 4. More thermite thermodynamics 10/23/2009 1 Please PICK UP your graded EXAM in front.
Test Review # 9. Chemistry R: Form TR9.13A
Chemistry R: Form TR9.13A TEST 9 REVIEW Name Date Period Test Review # 9 Collision theory. In order for a reaction to occur, particles of the reactant must collide. Not all collisions cause reactions.
Standard Free Energies of Formation at 298 K. Average Bond Dissociation Energies at 298 K
1 Thermodynamics There always seems to be at least one free response question that involves thermodynamics. These types of question also show up in the multiple choice questions. G, S, and H. Know what
Name Class Date. In the space provided, write the letter of the term or phrase that best completes each statement or best answers each question.
Assessment Chapter Test A Chapter: States of Matter In the space provided, write the letter of the term or phrase that best completes each statement or best answers each question. 1. The kinetic-molecular
Thermochemical equations allow stoichiometric calculations.
CHEM 1105 THERMOCHEMISTRY 1. Change in Enthalpy ( H) Heat is evolved or absorbed in all chemical reactions. Exothermic reaction: heat evolved - heat flows from reaction mixture to surroundings; products
Energy and Chemical Reactions. Characterizing Energy:
Energy and Chemical Reactions Energy: Critical for virtually all aspects of chemistry Defined as: We focus on energy transfer. We observe energy changes in: Heat Transfer: How much energy can a material
Physical and Chemical Properties of Matter
Physical and Chemical Properties of Matter What is matter? Anything that has mass and takes up space Chemical or Physical Property? Physical properties of matter: characteristics that can be observed or
Thermodynamics and Equilibrium
Chapter 19 Thermodynamics and Equilibrium Concept Check 19.1 You have a sample of 1.0 mg of solid iodine at room temperature. Later, you notice that the iodine has sublimed (passed into the vapor state).
Unit 19 Practice. Name: Class: Date: Multiple Choice Identify the choice that best completes the statement or answers the question.
Name: Class: Date: Unit 19 Practice Multiple Choice Identify the choice that best completes the statement or answers the question. 1) The first law of thermodynamics can be given as. A) E = q + w B) =
Chemistry 11 Some Study Materials for the Final Exam
Chemistry 11 Some Study Materials for the Final Exam Prefix Abbreviation Exponent giga G 10 9 mega M 10 6 kilo k 10 3 hecto h 10 2 deca da 10 1 deci d 10-1 centi c 10-2 milli m 10-3 micro µ 10-6 nano n
Thermodynamics of Mixing
Thermodynamics of Mixing Dependence of Gibbs energy on mixture composition is G = n A µ A + n B µ B and at constant T and p, systems tend towards a lower Gibbs energy The simplest example of mixing: What
AP CHEMISTRY 2007 SCORING GUIDELINES. Question 2
AP CHEMISTRY 2007 SCORING GUIDELINES Question 2 N 2 (g) + 3 F 2 (g) 2 NF 3 (g) ΔH 298 = 264 kj mol 1 ; ΔS 298 = 278 J K 1 mol 1 The following questions relate to the synthesis reaction represented by the
States of Matter CHAPTER 10 REVIEW SECTION 1. Name Date Class. Answer the following questions in the space provided.
CHAPTER 10 REVIEW States of Matter SECTION 1 SHORT ANSWER Answer the following questions in the space provided. 1. Identify whether the descriptions below describe an ideal gas or a real gas. ideal gas
CHEMISTRY STANDARDS BASED RUBRIC ATOMIC STRUCTURE AND BONDING
CHEMISTRY STANDARDS BASED RUBRIC ATOMIC STRUCTURE AND BONDING Essential Standard: STUDENTS WILL UNDERSTAND THAT THE PROPERTIES OF MATTER AND THEIR INTERACTIONS ARE A CONSEQUENCE OF THE STRUCTURE OF MATTER,
The First Law of Thermodynamics
Thermodynamics The First Law of Thermodynamics Thermodynamic Processes (isobaric, isochoric, isothermal, adiabatic) Reversible and Irreversible Processes Heat Engines Refrigerators and Heat Pumps The Carnot
FORMA is EXAM I, VERSION 1 (v1) Name
FORMA is EXAM I, VERSION 1 (v1) Name 1. DO NOT TURN THIS PAGE UNTIL DIRECTED TO DO SO. 2. These tests are machine graded; therefore, be sure to use a No. 1 or 2 pencil for marking the answer sheets. 3.
