Chapter 1 Structure and Bonding
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1 Chapter 1 Structure and Bonding Organic Chemistry, Third Edition Janice Gorzynski Smith University of Hawai i Prepared by Layne A. Morsch The University of Illinois - Springfield Modified and Used for Basic Org Chem Lecture by V.P. Hoven, as of August 2012 Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display. 1
2 Atomic Structure The nucleus contains positively charged protons and uncharged neutrons. The electron cloud is composed of negatively charged p g y g electrons. 2
3 No.of protons In a neutral atom, protons = electrons Isotopes are two atoms of the same element having a different number of neutrons. 3
4 The Periodic Table Figure 1.2 Common elements seen in organic chemistry Elements in the same column have similar electronic and chemical properties. Elements in the same row are similar in size. 4
5 Atomic Orbitals An s orbital has a sphere of electron density and is lower in energy than the other orbitals of the same shell. A p orbital has a dumbbell shape and contains a node (no electron density) at the nucleus. It is higher in energy than an s orbital. 5
6 The First Row There is only one orbital in the first shell. Each shell can hold a maximum of two electrons. Therefore, there are two elements in the first row: HandHe He. 6
7 The Second Row Each element in the second row of the periodic table has four orbitals available to accept additional electrons: one2sorbital, and three 2p orbitals. 7
8 Since each of the four orbitals in the second shell holds two electrons, there isamaximum capacity of eight valence electrons for elements in the second row. The second row of the periodic table consists of eight elements, obtained by adding electrons to the 2s and three 2p orbitals. 8
9 Bonding Bonding is the joining of two atoms in a stable arrangement. Atoms can form either ionic or covalent bonds to attain a complete outer shell (octet rule for second row elements, stable noble gas configuration). Ionic bonds result from the transfer of electrons from one element to another. Covalent bonds result from the sharing of electrons between two nuclei. 9
10 Ionic Bonding An ionic bond generally occurs when elements on the far left side of the periodic table combine with elements on the far right side, ignoringi noble gases. A positively charged cation formed from the element on the left side attracts a negatively charged anion formed from the element on the right side (e.g., sodium chloride, NaCl). 10
11 Li loses its one electron to make Li + which has no electrons in second shell. However, it has a complete first shell. F gains one electron to make F - which has a filled valence F gains one electron to make F which has a filled valence shell (an octet of electrons), like neon. 11
12 Covalent Bonding Covalent bonding occurs with elements like carbon in the middle of the table (e.g., CH 4 ) with elements that have similar electronegativity. Covalent bonds also occur between two of the same elements from the same sides of the table (e.g., H 2,Cl 2 ). A covalent bond is a two-electron bond, and a compound with covalent bonds is called a molecule. 12
13 Valence Electrons Second-row elements can have no more than eight electrons around them. For neutral molecules, this has two consequences: Atoms with one, two, three, or four valence electrons form one, two, three, or four bonds, respectively, in neutral molecules (e.g., BF 3,CH 4 ). Atoms with five or more valence electrons form enough bonds to give an octet (e.g., NH 3 ). This results in the following equation: 13
14 Nonbonded Electrons Figure 1.3 When second-row elements form fewer than four bonds, their octets consist of both bonding (shared) and nonbonding (unshared) electrons. Unshared electrons are also called lone pairs. 14
15 Lewis Structures Lewis structures are electron dot representations for molecules. A solid line indicates a two- electron covalent bond. General rules for drawing Lewis structures: 1. Draw only the valence electrons. 2. Give every second-row element no more than eight electrons. 3. Give each hydrogen two electrons. 15
16 How to Draw a Lewis Structure Step [1] Arrange atoms next to each other that you think are bonded together. Always place hydrogen and halogens on the periphery because they form only one bond each. Place no more atoms around an atom than the number of bonds it usually forms. 16
17 Step [2] Step [3] Count the electrons. Count the number of valence electrons from all atoms. Add one electron for each negativee charge. Subtract one electron for each positive charge. This gives the total number of electrons that must be used in drawing the Lewis structure. Arrange the electrons around the atoms. Place a bond between every two atoms, giving two electrons to each H and no more than eight to any second-row atom. Use all remaining electrons to fill octets with lone pairs. If all valence electrons are used and an atom does not have an octet, form multiple bonds. Step [4] Assign formal charges to all atoms. 17
18 Formal Charge Formal charge is the charge assigned to individual atoms in a Lewis structure. Formal charge is calculated as follows: The number of electrons owned by an atom is determined by its number of bonds and lone pairs. An atom owns all of its unshared electrons and half of its shared electrons. 18
