Electron Geometry. Remaining P-orbitals 4 Tetrahedral 109º sp Trigonal 120º sp 2 1. Bond Angle Hybridization B+L. 2 Linear 180º sp 2 EXAMPLES
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1 hem 350 Jasperse h. 2 andouts 1 VSEPR : Valence Shell Electron Pair Repulsion (Sections 2.4, 2.6) oncept: electron groups repel, determine structure 4 electron groups: tetrahedral, 109º angle 3 electron groups: trigonal planar, 120º angle 2 electron groups: linear, 180º angle 2 Types of Electron Groups 1. B = bonds to other atoms. Whether it s a single, double, or triple bond, it still counts as one electron group or one bond group 2. L = Lone pairs B+L Electron Geometry Bond Angle ybridization Remaining P-orbitals 4 Tetrahedral 109º sp Trigonal 120º sp 2 1 Planar 2 Linear 180º sp 2 EXAMPLES AB 4 N AB 3 L AB 2 L 2 AB 3 N AB 2 ABL AL 2 AB 2 AB 3 AB 3
2 hem 350 Jasperse h. 2 andouts 2 DRAWING 3-D (Section 2.5) Guidelines for Drawing Models: A. In-Plane/ut-of-Plane Designate an atom in front of plane with a wedge Designate an atom behind plane with a hash Designate an atom in the plane plane with a straight line B. 3-D Perspective 1. Keep as many atoms as possible in a single plane (plane of the paper) by zig-zagging. onnections within the paper are drawn with straight lines. 2. Use wedges to indicate atoms that are in front of the plane. 3. Use hashes to indicate atoms behind the plane.. For any tetrahedral atom, only 2 attachments can be in the plane, 1 must be in front, and 1 behind. -if the two in the plane are down, the hash/wedge should be up -if the two in plane are up, the hash/wedge should be down. -the hash/wedge should never point in same direction as the in-plane lines, or else the atom doesn t looks tetrahedral -for polyatomic molecules, it is strongly preferable to NT have either of the in-plane atoms pointing straight up. Straight-up in-plane atoms do not lend themselves to extended 3-D structures. Good! Look tetrahedral Bad! These don' t look tetrahedral! Draw: =l l or l
3 hem 350 Jasperse h. 2 andouts 3 ybrid rbitals (Sections 2.4, 2.6); π bonding (Section 2.3) 1s + 3p 4 sp 3 hybrids 109º 1s + 2p (+ 1 unhybridized p) 3 sp 2 hybrids (+ 1 unhybridized p) 120º 1s + 1p (+ 2 unhybridized p s) 2 sp hybrids (+ 2 unhybridized p s) 180º Why does hybridization occur? ybrid orbitals are big and point in one direction. Their directionality leads to better overlap which leads to strong bonds. ybrid orbitals leads to nice VSEPR angles If hybridization is so great, why aren t pure monatomic atoms hybridized? For an isolated atom, having 1 s and 3 p atomic orbitals is better than 4 sp 3 hybrid orbitals owever, when covalent bonds can result, the small price of hybridizing is paid off a thousandfold by the payoff of making strong, good VSEPR bonds If hybridization is so great, why aren t all carbons sp 3 hybridized? Why do some stay sp 2 or sp, and withhold some p orbitals from hybridization? p orbitals are withheld from hybridization for the sole purpose of using them to make π bonds. nly when double bonds or triple bonds are involved is the hybridization less than the full sp 3 Each π bond requires the attached atoms to use p orbitals 2 Kinds of ovalent Bonds sigma (σ) bonds: electron density is along the axis between the nuclei -σ bonds always involve the overlap of s or s-containing hybrids (s, sp, sp 2, sp 3 ) pi (π) bonds: electron density is either above/below or before/behind, but not along the internuclear axis - π bonds involve the overlap of parallel p orbitals The first bond in any bond (whether single, double, or triple), is a σ bond. The extra bonds in a double or triple bond are π bonds. Bond σ π Single 1 0 Double 1 1 Triple 1 2 π bonds are weaker and more reactive than σ bonds. Most organic reactions involve π bonds