Module 5: Combustion Technology. Lecture 34: Calculation of calorific value of fuels
1 P age Module 5: Combustion Technology Lecture 34: Calculation of calorific value of fuels 2 P age Keywords : Gross calorific value, Net calorific value, enthalpy change, bomb calorimeter 5.3 Calculation
Reading: Moore chapter 18, sections 18.6-18.11 Questions for Review and Thought: 62, 69, 71, 73, 78, 83, 99, 102.
Thermodynamics 2: Gibbs Free Energy and Equilibrium Reading: Moore chapter 18, sections 18.6-18.11 Questions for Review and Thought: 62, 69, 71, 73, 78, 83, 99, 102. Key Concepts and skills: definitions
11 Thermodynamics and Thermochemistry
Copyright ç 1996 Richard Hochstim. All rights reserved. Terms of use.» 37 11 Thermodynamics and Thermochemistry Thermodynamics is the study of heat, and how heat can be interconverted into other energy
CHEM 36 General Chemistry EXAM #1 February 13, 2002
CHEM 36 General Chemistry EXAM #1 February 13, 2002 Name: Serkey, Anne INSTRUCTIONS: Read through the entire exam before you begin. Answer all of the questions. For questions involving calculations, show
Why? Intermolecular Forces. Intermolecular Forces. Chapter 12 IM Forces and Liquids. Covalent Bonding Forces for Comparison of Magnitude
1 Why? Chapter 1 Intermolecular Forces and Liquids Why is water usually a liquid and not a gas? Why does liquid water boil at such a high temperature for such a small molecule? Why does ice float on water?
Introductory Chemistry, 3 rd Edition Nivaldo Tro. Roy Kennedy Massachusetts Bay Community College Wellesley Hills, Maqqwertd ygoijpk[l
Introductory Chemistry, 3 rd Edition Nivaldo Tro Quantities in Car an octane and oxygen molecules and carbon dioxide and water Chemical Reactions Roy Kennedy Massachusetts Bay Community College Wellesley
Unit 5 Practice Test. Name: Class: Date: Multiple Choice Identify the choice that best completes the statement or answers the question.
Name: Class: Date: Unit 5 Practice Test Multiple Choice Identify the choice that best completes the statement or answers the question. 1) The internal energy of a system is always increased by. A) adding
Heat of Solution. Purpose To calculate the heat of solution for sodium hydroxide (NaOH) and ammonium nitrate (NH 4 NO 3 )
Heat of Solution Purpose To calculate the heat of solution for sodium hydroxide (NaOH) and ammonium nitrate (NH 4 NO 3 ) Background For a given solute, the heat of solution is the change in enerrgy that
Answer, Key Homework 6 David McIntyre 1
Answer, Key Homework 6 David McIntyre 1 This print-out should have 0 questions, check that it is complete. Multiple-choice questions may continue on the next column or page: find all choices before making
Exp 13 Volumetric Analysis: Acid-Base titration
Exp 13 Volumetric Analysis: Acid-Base titration Exp. 13 video (time: 47:17 minutes) Titration - is the measurement of the volume of a standard solution required to completely react with a measured volume
Read the sections on Allotropy and Allotropes in your text (pages 464, 475, 871-2, 882-3) and answer the following:
Descriptive Chemistry Assignment 5 Thermodynamics and Allotropes Read the sections on Allotropy and Allotropes in your text (pages 464, 475, 871-2, 882-3) and answer the following: 1. Define the word allotrope
Chemistry 13: States of Matter
Chemistry 13: States of Matter Name: Period: Date: Chemistry Content Standard: Gases and Their Properties The kinetic molecular theory describes the motion of atoms and molecules and explains the properties
a) Use the following equation from the lecture notes: = ( 8.314 J K 1 mol 1) ( ) 10 L
