Changes to Chemical Labels and SDS. DG Employment, Social Affairs and Inclusion

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1 Changes to Chemical Labels and SDS DG Employment, Social Affairs and Inclusion

2 Changes to labels and SDS What is this training about? Changes to the way that chemical hazards are communicated How will I be affected? New labels and symbols (pictograms) Some changes to classifications What might I need to do? Review your risk assessments and update your risk management measures if necessary

3 Legislation on classification and labelling Before being placed on the market, all chemicals must be Classified to identify any intrinsic hazards Labelled if hazardous according to strict rules with information on Identity of the hazardous chemical(s) What type of hazard there is Safe use instructions Packaged safely

4 Legislation on classification and labelling For many years these requirements have been driven by The Dangerous Substances Directive 67/548/EEC (DSD) The Dangerous Preparations Directive 1999/45/EC (DPD) These Directives are implemented in each member state through national legislation This legislation is now being replaced by a new directly acting Regulation The Regulation (EC) No 1272/2008 on Classification, Labelling and Packaging of Substances and Mixtures (the CLP Regulation)

5 What is CLP? CLP adopts the UN Globally Harmonised System of Classification and Labelling of Chemicals (GHS) into the EU GHS aims to improve worker and consumer protection, and facilitate global trade by providing... a common basis to define and classify chemicals according to their hazards and to communicate this information via labels and safety data sheets

6 Timetable for transition to CLP Substances Mixtures All substances classified and labelled according to CLP. Both CLP and DSD classifications on the SDS. 2 yr derogation, for stock already on the market May be classified and labelled according to either DPD or CLP. If labelled according to CLP, both DPD and CLP classifications must appear on the SDS. All substances classified and labelled to CLP. Only CLP classifications need appear on the SDS All mixtures classified and labelled to CLP. Only CLP classifications need appear on the SDS 2 yr derogation for stock already on the market

7 Classification Classification identifies the type of hazard e.g. flammable, toxic The severity of the hazard e.g. very toxic, toxic, harmful Under CLP the type of hazards identified are mostly the same, but they are split into more hazard classes and sub divisions or categories different classification criteria and methods are used for some types of hazard, which may change the classification of some chemicals, or result in some chemicals being classified for the first time

8 Physical Hazards DSD/DPD Explosive Oxidising Extremely flammable Highly flammable Flammable * New under CLP CLP Explosives Flammable gases Flammable aerosols Oxidizing gases Gases under pressure* Flammable liquids Flammable solids Self-reactive substances and mixtures Pyrophoric liquids Pyrophoric solids Self-heating substances and mixtures * Emits flamm. gases in contact with water Oxidizing liquids Oxidizing solids Organic peroxides Corrosive to metals*

9 Physical Hazards Explosive, Self Reactive Organic Peroxide Flammable Gases, Liquids and Solids; Pyrophoric, Self-Reactive, Self-Heating; Flammable Aerosols; Organic Peroxides; Emits Flammable Gas in Contact with Water Oxidizing Gases, Liquids and Solids Gases under pressure Corrosive to metals

10 Health hazards DSD/DPD Very toxic Toxic Harmful Corrosive Irritant Sensitising Carcinogenic Mutagenic Toxic for Reproduction CLP Acute toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity single exposure Specific target organ toxicity repeated exposure Aspiration hazard

11 Health Hazards Acute toxicity - Very toxic (Fatal) - Toxic OR Corrosive (causes severe skin burns and eye damage) Serious Eye Damage Respiratory sensitiser Mutagen, Carcinogen, Reproductive toxicity Specific Target Organ Toxicity Single Exposure Specific Target Organ Toxicity Repeated Exposure Aspiration hazard Acute toxicity - Harmful Skin Irritation, Serious Eye Irritation, Skin Sensitiser Specific Target Organ Toxicity Single Exposure - Respiratory Irritant, Narcotic

12 Environmental hazards DSD/DPD Dangerous for the Environment CLP Hazardous to the Aquatic Environment Hazardous to the Ozone Layer Acute Aquatic Toxicity Chronic Aquatic Toxicity Dangerous for the ozone layer

13 Labelling Label elements under DSD/DPD Symbols Indications of Danger Risk Phrases Safety Phrases Additional labelling requirements Label elements under CLP Pictograms Signal Word Hazard Statements Precautionary Statements Supplementary labelling information

14 New hazard pictograms Type of hazard DSD/DPD Symbol CLP Pictogram The substance or mixture may cause serious longterm health effects, such as carcinogenicity or respiratory sensitisation Less serious health hazards such as irritation, skin sensitisation and less severe toxicity (harmful) Contains gases under pressure OR No symbol under DSD and DPD

15 DSD/DPD vs CLP Label Elements Indications of Danger Signal Words Explosive Danger Oxidising Warning Extremely Flammable Highly Flammable Very Toxic Toxic Harmful Corrosive Irritant Dangerous for the Environment