19 The number of electrons owned by different atoms is indicated in the following examples: Example 1 Example 3 Example 2 19
20 20
21 Isomers Sometimes more than one arrangement of atoms (Lewis structure) is possible for a given molecular formula. These two compounds are called isomers. Isomers are different molecules having the same molecular formula. Ethanol and dimethyl ether are constitutional isomers. 21
22 Exceptions to the Octet Rule Elements in Groups 2A and 3A Elements in the Third Row 22
23 Resonance Structures Some molecules cannot be adequately represented by a single Lewis structure. For example: These structures are called resonance structures or resonance forms. A double-headed arrow is used to separate the two resonance structures. Resonance structures are two Lewis structures having the same placement of atoms but a different arrangement of electrons. 23
24 Neither resonance structure is an accurate representation for (HCONH). The true structure is a composite of both resonance forms and is called a resonance hybrid. The hybrid shows s characteristics acte cs of both structures. Resonance allows certain electron pairs to be delocalized over two or more atoms, and this delocalization adds stability. A molecule with two or more resonance forms is said to be resonance stabilized. 24
25 Basic Principles of Resonance Theory Resonance structures are not real. An individual resonance structure does not accurately represent the structure of a molecule or ion. Only the hybrid does. Resonance structures are not in equilibrium with each other. There is no movement of electrons from one form to another. Resonance structures are not isomers. Two isomers differ in the arrangement of both atoms and electrons, whereas resonance structures differ only in the arrangement of electrons. 25
26 Drawing Resonance Structures Rule [1]: Two resonance structures differ in the position of multiple bonds and nonbonded d electrons. The placement of atoms and single bonds always stays the same. 26
27 Rule [2]: Two resonance structures must have the same number of unpaired electrons. Rule [3]: Resonance structures must be valid Lewis structures. Hydrogen must have two electrons and no second-row element can have more than eight electrons. 27
28 Curved Arrow Notation Curved arrow notation is a convention that shows how electron position differs between two resonance forms. Curved arrow notation shows the movement of an electron pair. The tail of the arrow always begins at the electron pair, either in a bond or lone pair. The head points to where the electron pair moves. Example 1: Example 2: 28
29 Occurrence of Resonance Two different resonance structures can be drawn when a lone pair is located on an atom directly bonded to a double bond. 29
30 Multiple resonance structures can also be drawn when an atom bearing a (+) charge is bonded either to a double bond or an atom with a lone pair. 30
31 Resonance Hybrid A resonance hybrid is a composite of all possible resonance structures. In the resonance hybrid, the electron pairs drawn in different locations in individual resonance forms are delocalized. When two resonance structures are different, the hybrid looks more like the better resonance structure. The better resonance structure is called the major contributor to the hybrid, and all others are minor contributors. 31
32 A better resonance structure is the one that has more bonds and fewer charges. 32
33 Molecular Geometry Two variables define a molecule s structure: bond length and bond angle. Bond length decreases across a row of the periodic table as the size of the atom decreases. Bond length increases down a column of the periodic table as the size of an atom increases. 33
34 34
35 The number of groups surrounding a particular atom determines its geometry. A group is either an atom or a lone pair of electrons. The most stable arrangement keeps these groups as far away from each other as possible. This is exemplified by Valence Shell Electron Pair Repulsion (VSEPR) theory. 35
36 36
37 Drawing Three-Dimensional Structures A solid line is used for a bond in the plane. A wedge is used for a bond in front of the plane. A dashed line is used for a bond behind the plane. 37
38 A Nonbonded Pair of Electrons is Counted as a Group 38
39 Varying Bond Angles Methane (CH 4 ) Ammonia (NH 3 ) Water (H 2 O) In both NH 3 and H 2 O, the bond angle is smaller than the theoretical tetrahedral bond angle because of repulsion of the lone pairs of electrons. The bonded atoms are compressed dinto a smaller space with a smaller bond angle. 39
40 Condensed Structures All atoms are drawn in, but the two-electron bond lines are generally omitted. Atoms are usually drawn next to the atoms to which they are bonded. Parentheses are used around similar groups bonded to the same atom. Lone pairs are omitted. 40
41 41
42 Skeletal Structures Assume there is a carbon atom at the junction of any two lines or at the end of any line. Assume there are enough hydrogens around each carbon to make it tetravalent. Draw in all heteroatoms and the hydrogens directly bonded to them. 42
43 43
44 A charge on a carbon atom takes the place of one hydrogen atom. The charge determines the number of lone pairs. Negatively charged carbon atoms have one lone pair and positively charged carbon atoms have none. 44