hermodynamics: Examples for chapter 4. 1. One mole of nitrogen gas is allowed to expand from 0.5 to 10 L reversible and isothermal process at 300 K. Calculate the change in molar entropy using a the ideal
vap H = RT 1T 2 = 30.850 kj mol 1 100 kpa = 341 K
Thermodynamics: Examples for chapter 6. 1. The boiling point of hexane at 1 atm is 68.7 C. What is the boiling point at 1 bar? The vapor pressure of hexane at 49.6 C is 53.32 kpa. Assume that the vapor
DETERMINING THE ENTHALPY OF FORMATION OF CaCO 3
DETERMINING THE ENTHALPY OF FORMATION OF CaCO 3 Standard Enthalpy Change Standard Enthalpy Change for a reaction, symbolized as H 0 298, is defined as The enthalpy change when the molar quantities of reactants
Chemistry B11 Chapter 4 Chemical reactions
Chemistry B11 Chapter 4 Chemical reactions Chemical reactions are classified into five groups: A + B AB Synthesis reactions (Combination) H + O H O AB A + B Decomposition reactions (Analysis) NaCl Na +Cl
Chapter 6 Thermodynamics: The First Law
Key Concepts 6.1 Systems Chapter 6 Thermodynamics: The First Law Systems, States, and Energy (Sections 6.1 6.8) thermodynamics, statistical thermodynamics, system, surroundings, open system, closed system,
Chem 420/523 Chemical Thermodynamics Homework Assignment # 6
Chem 420/523 Chemical hermodynamics Homework Assignment # 6 1. * Solid monoclinic sulfur (S α ) spontaneously converts to solid rhombic sulfur (S β ) at 298.15 K and 0.101 MPa pressure. For the conversion
4. Using the data from Handout 5, what is the standard enthalpy of formation of BaO (s)? What does this mean?
HOMEWORK 3A 1. In each of the following pairs, tell which has the higher entropy. (a) One mole of liquid water or one mole of water vapor (b) One mole of dry ice or one mole of carbon dioxide at 1 atm
CHEM 105 HOUR EXAM III 28-OCT-99. = -163 kj/mole determine H f 0 for Ni(CO) 4 (g) = -260 kj/mole determine H f 0 for Cr(CO) 6 (g)
CHEM 15 HOUR EXAM III 28-OCT-99 NAME (please print) 1. a. given: Ni (s) + 4 CO (g) = Ni(CO) 4 (g) H Rxn = -163 k/mole determine H f for Ni(CO) 4 (g) b. given: Cr (s) + 6 CO (g) = Cr(CO) 6 (g) H Rxn = -26
AP CHEMISTRY 2009 SCORING GUIDELINES (Form B)
AP CHEMISTRY 2009 SCORING GUIDELINES (Form B) Question 3 (10 points) 2 H 2 O 2 (aq) 2 H 2 O(l) + O 2 (g) The mass of an aqueous solution of H 2 O 2 is 6.951 g. The H 2 O 2 in the solution decomposes completely
Thermodynamics Worksheet I also highly recommend Worksheets 13 and 14 in the Lab Manual
Thermodynamics Worksheet I also highly recommend Worksheets 13 and 14 in the Lab Manual 1. Predict the sign of entropy change in the following processes a) The process of carbonating water to make a soda
1. The graph below represents the potential energy changes that occur in a chemical reaction. Which letter represents the activated complex?
1. The graph below represents the potential energy changes that occur in a chemical reaction. Which letter represents the activated complex? 4. According to the potential energy diagram shown above, the
ENTROPY AND THE SECOND LAW OF THERMODYNAMICS
ENTROPY AND THE SECOND LAW OF THERMODYNAMICS Energy Reservoir The system consists of the red circles in the blue box. Energy and entropy fl ow out of the system. TIME Additional Energy is added to the
Chapter 4 Practice Quiz
Chapter 4 Practice Quiz 1. Label each box with the appropriate state of matter. A) I: Gas II: Liquid III: Solid B) I: Liquid II: Solid III: Gas C) I: Solid II: Liquid III: Gas D) I: Gas II: Solid III:
Chapter Test A. States of Matter MULTIPLE CHOICE. a fixed amount of STAs2 a. a solid. b. a liquid. c. a gas. d. any type of matter.
