Global Harmonized System (GHS)
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1 Global Harmonized System (GHS)
2 What is GHS? The United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS) is: An international system for harmonizing classifying and labeling of hazardous chemicals Approach for: Defining health, physical, & environmental hazards Applying hazard criteria to classify chemicals based on hazardous effects Communicating hazard information thru labels & safety data sheets
3 Why is GHS needed? No country has the ability to identify and specifically regulate every hazardous chemical product. In the United States alone, 945,000 chemical products. Adoption of GHS addresses safety, health, and environmental issues universally.
4 How was GHS developed? International mandate was adopted in the 1992 United Nations Conference: A globally harmonized hazard classification and compatible labeling system, including material safety data sheets and easily understandable symbols, should be available, if feasible, by the year 2000.
5 Who is responsible for implementing GHS? GHS is considered to be is a non-mandatory recommendation. The GHS provisions are only mandatory in countries or regions that adopt the GHS. There is no international body that monitors implementation for compliance.
6 Why does the US need it? The US has regulatory requirements that address concerns in different sectors (EPA, DOT, OSHA, etc.) Agencies were not domestically harmonized Each has pursued independent regulations differing from one another Domestic producers have to classify and label multiple times for the same product
7 Inconsistency of Information OSHA / NFPA DOT / EPA Flammable = F Combustible = F Flammable = F Combustible = F GHS Flammable = F Combustible = F
8 US Agencies Affected by GHS EPA Pesticides Program DOT Hazardous Materials Regulations CPSC OSHA
9 Global Harmonized System (GHS) and Hazard Communication Standard (HCS)
10 How We Got Here Commitment in HazCom preamble UN mandate adopted First Edition of GHS in 2003 OSHA published an ANPR GHS System as it is now 2010 (4th Edition). Final Revised HazCom Standard became effective May 25, 2012
11 GHS & HCS OSHA adopted the provisions in GHS in its Final Rule Effective May 25, 2012 Made GHS mandatory Phased in compliance Many of the original standards provisions remain intact Compliance not all that different from Employer standpoint Changes mostly affect Importers, Mfg., etc.
12 GHS & OSHA Hazard Communication HazCom = Right to Know an update of the "Right to Know & Understand" Four most significant changes will impact: hazard classification (criteria based definitions), labeling, safety data sheets (16 required sections in particular order) and training
13 HCS Written Program Requirements to have a written program remain unchanged Framework for a written program are unchanged Labeling & other forms of warning Safety Data Sheets Employee information & training Chemical information list
14 HCS Hazard Classification No requirement to test chemical to determine hazard or category class May rely on scientific data already established. Appendix A consulted for health hazards (27 pgs) Appendix B consulted for physical hazards (9 pgs) Hazard Classification guidelines were non-existent previously.
15 What are the classes within the Health hazard group? Acute Toxicity Skin Corrosion/Irritation Serious eye damage/eye irritation Respiratory or Skin Sensitization Germ Cell Mutagenicity Carcinogenicity Reproductive Toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Specific classification rules for chemical mixtures for health hazard class.
16 Mixture Provisions Mixture approach for providing data remains unchanged Based on either test data for the mixture as a whole, or a one percent cut-off approach Greatly changes in the classification requirements of chemical mixtures
17 Carcinogens Information remains unchanged from previous standard 0.1 percent for known or suspected carcinogen National Toxicology Program report list International Agency for Research on Cancer (IARC) list
18 Acute Toxicity Hazard Categories
19 Skin Hazard Categories
20 Eye Hazard Categories
21 Mutagen Categories
22 Cancer Causing Chemical Categories
23 What are the classes within the Physical Hazard group? Explosives Pyrophoric solids Flammable gases Self-heating substances and mixtures Aerosols Substances & mixtures in contact w/ water, emit flammable gases Oxidizing gases Gases under pressure Oxidizing liquids Flammable liquids Oxidizing solids Flammable solids Organic peroxides Self-reactive substances & mixtures Corrosive to metals Pyrophoric liquids
24 Physical Hazard Category
25 HCS Labeling Getting Harmonized Product identifier Signal word Hazard statements Pictogram(s) Precautionary statements Chemical Mfg info: Name Address Telephone number
26 Signal Word Hazard Statement Pictogram
27 GHS & HCS Pictograms Health Hazard Carcinogen Mutagenicity Reproductive Toxicity Respiratory Sensitizer Target Organ Toxicity Aspiration Toxicity Flame Flammables Pyrophorics Self-Heating Emits Flammable Gas Self-Reactives Organic Peroxides Exclamation Mark Irritant (skin and eye) Skin Sensitizer Acute Toxicity Narcotic Effects Respiratory Tract Irritant Hazardous to Ozone Layer (Non-Mandatory)
28 GHS & HCS Pictograms (cont.) Gas Cylinder Gases Under Pressure Corrosion Skin Corrosion/Burns Eye Damage Corrosive to Metals Exploding Bomb Explosives Self-Reactives Organic Peroxides
29 GHS & HCS Pictograms (cont.) Flame Over Circle Oxidizers Environment (Non-Mandatory) Aquatic Toxicity Skull and Crossbones Acute Toxicity (fatal or toxic)
30
31 HCS Secondary Container Labeling Same requirements as previous: All primary containers must be labeled Can not deface original labels Stationary Process Containers must be labeled Alternatives to providing identical info as original product label Method must be able to convey the same information as that of the original label. All secondary container must be labeled with same info. as original product label UNLESS immediate use by employee who transferred from labeled container Used to be same shift
32 Safety Data Sheets No longer Material Safety Sheets Unchanged Requirements Requirements for importer, mfg. to provide to end users (1st shipment, changes, etc.) Requirements to make available to employee Changes Required to provide sections in specific order. 16 required sections OSHA recommended format OSHA recommended minimum information to be included No particular order Provide data in accordance with hazard classification section of the standard
33 Training All employees must receive effective training on hazardous chemicals: At time of initial assignment New chemical hazard introduced Training covers: Location and availability of written HCP Labels SDS availability and how to read Operations where hazardous chemicals are present Methods to detect release of hazardous chemical Methods to protect employee from hazards (PPE, ventilation, etc.)
34 Compliance Deadlines December 1, 2013 June 1st, 2015 Employees must be trained on the new label and SDS formats. Re-author current MSDSs into the GHScompliant SDS format. June 1st, 2016 All written programs, training programs and alternative labeling must be compliant with the new HazCom Standard.
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