45 Orbitals and Bonding: Hybridization When the 1s orbital of one H atom overlaps with the 1s orbital of another H atom, a sigma (σ) bond that t concentrates electron density between the two nuclei is formed. This bond is cylindrically symmetrical because the electrons forming the bond are distributed symmetrically y about an imaginary line connecting the two nuclei. 45
46 To account for the bonding patterns observed in more complex molecules, we must take a closer look at how the 2s and 2p orbitals of atoms in the second row are utilized. In addition to its two core electrons, carbon has four valence electrons. In its ground state, carbon places two electrons in the 2s orbital and one each in 2p orbitals. Note: The lowest energy arrangement of electrons for an atom is called its ground state. t 46
47 Promotionofanelectronfrom a 2s to a vacant 2p orbital would form four unpaired electrons for bonding. This higher energy electron configuration is called an electronically excited state. Carbon would form two different types of bonds: three with 2p orbitals and one with a 2s orbital. Experimental evidence points to carbon forming four identical bonds in methane. 47
48 To solve this dilemma, chemists have proposed that atoms like carbon do not use pure s and pure p orbitals in forming bonds. Instead, atoms use a set of new orbitals called hybrid orbitals. Hybridization is the combination of two or more atomic orbitals to form the same number of hybrid orbitals, each having the same shape and energy. 48
49 Shape and Orientation of sp 3 Hybrid Orbitals The mixing of a spherical 2s orbital and three dumbbell shaped 2p orbitals together produces four hybrid orbitals, each having one large lobe and one small lobe. The four hybrid orbitals are oriented toward the corners of a tetrahedront and form four equivalent bonds. 49
50 50
51 Bonding Using sp 3 Hybrid Orbitals Each bond in CH 4 is formed by overlap of an sp 3 hybrid orbital of carbon with a 1s orbital of hydrogen. These four bonds point to the corners of a tetrahedron. 51
52 Other Hybridization Patterns One 2s orbital + three 2p orbitals = four sp 3 hybrid orbitals. One 2s orbital + two 2p orbitals = three sp 2 hybrid orbitals. One 2s orbital + one 2p orbital = two sp hybrid orbitals. 52
53 Determining Hybridization Count the number of groups (atoms and nonbonded electron pairs) around the atom. The number of groups corresponds to the number of atomic orbitals that must be hybridized to form the hybrid orbitals. 53
54 54 Hybridization Examples
55 sp 3 Hybridization and Bonding in Organic Molecules 55
56 Rotation around C-C Bond Making a model of ethane illustrates one additional feature about its structure. t Rotation occurs around the central C C σ bond. 56
57 sp 2 Hybridization and Bonding in Organic Molecules Each carbon is trigonal planar. Each carbon is sp 2 hybridized. 57
58 Unhybridized 2p z orbital (gray), which is perpendicular to the plane of the hybrid (green) orbitals. 58
59 Sigma bond (s) electron density between the 2 atoms Pi b d ( ) l t d it b d b l l f l i Pi bond (p) electron density above and below plane of nuclei of the bonding atoms 59
60 No Rotation around C=C Bond Unlike the C C bond in ethane, rotation about the C C double bond in ethylene is restricted. It can only occur if the π bond first breaks and then reforms, a process that requires considerable energy. 60
61 sp Hybridization and Bonding in Organic Molecules 61
62 62
63 Each carbon atom has two unhybridized 2p orbitals that are perpendicular to each other and to the sp hybrid orbitals. 63
64 Summary of Covalent Bonding 64
65 Bond Length and Bond Strength As the number of electrons between two nuclei increases, bonds become shorter and stronger. The length and strength of C H bonds vary depending on the hybridization of the carbon atom. 65
66 66
67 Percent s-character 67
68 Electronegativity Electronegativity is a measure of an atom s attraction for electrons in a bond. 68
69 Bond Polarity Electronegativity values are used are used as a guideline to indicate whether the electrons in a bond are equally shared or unequally shared between two atoms. When electrons are equally shared, the bond is nonpolar. A carbon carbon bond is nonpolar. The same is true whenever two different atoms having similar il electronegativities i i are bonded d together. C H bonds are considered to be nonpolar because the C H bonds are considered to be nonpolar because the electronegativity difference between C and H is small. 69
70 Bonding between atoms of different electronegativity values results in unequal sharing of electrons. The tail of the arrow is drawn at the less electronegative element the head of the arrow pointing toward the more electronegative element In the C O bond, the electrons are pulled away from C (2.5) toward O (3.4), the element of higher electronegativity. The bond is polar or polar covalent. The bond is said to have a dipole; that is, separation of charge. 70
71 Polarity of Molecules Use the following procedure to determine if a molecule has a net dipole: Use electronegativity differences to identify all of the polar bonds and the directions of the bond dipoles. Determine the geometry around individual atoms by counting groups, and decide if individual dipoles cancel or reinforce each other in space. 71
72 A polar molecule has either one polar bond, or two or more bond dipoles that reinforce each other. A nonpolar molecule has either no polar bonds, or two or more bond dipoles that cancel. 72
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