Assessment Chapter Test A States of Matter MULTIPLE CHOICE Write the letter of the correct answer in the space provided. 1. Boyle s law explains the relationship between volume and pressure for a fixed
Gibbs Free Energy and Chemical Potential. NC State University
Chemistry 433 Lecture 14 Gibbs Free Energy and Chemical Potential NC State University The internal energy expressed in terms of its natural variables We can use the combination of the first and second
Transfer of heat energy often occurs during chemical reactions. A reaction
Chemistry 111 Lab: Thermochemistry Page I-3 THERMOCHEMISTRY Heats of Reaction The Enthalpy of Formation of Magnesium Oxide Transfer of heat energy often occurs during chemical reactions. A reaction may
Problem Set 4 Solutions
Chemistry 360 Dr Jean M Standard Problem Set 4 Solutions 1 Two moles of an ideal gas are compressed isothermally and reversibly at 98 K from 1 atm to 00 atm Calculate q, w, ΔU, and ΔH For an isothermal
The value of a state function is independent of the history of the system.
1 THERMODYNAMICS - The study of energy in matter - Thermodynamics allows us to predict whether a chemical reaction occurs or not. - Thermodynamics tells us nothing about how fast a reaction occurs. - i.
Final Exam CHM 3410, Dr. Mebel, Fall 2005
Final Exam CHM 3410, Dr. Mebel, Fall 2005 1. At -31.2 C, pure propane and n-butane have vapor pressures of 1200 and 200 Torr, respectively. (a) Calculate the mole fraction of propane in the liquid mixture
ENTHALPY CHANGES FOR A CHEMICAL REACTION scaling a rxn up or down (proportionality) quantity 1 from rxn heat 1 from Δ r H. = 32.
CHEMISTRY 103 Help Sheet #10 Chapter 4 (Part II); Sections 4.6-4.10 Do the topics appropriate for your lecture Prepared by Dr. Tony Jacob http://www.chem.wisc.edu/areas/clc (Resource page) Nuggets: Enthalpy
Spring 2009. kj mol 125 0-229 -92. H f. H rxn = Σ H f (products) - Σ H f (reactants)
Spring 2009 2. The reaction of an elemental halogen with an alkane is a very common reaction. The reaction between chlorine and butane is provided below. (NOTE: Questions a d and f pertain to this reaction.)
UNIT 1 THERMOCHEMISTRY
UNIT 1 THERMOCHEMISTRY THERMOCHEMISTRY LEARNING OUTCOMES Students will be expected to: THERMOCHEMISTRY STSE analyse why scientific and technological activities take place in a variety individual and group
13.1 The Nature of Gases. What is Kinetic Theory? Kinetic Theory and a Model for Gases. Chapter 13: States of Matter. Principles of Kinetic Theory
Chapter 13: States of Matter The Nature of Gases The Nature of Gases kinetic molecular theory (KMT), gas pressure (pascal, atmosphere, mm Hg), kinetic energy The Nature of Liquids vaporization, evaporation,
Chemical Formulas, Equations, and Reactions Test Pre-AP Write all answers on your answer document.
