Molecular motions of water: The effect of charged and hydrophobic solutes Tielrooij, K.J.

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1 UvA-DARE (Digital Academic Repository) Molecular motions of water: The effect of charged and hydrophobic solutes Tielrooij, K.J. Link to publication Citation for published version (APA): Tielrooij, K. J. (2010). Molecular motions of water: The effect of charged and hydrophobic solutes General rights It is not permitted to download or to forward/distribute the text or part of it without the consent of the author(s) and/or copyright holder(s), other than for strictly personal, individual use, unless the work is under an open content license (like Creative Commons). Disclaimer/Complaints regulations If you believe that digital publication of certain material infringes any of your rights or (privacy) interests, please let the Library know, stating your reasons. In case of a legitimate complaint, the Library will make the material inaccessible and/or remove it from the website. Please Ask the Library: or a letter to: Library of the University of Amsterdam, Secretariat, Singel 425, 1012 WP Amsterdam, The Netherlands. You will be contacted as soon as possible. UvA-DARE is a service provided by the library of the University of Amsterdam ( Download date: 22 Jan 2017

2 Molecular Motions of Water The effect of charged and hydrophobic solutes

3 ISBN c 2010, Klaas-Jan Tielrooij All rights reserved. No part of this publication may be reproduced, stored in a retrieval system or transmitted in any form or by any means, electronic, mechanical, photocopying, recording, scanning or otherwise, without the permission in writing of the author. Cover design by Eva Janssens & Klaas-Jan Tielrooij. Front image: studies of water flow by Leonardo da Vinci,

4 Molecular Motions of Water The effect of charged and hydrophobic solutes ACADEMISCH PROEFSCHRIFT ter verkrijging van de graad van doctor aan de Universiteit van Amsterdam op gezag van de Rector Magnificus prof. dr. D. C. van den Boom ten overstaan van een door het college voor promoties ingestelde commissie, in het openbaar te verdedigen in de Agnietenkapel op woensdag 15 december 2010, te 14:00 uur door Klaas-Jan Tielrooij geboren te Eindhoven

5 Promotiecommissie promotor: copromotor: overige leden: prof. dr. H.J. Bakker prof. dr. M. Bonn prof. dr. P.G. Bolhuis prof. dr. D. Bonn prof. dr. D. Frenkel prof. dr. N. Agmon prof. dr. L. Kuipers dr. M.S. Pshenichnikov Faculteit der Natuurwetenschappen, Wiskunde en Informatica The work described in this thesis was performed at the FOM-Institute for Atomic and Molecular Physics (AMOLF), Science Park 104, 1098 XG Amsterdam, The Netherlands. This work is part of the research programme of the Stichting Fundamenteel Onderzoek der Materie (FOM), which is financially supported by the Nederlandse Organisatie voor Wetenschappelijk Onderzoek (NWO).

6 VOOR MIJN OUDERS Spetter, pieter, pater Lekker in het water Ga maar vast naar huis Ik kom een druppel later (Herman van Veen)

7 This thesis is based on the following publications: K.J. Tielrooij, M.J. Cox and H.J. Bakker: Effect of confinement on proton-transfer reactions in water nanopools. Chem. Phys. Chem., 10: (2009). Chapter 8 K.J. Tielrooij, C. Petersen, Y.L.A. Rezus and H.J. Bakker: Reorientation of HDO in liquid H 2 O at different temperatures: Comparison of first and second order correlation functions. Chem. Phys. Lett., 471:71-74 (2009). Chapter 5 K.J. Tielrooij, R.L.A. Timmer, H.J. Bakker and M. Bonn: Structure dynamics of the proton in liquid water probed with terahertz time-domain spectroscopy. Phys. Rev. Lett., 102: (2009). Chapter 7 K.J. Tielrooij, D. Paparo, L. Piatkowski, H.J. Bakker and M. Bonn: Dielectric relaxation dynamics of water in model membranes probed by terahertz spectroscopy. Biophys. J., 97: (2009). Chapter 10 K.J. Tielrooij, N. Garcia-Araez, M. Bonn and H.J. Bakker: Cooperativity in ion hydration. Science, 328: (2010). Chapter 6 K.J. Tielrooij, J. Hunger, R. Buchner M. Bonn and H.J. Bakker: Influence of concentration and temperature on the dynamics of water in the hydrophobic hydration shell of tetramethylurea. J. Am. Chem. Soc., 132: (2010). Chapter 9 K.J. Tielrooij, M. Bonn and H.J. Bakker: Water reorientation dynamics around ions studied with terahertz dielectric relaxation and femtosecond pump-probe spectroscopy. To be submitted. Chapter 6 Other publications by the same author: F.H.L. Koppens, C. Buizert, K.J. Tielrooij, I.T. Vink, K.C. Nowack, T. Meunier, L.P. Kouwenhoven and L.M.K. Vandersypen: Driven coherent oscillations of a single electron spin in a quantum dot. Nature, 442: (2006). T. Meunier, K.-J. Tielrooij, I.T. Vink, F.H.L. Koppens, H.P. Tranitz, W. Wegscheider, L.P. Kouwenhoven and L.M.K. Vandersypen: High fidelity measurement of singlet-triplet state in a QD. Phys. Stat. Sol. (b), 243: (2006). T. Meunier, I.V. Vink, L.H. Willems van Beveren, K-J. Tielrooij, R. Hanson, F.H.L. Koppens, H.P. Tranitz, W. Wegscheider, L.P. Kouwenhoven and L.M.K. Vandersypen: Experimental signature of phonon-mediated spin relaxation. Phys. Rev. Lett., 98: (2007). D. Paparo, K.J. Tielrooij, H. Bakker and M. Bonn: Terahertz dielectric relaxation of biological water confined in model membranes made of lyotropic phospholipids. Mol. Cryst. Liq. Cryst., 500: (2009). C. Petersen, K.-J. Tielrooij, and H.J. Bakker: Strong temperature dependence of water reorientation in hydrophobic hydration shells. J. Chem. Phys., 130: (2009). J.J.H. Pijpers, R. Ulbricht, K.J. Tielrooij, A. Osherov, Y. Golan, C. Delerue, G. Allan and M. Bonn: Assesment of carrier-multiplication efficiency in bulk PbSe and PbS. Nature Phys., 5: (2009). R.L.A. Timmer, K.J. Tielrooij and H.J. Bakker: Vibrational Förster energy transfer between water and hydrated protons. J. Chem. Phys., 132: (2010).