4 hem 350 Jasperse h. 2 andouts 4 lassification of Isomers ( ) isomers-different compounds with the same molecular formula. structural isomers (or constitutional isomers)-isomers that have their atoms connected in a different order. l l stereoisomers (or configurational isomers)-isomers in which atoms are joined in the same order but differ in the way their atoms are arranged in space. Stereoisomers have the same condensed formula (if not, they aren t stereoisomers) Stereoisomers can not be interconverted by bond rotation or by being turned over If two things can be interconverted by bond rotation or being turned over, then they aren t stereoisomers! Stereoisomers are subdivided into two categories: enantiomers and diastereomers. o Diastereomers: have cis/trans relationship cis trans cis trans o Enantiomers: have mirror image (left hand/right hand) relationship Problem: For the following pairs of structures, classify whether they are related as same, structural isomers, or stereoisomers. a. c. Same Structural b. Same l l l d. l stereoisomer (cis trans diastereomer) e. l l l l Same f. stereoisomer (cis trans diastereomer) g. Structural h. Same
5 hem 350 Jasperse h. 2 andouts Polarity -molecular dipole: vector sum of bond and lone-pair dipoles A simple molecule is totally nonpolar only if: 1. entral atom has no lone pairs 2. All attached atoms are the same Practical: Lone pairs and - or N- bonds usually dominate -, -, and -halogen bonds are practically nonpolar or at best only weakly polar Problems: lassify as totally nonpolar or polar. a. 2 b. l 4 c. 4 d Nonpolar Nonpolar Nonpolar Nonpolar e. 2 f. N 3 g. 3 2 h. l 3 Polar Polar Polar Weakly Polar 2.10 Intermolecular Forces and Boiling Points 1. ydrogen bonds (- or N-) 2. Dipole-Dipole Much weaker than hydrogen bonds 3. London Forces Increases with increasing molecular weight Intermolecular Forces impact: 1. Boiling points and melting points 2. Solubility For Boiling Points: 1. If weight is about equal -bonder > polar > nonpolar 2. If -bonding/polarity is comparable: high mw > lower mw Problem: Rank the boiling points, 1 being highest a b. c
6 hem 350 Jasperse h. 2 andouts Polarity and Solubility 2 Practical Rules: 1. The more N s or s in a molecular, the greater it s water solubility 2. The more s, the lower it s water solubility Facts/Theory 1. Like dissolves like enthalpy and entropy factors Good solubility Bad solubility a. Polar solvent-polar solute a. Polar solvent-nonpolar solute b. Nonpolar solvent-nonpolar solute b. Nonpolar solvent-polar solute 2. Water is very polar 3. Any molecules with N or can -bond with water (even if it can t necessarily -bond itself) (Rule 1) 4. Adding s adds -, - nonpolar bonds reduces water solubility (Rule 2) 5. ydrocarbons and halocarbons are insoluble in water Many other organics have low solubility in water Depends on the ratio of nonpolar/polar, N or to Problems: ircle the more water soluble of the following pairs: Problem: Box the higher boiling in each pair. Does water solubility and boiling point always correspond? Why or why not? 1 2 Not always, many factors are the same (-bonding, polarity raises both. 2 1 But extra s is good for boiling point but bad for water solubility) 1 2
7 hem 350 Jasperse h. 2 andouts 7 Twelve To Remember: The Functional Groups 1. Alkene -= double bond 0. Alkane -all single bonds -no heteroatoms 2. Alkyne -triple bond Tip: A-E-I so alkane, alkene, alkyne 5. Alcohol -oxygen - -single bonds (Special properties due to resonance) 3. Arene -alternating double bonds in a 6-carbon ring 7. Aldehyde -oxygen -= double bond -one connected to = 4. aloalkane 6. Ether -oxygen -no -single bonds 8. Ketone -oxygen -= double bond -two 's connected to = (l, I, F) Alcohols and Ethers an be Seen as 2 Derivatives: xygen Molecules With Single Bonds nly Tip: A before E Aldehydes and Ketones ave = (arbonyl) Double Bonds Tip: A before key; Aldehyde has less 's attached to = 9. (arboxylic) Acid -2 oxygens -= double bond, with - directly attached 10. Ester -2 oxygens -= double bond, with - directly attached A(cid) before E(ster) N Amide -one nitrogen, one = -= double bond, with N directly attached -"D" for = double bond N Amine -one nitrogen, no = -"N" for No = double bond N compounds
8 hem 350 Jasperse h. 2 andouts 8 The Functional Groups, R-Z Functional Group Z Name -R Alkane Alkene Alkyne Arene Suffix (or Prefix) Used in Systematic Name -ane -ene -yne not responsible Nomenclature Review methanethanpropanbutanpentanhexanheptanoctannonandecan X (l,, I, or F) aloalkane - Alcohol -ol -R Ether not responsible Aldehyde -al R R Ketone arboxylic Acid Ester Amide -one -oic acid -oate -amide N 2 -N 2 Amine halo- amino-
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