Name: Period: Chemical Formulas, Equations, and Reactions Test Pre-AP Write all answers on your answer document. 1. Which of the following is a NOT a physical property of hydrogen? A. It is gas C. It is
Chemistry 151 Final Exam
Chemistry 151 Final Exam Name: SSN: Exam Rules & Guidelines Show your work. No credit will be given for an answer unless your work is shown. Indicate your answer with a box or a circle. All paperwork must
SUPPLEMENTARY TOPIC 3 ENERGY AND CHEMICAL REACTIONS
SUPPLEMENTARY TOPIC 3 ENERGY AND CHEMICAL REACTIONS Rearranging atoms. In a chemical reaction, bonds between atoms in one or more molecules (reactants) break and new bonds are formed with other atoms to
Lecture 1: Physical Equilibria The Temperature Dependence of Vapor Pressure
Lecture 1: Physical Equilibria The Temperature Dependence of Vapor Pressure Our first foray into equilibria is to examine phenomena associated with two phases of matter achieving equilibrium in which the
Enthalpy of Reaction and Calorimetry worksheet
Enthalpy of Reaction and Calorimetry worksheet 1. Calcium carbonate decomposes at high temperature to form carbon dioxide and calcium oxide, calculate the enthalpy of reaction. CaCO 3 CO 2 + CaO 2. Carbon
1 Exercise 2.19a pg 86
In this solution set, an underline is used to show the last significant digit of numbers. For instance in x = 2.51693 the 2,5,1, and 6 are all significant. Digits to the right of the underlined digit,
Freezing Point Depression: Why Don t Oceans Freeze? Teacher Advanced Version
Freezing Point Depression: Why Don t Oceans Freeze? Teacher Advanced Version Freezing point depression describes the process where the temperature at which a liquid freezes is lowered by adding another
Chemical reactions allow living things to grow, develop, reproduce, and adapt.
Section 2: Chemical reactions allow living things to grow, develop, reproduce, and adapt. K What I Know W What I Want to Find Out L What I Learned Essential Questions What are the parts of a chemical reaction?
CHEMISTRY. Matter and Change. Section 13.1 Section 13.2 Section 13.3. The Gas Laws The Ideal Gas Law Gas Stoichiometry
CHEMISTRY Matter and Change 13 Table Of Contents Chapter 13: Gases Section 13.1 Section 13.2 Section 13.3 The Gas Laws The Ideal Gas Law Gas Stoichiometry State the relationships among pressure, temperature,
1. The Kinetic Theory of Matter states that all matter is composed of atoms and molecules that are in a constant state of constant random motion
Physical Science Period: Name: ANSWER KEY Date: Practice Test for Unit 3: Ch. 3, and some of 15 and 16: Kinetic Theory of Matter, States of matter, and and thermodynamics, and gas laws. 1. The Kinetic
Problem Set 3 Solutions
Chemistry 360 Dr Jean M Standard Problem Set 3 Solutions 1 (a) One mole of an ideal gas at 98 K is expanded reversibly and isothermally from 10 L to 10 L Determine the amount of work in Joules We start
Chapter 13. Properties of Solutions
Sample Exercise 13.1 (p. 534) By the process illustrated below, water vapor reacts with excess solid sodium sulfate to form the hydrated form of the salt. The chemical reaction is Na 2 SO 4(s) + 10 H 2
Chemical Bonds. Chemical Bonds. The Nature of Molecules. Energy and Metabolism < < Covalent bonds form when atoms share 2 or more valence electrons.
The Nature of Molecules Chapter 2 Energy and Metabolism Chapter 6 Chemical Bonds Molecules are groups of atoms held together in a stable association. Compounds are molecules containing more than one type
Thermodynamics. Chapter 13 Phase Diagrams. NC State University
Thermodynamics Chapter 13 Phase Diagrams NC State University Pressure (atm) Definition of a phase diagram A phase diagram is a representation of the states of matter, solid, liquid, or gas as a function
Experiment 12E LIQUID-VAPOR EQUILIBRIUM OF WATER 1