16 DSD/DPD vs CLP Label Elements Risk Phrases R11 Highly flammable R26 Very toxic by inhalation R34Causes burns Safety Phrases S7 Keep container tightly closed S24/25 Avoid contact with skin and eyes S36 Wear suitable protective clothing Hazard Statements H225 Highly flammable liquid and vapour H330 Fatal if inhaled H314 Causes severe skin burns and eye damage Precautionary Statements P233 Keep container tightly closed P262 Do not get in eyes, on skin or on clothing P280 Wear protective gloves/protective clothing/eye protection/face protection

17 Chemical Name and Product Identifier Name, Address and Tel. No of Supplier Pictograms Acetone EC No ABC Chemicals Main Street Anytown Tel.: Danger Highly flammable liquid and vapour. Causes serious eye irritation. May cause drowsiness or dizziness Keep away from heat/sparks/open flames/hot surfaces - No smoking. Avoid breathing vapours. Wear protective gloves/eye protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store in a wellventilated place. Keep container tightly closed. Repeated exposure may cause skin dryness and cracking 500 ml Signal Word Hazard and Precautionary Statements Nominal Quantity Supplementary Information

18 Single Packagings On single packagings, e.g. drums, IBCs labelled for both transport and CLP, suppliers may omit hazard pictograms if they duplicate the transport labels Check all labels on the package to make sure all hazards are identified

19 Combined label for single packaging Proper Shipping Name and UN No. Methanol UN1230 Transport Labels XYZ Chemicals High Street New Town Methanol X Danger Highly flammable liquid and vapour. Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. Causes damage to organs. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe mist/vapours/spray. Wear protective gloves/protective clothing/eye protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Store in a well-ventilated place. Keep container tightly closed. Chemical Name and Product Identifier Pictograms and Signal Word Hazard and Precautionary Statements

20 Safety Data Sheets Safety Data Sheets are required by REACH Format revised to align with GHS still 16 section format, but additional sub-headings introduced Classification and labelling information now in Section 2 For substances, and for mixtures which have already been labelled according to CLP, the classification and labelling of the product should be given for both the DSD/DPD and for CLP until 1 June Many other changes to SDS as a result of REACH

21 Safety Data Sheets Classification according to both DSD/DPD and CLP for substances and for mixtures already labelled to CLP until 1 June 2015 Label information including any pictograms Classification of component substances according to both DSD and CLP for mixtures until 1 June 2015

22 Why might the classification of a product change? The classification for some substances and mixtures may increase (or decrease) in severity under CLP because: The hazard data are still the same, but CLP classification criteria and methods result in a different classification New hazard information has been identified, e.g. through REACH and the substance or mixture is more/less hazardous than previously thought A mixture has been reformulated with different component substances that have different hazards

23 What to do now Look out for new labels and safety data sheets Make sure you understand and recognise the new label information Check that your use of the substance or mixture is covered in section 1 of the SDS and any Exposure Scenarios, and is not advised against Follow the advice provided on the new labels and in safety data sheets Check whether the classification has changed Evaluate the risks from your use of the substance or mixture and update workplace risk assessments if necessary If you are an employer, communicate these changes to your employees If you have any questions about the new label or safety data sheet, speak to your supervisor or the supplier

24 Further Reading Occupational Safety and Health and the CLP Regulation Guidance To Help Employers And Workers To Manage The Transition To The New System

25 Acknowledgements This publication is supported by the Community Programme for Employment and Social Solidarity - PROGRESS ( ). This programme is managed by the Directorate-General for Employment, social affairs and equal opportunities of the European Commission. It was established to financially support the implementation of the objectives of the European Union in the employment and social affairs area, as set out in the Social Agenda, and thereby contribute to the achievement of the Lisbon Strategy goals in these fields. The seven-year Programme targets all stakeholders who can help shape the development of appropriate and effective employment and social legislation and policies, across the EU-27, EFTA-EEA and EU candidate and pre-candidate countries. PROGRESS mission is to strengthen the EU contribution in support of Member States' commitment. PROGRESS will be instrumental in: providing analysis and policy advice on PROGRESS policy areas; monitoring and reporting on the implementation of EU legislation and policies in PROGRESS policy areas; promoting policy transfer, learning and support among Member States on EU objectives and priorities; and relaying the views of the stakeholders and society at large For more information see: Furthermore, the production of this document by the RPA Consortium (Risk and Policy Analysts Ltd, Denehurst Chemical Safety Ltd, Milieu, Gillies Associates and Imperial College) was funded by the European Commission as part of a Study Service Contract to provide on Analysis and Evaluation of the Health, Social, Economic and Environmental Impact of a Possible Amendment of Certain EC Directives on Health and Safety at Work as a Result of the Adoption of Regulation (EC) No 1272/2008 (Contract number: VC/2010/0446). Document completed December 2011 Reproduction is authorised provided the source is acknowledged.

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