Experiment 12E LIQUID-VAPOR EQUILIBRIUM OF WATER 1 FV 6/26/13 MATERIALS: PURPOSE: 1000 ml tall-form beaker, 10 ml graduated cylinder, -10 to 110 o C thermometer, thermometer clamp, plastic pipet, long
Problem Set 1 3.20 MIT Professor Gerbrand Ceder Fall 2003
LEVEL 1 PROBLEMS Problem Set 1 3.0 MIT Professor Gerbrand Ceder Fall 003 Problem 1.1 The internal energy per kg for a certain gas is given by U = 0. 17 T + C where U is in kj/kg, T is in Kelvin, and C
Chem 338 Homework Set #5 solutions October 10, 2001 From Atkins: 5.2, 5.9, 5.12, 5.13, 5.15, 5.17, 5.21
Chem 8 Homework Set #5 solutions October 10, 2001 From Atkins: 5.2, 5.9, 5.12, 5.1, 5.15, 5.17, 5.21 5.2) The density of rhombic sulfur is 2.070 g cm - and that of monoclinic sulfur is 1.957 g cm -. Can
Science Department Mark Erlenwein, Assistant Principal
Staten Island Technical High School Vincent A. Maniscalco, Principal The Physical Setting: CHEMISTRY Science Department Mark Erlenwein, Assistant Principal - Unit 1 - Matter and Energy Lessons 9-14 Heat,
Energetic Reactions: Ice Cream Experiment Teacher Guide
Module Overview Heat transfer is an important part of many chemical reactions, but it is often not directly observed. In this module students conduct an experiment making homemade ice cream that requires
Equilibrium. Ron Robertson
Equilibrium Ron Robertson Basic Ideas A. Extent of Reaction Many reactions do not go to completion. Those that do not are reversible with a forward reaction and reverse reaction. To be really correct we
Guide to Chapter 13. Chemical Equilibrium
Guide to Chapter 13. Chemical Equilibrium We will spend five lecture days on this chapter. During the first class meeting we will focus on how kinetics makes a segue into equilibrium. We will learn how
PV (0.775 atm)(0.0854 L) n = = = 0.00264 mol RT -1-1
catalyst 2 5 g ¾¾¾¾ 2 4 g 2 g DH298 = rxn DS298 C H OH( ) C H ( ) + H O( ) 45.5 kj/mol ; = 126 J/(K mol ) ethanol ethene water rxn 1 atm 760 torr PV (0.775 atm)(0.0854 L) n = = = 0.00264 mol RT -1-1 (0.08206
5 Answers and Solutions to Text Problems
Energy and States of Matter 5 Answers and Solutions to Text Problems 5.1 At the top of the hill, all of the energy of the car is in the form of potential energy. As it descends down the hill, potential
Chapter 12 - Liquids and Solids
Chapter 12 - Liquids and Solids 12-1 Liquids I. Properties of Liquids and the Kinetic Molecular Theory A. Fluids 1. Substances that can flow and therefore take the shape of their container B. Relative
AP Chemistry 2005 Scoring Guidelines Form B
AP Chemistry 2005 Scoring Guidelines Form B The College Board: Connecting Students to College Success The College Board is a not-for-profit membership association whose mission is to connect students to
Phase diagram of water. Note: for H 2 O melting point decreases with increasing pressure, for CO 2 melting point increases with increasing pressure.
Phase diagram of water Note: for H 2 O melting point decreases with increasing pressure, for CO 2 melting point increases with increasing pressure. WATER Covers ~ 70% of the earth s surface Life on earth
In the box below, draw the Lewis electron-dot structure for the compound formed from magnesium and oxygen. [Include any charges or partial charges.
Name: 1) Which molecule is nonpolar and has a symmetrical shape? A) NH3 B) H2O C) HCl D) CH4 7222-1 - Page 1 2) When ammonium chloride crystals are dissolved in water, the temperature of the water decreases.
Give all answers in MKS units: energy in Joules, pressure in Pascals, volume in m 3, etc. Only work the number of problems required. Chose wisely.
Chemistry 45/456 0 July, 007 Midterm Examination Professor G. Drobny Universal gas constant=r=8.3j/mole-k=0.08l-atm/mole-k Joule=J= Nt-m=kg-m /s 0J= L-atm. Pa=J/m 3 =N/m. atm=.0x0 5 Pa=.0 bar L=0-3 m 3.
LN 10. 3.091 Introduction to Solid State Chemistry. Lecture Notes No. 10 PHASE EQUILIBRIA AND PHASE DIAGRAMS
3.091 Introduction to Solid State Chemistry Lecture Notes No. 10 PHASE EQUILIBRIA AND PHASE DIAGRAMS * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * Sources
Every mathematician knows it is impossible to understand an elementary course in thermodynamics. ~V.I. Arnold
Every mathematician knows it is impossible to understand an elementary course in thermodynamics. ~V.I. Arnold Radiation Radiation: Heat energy transmitted by electromagnetic waves Q t = εσat 4 emissivity
Chapter 18 Temperature, Heat, and the First Law of Thermodynamics. Problems: 8, 11, 13, 17, 21, 27, 29, 37, 39, 41, 47, 51, 57
Chapter 18 Temperature, Heat, and the First Law of Thermodynamics Problems: 8, 11, 13, 17, 21, 27, 29, 37, 39, 41, 47, 51, 57 Thermodynamics study and application of thermal energy temperature quantity
Current Staff Course Unit/ Length. Basic Outline/ Structure. Unit Objectives/ Big Ideas. Properties of Waves A simple wave has a PH: Sound and Light
Current Staff Course Unit/ Length August August September September October Unit Objectives/ Big Ideas Basic Outline/ Structure PS4- Types of Waves Because light can travel through space, it cannot be
Chapter 13 - Solutions
Chapter 13 - Solutions 13-1 Types of Mixtures I. Solutions A. Soluble 1. Capable of being dissolved B. Solution 1. A homogeneous mixture of two or more substances in a single phase C. Solvent 1. The dissolving
Liquid phase. Balance equation Moles A Stoic. coefficient. Aqueous phase
STOICHIOMETRY Objective The purpose of this exercise is to give you some practice on some Stoichiometry calculations. Discussion The molecular mass of a compound is the sum of the atomic masses of all
Chapter 5 Student Reading
Chapter 5 Student Reading THE POLARITY OF THE WATER MOLECULE Wonderful water Water is an amazing substance. We drink it, cook and wash with it, swim and play in it, and use it for lots of other purposes.
Final Exam Review. I normalize your final exam score out of 70 to a score out of 150. This score out of 150 is included in your final course total.
Final Exam Review Information Your ACS standardized final exam is a comprehensive, 70 question multiple choice (a d) test featuring material from BOTH the CHM 101 and 102 syllabi. Questions are graded
Chemistry 212 VAPOR PRESSURE OF WATER LEARNING OBJECTIVES
Chemistry 212 VAPOR PRESSURE OF WATER LEARNING OBJECTIVES The learning objectives of this experiment are to explore the relationship between the temperature and vapor pressure of water. determine the molar
AAHS-CHEMISTRY FINAL EXAM PREP-REVIEW GUIDE MAY-JUNE 2014 DR. GRAY CLASS OF 2016
AAHS-CHEMISTRY FINAL EXAM PREP-REVIEW GUIDE MAY-JUNE 2014 DR. GRAY CLASS OF 2016 UNIT I: (CHAPTER 1-Zumdahl text) The Nature of Science and Chemistry 1. Explain why knowledge of chemistry is central to
Part B 2. Allow a total of 15 credits for this part. The student must answer all questions in this part.
Part B 2 Allow a total of 15 credits for this part. The student must answer all questions in this part. 51 [1] Allow 1 credit for 3 Mg(s) N 2 (g) Mg 3 N 2 (s). Allow credit even if the coefficient 1 is
The final numerical answer given is correct but the math shown does not give that answer.
Note added to Homework set 7: The solution to Problem 16 has an error in it. The specific heat of water is listed as c 1 J/g K but should be c 4.186 J/g K The final numerical answer given is correct but
CST Practice Test. Multiple Choice Questions
CST Practice Test Young NAME CST Practice Test Multiple Choice Questions 1) At 1 atm and 298 K, which of the K a values listed below represents the strongest acid? 5) Which electron-dot symbol represents
Thermochemistry: Calorimetry and Hess s Law
Thermochemistry: Calorimetry and Hess s Law Some chemical reactions are endothermic and proceed with absorption of heat while others are exothermic and proceed with an evolution of heat. The magnitude
Chem 1A Exam 2 Review Problems
Chem 1A Exam 2 Review Problems 1. At 0.967 atm, the height of mercury in a barometer is 0.735 m. If the mercury were replaced with water, what height of water (in meters) would be supported at this pressure?